CN106544132A - 一种哈氏b系列合金强力旋压加工工艺润滑剂组合物 - Google Patents

一种哈氏b系列合金强力旋压加工工艺润滑剂组合物 Download PDF

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CN106544132A
CN106544132A CN201610966095.1A CN201610966095A CN106544132A CN 106544132 A CN106544132 A CN 106544132A CN 201610966095 A CN201610966095 A CN 201610966095A CN 106544132 A CN106544132 A CN 106544132A
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kazakhstan
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黄福川
唐弓斌
肖锋
张姗姗
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Guangxi University
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Abstract

本发明公开了一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，采用质量比50％的HVI120BS基础油与50％的酯类油Radia7543复合为复合基础油，配合多种复合添加剂。包括：抗氧剂、金属减活剂、油性剂、摩擦改进剂、极压剂、抗磨剂、防锈剂、抗氧抗腐剂、增粘剂、抗泡剂、填充剂等。本发明的组合本发明的组合物具有良好的冷却性、润滑性、极压抗磨承载性、扩散性、清洗性、防锈性、抗氧防腐性、抗氧化安定性、抗剪切安定性、粘附性，减少表面擦伤和划痕，延长模具使用寿命。

Description

一种哈氏B系列合金强力旋压加工工艺润滑剂组合物
技术领域
本发明一种哈氏B系列合金强力旋压加工工艺润滑剂组合物属于金属加工润滑剂领域。
背景技术
哈氏合金(Hastelloyalloy)主要分为B、C、G三个系列，它主要用于铁基Cr-Ni或Cr-Ni-Mo不锈钢、非金属材料等无法使用的强腐蚀性介质场合。每个牌号都有具体的化学成分，机械性能，各有所长，不能一概而论说哈氏合金有什么特性。哈氏合金板适用于各种含有氧化和还原性介质的化学工业。
哈氏B系列主要是B-2(00N：70MO28)。化学成分N≤1.0，Cr:26.0～30，MO≤2.0，Fe≤0.02，C≤0.10，Si≤1.0，CO≤1.0，Mn≤0.04，P≤0，S≤0.3.
旋压技术起源于古代制陶工艺。是一种综合了锻造、挤压、拉件、弯曲、环轧、横轧和滚挤等工艺特点的少无切削加工的先进工艺。通常将金属简坯、平板毛坯或预制坯用尾顶顶紧在旋压机模上，由主轴带动芯棒和坯料旋转；同时旋压轮从毛坯一侧将材料挤压在旋转的芯模上，使材料产生逐点连续的塑性变形，从而获得各种母线形状的空心旋转体零件。根据旋压加工过程中的毛坯厚度变化情况，把旋压工艺分为普通旋压和强力旋压两种，即普通旋压和强力旋压。
普通旋压简称普旋。普旋过程中毛坯的厚度基本保持不变，成形主要依靠坯料沿圆周的收缩及沿半径方向上伴长不变形来实现。其主要特征是在成形过程中，可以明显看出坯料外径的变化。普通旋压的基本方式有：拉深旋压(拉旋)、缩径旋压(缩旋)和扩径旋压(扩旋)等三种。
强力旋压又称变薄旋压，强力旋压是在普通旋压基础上发展起来的一种近无余量加工方法,其实质为利用旋压辊子加高压于坯料,旋转坯料借助外力沿成形模具进行局部逐渐辗压产生塑性变形而变薄,从而得到高精度薄壁回转体零件。
旋压时采用尾顶或别的方式将毛坯固定于模具，模具旋转，旋轮作进给运动，使毛坯连续地逐点变薄并贴靠模具而形成所需要形状的零件，强力旋压主要依靠坯料厚度的减薄来实现工件的成形。
发明内容
本发明要解决的技术问题是提供一种稳定性、润滑性、抗腐蚀性能好，热氧化安定性优良的哈氏B系列合金强力旋压加工工艺润滑剂组合物。
本发明通过如下技术方案解决上述技术问题：
一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，采用质量比50％的HVI120BS基础油与50％的酯类油Radia7543复合为复合基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 余量
抗氧剂 0.05％～0.3％
金属减活剂 0.05％～0.2％
油性剂 4％～8％
摩擦改进剂 1％～2％
极压剂 5％～8％
抗磨剂 5％～8％
防锈剂 0.05％～0.3％
抗氧抗腐剂 0.8％～1.5％
增粘剂 2％～6％
抗泡剂 10ppm～50ppm
填充剂 2％～4％
以上各组分的质量百分比总和是100％。
抗氧剂是质量比50％的硫化烷基酚T504与50％的N,N’-二亚水杨酸丙二胺复合。
金属减活剂剂是苯三唑衍生物T551。油性剂是硫化猪油。
摩擦改进剂是硫磷酸钼T461A。
极压剂是氯化石蜡T302。抗磨剂是硫化异丁烯T321。
防锈剂是质量比50％的苯并三氮唑T706与50％的十七烯基咪唑啉烯基丁二酸盐T703复合。抗氧抗腐剂是硫磷双辛基碱性锌盐T203。增粘剂是聚异丁烯T603D。
抗泡剂是甲基硅油。填充剂是液体石蜡。
本发明的显著优点：本发明的组合物具有良好的冷却性、润滑性、极压抗磨承载性、扩散性、清洗性、防锈性、抗氧防腐性、抗氧化安定性、抗剪切安定性、粘附性，减少表面擦伤和划痕，延长模具使用寿命。
具体实施方式
实施例1：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例2：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例3：
将以下各组分按下列质量百分比调和而成：
以上各组分质量百分比含量总和为100％。
实施例1产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 335.9
粘度指数 149
闪点(开口)/℃ 274
凝点/℃ -34
摩擦系数 0.040
腐蚀性(铜片，100℃，3h)/级 1
氧化安定性(旋转氧弹，150℃)/min 349
抗乳化性(84℃，40-40-0)/min 15
四球机试验/Pb/N 955
烧结负荷/PD/N 7190
梯姆肯/N 308
FZG/级 14
蒸发损失(Noack法，250℃，1h)(m)，％ 6.4
机械杂质，％ 0.004
水分，％ 痕迹
实施例2产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 338.1
粘度指数 146
闪点(开口)/℃ 279
凝点/℃ -32
摩擦系数 0.042
腐蚀性(铜片，100℃，3h)/级 1
氧化安定性(旋转氧弹，150℃)/min 361
抗乳化性(84℃，40-40-0)/min 17
四球机试验/Pb/N 966
烧结负荷/PD/N 7350
梯姆肯/N 312
FZG/级 14
蒸发损失(Noack法，250℃，1h)(m)，％ 6.1
机械杂质，％ 0.005
水分，％ 痕迹
实施例3产品的典型理化技术指标：
项目 质量指标
运动粘度(40℃)/mm2/s-1 336.7
粘度指数 141
闪点(开口)/℃ 271
凝点/℃ -33
摩擦系数 0.041
腐蚀性(铜片，100℃，3h)/级 1
氧化安定性(旋转氧弹，150℃)/min 364
抗乳化性(84℃，40-40-0)/min 16
四球机试验/Pb/N 961
烧结负荷/PD/N 7290
梯姆肯/N 307
FZG/级 14
蒸发损失(Noack法，250℃，1h)(m)，％ 6.3
机械杂质，％ 0.002
水分，％ 痕迹

Claims (10)

1.一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于：采用质量比50％的HVI120BS基础油与50％的酯类油Radia7543复合为复合基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 余量 抗氧剂 0.05％～0.3％ 金属减活剂 0.05％～0.2％ 油性剂 4％～8％ 摩擦改进剂 1％～2％ 极压剂 5％～8％ 抗磨剂 5％～8％ 防锈剂 0.05％～0.3％ 抗氧抗腐剂 0.8％～1.5％ 增粘剂 2％～6％ 抗泡剂 10ppm～50ppm 填充剂 2％～4％
以上各组分的质量百分比总和是100％。
2.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于抗氧剂是质量比50％的硫化烷基酚T504与50％的N,N’-二亚水杨酸丙二胺复合。
3.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于金属减活剂剂是苯三唑衍生物T551。
4.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于油性剂是硫化猪油。
5.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于摩擦改进剂是硫磷酸钼T461A；极压剂是氯化石蜡T302。
6.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于抗磨剂是硫化异丁烯T321。
7.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于防锈剂是质量比50％的苯并三氮唑T706与50％的十七烯基咪唑啉烯基丁二酸盐T703复合。
8.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于抗氧抗腐剂是硫磷双辛基碱性锌盐T203。
9.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于增粘剂是聚异丁烯T603D；抗泡剂是甲基硅油。
10.如权利要求1所述的一种哈氏B系列合金强力旋压加工工艺润滑剂组合物，其特征在于填充剂是液体石蜡。
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