CN1650710A - Insecticide composition containing methylamino Avermectin and matrine - Google Patents
Insecticide composition containing methylamino Avermectin and matrine Download PDFInfo
- Publication number
- CN1650710A CN1650710A CN 200510007412 CN200510007412A CN1650710A CN 1650710 A CN1650710 A CN 1650710A CN 200510007412 CN200510007412 CN 200510007412 CN 200510007412 A CN200510007412 A CN 200510007412A CN 1650710 A CN1650710 A CN 1650710A
- Authority
- CN
- China
- Prior art keywords
- matrine
- affirm
- merck
- benzoate
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A synergistic composite insecticide contains matrine including oxymatrine, etc and methylamino Avermectin or its salt in the ratio of (0.01-100):1.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, it contains the combination of Affirm (Merck Co.) or its salt and matrine as active component.
Background technology
Crops all need to use a large amount of agricultural chemicals for this reason and carry out the extermination of disease and insect pest, to retrieve crop yield loss because damage by disease and insect causes crop yield loss to estimate every year.In recent years, for example the harm on paddy rice, fruit tree, vegetables, flowers and the diversified economy crop is more and more serious crops in insect pest, and because the agricultural chemicals abuse makes insect produce more and more serious resistance to agricultural chemicals, causes pest controling effect to reduce year by year.In addition, at present agriculture and forestry are principal item with the chemical pesticide just still in producing, and many chemical pesticides residue in environment, environment is polluted, therefore, more efficient, safer, the pesticide species of environmental protection more of needs just still.
Affirm (Merck Co.) and salt thereof (particularly benzoate) they are 4 "-deoxidation-4 " N-Affirm (Merck Co.) B
1a/ B
1bMixture, be disclosed in U.S. Pat-P-4,874, in 749, also be known as MK-244, be a kind of known wide spectrum, low toxicity insecticidal/acaricidal agent, can prevent effectively eliminating aphis, the multiple insect that is difficult to prevent and treat such as mite class, diamond-back moth, cabbage caterpillar, Americal rice leaf miner, beet flea beetle, colorado potato beetle, fruit tree leaf roller, oriental fruit moth and scale insect.
Matrine comprises a series of alkaloid formulations that extract from fabaceous of Chinese herbal medicine kuh-seng, Sophora alopecuroide, root of subprostrate sophora etc., stem, fruit, in the composite embodiment of matrine and emamectin-benzoate, mainly refer to matrine (Matrine, C15H24ON2) and oxymatrine (Oxymatrine, C15H24N202) be main
Wherein the structural formula of oxymatrine is as follows:
Though the existing at present report that adopts combinations such as Avermectin and matrine is referring to for example CN1309900A.Can not have which kind of unexpected effect, for example synergistic effect but these documents are actual after mentioning Affirm (Merck Co.) and matrine combination.Therefore, according to disclosed document, those skilled in the art can not obtain containing the combination as active component of Affirm (Merck Co.) and matrine.The present inventor is surprised to find that the combination of Affirm (Merck Co.) and matrine has synergistic effect, so finished the present invention.
Summary of the invention
The purpose of this invention is to provide a kind of Pesticidal combination that contains the combination of Affirm (Merck Co.) and matrine as active component, it has excellent synergy control efficiency.
Another object of the present invention provides various preparations of described Pesticidal combination and its production and application.
Coming in and going out is unexpectedly, and the two the combination of Affirm (Merck Co.) and matrine has synergistic effect.The present composition contains the described active component combination of synergy effective dose, and ratio can be arbitrarily between active component, as long as can produce synergistic effect.For example, Affirm (Merck Co.) or its salt: the weight ratio of matrine=1: 0.01-100 is preferably 1: 0.1-10.
The Affirm (Merck Co.) that the present composition adopted is benzoate, benzene sulfonate, citrate, phosphate, tartrate or the maleate of its agriculture pharmaceutically acceptable salt, particularly benzoate, replacement preferably; More preferably benzoate or benzene sulfonate; Benzoate most preferably.Described salt can be anhydrous, or its possible moisture crystal formation.
Equally preferably, B in the Affirm (Merck Co.)
1a/ B
1bRatio be B
1a＞80wt%, B
1b＜20wt%, particularly B
1a＞90wt%, B
1b＜10wt%.
Matrine is a commercially produced product.Matrine also can be the matrine extract.
The present invention's combination can convert conventional formulation such as missible oil, wetting powder, granula, soluble powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, emulsion, pulvis, paste, the agent of kind clothing and water surface leafing agent etc. to.
Administration form depends on specific use.In all cases, must guarantee that their dispersion is trickle as much as possible and even.
These preparations can prepare in a known manner, for example by with active component solvent and/or carrier, if desired, adopt emulsifier and dispersant to fill, if use water as thinner, also can make cosolvent with other organic solvent.
The cosolvent that is applicable to this purpose mainly is:
Solvent such as aromatic compounds (for example benzene,toluene,xylene), chloro aromatic compounds (for example chlorobenzene), paraffin (for example petroleum cuts), alcohols (for example methyl alcohol, isopropyl alcohol, isooctanol, ethylene glycol, propane diols, glycerine etc.), alcohols (for example cyclohexanone), amine (for example monoethanolamine, dimethyl formamide etc.) and water.
The surface reactive material that is fit to is aromatic sulfonic acid (for example lignosulphonic acid, phenolsulfonic acid, naphthalene sulfonic acids and a dibutyl naphthalene sulfonic acids)
Alkali metal with fatty acid, alkaline earth metal and ammonium salt, alkylsulfonate and alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfuric acid and aliphatic alcohol sulfate, and Sulfated 16-, 17-and the salt of octadecanol and fatty alcohol ether, the condensation product of sulfonated naphthalene and derivative thereof and formaldehyde, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, polyoxyethylene octylphenol ether, the iso-octyl of ethyoxyl alkanisation-, octyl group-or nonyl phenol, alkylphenol or tributyl phenyl polyglycol ether, alkyl aryl polyether alcohol, different three decyl alcohol, the fatty alcohol ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene-or the polyoxypropylene alkyl ether, laruyl alcohol polyglycol ether acetic acid esters, sorbitan ester, lignin sulfite waste liquor or methylcellulose class.
When preparation example such as missible oil, paste or liquid water surface leafing agent,, material is homogenized in water or be dissolved in oil or the solvent by adding wetting agent, adhesive, dispersant or emulsifier etc.
Pulvis, solid-state water surface leafing agent etc. can be by mixing active component or grinding and produce with solid carrier.
Granule (for example apply, dipping or homogeneous particle agent) can prepare by active component is adhered on the solid carrier.
Solid carrier is for example silica gel, silicic acid, silicate, talcum, kaolin, lime stone, lime, chalk, bole, loess, potter's clay, dolomite, diatomite, calcium sulphate and magnesium sulfate, a magnesia of ore soil, the synthetic material, the chemical fertilizer that grind, for example ammonium sulfate, ammonium phosphate, ammonium nitrate, urea and plant produce thing such as flour, bark powder, wood powder and shuck powder, cellulose powder and other solid carrier.
In the present invention, preferably suspending agent, soluble powder, water-dispersible granules, granule, the agent of kind clothing and capsule.Particularly following pharmaceutical formulation.
In the present invention, percentage all is meant the w/w percentage, unless otherwise indicated.
Suspending agent is preferably as follows prescription, and it is to contain following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
Ase-60 1-10％
XG 0.5-3％
10％PVA 5-15％
Alcohols 1-8% and
Water.
Aqua is preferably as follows prescription, and it is to contain following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
C
1-C
4-low-grade alkane alcohol 20-50%
Tweens 1-40% and
Water.
Aqueous emulsion is preferably as follows prescription, and it is to contain following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
Turpentine oil 5-20%
C
1-C
4-low-grade alkane alcohol 5-30%
Tweens 5-15%
Dimethyl sulfoxide (DMSO) 1-10% and
Water.
Usually, by composition content, contain the Affirm (Merck Co.) of 0.1-25% and the matrine of 0.1-10% in the composition.
During pest control, preparation contains by weight 0.00001% to 10%, and preferred 0.001% to 1% active component by weight is preferred.
Moisture administration form can be by adding water, but for example by missible oil, emulsion, paste, wetting powder or the preparation of water dispersible granule.
When the present composition was used, the difference according to factors such as different crops, time of application, weather conditions was generally 0.5-500g a.i/ha, is preferably 1-100g a.i/ha, generally adopts foliage applying, and for example foliar spray is handled.Also can do other and handle as seed dressing, filling root etc., in this case, can adjust application dosage as required.For example when soil treatment control soil insect, application dosage is between 10-1000g a.i./ha.
Pesticidal combination of the present invention can be widely used in the insect on control vegetables (for example tomato, capsicum, cucumber, Chinese cabbage, custard squash etc.), potato, beet, paddy rice, cotton, tobacco and the fruit tree crops such as (for example apple, citrus, cherries etc.), is used to prevent and treat for example various pests such as aphid, leafhopper, plant hopper, thrips, aleyrodid, wireworm, beet flea beetle, colorado potato beetle, fruit tree leaf roller, oriental fruit moth, scale insect, diamond-back moth, cabbage caterpillar, Americal rice leaf miner, rice borer, tetranychid, Panonychus citri, goitre mite, tarsonemid.
Other purpose of the present invention and advantage are described further by following examples.
Embodiment
Example of formulations
Example of formulations 1 2% emamectin-benzoate matrine missible oil
Emamectin-benzoate 1.8g
Matrine 0.2g
No. 2201 12g of farming breast
Cyclohexanone 1g
Dimethylbenzene is mended 100g
Emamectin-benzoate is dissolved with cyclohexanone, add above-mentioned other composition, mix, promptly get missible oil.
Example of formulations 2 2.1% emamectin-benzoate matrine wetting powders
Emamectin-benzoate 1.1g
Matrine 1g
Lauryl sodium sulfate 2g
Neopelex 4g
Spaonin powder 5g
Kaolin 25g
Diatomite is mended to 100g
Mentioned component is mixed, and comminution by gas stream promptly gets wetting powder.
Example of formulations 3 2.38% emamectin-benzoate matrine pulvis
Emamectin-benzoate 2g
Matrine 0.38g
Dodecyl sodium sulfate 0.1g
Diatomite 30g
Talcum powder is mended to 100g
The mentioned component mechanical crushing is ground, promptly get wetting powder.
Example of formulations 4 4% emamectin-benzoate aqueous matrine solutions
Emamectin-benzoate 3g
Matrine 1g
Ethanol 40g
Tween 30 4g
JFC 8g
Sodium Benzoate 1g
Water is mended to 100g
With the emamectin-benzoate dissolve with ethanol, add other composition, homogenizing is disperseed, and promptly gets aqua.
Example of formulations 5 1.5% emamectin-benzoate matrine water emulsions
Emamectin-benzoate 1.0g
Matrine 0.5 gram
Turpentine oil 14.5g
Ethanol 22g
Polysorbate60 8g
Dimethyl sulfoxide (DMSO) 4g
Sorbic acid 0.5g
Water is mended 100g
With the emamectin-benzoate dissolve with ethanol, add other composition, homogenizing is disperseed, and promptly gets aqueous emulsion.
Example of formulations 6 1.9% emamectin-benzoate matrine suspending agents
Emamectin-benzoate 0.8g
Matrine 1.1g
Ase-60 2g
10％PVA 12g
XG 0.3g
Ethylene glycol 4g
Isooctanol 2g
Water is mended to 100g
The solid constituent of above-mentioned active component is pulverized, and joins in the liquid component, and homogenizing is disperseed, and promptly gets suspending agent.
Indoor biologic test
Biological Examples 1
1, reagent agent
Matrine 0.36% aqua, Henan Dongfangren Agrochemicals Co., Ltd. provides.
Emamectin-benzoate 50%, Beijing Orient wins Bioisystech Co., Ltd of nation to be provided.
2, for the examination object
Diamond-back moth: be the field collection, indoor feeding, upgrowth situation is good, and resistance level is moderate.
3, experimental technique:
Cabbage leaves is cut into 3cm * 4cm small pieces, puts into the culture dish that diameter is 9cm, be lined with filter paper in the ware.Behind soup of dish leaf foliage-spray, the upset blade also connects 10 larvas, sprays medicine more once, and each spray amount is 10ml.If clear water contrast.1d, 3d, 5d, 10d check death state after handling.3 repetitions of every processing.In the Potter spray tower, handle.
4, co-toxicity evaluation method:
Press SUN-Johnson suggestion, convert concentration to logarithm, lethality converts the probability value to, carries out linear regression, obtains the LC50 value of single agent and mixture, calculating co-toxicity coefficient CTC value.
5, experimental result:
Experimental result shows: matrine and emamectin-benzoate are obvious to the virulence of diamond-back moth 3 instar larvaes and the inhibitory action of growing, and larva and pupa general mortality rate rise with the rising of two drug concentrations, and pupation rate and eclosion rate descend.Behind two pharmacy mix, three enter the using dosage with and handle diamond-back moth of test after, the relative increase of lethality of larva and pupa, pupation rate is relative with eclosion rate obviously to be reduced.Measure CTC value result such as following table 1 after the detection general mortality rate:
The different proportionings with matrine of table 1 emamectin-benzoate are to the joint toxicity measuring of diamond-back moth
Use proportioning A with: B regression equation correlation coefficient LC50 (ai) ug.mL-1 CTC
Matrine (A) Y=4.620+1.358x 0.9964 1.905
Emamectin-benzoate (B) Y=3.347+2.364x 0.9586 5.000
A∶B＝1∶10 Y＝4.077+1.342x 0.9599 4.873 243.6
A∶B＝2∶7 Y＝4.176+1.248x 0.9655 4.566 265.4
A∶B＝3∶6 Y＝4.021+1.643x 0.9811 3.9435 278.3
A∶B＝1∶1 Y＝4.027+1.764x 0.9624 3.562 242.8
A∶B＝6∶3 Y＝3.974+2.023x 0.9745 3.2136 318.6
A∶B＝7∶2 Y＝4.22+2.335x 0.9665 2.157 366.3
A∶B＝10∶1 Y＝4.261+2.462x 0.9781 1.996 382.3
Annotate: A is a matrine, and B is an emamectin-benzoate.
From table 1, five kinds of ratio combinations of matrine and emamection benaoate, enter and record co-toxicity coefficient after the experiment and be respectively 243.6,265.4,278.3,242.8,318.6,366.3,382.3, all the synergy standard of recommending far above SUN-Johnson.Matrine mixes with the various ratios of emamectin-benzoate and all produces synergy.
Biological Examples 2
1, reagent agent
0.36% aqueous matrine solution
1% emamectin-benzoate missible oil
4% emamectin-benzoate aqueous matrine solution (example of formulations 4)
2, for examination worm source
Cotton bollworm (Heliothis armigera) is picked up from natural conditions growths cotton field, indoorly again raises the generation to F1 with feed, and 3 instar larvaes of selecting worm unanimity in age are for examination.
3, test method: be mixed with the series concentration medicament, be sprayed on the cotton blade, behind the natural air drying, will try worm and place on the cotton leaf.1d, 3d, 7d investigate lethality behind the medicine.
4, investigation result
Investigation in 1 day behind the medicine, three medicaments that enter experiment are respectively 37.9%, 65%, 87.5% to the preventive effect of cotton bollworm, and the quick-acting of matrine is best, and preventive effect is the highest, and mixture takes second place.But the preventive effect that 3d behind the medicine, 7d elder brother agent are handled cotton bollworm is respectively 96.8%, 99.9%, is higher than 93.8%, 95.6% preventive effect of contrast medicament 1% emamectin-benzoate missible oil, and the preventive effect of 0.36% matrine only is 95%, 86.7%.The synergy of mixture is remarkable.The results are shown in Table 2
The effect of 1% emamectin-benzoate matrine pulvis control cotton bollworm behind table 2 medicine
Medicament title consumption
Preventive effect behind the medicine (%)
ml/mu 1d 3d 7d
1% emamectin-benzoate 90 37.9 93.8 95.6
0.36% aqueous matrine solution 80 78 95 86.7
4% emamectin-benzoate aqueous matrine solution 70 65 96.8 99.9
Though above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements all belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (8)
1, a kind of Pesticidal combination, it contains the combination of Affirm (Merck Co.) and matrine as active component, wherein, Affirm (Merck Co.): the weight ratio of matrine=1: 0.01-100.
2, according to the Pesticidal combination of claim 1, wherein, Affirm (Merck Co.): the weight ratio of matrine=1: 0.1-10.
3, according to the Pesticidal combination of claim 1 or 2, wherein, Affirm (Merck Co.) is a methylamino avermitilis strain benzoate.
4, according to arbitrary Pesticidal combination of claim 1-3, it is a kind of missible oil, wetting powder, suspending agent, aqua, water and milk, sustained release agent or capsule.
5,, wherein contain the Affirm (Merck Co.) of 0.1-25% and the matrine of 0.1-10% according to arbitrary Pesticidal combination of claim 1-4.
6, according to the Pesticidal combination of claim 5, it is the suspending agent (w/v%) that contains following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
Ase-60 1-10％
XG 0.5-3％
10％PVA 5-15％
Alcohols 1-8% and
Water.
7, according to the Pesticidal combination of claim 5, it is the aqua that contains following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
C
1-C
4-low-grade alkane alcohol 20-50%
Tweens 1-40% and
Water.
8, according to the Pesticidal combination of claim 5, it is the aqueous emulsion that contains following composition and content:
Affirm (Merck Co.) 0.1-25%
Matrine 0.1-10%
Turpentine oil 5-20%
C
1-C
4-low-grade alkane alcohol 5-30%
Tweens 5-15%
Dimethyl sulfoxide (DMSO) 1-10% and
Water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100074129A CN1297196C (en) | 2005-02-18 | 2005-02-18 | Insecticide composition containing methylamino Avermectin and matrine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100074129A CN1297196C (en) | 2005-02-18 | 2005-02-18 | Insecticide composition containing methylamino Avermectin and matrine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1650710A true CN1650710A (en) | 2005-08-10 |
| CN1297196C CN1297196C (en) | 2007-01-31 |
Family
ID=34875289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100074129A Expired - Fee Related CN1297196C (en) | 2005-02-18 | 2005-02-18 | Insecticide composition containing methylamino Avermectin and matrine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1297196C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101036476B (en) * | 2007-03-28 | 2010-10-27 | 陆致平 | Sophora tonkinensis root total base microemulsifier of botanical insecticide and the method for preparing the same |
| CN102028001A (en) * | 2010-12-14 | 2011-04-27 | 杨凌农科大无公害农药研究服务中心 | Sophora alopecuroides L alkaloid-containing plant-derived synergistic compound aphicide and preparation method thereof |
| CN103585262A (en) * | 2013-08-31 | 2014-02-19 | 内蒙古农牧业科学院 | Sophora alopecuroides L alkaloid preparation for preventing and curing livestock ectoparasite disease |
| CN106538586A (en) * | 2016-10-13 | 2017-03-29 | 深圳诺普信农化股份有限公司 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
| CN107087625A (en) * | 2017-05-03 | 2017-08-25 | 广西南宁益土生物科技有限责任公司 | A kind of miticide composition containing cyflumetofen and matrine |
| CN107183038A (en) * | 2017-06-22 | 2017-09-22 | 北京清源保生物科技有限公司 | Plant extracts containing matrine and its applied in pest control |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1308871A (en) * | 2000-11-23 | 2001-08-22 | 刘茂萱 | Agricultural chemical prepared from avermectin and alkaloid extracted from plant and its preparing process |
| CN1322472A (en) * | 2001-06-12 | 2001-11-21 | 都江堰市大发实业有限责任公司 | All biological pesticide solution |
| CN1428078A (en) * | 2001-12-28 | 2003-07-09 | 冉隆中 | Biological pesticide yield-increasing agent |
-
2005
- 2005-02-18 CN CNB2005100074129A patent/CN1297196C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101036476B (en) * | 2007-03-28 | 2010-10-27 | 陆致平 | Sophora tonkinensis root total base microemulsifier of botanical insecticide and the method for preparing the same |
| CN102028001A (en) * | 2010-12-14 | 2011-04-27 | 杨凌农科大无公害农药研究服务中心 | Sophora alopecuroides L alkaloid-containing plant-derived synergistic compound aphicide and preparation method thereof |
| CN102028001B (en) * | 2010-12-14 | 2013-04-03 | 杨凌农科大无公害农药研究服务中心 | Sophora alopecuroides L alkaloid-containing plant-derived synergistic compound aphicide and preparation method thereof |
| CN103585262A (en) * | 2013-08-31 | 2014-02-19 | 内蒙古农牧业科学院 | Sophora alopecuroides L alkaloid preparation for preventing and curing livestock ectoparasite disease |
| CN106538586A (en) * | 2016-10-13 | 2017-03-29 | 深圳诺普信农化股份有限公司 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
| CN106538586B (en) * | 2016-10-13 | 2018-10-23 | 深圳诺普信农化股份有限公司 | A kind of Synergistic insecticidal compositions containing double third ring worm esters |
| CN107087625A (en) * | 2017-05-03 | 2017-08-25 | 广西南宁益土生物科技有限责任公司 | A kind of miticide composition containing cyflumetofen and matrine |
| CN107183038A (en) * | 2017-06-22 | 2017-09-22 | 北京清源保生物科技有限公司 | Plant extracts containing matrine and its applied in pest control |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1297196C (en) | 2007-01-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN86108526A (en) | Bactericide | |
| CN1297196C (en) | Insecticide composition containing methylamino Avermectin and matrine | |
| CN101027991A (en) | Pyraphione compound active insecticide | |
| CN101073324A (en) | Synergistic insect-killing composition | |
| CN1072817A (en) | Mixed agrochemical combination | |
| CN1759675A (en) | Pesticide containing comptothecin or dreivates of camptothecin, and preparation method | |
| CN1255830A (en) | Fungicidal combinations comprising 4-phenoxyquinoline | |
| KR20110033691A (en) | Environment-friendly organic agricultural products for soil insect pest control | |
| CN1650718A (en) | Insecticide composition containing methyl amino Avermectin and nucleo type polyhedron viruse | |
| CN1295960C (en) | Weeding composition, application and method of application | |
| CN1209017C (en) | Plant growth regulator composition with cold-resisting action | |
| CN1568695A (en) | Stable methylamino avermectin water dispersed granula | |
| CN1099220A (en) | A plant-microbicidal composition having synergistic action, comprising at least two active ingredient components, eherein...... | |
| CN1209021C (en) | Pesticidal composition containing emamectin and pyrethroid compounds | |
| CN100342787C (en) | Combination of insect disinfectations containing benzoate of Avermectin in methylamine group and azadirachtin | |
| CN1647652A (en) | Pesticide composition containing methyl amino abamectin and bacillus thuringiensis | |
| CN1918988A (en) | Sterilizing and insecticidal composition | |
| CN1781375A (en) | Bicao mixture | |
| CN1043947C (en) | Method of controlling insects | |
| CN1452865A (en) | Bactericide composition | |
| CN1918989A (en) | Bactericide composition | |
| CN1150819C (en) | Plant growth regualting composition with drought resistance function | |
| CN1265708C (en) | Bactericide composition of SYP-Zo48 and thiocarbamate | |
| CN1294817C (en) | Application of anemarrhena extractive as bactericide and contained bactericide | |
| CN1257669C (en) | Bactericide composition containing enostroburin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070131 Termination date: 20100218 |