CN106521976B - 一种生态型pvc装饰人造革 - Google Patents

一种生态型pvc装饰人造革 Download PDF

Info

Publication number
CN106521976B
CN106521976B CN201611068014.2A CN201611068014A CN106521976B CN 106521976 B CN106521976 B CN 106521976B CN 201611068014 A CN201611068014 A CN 201611068014A CN 106521976 B CN106521976 B CN 106521976B
Authority
CN
China
Prior art keywords
soybean oil
artificial leather
ecological
epoxidized soybean
pvc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201611068014.2A
Other languages
English (en)
Other versions
CN106521976A (zh
Inventor
李华令
刘华平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Suoya Decorative Materials Co Ltd
Original Assignee
Anhui Suoya Decorative Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Suoya Decorative Materials Co Ltd filed Critical Anhui Suoya Decorative Materials Co Ltd
Priority to CN201611068014.2A priority Critical patent/CN106521976B/zh
Publication of CN106521976A publication Critical patent/CN106521976A/zh
Application granted granted Critical
Publication of CN106521976B publication Critical patent/CN106521976B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/106—Roughness, anti-slip, abrasiveness
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/145—Oleophobic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1692—Weather resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

发明公开了一种生态型PVC装饰人造革，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉、改性环氧大豆油、非重金属色饼、稳定剂、发泡剂、改性绢云母；本发明通过对环氧大豆油进行改性以及特定的浆料配方的条件下，并且通过改性绢云母以及其他条件的配合下，可以极大的克服人造皮革易硬脆的缺点，尤其是，能够极大的改善人造革透气性和吸湿性差的问题。

Description

一种生态型PVC装饰人造革
技术领域
本发明涉及人造革制造领域，特别是涉及一种生态型PVC装饰人造革。
背景技术
人造革是最早发明用于皮质面料的代用品，它是用PVC加增塑剂和其他的助剂压延复合在布上制成。目前国内PVC装饰人造革生产过程中，通常采用增塑剂、PVC树脂粉、重钙、稳定剂、发泡剂、色饼等主要原料组成。这种人造革容易变硬、变脆，其中如增塑剂等化工原料会给装饰人造革带来环境污染。
发明内容
本发明的目的是提供一种生态型PVC装饰人造革。
本发明通过以下技术方案实现：
一种生态型PVC装饰人造革，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉110-115、改性环氧大豆油32-38、非重金属色饼 4-6、稳定剂1-3、发泡剂2-4、改性绢云母15-22。
进一步的，所述改性环氧大豆油按重量份计由以下成分制成：环氧大豆油100、丙烯酸酯4、松香2、氢氧化钠0.4，其制备方法为：
（1）按各重量份将环氧大豆油、丙烯酸酯、松香和氢氧化钠添加到反应釜，控制温度在128℃，持续2小时；
（2）将步骤（1）所得环氧大豆油进行蒸馏，控制压力1.8MPa，在118℃下持续3小时；
（3）将步骤（2）所得环氧大豆油进行水洗，将环氧大豆油与水混合后以800r/min转速搅拌30min，环氧大豆油与水的质量比为1:40；
（4）对步骤（3）所得环氧大豆油进行脱水，至环氧大豆油含水量小于1%，即得。
进一步的，所述改性绢云母制备方法为：将绢云母与硅藻土按100:1质量比例混合然后在350℃下煅烧20min，然后将混合后的绢云母研磨至500目，按1:2:80质量比例将马来酸酐、硅烷偶联剂和水均匀混合制成混合溶液，将混合后的绢云母与混合溶液均匀混合到一起，加热至80℃，保温4小时，然后过滤，采用清水清洗，烘干，即得改性绢云母。
进一步的，所述的稳定剂为PVC复合稳定剂。
进一步的，所述发泡剂为十二烷基硫酸钠。
进一步的，所述的压延法为将生态型PVC浆料的原料按各自重量份在120℃下高速搅拌后于165℃下密炼，得到生态型PVC浆料；将基材于120℃下上PU浆料开幅后，再与所述生态型PVC浆料进入四滚压延机于180℃下贴合，最后于235℃下进行发泡压花处理。
进一步的，所述高速搅拌的速度为2000r/min。
本发明的有益效果是，与现有技术相比：
本发明通过对环氧大豆油进行改性以及特定的浆料配方的条件下，并且通过改性绢云母以及其他条件的配合下，可以极大的克服人造皮革易硬脆的缺点，尤其是，能够极大的改善人造革透气性和吸湿性差的问题，本发明人造革内部形成有若干细小微孔，这些微孔可使人造革透气得到极大提高，并且不会降低人造革的机械性能，经过本发明对环氧大豆油的改性和对绢云母的改性，制备的人造革耐油性得极大的加强。通过本发明各成分之间的协同配合作用，制成的人造革不仅具有较好的机械性能(如拉伸负荷、断裂伸长率、撕裂伸长率、撕裂负荷等)，相较于普通人造革，本发明人造革拉伸负荷提高了20%左右，撕裂负荷提高了45%左右，还具有较佳的耐折牢度老化性能，该皮革通过了32000次耐折牢度实验，老化性能实验结果为不开裂。试验发现，本发明人造革表面的摩擦系数得到极大的提高，增加了防滑能力，使人手易于握持，保证了使用效果很好。
具体实施方式
实施例1
一种生态型PVC装饰人造革，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉110、改性环氧大豆油32、非重金属色饼 4、稳定剂1、发泡剂2、改性绢云母15。
实施例2
一种生态型PVC装饰人造革，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉115、改性环氧大豆油38、非重金属色饼6、稳定剂3、发泡剂4、改性绢云母22。
实施例3
一种生态型PVC装饰人造革，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉112、改性环氧大豆油34、非重金属色饼5、稳定剂2、发泡剂3、改性绢云母18。
以上实施例中：
进一步的，所述改性环氧大豆油按重量份计由以下成分制成：环氧大豆油100、丙烯酸酯4、松香2、氢氧化钠0.4，其制备方法为：
（1）按各重量份将环氧大豆油、丙烯酸酯、松香和氢氧化钠添加到反应釜，控制温度在128℃，持续2小时；
（2）将步骤（1）所得环氧大豆油进行蒸馏，控制压力1.8MPa，在118℃下持续3小时；
（3）将步骤（2）所得环氧大豆油进行水洗，将环氧大豆油与水混合后以800r/min转速搅拌30min，环氧大豆油与水的质量比为1:40；
（4）对步骤（3）所得环氧大豆油进行脱水，至环氧大豆油含水量小于1%，即得。
进一步的，所述改性绢云母制备方法为：将绢云母与硅藻土按100:1质量比例混合然后在350℃下煅烧20min，然后将混合后的绢云母研磨至500目，按1:2:80质量比例将马来酸酐、硅烷偶联剂和水均匀混合制成混合溶液，将混合后的绢云母与混合溶液均匀混合到一起，加热至80℃，保温4小时，然后过滤，采用清水清洗，烘干，即得改性绢云母。
进一步的，所述的稳定剂为PVC复合稳定剂。
进一步的，所述发泡剂为十二烷基硫酸钠。
进一步的，所述的压延法为将生态型PVC浆料的原料按各自重量份在120℃下高速搅拌后于165℃下密炼，得到生态型PVC浆料；将基材于120℃下上PU浆料开幅后，再与所述生态型PVC浆料进入四滚压延机于180℃下贴合，最后于235℃下进行发泡压花处理。
进一步的，所述高速搅拌的速度为2000r/min。
对比例1：与实施例3的区别仅为采用不经过处理的普通环氧大豆油。
对比例2：与实施例3的区别仅为采用不经过处理的普通绢云母。
对比例3：与实施例3的区别仅为将改性绢云母替换为贝壳粉。
人造革性能如下：
实施例1：经向拉伸负荷330N，纬向拉伸负荷242N，经向断裂伸长率12.6％，纬向断裂伸长率17.2％，撕裂强度为92N/mm，表面颜色牢度6级，通过32000次耐折牢度试验，老化性测试不开裂，耐油性佳。
实施例2：经向拉伸负荷331N，纬向拉伸负荷243N，经向断裂伸长率12..8％，纬向断裂伸长率17.5％，撕裂强度为93N/mm，表面颜色牢度6级，通过32000次耐折牢度试验，老化性测试不开裂，耐油性佳。
实施例3：经向拉伸负荷332N，纬向拉伸负荷244N，经向断裂伸长率12.9％，纬向断裂伸长率17.7％，撕裂强度为95N/mm，表面颜色牢度6级，通过32000次耐折牢度试验，老化性测试不开裂，耐油性佳。
对比例1：经向拉伸负荷302N，纬向拉伸负荷224N，经向断裂伸长率10.2％，纬向断裂伸长率16.2％，撕裂强度为77N/mm，表面颜色牢度6级，通过31000次耐折牢度试验，老化性测试不开裂，耐油性较差。
对比例2：经向拉伸负荷310N，纬向拉伸负荷228N，经向断裂伸长率10.5％，纬向断裂伸长率16.6％，撕裂强度为75N/mm，表面颜色牢度6级，通过31000次耐折牢度试验，老化性测试不开裂，耐油性一般。
对比例3：经向拉伸负荷302N，纬向拉伸负荷218N，经向断裂伸长率9.3％，纬向断裂伸长率15.2％，撕裂强度为71N/mm，表面颜色牢度6级，通过30000次耐折牢度试验，老化性测试不开裂，耐油性较差。
由以上试验结果可发现，本发明人造革质量优异。

Claims (5)

1.一种生态型PVC装饰人造革，其特征在于，该人造革利用生态型PVC浆料采用压延法制备而成，所述生态型PVC浆料按重量份计由以下成分制成：PVC树脂粉110-115、改性环氧大豆油32-38、非重金属色饼 4-6、稳定剂1-3、发泡剂2-4、改性绢云母15-22；所述改性环氧大豆油按重量份计由以下成分制成：环氧大豆油100、丙烯酸酯4、松香2、氢氧化钠0.4，其制备方法为：
（1）按各重量份将环氧大豆油、丙烯酸酯、松香和氢氧化钠添加到反应釜，控制温度在128℃，持续2小时；
（2）将步骤（1）所得环氧大豆油进行蒸馏，控制压力1.8MPa，在118℃下持续3小时；
（3）将步骤（2）所得环氧大豆油进行水洗，将环氧大豆油与水混合后以800r/min转速搅拌30min，环氧大豆油与水的质量比为1:40；
（4）对步骤（3）所得环氧大豆油进行脱水，至环氧大豆油含水量小于1%，即得；
所述改性绢云母制备方法为：将绢云母与硅藻土按100:1质量比例混合然后在350℃下煅烧20min，然后将混合后的绢云母研磨至500目，按1:2:80质量比例将马来酸酐、硅烷偶联剂和水均匀混合制成混合溶液，将混合后的绢云母与混合溶液均匀混合到一起，加热至80℃，保温4小时，然后过滤，采用清水清洗，烘干，即得改性绢云母。
2.根据权利要求1所述的生态型PVC装饰人造革，其特征在于，所述的稳定剂为PVC复合稳定剂。
3.根据权利要求1所述的生态型PVC装饰人造革，其特征在于，所述发泡剂为十二烷基硫酸钠。
4.根据权利要求1所述的生态型PVC装饰人造革，其特征在于，所述的压延法为将生态型PVC浆料的原料按各自重量份在120℃下高速搅拌后于165℃下密炼，得到生态型PVC浆料；将基材于120℃下上PU浆料开幅后，再与所述生态型PVC浆料进入四滚压延机于180℃下贴合，最后于235℃下进行发泡压花处理。
5.根据权利要求1所述的生态型PVC装饰人造革，其特征在于，所述高速搅拌的速度为2000r/min。
CN201611068014.2A 2016-11-29 2016-11-29 一种生态型pvc装饰人造革 Active CN106521976B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611068014.2A CN106521976B (zh) 2016-11-29 2016-11-29 一种生态型pvc装饰人造革

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611068014.2A CN106521976B (zh) 2016-11-29 2016-11-29 一种生态型pvc装饰人造革

Publications (2)

Publication Number Publication Date
CN106521976A CN106521976A (zh) 2017-03-22
CN106521976B true CN106521976B (zh) 2017-11-21

Family

ID=58353440

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611068014.2A Active CN106521976B (zh) 2016-11-29 2016-11-29 一种生态型pvc装饰人造革

Country Status (1)

Country Link
CN (1) CN106521976B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107090722A (zh) * 2017-05-16 2017-08-25 佛山高明骏宏塑胶有限公司 一种高钙的pvc人造革
CN107938371A (zh) * 2017-11-15 2018-04-20 佛山市高明区生产力促进中心 一种pvc人造革及其制备方法
CN109054222A (zh) * 2018-06-22 2018-12-21 安徽索亚装饰材料有限公司 一种清洁生态可降解pvc装饰人造革
CN108998988A (zh) * 2018-06-22 2018-12-14 安徽索亚装饰材料有限公司 一种环保耐磨可降解pvc装饰人造革

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838937B (zh) * 2010-05-27 2012-02-01 江苏国信合成革有限公司 一种生态型pvc装饰人造革及其制备方法
CN102660387B (zh) * 2012-04-12 2014-06-18 广州市博兴化工科技有限公司 一种丙烯酸酯改性环氧大豆油及其制备方法和应用
CN102851998B (zh) * 2012-09-04 2015-12-02 佛山威明塑胶有限公司 环保型pvc合成革及其制备方法
CN104480737A (zh) * 2014-10-23 2015-04-01 合肥金伶俐服饰有限公司 一种耐磨损聚氨酯合成革及其生产方法
CN105601591A (zh) * 2015-12-24 2016-05-25 宜兴市顺发化工有限公司 一种改性环氧大豆油及其制备方法

Also Published As

Publication number Publication date
CN106521976A (zh) 2017-03-22

Similar Documents

Publication Publication Date Title
CN106521976B (zh) 一种生态型pvc装饰人造革
CN101838937B (zh) 一种生态型pvc装饰人造革及其制备方法
CN102153792B (zh) 湿法混炼天然橡胶料的制备方法
CN103992590B (zh) 一种废旧塑料资源再生利用生产木塑材料的配方及其制备方法
CN106867448B (zh) 一种无石棉密封垫片的制作工艺
CN109776726B (zh) 丁苯橡胶的制备方法及丁苯橡胶
CN101456961A (zh) 一种反应型纳米碳酸钙-天然橡胶复合材料的制备方法
CN104292524A (zh) 一种改性天然橡胶电缆护套材料
CN104141259A (zh) 一种环保型阳离子苯丙表面施胶剂及其制备方法
CN105694104A (zh) 一种橡胶用纳米碳酸钙的制备方法
CN103820860A (zh) 一种对苯二甲酸金属盐片晶的制备方法及其应用
CN103360687A (zh) 一种高岭土/三元乙丙橡胶高耐久密封垫及其制备方法
CN106592259B (zh) 一种耐磨pvc装饰人造革
CN104004478A (zh) 一种酸解乙酰化淀粉胶粘剂的制作方法和应用
CN107286863B (zh) 一种高强度植物基胶黏剂及其制备方法
CN106519363A (zh) 一种氢化丁腈橡胶组合物
CN107964127A (zh) 一种金属离子增强的改性热塑性淀粉及其制备方法和应用
CN109399683B (zh) 一种pvc汽车底涂胶屈服增强用纳米碳酸钙的制备方法
CN104059389A (zh) 一种增加韧性的改性碳酸钙及其制备方法
CN104650414B (zh) 一种稻壳灰改性粉末丁二烯-丙烯腈聚合物的制备方法
CN103102549B (zh) 一种废弃磷矿渣-环氧化天然橡胶复合材料及其制备方法
CN103289526B (zh) 一种高耐水的粉末涂料
CN103483692A (zh) 一种铁路信号电缆护套料
CN104772810A (zh) 一种软木地板的生产工艺
CN102219981B (zh) 一种改性丙烯腈–丁二烯–苯乙烯共聚物及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant