CN106497344A - A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient - Google Patents
A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient Download PDFInfo
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- CN106497344A CN106497344A CN201610948374.5A CN201610948374A CN106497344A CN 106497344 A CN106497344 A CN 106497344A CN 201610948374 A CN201610948374 A CN 201610948374A CN 106497344 A CN106497344 A CN 106497344A
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- vinyl ester
- ester resin
- aldehyde type
- type vinyl
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, belongs to building material field.The coating is prepared from the following raw materials in parts by weight：1.3 2.6 parts of 3.5 8 parts of phenol aldehyde type vinyl ester resin, 1.2 2.4 parts of feldspar powder, 1.3 3.7 parts of coumarone indene resin, 0.8 2.2 parts of wollastonite, 1.2 3 parts of diisooctyl succinate sulfonate, 1.3 3.4 parts of double phenethyl phenol polyethenoxy ethers, 2.3 3.5 parts of polyoxyethylene carboxylate phosphate and dihyaroquinoline.Of the invention can be used to roof waterproof compared with existing aging resistant coating, non-aging, dry and cracked, deform, fracture, being layered；Can be used for indoor waterproof, for complex-shaped place, easy construction, seepage is manifested and is protected, for a long time without reprocessing, increased the service life of whole building building.Have simultaneously and be easy to construct, low temperature resistant, the good advantage of storage stability.
Description
Technical field
The present invention relates to building material field, more particularly to a kind of ageing-resistant with phenol aldehyde type vinyl ester resin as major ingredient
Coating.
Background technology
Coating act as decorating and protects, and protects the surface for being applied jewelry, prevent from extraneous light, oxygen, chemical substance,
The erosion of solvent etc., improves the service life for being applied thing, and paint finishing material surface changes its color, decorative pattern, gloss, matter
Sense etc., improves the aesthetic value of object.Building coating mode classification is various, and row are as by use environment point inner-outer wall, ground and top
Canopy coating；By the organic and inorganic and organic-inorganic hybrid coatings of main film forming substance point；State point water by main film forming substance
Dissolubility, type of latex type and solvent borne powder-type；According to decoration functions point planomural shape, sand wall-like and three-dimensional pattern shape；Press specific function
Divide fire prevention, waterproof, mould proof and anti-condensation etc..
In existing decoration of exterior wall protection technique, people coat anti-on exterior wall in order to protect decoration of exterior wall, typically
Water paint.However, existing exterior wall waterproofing coating common on the market, its product quality is uneven, after coating on the short time also
It is with preferable waterproof effect.But, increasing over time, conventional coating just occurs whiting, jaundice, emetine phenomenon,
The generally existing aging resistance phase is short, and dirty dirt, ink can not be cleaned, moisture-proof, the shortcomings of water-fast, washing fastness is poor, in outdoor buildings
Top surface service life is short, therefore some products are only limitted to indoor use, and as its raw material is mostly using new material, causes to give birth to
Produce relatively costly.They more or less exist some such as easily aging, peeling, easy to fall off, can change colour, weatherability is poor, poisonous
There are the defects such as taste, construction inconvenience.And, most this coating, as use time increases, can also produce foaming phenomena,
So that paint film surface is uneven, the slickness of paint film is affected, and then is accumulated dust, cause overall appearance effect day condition to heal
Difference.
Content of the invention
It is an object of the invention to the above-mentioned deficiency in the presence of overcoming prior art, there is provided one kind is with phenol aldehyde type vinyl
Aging resistant coating of the ester resin for major ingredient, with being easy to construct, ageing-resistant, low temperature resistant, the good advantage of storage stability.
In order to realize foregoing invention purpose, the invention provides technical scheme below：
A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, is prepared from the following raw materials in parts by weight：
Phenol aldehyde type vinyl ester resin 3.5-8 parts, feldspar powder 1.2-2.4 parts, coumarone indene resin 1.3-3.7 parts, wollastonite 0.8-2.2
Part, diisooctyl succinate sulfonate 1.2-3 part, double phenethyl phenol polyethenoxy ether 1.3-3.4 parts, aliphatic acid polyethenoxy
Ester phosphate 2.3-3.5 parts and dihyaroquinoline 1.3-2.6 parts.
Preferably, the above-mentioned aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：Phenol aldehyde type vinyl ester resin 4.2-7.6 parts, feldspar powder 1.3-2.1 parts, coumarone indene resin 1.5-3.5 parts, wollastonite
0.9-2 parts, diisooctyl succinate sulfonate 1.5-2.6 part, double phenethyl phenol polyethenoxy ether 1.6-3.2 parts, fatty acid
Polyoxyethylene ester phosphate 2.5-3.2 parts and dihyaroquinoline 1.5-2.4 parts.
It is furthermore preferred that the above-mentioned aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by following parts by weight
Raw material is made：Phenol aldehyde type vinyl ester resin 4.5-7.2 parts, feldspar powder 1.5-1.9 parts, coumarone indene resin 1.8-3.2 parts, silicon ash
Stone 1.1-1.8 parts, diisooctyl succinate sulfonate 1.8-2.3 part, double phenethyl phenol polyethenoxy ether 1.9-2.8 parts, fat
Fat acid polyoxyethylene ester phosphate 2.8-3.1 parts and dihyaroquinoline 1.7-2.3 parts.
Most preferably, the above-mentioned aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by following parts by weight
Raw material is made：5.6 parts of phenol aldehyde type vinyl ester resin, 1.7 parts of feldspar powder, 2.5 parts of coumarone indene resin, 1.4 parts of wollastonite, two different
2.1 parts of octyl group succinate sulfonate, 2.3 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of polyoxyethylene carboxylate phosphate and
1.9 parts of dihyaroquinoline.
Compared with prior art, beneficial effects of the present invention：
Of the invention can be used to roof waterproof compared with existing aging resistant coating, non-aging, dry and cracked, deformation, folding
Disconnected, layering；Can be used for indoor waterproof, for complex-shaped place, easy construction, seepage is manifested and is protected, for a long time
Without reprocessing, the service life of whole building building is increased.Simultaneously have and be easy to construct, low temperature resistant, good excellent of storage stability
Point.
Specific embodiment
With reference to test example and specific embodiment, the present invention is described in further detail.But this should not be understood
Scope for above-mentioned theme of the invention is only limitted to below example, and all technology that is realized based on present invention belong to this
The scope of invention
Embodiment 1
The present invention is a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：5.6 parts of phenol aldehyde type vinyl ester resin, 1.7 parts of feldspar powder, 2.5 parts of coumarone indene resin, 1.4 parts of wollastonite, two different pungent
2.1 parts of base succinate sulfonate, 2.3 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of polyoxyethylene carboxylate phosphate and two
1.9 parts of hydrogenated quinoline.
Embodiment 2
The present invention is a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：3.5 parts of phenol aldehyde type vinyl ester resin, 1.2 parts of feldspar powder, 1.3 parts of coumarone indene resin, 0.8 part of wollastonite, two different pungent
3 parts of base succinate sulfonate, 3.4 parts of double phenethyl phenol polyethenoxy ethers, 3.5 parts of polyoxyethylene carboxylate phosphate and two
2.6 parts of hydrogenated quinoline.
Embodiment 3
The present invention is a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：8 parts of phenol aldehyde type vinyl ester resin, 2.4 parts of feldspar powder, 3.7 parts of coumarone indene resin, 0.8 part of wollastonite, diisooctyl
1.2 parts of succinate sulfonate, 1.3 parts of double phenethyl phenol polyethenoxy ethers, 2.3 parts of polyoxyethylene carboxylate phosphate and two
1.3 parts of hydrogenated quinoline.
Embodiment 4
The present invention is a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：5 parts of phenol aldehyde type vinyl ester resin, 2 parts of feldspar powder, 2 parts of coumarone indene resin, 1 part of wollastonite, diisooctyl succinic acid
2 parts of 2 parts of sulfonated ester, 2 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of polyoxyethylene carboxylate phosphate and dihyaroquinoline.
Embodiment 5
The present invention is a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, by the original of following parts by weight
Material is made：4 parts of phenol aldehyde type vinyl ester resin, 2 parts of feldspar powder, 3 parts of coumarone indene resin, 2 parts of wollastonite, diisooctyl succinic acid
2 parts of 2 parts of sulfonated ester, 2 parts of double phenethyl phenol polyethenoxy ethers, 3 parts of polyoxyethylene carboxylate phosphate and dihyaroquinoline.
Water-repellent paint obtained by above example, its are used for the construction method of external wall and require as follows：
Substrate surface is clean, dries, cleaning, free from dust, and without greasy dirt, such as basic unit is untreated good, and the easy peeling of film can affect
Waterproof effect.The crack of metope, it is smooth that hole position should mix putty repairing with marine glue interpolation cement in advance.External wall construction is not
Must be less than two times, every square of 0.8-1.2kg of film consumption, with painting brush, Cylinder coating brush.Through the abundant solidification of 72h, which is determined
Coating performance, its coating impact strength》93cm, artificial accelerated aging time》2900h, heat resistance》570, exposure to weather(ing) 12
Month non-foaming, non-corrosive, does not ftracture, does not peel off.
Certainly, described above is not limitation of the present invention, and the present invention is also not limited to the example above, the art
Those of ordinary skill, in the essential scope of the present invention, the change made, remodeling, add or replace, should all belong to of the invention
Protection domain.
Claims (4)
1. a kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient, it is characterised in that：By following parts by weight
Raw material is made：Phenol aldehyde type vinyl ester resin 3.5-8 parts, feldspar powder 1.2-2.4 parts, coumarone indene resin 1.3-3.7 parts, wollastonite
0.8-2.2 parts, diisooctyl succinate sulfonate 1.2-3 part, double phenethyl phenol polyethenoxy ether 1.3-3.4 parts, fatty acid
Polyoxyethylene ester phosphate 2.3-3.5 parts and dihyaroquinoline 1.3-2.6 parts.
2. the aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient according to claim 1, it is characterised in that：By
The raw material of following parts by weight is made：Phenol aldehyde type vinyl ester resin 4.2-7.6 parts, feldspar powder 1.3-2.1 parts, coumarone indene resin
1.5-3.5 parts, wollastonite 0.9-2 parts, diisooctyl succinate sulfonate 1.5-2.6 part, double phenethyl phenol polyethenoxy ethers
1.6-3.2 parts, polyoxyethylene carboxylate phosphate 2.5-3.2 parts and dihyaroquinoline 1.5-2.4 parts.
3. the aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient according to claim 2, it is characterised in that：By
The raw material of following parts by weight is made：Phenol aldehyde type vinyl ester resin 4.5-7.2 parts, feldspar powder 1.5-1.9 parts, coumarone indene resin
1.8-3.2 parts, wollastonite 1.1-1.8 parts, diisooctyl succinate sulfonate 1.8-2.3 part, double phenethyl phenol Polyethylene oxide
Ether 1.9-2.8 parts, polyoxyethylene carboxylate phosphate 2.8-3.1 parts and dihyaroquinoline 1.7-2.3 parts.
4. the aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient according to claim 3, it is characterised in that：By
The raw material of following parts by weight is made：5.6 parts of phenol aldehyde type vinyl ester resin, 1.7 parts of feldspar powder, 2.5 parts of coumarone indene resin, silicon
1.4 parts of lime stone, 2.1 parts of diisooctyl succinate sulfonate, 2.3 parts of double phenethyl phenol polyethenoxy ethers, fatty acid polyoxy second
1.9 parts of 3 parts of alkene ester phosphate and dihyaroquinoline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610948374.5A CN106497344A (en) | 2016-10-26 | 2016-10-26 | A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610948374.5A CN106497344A (en) | 2016-10-26 | 2016-10-26 | A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106497344A true CN106497344A (en) | 2017-03-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610948374.5A Pending CN106497344A (en) | 2016-10-26 | 2016-10-26 | A kind of aging resistant coating with phenol aldehyde type vinyl ester resin as major ingredient |
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| Country | Link |
|---|---|
| CN (1) | CN106497344A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN103554850A (en) * | 2013-10-25 | 2014-02-05 | 苏笮斌 | Environment-friendly type anti-cracking corrosion-resistant waterproof material and preparation method thereof |
-
2016
- 2016-10-26 CN CN201610948374.5A patent/CN106497344A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN103554850A (en) * | 2013-10-25 | 2014-02-05 | 苏笮斌 | Environment-friendly type anti-cracking corrosion-resistant waterproof material and preparation method thereof |
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| C06 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170315 |
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| RJ01 | Rejection of invention patent application after publication |