CN106519820A - Ageing-resistant paint - Google Patents

Ageing-resistant paint Download PDF

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Publication number
CN106519820A
CN106519820A CN201610948911.6A CN201610948911A CN106519820A CN 106519820 A CN106519820 A CN 106519820A CN 201610948911 A CN201610948911 A CN 201610948911A CN 106519820 A CN106519820 A CN 106519820A
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CN
China
Prior art keywords
parts
fluorine
paint
ageing
raw materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610948911.6A
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Chinese (zh)
Inventor
不公告发明人
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Li Long Yun Intellectual Property Operation Co Ltd
Original Assignee
Sichuan Li Long Yun Intellectual Property Operation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Li Long Yun Intellectual Property Operation Co Ltd filed Critical Sichuan Li Long Yun Intellectual Property Operation Co Ltd
Priority to CN201610948911.6A priority Critical patent/CN106519820A/en
Publication of CN106519820A publication Critical patent/CN106519820A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses ageing-resistant paint and belongs to the field of building materials. The paint is composed of following raw materials including, by weight, 3.5-8 parts of fluorine modified styrene-acrylic latex, 1.2-2.4 parts of colorized slices, 1.3-3.7 parts of fluorocarbon modified ammonium polyacrylate, 0.8-2.2 parts of ethanediol, 1.2-3 parts of isotridecyloxy propylamine, 1.3-3.4 parts of bisphenethylphenol polyoxyethylene ether, 2.3-3.5 parts of dibutyl phthalate and 1.3-2.6 parts of dihydroquinoline. Compared with existing anti-aging paint, the ageing-resistant paint can be used for roof waterproofing and is not prone to being aged, cracked, deformed, broken and layered; the ageing-resistant paint can be used for indoor waterproofing, as for the places in complex shapes, construction is simple and convenient, the leakage appearance protection is good, the paint does not need to be reworked for long time, the building life of a whole building is prolonged. Meanwhile, the ageing-resistant paint has the advantages of easy construction, low temperature resistance and good storage stability.

Description

A kind of aging resistant coating
Technical field
The present invention relates to building material field, more particularly to a kind of aging resistant coating.
Background technology
Coating act as decorating and protects, and protects the surface for being applied jewelry, prevent from extraneous light, oxygen, chemical substance, The erosion of solvent etc., improves the service life for being applied thing, and paint finishing material surface changes its color, decorative pattern, gloss, matter Sense etc., improves the aesthetic value of object.Building coating mode classification is various, and row are as by use environment point inner-outer wall, ground and top Canopy coating;By the organic and inorganic and organic-inorganic hybrid coatings of main film forming substance point;By the state point water of main film forming substance Dissolubility, type of latex type and solvent borne powder-type;According to decoration functions point planomural shape, sand wall-like and three-dimensional pattern shape;By specific function Divide fire prevention, waterproof, mould proof and anti-condensation etc..
In existing decoration of exterior wall protection technique, people coat anti-on exterior wall in order to protect decoration of exterior wall, typically Water paint.However, existing exterior wall waterproofing coating common on the market, its product quality is uneven, after coating on the short time also It is with preferable waterproof effect.But, increasing over time, conventional coating just occurs whiting, jaundice, emetine phenomenon, The generally existing anti-aging phase is short, and dirty dirt, ink can not be cleaned, moisture-proof, the shortcomings of water-fast, washing fastness is poor, in outdoor buildings Top surface service life is short, therefore some products are only limitted to indoor use, and as its raw material mostly adopts new material, causes life Produce relatively costly.They more or less exist some such as easily aging, peelings, it is easy to fall off, can change colour, weatherability is poor, poisonous There are the defects such as taste, construction inconvenience.And, most this coating, as use time increases, can also produce foaming phenomena, So that paint film surface is uneven, the slickness of paint film is affected, and then is accumulated dust, cause overall appearance effect day condition to heal Difference.
The content of the invention
It is an object of the invention to the above-mentioned deficiency in the presence of overcoming prior art, there is provided a kind of aging resistant coating, tool Have and be easy to construction, ageing-resistant, low temperature resistant, the good advantage of storage stability.
In order to realize foregoing invention purpose, the invention provides technical scheme below:
A kind of aging resistant coating, is prepared from the following raw materials in parts by weight:Fluorine richness styrene-acrylic latex 3.5-8 parts, colored rock Piece 1.2-2.4 parts, fluorine-carbon modified ammonium polyacrylate salt 1.3-3.7 part, ethylene glycol 0.8-2.2 parts, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine 1.2-3 parts, double phenethyl phenol polyethenoxy ether 1.3-3.4 parts, dibutyl phthalate 2.3-3.5 parts and dihyaroquinoline 1.3-2.6 part.
Preferably, above-mentioned aging resistant coating, is prepared from the following raw materials in parts by weight:Fluorine richness styrene-acrylic latex 4.2-7.6 Part, colored sliver 1.3-2.1 parts, fluorine-carbon modified ammonium polyacrylate salt 1.5-3.5 part, ethylene glycol 0.9-2 parts, isotridecyloxypropylpolyoxyethylene polyoxyethylene base Propyl group amine 1.5-2.6 parts, double phenethyl phenol polyethenoxy ether 1.6-3.2 parts, dibutyl phthalate 2.5-3.2 parts and dihydro Change quinoline 1.5-2.4 parts.
It is furthermore preferred that above-mentioned aging resistant coating, is prepared from the following raw materials in parts by weight:Fluorine richness styrene-acrylic latex 4.5- 7.2 parts, colored sliver 1.5-1.9 parts, fluorine-carbon modified ammonium polyacrylate salt 1.8-3.2 part, ethylene glycol 1.1-1.8 parts, different 13 Alkoxyl propyl group amine 1.8-2.3 parts, double phenethyl phenol polyethenoxy ether 1.9-2.8 parts, dibutyl phthalate 2.8-3.1 parts With dihyaroquinoline 1.7-2.3 parts.
Most preferably, above-mentioned aging resistant coating, is prepared from the following raw materials in parts by weight:5.6 parts of fluorine richness styrene-acrylic latex, 1.7 parts of colored sliver, 2.5 parts of fluorine-carbon modified ammonium polyacrylate salt, 1.4 parts of ethylene glycol, 2.1 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, 1.9 parts of 2.3 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of dibutyl phthalate and dihyaroquinoline.
Compared with prior art, beneficial effects of the present invention:
It is of the invention to can be used to roof waterproof compared with existing aging resistant coating, non-aging, dry and cracked, deformation, folding Disconnected, layering;Can be used for indoor waterproof, for complex-shaped place, easy construction, seepage is manifested and is protected, long-time Without reprocessing, the service life of whole building building is increased.Simultaneously have and be easy to construction, low temperature resistant, good excellent of storage stability Point.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood Scope for above-mentioned theme of the invention is only limitted to below example, and all technologies realized based on present invention belong to this The scope of invention
Embodiment 1
The present invention is a kind of aging resistant coating, is prepared from the following raw materials in parts by weight:5.6 parts of fluorine richness styrene-acrylic latex, 1.7 parts of colored sliver, 2.5 parts of fluorine-carbon modified ammonium polyacrylate salt, 1.4 parts of ethylene glycol, 2.1 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, 1.9 parts of 2.3 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of dibutyl phthalate and dihyaroquinoline.
Embodiment 2
The present invention is a kind of aging resistant coating, is prepared from the following raw materials in parts by weight:3.5 parts of fluorine richness styrene-acrylic latex, It is 1.2 parts of colored sliver, 1.3 parts of fluorine-carbon modified ammonium polyacrylate salt, 0.8 part of ethylene glycol, 3 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, double 2.6 parts of 3.4 parts of phenethyl phenol polyethenoxy ether, 3.5 parts of dibutyl phthalate and dihyaroquinoline.
Embodiment 3
The present invention is a kind of aging resistant coating, is prepared from the following raw materials in parts by weight:8 parts of fluorine richness styrene-acrylic latex, coloured silk It is 2.4 parts of color sliver, 3.7 parts of fluorine-carbon modified ammonium polyacrylate salt, 0.8 part of ethylene glycol, 1.2 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, double 1.3 parts of 1.3 parts of phenethyl phenol polyethenoxy ether, 2.3 parts of dibutyl phthalate and dihyaroquinoline.
Embodiment 4
The present invention is a kind of aging resistant coating, is prepared from the following raw materials in parts by weight:5 parts of fluorine richness styrene-acrylic latex, coloured silk 2 parts of color sliver, 2 parts of fluorine-carbon modified ammonium polyacrylate salt, 1 part of ethylene glycol, 2 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, double phenethyl phenols 2 parts of 2 parts of APEO, 3 parts of dibutyl phthalate and dihyaroquinoline.
Embodiment 5
The present invention is a kind of aging resistant coating, is prepared from the following raw materials in parts by weight:4 parts of fluorine richness styrene-acrylic latex, coloured silk 2 parts of color sliver, 3 parts of fluorine-carbon modified ammonium polyacrylate salt, 2 parts of ethylene glycol, 2 parts of isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine, double phenethyl phenols 2 parts of 2 parts of APEO, 3 parts of dibutyl phthalate and dihyaroquinoline.
Water-repellent paint obtained by above example, which is used for the construction method of external wall and requires as follows:
Substrate surface is clean, is dried, cleaning, free from dust, and without greasy dirt, such as basic unit is untreated good, and the easy peeling of film can affect Waterproof effect.The crack of metope, it is smooth that hole position should mix putty repairing with marine glue addition cement in advance.External wall construction is not Must be less than two times, every square of 0.8-1.2kg of film consumption, with painting brush, Cylinder coating brush.The abundant solidification of Jing 72h, determines which Coating performance, its coating impact strength》87cm, artificial accelerated aging time》3050h, heat resistance》580, exposure to weather(ing) 12 Month non-foaming, non-corrosive, does not ftracture, does not peel off.
Certainly, described above is not limitation of the present invention, and the present invention is also not limited to the example above, the art Those of ordinary skill, in the essential scope of the present invention, the change made, remodeling, addition or replace, should all belong to of the invention Protection domain.

Claims (4)

1. a kind of aging resistant coating, it is characterised in that:It is prepared from the following raw materials in parts by weight:Fluorine richness styrene-acrylic latex 3.5-8 Part, colored sliver 1.2-2.4 parts, fluorine-carbon modified ammonium polyacrylate salt 1.3-3.7 part, ethylene glycol 0.8-2.2 parts, isotridecyloxypropylpolyoxyethylene polyoxyethylene Base propyl group amine 1.2-3 parts, double phenethyl phenol polyethenoxy ether 1.3-3.4 parts, dibutyl phthalate 2.3-3.5 parts and dihydro Change quinoline 1.3-2.6 parts.
2. aging resistant coating according to claim 1, it is characterised in that:It is prepared from the following raw materials in parts by weight:Fluorine changes Property styrene-acrylic latex 4.2-7.6 parts, colored sliver 1.3-2.1 parts, fluorine-carbon modified ammonium polyacrylate salt 1.5-3.5 part, ethylene glycol 0.9-2 parts, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine 1.5-2.6 parts, double phenethyl phenol polyethenoxy ether 1.6-3.2 parts, phthalic acid Dibutyl ester 2.5-3.2 parts and dihyaroquinoline 1.5-2.4 parts.
3. aging resistant coating according to claim 2, it is characterised in that:It is prepared from the following raw materials in parts by weight:Fluorine changes Property styrene-acrylic latex 4.5-7.2 parts, colored sliver 1.5-1.9 parts, fluorine-carbon modified ammonium polyacrylate salt 1.8-3.2 part, ethylene glycol 1.1-1.8 parts, isotridecyloxypropylpolyoxyethylene polyoxyethylene base propyl group amine 1.8-2.3 parts, double phenethyl phenol polyethenoxy ether 1.9-2.8 parts, O-phthalic Dibutyl phthalate 2.8-3.1 parts and dihyaroquinoline 1.7-2.3 parts.
4. aging resistant coating according to claim 3, it is characterised in that:It is prepared from the following raw materials in parts by weight:Fluorine changes Property 5.6 parts of styrene-acrylic latex, colored 1.7 parts of sliver, 2.5 parts of fluorine-carbon modified ammonium polyacrylate salt, 1.4 parts of ethylene glycol, different tridecane 2.1 parts of epoxide propyl group amine, 2.3 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of dibutyl phthalate and dihyaroquinoline 1.9 Part.
CN201610948911.6A 2016-10-26 2016-10-26 Ageing-resistant paint Pending CN106519820A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610948911.6A CN106519820A (en) 2016-10-26 2016-10-26 Ageing-resistant paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610948911.6A CN106519820A (en) 2016-10-26 2016-10-26 Ageing-resistant paint

Publications (1)

Publication Number Publication Date
CN106519820A true CN106519820A (en) 2017-03-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610948911.6A Pending CN106519820A (en) 2016-10-26 2016-10-26 Ageing-resistant paint

Country Status (1)

Country Link
CN (1) CN106519820A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417783A (en) * 2011-10-10 2012-04-18 漳州市奈特新型建材有限责任公司 Waterproof/sealing paint with aqueous resin as main body
CN103554850A (en) * 2013-10-25 2014-02-05 苏笮斌 Environment-friendly type anti-cracking corrosion-resistant waterproof material and preparation method thereof
CN104789057A (en) * 2015-05-07 2015-07-22 广州爱迪斯建筑材料有限公司 Colored organic fluorine-modified styrene-acrylic waterproof paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417783A (en) * 2011-10-10 2012-04-18 漳州市奈特新型建材有限责任公司 Waterproof/sealing paint with aqueous resin as main body
CN103554850A (en) * 2013-10-25 2014-02-05 苏笮斌 Environment-friendly type anti-cracking corrosion-resistant waterproof material and preparation method thereof
CN104789057A (en) * 2015-05-07 2015-07-22 广州爱迪斯建筑材料有限公司 Colored organic fluorine-modified styrene-acrylic waterproof paint and preparation method thereof

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Application publication date: 20170322

RJ01 Rejection of invention patent application after publication