CN106538586A - A kind of Synergistic insecticidal compositions containing double third ring worm esters - Google Patents
A kind of Synergistic insecticidal compositions containing double third ring worm esters Download PDFInfo
- Publication number
- CN106538586A CN106538586A CN201610892568.8A CN201610892568A CN106538586A CN 106538586 A CN106538586 A CN 106538586A CN 201610892568 A CN201610892568 A CN 201610892568A CN 106538586 A CN106538586 A CN 106538586A
- Authority
- CN
- China
- Prior art keywords
- ring worm
- matrine
- double
- worm esters
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 208000002474 Tinea Diseases 0.000 title claims abstract description 77
- 241000893966 Trichophyton verrucosum Species 0.000 title claims abstract description 77
- 150000002148 esters Chemical class 0.000 title claims abstract description 70
- 239000000203 mixture Substances 0.000 title claims abstract description 49
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 18
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 9
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229930014456 matrine Natural products 0.000 claims abstract description 68
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 claims abstract description 53
- 239000000375 suspending agent Substances 0.000 claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 16
- 241001498622 Cixius wagneri Species 0.000 claims abstract description 13
- 239000004480 active ingredient Substances 0.000 claims abstract description 13
- 240000007594 Oryza sativa Species 0.000 claims abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 10
- 241001414989 Thysanoptera Species 0.000 claims abstract description 10
- 235000009566 rice Nutrition 0.000 claims abstract description 10
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 8
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 8
- 239000003094 microcapsule Substances 0.000 claims abstract description 8
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- 239000000725 suspension Substances 0.000 claims abstract description 6
- 239000004563 wettable powder Substances 0.000 claims abstract description 5
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 244000269722 Thea sinensis Species 0.000 claims abstract 2
- 238000009472 formulation Methods 0.000 claims description 16
- 230000000361 pesticidal effect Effects 0.000 claims description 11
- 241000931705 Cicada Species 0.000 claims 1
- 241000238631 Hexapoda Species 0.000 abstract description 27
- 239000003795 chemical substances by application Substances 0.000 abstract description 24
- 241001414720 Cicadellidae Species 0.000 abstract description 19
- 239000000575 pesticide Substances 0.000 abstract description 16
- 239000002917 insecticide Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 38
- 239000003814 drug Substances 0.000 description 29
- -1 matrine compound Chemical class 0.000 description 21
- 238000000034 method Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 241001122767 Theaceae Species 0.000 description 17
- 230000000694 effects Effects 0.000 description 15
- 231100000419 toxicity Toxicity 0.000 description 15
- 230000001988 toxicity Effects 0.000 description 15
- 241000927584 Frankliniella occidentalis Species 0.000 description 12
- 230000002265 prevention Effects 0.000 description 11
- 238000007796 conventional method Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 240000008067 Cucumis sativus Species 0.000 description 7
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 5
- 240000003553 Leptospermum scoparium Species 0.000 description 5
- 235000015459 Lycium barbarum Nutrition 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 238000003556 assay Methods 0.000 description 5
- 210000000481 breast Anatomy 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 4
- 206010011732 Cyst Diseases 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 241001556089 Nilaparvata lugens Species 0.000 description 4
- 239000005934 Sulfoxaflor Substances 0.000 description 4
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 208000031513 cyst Diseases 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000007619 statistical method Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 241001674939 Caulanthus Species 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000995023 Empoasca Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- 239000005903 Gamma-cyhalothrin Substances 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004117 Lignosulphonate Substances 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 244000131316 Panax pseudoginseng Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- LRZWFURXIMFONG-HRSIRGMGSA-N afidopyropen Chemical compound C([C@@]1(C)[C@H]2[C@]([C@H]3[C@@H](O)C=4C(=O)OC(=CC=4O[C@]3(C)[C@@H](O)C2)C=2C=NC=CC=2)(C)CC[C@@H]1OC(=O)C1CC1)OC(=O)C1CC1 LRZWFURXIMFONG-HRSIRGMGSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Synergistic insecticidal compositions containing double third ring worm esters, its active ingredient is double third ring worm esters and matrine, and both mass ratioes are 50:1～1:10, in composition, the gross mass percentage composition of active ingredient is 3%～65%.This composition can be configured to suspending agent, suspension emulsion, microemulsion, aqueous emulsion, wettable powder, water dispersible granules or the microcapsule suspending agent for agriculturally allowing.Instant component is reasonable, it is preferable to the pierce-suck types such as the plant hopper on paddy rice, tealeaves and vegetable crop, tea lesser leafhopper and thrips and rasping-sucking mouthparts insect, compared with existing unitary agent, with significant insecticidal effect, and have significant synergistic effect, Pesticide use amount is reduced, so as to reducing cost and reducing the pollution to environment, be conducive to the improvement of pest resistance to insecticide, its popularization and application has larger economic and social benefit.
Description
Technical field
The present invention relates to a kind of Synergistic insecticidal compositions, especially a kind of Synergistic insecticidal compositions containing double third ring worm esters
And its preventing and treating crops on mini pest application, belong to technical field of compounded pesticide.
Background technology
The common mini pest such as plant hopper, tea lesser leafhopper and thrips has that host range is wide, breeding soon, year generation it is many
And the features such as the easy generation resistance to agricultural chemicals, greater loss is caused to agricultural production, at present the chlorine of conventional pesticide control such as chrysanthemum esters
Cyano chrysanthemate and gamma cyhalothrin, the imidacloprid of anabasine, Diacloden, Acetamiprid etc. produce more resistance.Therefore city
It is badly in need of a kind of medicament of the mini pests such as preventing and treating plant hopper, tea lesser leafhopper and the thrips of high-efficiency low-toxicity on field.
Double third ring worm esters, english common name：Afidopyropen, is botanical pesticide, and its structure is novel and has complete
New mechanism of action, can be used for preventing and treating paddy rice, fruit tree, vegetables, mini pest such as scale insect on imtertilled crop and ornamental plant,
Thrips, leafhopper, aleyrodid and wood louse etc., either foliar treatment, Seed Treatment or soil treatment have good result, and toxicity
It is very low.
Matrine, English common name matrine are natural source pesticide, with stomach toxicity and action of contace poison, directly act on worm
Multiple action targets of body, benumb nerve center, make then polypide protein coagulating, block pore, death by suffocation；Can destroy
The resistance to the action of a drug system of insect, with other agricultural chemicals no interactions resistances.It is by the dry root of legume kuh-seng, plant, fruit Jing
Made by the Solvent Extract methods such as ethanol, can degrade in nature.General free from environmental pollution and agricultural product are relative to people and livestock
Safety, injures little to pest natural enemy, and insect is difficult to produce antibody to which, the characteristics of with low toxicity, low-residual, can adhere to agriculture
The high-quality of product, wide market.Matrine is to vegetables lepidoptera pest Euproctis pseudoconspersa, diamondback moth, sucking mouth parts and file
Suction mouthpart insect aphid, plant hopper, thrips and tea lesser leafhopper etc. all have preferable preventive effect.
So far, double third ring worm esters and matrine are compounded there is not yet any report.
The content of the invention
It is an object of the invention to：A kind of Synergistic insecticidal compositions for being adapted to and agriculturally using are provided, and contribute to subtracting
Lack dosage, delay insect to produce resistance and reduce use cost.
To overcome the deficiencies in the prior art, inventor to test by a large amount of indoor bioassay, double third ring worms are had been surprisingly found that
After ester and matrine are with certain proportion compounding, plant hopper, tea lesser leafhopper and thrips are had significant synergies.
The technical scheme is that：A kind of Synergistic insecticidal compositions containing double third ring worm esters, it is characterised in that：Contain
The double third ring worm esters of active ingredient and matrine, both mass ratioes are 50:1～1:10, preferred mass ratio is 10:1～1:1.
In the Pesticidal combination of the present invention, the gross mass percentage composition of active ingredient is 3%～65%, remaining be auxiliary agent,
Filler is beneficial to the active ingredient known substance that stable and drug effect is played in storage and use with other.
The composition pesticide of the present invention can adopt known method to be prepared into any one agent for being adapted to agriculturally use
Type, reasonable formulation have suspending agent, suspension emulsion, microemulsion, aqueous emulsion, wettable powder, water dispersible granules or microcapsule suspension
Agent.
Also containing the usual auxiliaries prepared needed for pesticidal preparations, usual auxiliaries are dispersant, breast to described composition pesticide
The mixing of one or more in agent, wetting agent, stabilizer, thickener, defoamer, antifreezing agent, packing agent etc., is agricultural chemicals system
The various auxiliary agents commonly used in agent, are not specially limited, can be varied from according to different situations.
Described composition pesticide, for preventing and treating the insect on crops, composition pesticide described in the invention can be with
Finished product preparation form is provided, i.e., exist as a mixture, the composition of composition can also unit dose form provide, using it is front directly
Mix in bucket or tank in proportion, be then diluted to desired concn.
Compared with prior art, what the present invention was produced has the beneficial effect that：(1) composition synergistic effect substantially, preventive effect and list
Agent is compared and is significantly improved；(2), after drug effect is improved, field dosage and use cost is reduced, residues of pesticides and environment is reduced
Pollution；(3) composition is made up of the active ingredient of different mechanism of action, and action site increases, and is conducive to overcoming and delays insect
Produce resistance.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.
The pesticide active ingredient of different types of structure is compounded, is to solve cost during agricultural chemicals single dose use at present
And effective measures the problems such as resistance.After the pesticide active ingredient mixing of different types of structure, three kinds of works are typically exhibited
With type, i.e. summation action, synergistic effect and antagonism.But which kind of effect be specially, it is impossible to predict, can only be by a large amount of examinations
Test and reach a conclusion.Compound synergic is preferably filled a prescription, and can improve actual prevention effect, reduces Pesticide use dosage, contributes to delaying
The generation of resistance, is one of important means of resistance management.
The present composition has an obvious synergistic effect to plant hopper, tea lesser leafhopper and thrips etc., and not exclusively two
The simple addition of pharmacy effect is planted, this can be clear that from the result of following Toxicity Determination test.
Assays Example 1：The indoor joint toxicity measuring test of double third ring worm esters and matrine compound to planthopper
Subjects：Brown paddy plant hopper Nilaparvata lugens (Stdl), indoors artificial raise many generations.
Test method：Test method reference《People's Republic of China (PRC) agricultural industry criteria NY/T1154.11-2008》, adopt
Method is soaked with rice stem.The rice strain of the late tillering state of stalwartness is extracted with root, is cleaned, is cut into the band root rice stem of 15cm length, 4 plants one group, in
Shady place is dried in the air to surface without washmarking.By rice stem respectively in the medicament for having diluted soak 30 seconds, taking-up dry after, with the degreasing soaked
Cotton is embraced root and is put in culture dish, draws 3 age mid-term nymphs and is put in culture dish, 25 per glass, if leaching clear water is blank right
According to each concentration is repeated 4 times.It is 16h to process 27 DEG C of rearmounted temperature, photoperiod:8h(L:D raise in culture dish).Examine after 7 days
Look into death toll.
The total borer population * of the death rate (%)=dead borer population/process 100
Corrected mortality (%)=(the treatment group death rate-control group death rate)/(the 1- control group death rates) * 100
Statistical analysis is carried out with DPS9.50 statistical analysis softwares, by each process variable concentrations gradient calibration death rate meter
Calculate the LC of each medicament50, then co-toxicity coefficient (CTC) is calculated according to the abundant methods of Sun Yun.
When CTC≤80, then composition shows as antagonism, and as 80 ＜ CTC ＜ 120, then composition shows as being added and makees
With when CTC≤120, then composition shows as synergistic effect.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B the medicament toxicity index of A in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.Poison
Power measurement result is shown in Table 1.
The indoor joint toxicity measuring test result of table 1, double third ring worm esters and matrine compound to brown paddy plant hopper
The proportioning of double third ring worm esters and matrine be can be seen that 50 from result of the test in table 1:1～1:It is when between 10, right
The co-toxicity coefficient of brown paddy plant hopper more than 120, with synergistic effect, particularly proportioning 10:1～1:When between 1, synergistic effect
Most substantially, its co-toxicity coefficient is more than 230.
Assays Example 2：The indoor joint toxicity measuring test of double third ring worm esters and matrine compound to thrips
Subjects：Frankliniella occidentalis (Frankliniella occidentalis), cucumber seedling artificial feeding in incubator
Seven generations.
Test method：Test reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1154.14-2008》Using leaching
Leaf method is measured.Preprepared cabbage leaf (3 ㎝ × 4 ㎝) is soaked 10 seconds in liquid, nature is taken out and is dried
To surface without washmarking, chosen into Frankliniella occidentalis 3 age nymph with writing brush, test worm is moved to (25 ± 1) DEG C, 14/10 (L/D), with respect to wet
Normally cultivate in the greenhouse of degree 70%.3 repetitions are processed often, often repeatedly 30 test worms.
With Assays Example 1, toxicity test the results are shown in Table 2 to statistical analysis technique.
The indoor joint toxicity measuring result of table 2, double third ring worm esters and matrine compound to Frankliniella occidentalis
The proportioning of double third ring worm esters and matrine be can be seen that 50 from result of the test in table 2:1～1:It is when between 10, right
The co-toxicity coefficient of Frankliniella occidentalis more than 120, with synergistic effect, particularly proportioning 10:1～1:When between 1, synergy is made
With most substantially, its co-toxicity coefficient is more than 230.
Assays Example 3：The indoor joint toxicity measuring of double third ring worm esters and matrine compound to tea lesser leafhopper
Test
Subjects：Tea lesser leafhopper Empoasca pirisuga (Matumura), indoor wild cabbage raised for eight generations.
Test method：Test reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1154.14-2008》Using leaching
Leaf method is measured.Preprepared wild cabbage leaf (3 ㎝ × 4 ㎝) is soaked 10 seconds in liquid, nature is taken out and is dried
To surface without washmarking, age consistent tea lesser leafhopper adult is chosen with writing brush and is put in insect box, be transferred to (25 ± 1) DEG C,
14/10 (L/D), normally cultivates in the greenhouse of relative humidity 70%.3 repetitions are processed often, often repeatedly 50 test worms.Examine in 72h
Dead borer population is looked into, the death rate and corrected mortality is calculated.If the control death rate is more than 10%, it is considered as invalid test.
With Assays Example 1, toxicity test the results are shown in Table 3 to statistical analysis technique.
The indoor joint toxicity measuring result of table 3, double third ring worm esters and matrine compound to tea lesser leafhopper
The proportioning of double third ring worm esters and matrine be can be seen that 50 from result of the test in table 3:1～1:It is when between 10, right
The co-toxicity coefficient of tea lesser leafhopper more than 120, with synergistic effect, particularly proportioning 10:1～1:When between 1, synergy
Most substantially, its co-toxicity coefficient is more than 220 for effect.
Pesticidal combination of the present invention can with known method be prepared into be adapted to agriculturally use suspending agent, suspension emulsion,
Microemulsion, water dispersible granules, wettable powder, aqueous emulsion or microcapsule suspending agent.Described below is only that the present invention is preferably implemented
Example, only to explain the present invention, therefore can not be interpreted as the restriction to the scope of the claims of the present invention.
Example of formulations 1：51% pair of the third ring worm ester matrine water dispersible granule
Double third ring worm esters 50%, matrine 1%, Negel 6%, calcium dodecyl benzene sulfonate 10%, alkyl sulfide
Sour calcium 5%, sodium carboxymethylcellulose 4%, diatomite supplies 100%.Mentioned component is processed according to a conventional method and be can be prepared by
51% pair of the third ring worm ester 〃 matrine water dispersible granule.
Example of formulations 2：62% pair of the third ring worm ester aqueous matrine solution
Double third ring worm esters 60%, matrine 2%, alkyl naphthalene formaldehyde condensation product sodium sulfonate 4%, alkylsurfuric acid calcium 6%, hard charcoal
It is black to supply 100%.Mentioned component is processed according to a conventional method and can be prepared by 62% pair of the third ring worm ester 〃 aqueous matrine solution.
Example of formulations 3：22% pair of the third ring worm ester microemulsion containing matrine agent
Double third ring worm esters 20%, matrine 2%, 1-METHYLPYRROLIDONE 8%, Nongru-700 #4%, sodium alkyl sulfonate
10%th, Negel 5%, organosilicon 3%, thiophene ketone 4%, deionized water supplies 100%.By mentioned component according to a conventional method
Processing can be prepared by 22% double third ring worm ester 〃 microemulsion containing matrine agent.
Example of formulations 4：18% pair of the third ring worm ester matrine water emulsion
Double third ring worm esters 16%, matrine 2%, 1-METHYLPYRROLIDONE 5%, agriculture breast 800#4%, Tween-60 #3%, agriculture
Newborn 2201#4%, epoxychloropropane 6%, Sodium Benzoate 3%, polyethylene glycol 3%, deionized water supplies 100%.By mentioned component
Processing according to a conventional method can be prepared by 18% double third ring worm ester 〃 matrine water emulsions.
Example of formulations 5：21% pair of the third ring worm ester matrine microcapsule suspension agent
Double third ring worm esters 18%, matrine 3%, macromolecule cyst material polymer MDI3%, solvent linseed oil 5% and S-
150 solvent naphthas 10%, emulsifying agent triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 4.5%, dispersant lignin
Sodium sulfonate 6%.By above-mentioned active ingredient, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, emulsifying agent, dispersion
Agent is soluble in water to be prepared into homogeneous aqueous phase, in a shear condition, oil phase is added in aqueous phase solution, emulsion is prepared into, under stirring
10% ethylenediamine solution 4% is added, 65 DEG C of insulation reactions 4.0h are warming up to, bi-material reacts in oil-water interfaces, shape
Into high score ascus wall, you can 21% pair of the third ring worm ester 〃 matrine microcapsule suspension agent is obtained.
Example of formulations 6：10% pair of the third ring worm ester matrine suspending agent
Double third ring worm esters 8%, matrine 2%, alkyl polyoxyethylene ether sodium sulfonate 4%, phenethyl phenol polyoxyethylene ether
Phosphate 5%, carboxymethylcellulose calcium 4%, polyethylene glycol 4%, silicone oil 0.8%, deionized water supplies 100%.By mentioned component
Processing according to a conventional method can be prepared by 10% pair of the third ring worm ester matrine suspending agent.
Example of formulations 7：9% pair of the third ring worm ester matrine water dispersible granule
Double third ring worm esters 6%, matrine 3%, sodium lignin sulfonate 6%, sodium naphthalene sulfonate 9%, alkyl naphthalene sulfonic acid calcium 5%,
Polyvinyl alcohol 5%, kaolin supplies 100%.Mentioned component processed to can be prepared by 9% couple of the third ring worm ester 〃 bitter according to a conventional method
Ginseng buck dispersible granule.
Example of formulations 8：6% pair of the third ring worm ester matrine suspending agent
Double third ring worm esters 3%, matrine 3%, alkyl polyoxyethylene ether sodium sulfonate 4%, phenethyl phenol polyoxyethylene ether
Phosphate 5%, carboxymethylcellulose calcium 4%, polyethylene glycol 4%, silicone oil 0.8%, deionized water supplies 100%.By mentioned component
Processing according to a conventional method can be prepared by 6% pair of the third ring worm ester matrine suspending agent.
Example of formulations 9：3% pair of the third ring worm ester microemulsion containing matrine agent
Double third ring worm esters 1%, matrine 2%, 1-METHYLPYRROLIDONE 8%, agriculture breast 2201#4%, alkylphenol-polyethenoxy
Base ether phosphate 8%, epoxidized soybean oil 3%, organosilicon 3%, thiophene ketone 5%, deionized water supplies 100%.Mentioned component is pressed
Conventional method processing can be prepared by 3% double third ring worm ester 〃 microemulsion containing matrine agent.
Example of formulations 10：5% pair of the third ring worm ester sulfoxaflor suspension emulsion
Weigh double third ring worm esters 1%, matrine 4%, ethoxylated castor oil 5%, AEO sulfo group amber
Amber acid monoester dicalcium 12%, MODIFIED LIGNOSULPHONATE 6%, aluminium-magnesium silicate 5%, xanthans 4%, ethylene glycol 4%, deionized water
Supply 100%.First sulfoxaflor is dissolved in Solvesso200, adds ethoxylated castor oil to obtain sulfoxaflor
Missible oil, then above-mentioned each component is mixed in proportion, Jing sand millings are prepared into suspending agent.The oil phase of sulfoxaflor is added
To in the suspending agent containing double third ring worm esters, 5% pair of the third ring worm ester matrine suspension emulsion is obtained.
Example of formulations 11：3.5% pair of the third ring worm ester aqueous matrine solution
Double third ring worm esters 0.5%, matrine 3%, aliphatic alcohol polyoxyvinethene phosphate 4%, alkylsurfuric acid calcium 7%, silicon
Diatomaceous earth supplies 100%.Mentioned component is processed according to a conventional method and can be prepared by 3.5% pair of the third ring worm ester 〃 matrine wettable powder
Agent.
Example of formulations 12：4.5% pair of the third ring worm ester matrine water emulsion
Double third ring worm esters 0.5%, matrine 4%, 1-METHYLPYRROLIDONE 5%, agriculture breast 2201#3%, this disk -60#3%,
Agriculture breast 1601#4%, epoxidized soybean oil 5%, benzoic acid 4%, sorbierite 5%, deionized water supplies 100%.Mentioned component is pressed
Conventional method processing can be prepared by 4.5% double third ring worm ester 〃 matrine water emulsions.
Example of formulations 13：4.4% pair of the third ring worm ester matrine microcapsule suspension agent
Double third ring worm esters 0.4%, matrine 4%, macromolecule cyst material polymer MDI3%, 5% and of solvent linseed oil
S-180 solvent naphthas 8%, emulsifying agent triphenoethyl benzene phenol polyethenoxy ether phosphate 4%, dispersant Negel 6%.Will
Above-mentioned active ingredient, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, emulsifying agent, dispersant system soluble in water
Standby uniformly water phase, in a shear condition, oil phase is added in aqueous phase solution, is prepared into emulsion, and stirring is lower to add 10% second two
Amine aqueous solution 4%, is warming up to 65 DEG C of insulation reactions 4.0h, and bi-material reacts in oil-water interfaces, forms high score ascus wall,
Can be prepared by 4.4% pair of the third ring worm ester 〃 matrine microcapsule suspension agent.
Field information embodiment 1：Double third ring worm esters prevent and treat Brown Planthopper Nilaparvata with matrine compound
Lugens (Stdl) field control effectiveness test
Test selects to carry out in Hubei Province Tianmen City Fo Zishan towns sky dragon village.Ridging before test, draws cell, and plot area is
40m2, even spraying is carried out using knapsack sprayer, the paddy rice growth of selection is basically identical, is in late tillering state,
That a situation arises is basically identical for brown paddy plant hopper, and insect population, and 7d, 15d, 30d investigation worm living after medicine are investigated before clapping method medicine using basin
Number.
Insect population * 100 before Revision insect recluced rate %=(borer population living after insect population-medicine before medicine)/medicine
Prevention effect (%)=(treatment region Revision insect recluced rate-clear area Revision insect recluced rate)/(100- clear areas insect population goes down
Rate) * 100
Table 4, double third ring worm ester matrine compound agents prevent and treat the field control effectiveness test result of Brown Planthopper
Double third ring worm ester 〃 matrine compound agents be can be seen that in preventing and treating Brown Planthopper field medicine from result of the test in table 4
During effect test, after each built agent medicine, the preventive effect of 7d, 15d and 30d is above 10% pair of the third ring worm ester suspending agent of comparison medicament and 2%
The preventive effect of aqueous matrine solution, illustrates that double third ring worm ester 〃 matrine compounds are good to the prevention effect of brown paddy plant hopper.In process of the test
It was observed that each medicament on paddy rice and natural enemy without impact.
Field information embodiment 2：Double third ring worm esters and field control effectiveness test of the matrine compound to cucumber thrips
It is Frankliniella occidentalis (Frankliniella occidentalis) for trying object, test selection is in Zhaoqing City of Guangdong Province
Carry out on Gao Yao areas Ma An towns crow stone pit village wild cabbage.Per cell 8 plants of cucumber seedlings of mark, insect population is investigated before dispenser, after dispenser
1d, 3d and 7d investigate residual borer population living respectively, and blank district spray clear water calculates prevention effect.
Insect population * 100 before Revision insect recluced rate %=(borer population living after insect population-medicine before medicine)/medicine
Prevention effect (%)=(treatment region Revision insect recluced rate-clear area Revision insect recluced rate)/(100- clear areas insect population goes down
Rate) * 100
Table 5, double third ring worm ester matrine compound agents preventing and treating cucumber Frankliniella occidentalis field control effectiveness test result
Double third ring worm ester matrine compound agents be can be seen that in preventing and treating cucumber Frankliniella occidentalis field from result of the test in table 5
Between the test of pesticide effectiveness when, after medicine the preventive effect of 1d, 3d and 7d apparently higher than control higher than 10% pair of the third ring worm ester suspending agent of comparison medicament
With 1% aqueous matrine solution preventive effect, show equal to the quick-acting and lasting effect of Frankliniella occidentalis after double third ring worm ester matrine compounds
It is better than two kinds of single doses, obvious to Frankliniella occidentalis prevention effect.Also in observing process of the test simultaneously, each medicament is to cucumber seedling and day
Enemy is without impact.
Field information embodiment 3：Double third ring worm esters are tried to the field efficacy of tea tree tea lesser leafhopper with matrine compound agent
Test
Test is selected in Quanzhou City of Fujian Province Hui'an County Luo Yang towns Su Keng villages, is tea tree (Fujian Shuihsien) for studying thing, often
Repeat 3 trees, often process 3 repetitions, each tree investigation tea lesser leafhopper sum investigates tea lesser leafhopper insect population base before dispenser
Number, after medicine, 3d, 7d, 15d investigate residual borer population living respectively, calculate prevention effect.Prevention effect computational methods are as follows：
Insect population * 100 before Revision insect recluced rate %=(borer population living after insect population-medicine before medicine)/medicine
Prevention effect (%)=(treatment region Revision insect recluced rate-clear area Revision insect recluced rate)/(100- clear areas insect population goes down
Rate) * 100
Table 6, double third ring worm ester matrine compound agents prevent and treat the field control effectiveness test result of tea tree tea lesser leafhopper
Double third ring worm ester matrine compound agents be can be seen that in preventing and treating tea lesser leafhopper field from result of the test in table 6
During the test of pesticide effectiveness, after medicine, the preventive effect of 3d, 7d and 15d is above compareing 10% couple of the third ring worm ester SC of single dose and 1% matrine is solvable
The preventive effect of liquor, illustrates that double third ring worm ester matrine compound medicaments are superior to two kinds to the quick-acting and lasting effect of tea lesser leafhopper
Single dose, it is good to the prevention effect of tea lesser leafhopper.Simultaneously in process of the test, also it was observed that each medicament is to tea tree safety, to day
Enemy is also without impact.
Pesticidal combination of the present invention be can be seen that from the result of the test of above field control effectiveness test embodiment to fly Rice Brown
Lice, cucumber Frankliniella occidentalis and tea tree tea lesser leafhopper prevention effect are outstanding, and composition quick-acting has than single dose and significantly carries
Height, lasting effect are also improved.Process of the test Chinese medicine to supply examination crop safety, on natural enemy without impact, be a kind of market potential very
Big pesticide species.
Claims (6)
1. a kind of Synergistic insecticidal compositions containing double third ring worm esters, it is characterised in that：The active ingredient of the Pesticidal combination
For double third ring worm esters and matrine, both mass ratioes are 50:1～1:10.
2. Pesticidal combination according to claim 1, it is characterised in that：The matter of the double third ring worm esters of active ingredient and matrine
Amount is than being 10:1～1:1.
3. Pesticidal combination according to claim 1 and 2, it is characterised in that：Total matter of active ingredient in Pesticidal combination
Amount percentage composition is 3%～65%.
4. Pesticidal combination according to claim 3, it is characterised in that：Make during practical application and be adapted to what is agriculturally used
Any one formulation, its formulation are suspending agent, suspension emulsion, microemulsion, aqueous emulsion, wettable powder, water dispersible granules or micro-capsule
Suspending agent.
5. Pesticidal combination described in claim 1-4 is used for the application on the crops such as paddy rice, tealeaves and vegetables in terms of mini pest.
6. the application of Pesticidal combination according to claim 5, it is characterised in that：Mini pest is plant hopper, the little greenery of tea
Cicada and thrips.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610892568.8A CN106538586B (en) | 2016-10-13 | 2016-10-13 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610892568.8A CN106538586B (en) | 2016-10-13 | 2016-10-13 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106538586A true CN106538586A (en) | 2017-03-29 |
| CN106538586B CN106538586B (en) | 2018-10-23 |
Family
ID=58369116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610892568.8A Active CN106538586B (en) | 2016-10-13 | 2016-10-13 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106538586B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107006495A (en) * | 2017-03-31 | 2017-08-04 | 山东省烟台市农业科学研究院 | A kind of compounded pesticides and its application containing double third ring worm esters and matrine |
| CN107212016A (en) * | 2017-07-14 | 2017-09-29 | 江苏沿海地区农业科学研究所 | A kind of Pesticidal combination for preventing and treating peach aphid and its application |
| CN108496985A (en) * | 2018-05-15 | 2018-09-07 | 信阳农林学院 | A kind of agricultural chemical composition for disinsection of prevention rice grub |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1650710A (en) * | 2005-02-18 | 2005-08-10 | 李建中 | Insecticide composition containing methylamino Avermectin and matrine |
| CN101647459A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Matrine composition |
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
| CN105532713A (en) * | 2015-12-18 | 2016-05-04 | 广东中迅农科股份有限公司 | Insecticidal composition comprising afidopyropen and flonicamid |
| CN105918341A (en) * | 2016-04-25 | 2016-09-07 | 广东中迅农科股份有限公司 | Insecticidal composition containing chlorfenaypr and afidopyropen |
| CN105941437A (en) * | 2016-06-24 | 2016-09-21 | 江苏省绿盾植保农药实验有限公司 | Compound insecticide containing afidopyropen and fipronil and application thereof |
-
2016
- 2016-10-13 CN CN201610892568.8A patent/CN106538586B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1650710A (en) * | 2005-02-18 | 2005-08-10 | 李建中 | Insecticide composition containing methylamino Avermectin and matrine |
| CN101647459A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Matrine composition |
| CN102905528A (en) * | 2010-05-28 | 2013-01-30 | 巴斯夫欧洲公司 | Pesticidal mixtures |
| CN105532713A (en) * | 2015-12-18 | 2016-05-04 | 广东中迅农科股份有限公司 | Insecticidal composition comprising afidopyropen and flonicamid |
| CN105918341A (en) * | 2016-04-25 | 2016-09-07 | 广东中迅农科股份有限公司 | Insecticidal composition containing chlorfenaypr and afidopyropen |
| CN105941437A (en) * | 2016-06-24 | 2016-09-21 | 江苏省绿盾植保农药实验有限公司 | Compound insecticide containing afidopyropen and fipronil and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107006495A (en) * | 2017-03-31 | 2017-08-04 | 山东省烟台市农业科学研究院 | A kind of compounded pesticides and its application containing double third ring worm esters and matrine |
| CN107212016A (en) * | 2017-07-14 | 2017-09-29 | 江苏沿海地区农业科学研究所 | A kind of Pesticidal combination for preventing and treating peach aphid and its application |
| CN108496985A (en) * | 2018-05-15 | 2018-09-07 | 信阳农林学院 | A kind of agricultural chemical composition for disinsection of prevention rice grub |
| CN108496985B (en) * | 2018-05-15 | 2021-01-22 | 信阳农林学院 | Insecticidal pesticide composition for preventing and treating rice pests |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106538586B (en) | 2018-10-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105532713A (en) | Insecticidal composition comprising afidopyropen and flonicamid | |
| CN104488949A (en) | Dinotefuran-containing insecticidal combination | |
| CN106106501A (en) | A kind of Synergistic insecticidal compositions containing double third ring worm esters | |
| CN106538586B (en) | A kind of Synergistic insecticidal compositions containing double third ring worm esters | |
| CN102204564B (en) | Pesticide composition containing fosthiazate and carbosulfan | |
| CN102484996B (en) | Synergy composition for matrine and tetronic acid pesticides | |
| CN105901007A (en) | Pesticidal composition containing cyclaniliprole and chloropyridine | |
| CN103202299A (en) | Pesticide composition for preventing and controlling plant virus disease | |
| CN105475317A (en) | Sterilization combination containing efficient metalaxyl-M and cymoxanil | |
| CN106982837A (en) | A kind of Pesticidal combination containing fluorine cyanogen insect amide and its application | |
| CN106857636A (en) | A kind of Synergistic insecticidal compositions containing double third ring worm esters | |
| CN106342843A (en) | Insecticide composition containing haloxyfop furanone | |
| CN103392726B (en) | A kind of bactericidal composition that contains iprodione and prothioconazoles | |
| CN104542675A (en) | Pesticide composition and application thereof | |
| CN105941423B (en) | A kind of Pesticidal combination containing capillary and cyromazine | |
| CN106305762A (en) | Synergistic insecticidal composite containing afidopyropen | |
| CN103039467A (en) | Insecticidal composition containing flufenzine and spirotetramat | |
| CN107950549A (en) | A kind of Pesticidal combination | |
| CN106689138A (en) | Insecticidal composition | |
| CN106973949B (en) | A kind of Pesticidal combination and application thereof comprising bitter pueraria root extract and matrine | |
| CN106900756B (en) | Insecticidal composition of pueraria peduncularis extract and azadirachtin for preventing and treating agricultural pests and application thereof | |
| CN105994307A (en) | Insecticide composition containing cyclaniliprole and triflumezopyrim | |
| CN105409978A (en) | Pesticide composition, herbicide and application | |
| CN106538588A (en) | A kind of Synergistic insecticidal compositions containing double third ring worm esters | |
| CN105123697A (en) | Pesticidal composition containing pyridalyl and spinosad |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Guangze Inventor after: Yang Liping Inventor after: Cao Huan Inventor after: Zhu Weifeng Inventor after: Huang Kecheng Inventor before: Cao Huan Inventor before: Li Guangze Inventor before: Zhu Weifeng Inventor before: Huang Kecheng Inventor before: Yang Liping |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China |