CN106519382A - Low-friction-factor low-smoke halogen-free insulation shielding material - Google Patents
Low-friction-factor low-smoke halogen-free insulation shielding material Download PDFInfo
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- CN106519382A CN106519382A CN201610947680.7A CN201610947680A CN106519382A CN 106519382 A CN106519382 A CN 106519382A CN 201610947680 A CN201610947680 A CN 201610947680A CN 106519382 A CN106519382 A CN 106519382A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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Abstract
The invention discloses a low-friction-factor low-smoke halogen-free insulation shielding material which is prepared from the following raw materials in parts by weight: 40-45 parts of low-density polyethylene, 11-13 parts of ammonium polyphosphate, 0.3-0.5 part of OP10, 12-15 parts of ethyl orthosilicate, 8-10 parts of glass powder, 4-6 parts of niobium diboride, 2.2-2.5 parts of natural latex, 0.2-0.4 part of antioxidant 1010, 2.3-2.5 parts of agar, 3-3.5 parts of graphene, 6.6-8 parts of calcium carbonate, 1.3-1.6 parts of stearic acid, 2.2-3 parts of oxygen delignification, 14-18 parts of ambary fiber, 2.4-3 parts of epoxypropane, 24-28 parts of polyphenylene oxide, a right amount of anhydrous ethanol and a right amount of deionized water. The prepared cable material has the advantages of favorable ultraviolet aging resistance, higher electric insulativity, higher heat resistance, higher corrosion resistance, higher oil resistance, higher flame retardancy, higher fire resistance, simple preparation method, operable process, precise dimension and the like, and is worthy of popularization.
Description
Technical field
A kind of the present invention relates to CABLE MATERIALS technical field, more particularly to low-friction coefficient low smoke and zero halogen insulating protection material.
Background technology
Low Density Polyethylene is as viscosity in process is relatively low and in drawing process has high fondant-strength same
When also have both not available for the conventional materials such as extremely strong resistance to chemical attack, acid and alkali-resistance, oil resistant, the nontoxic, long service life of light weight
It is advantage, therefore its range of application is throughout development and the various aspects of people's lives of national economy, such as electric wire, defeated
Send pipeline, automotive trim and construction material etc..But the oxygen index value of polyethylene is low, inflammable, and under field conditions (factors), with regard to energy
Deflagrate, thermal discharge are big, worse with molten drop behavior, may cause spot fire, and also can during decomposes
A large amount of toxic and harmfuls are volatilized, people life property safety is threatened, and resistance to water is also poor, cause its application to be received
To restriction.So needing fire-retardant to which, and water resistance is improved, reduce the probability that fire hazard occurs, therefore which is carried out fire-retardant
Process is particularly important.
《The preparation and its performance study of expansible fire retardant low-density polyethylene》One literary author is poly- for current low-density
There is the technical barrier of poor water resistance during vinyl material halogen-free flameproof, using macromolecular carbon forming technology and encapsulation skill
The mode that art combines, development of new is water-fast halogen-free expanded flame-retardant LDPE Composite, wherein carbon forming agent select three
The APP of piperazine analog derivative CFA, dehydrant and foaming agent from Silica hydrogel parcel, this new Low Density Polyethylene material
Material not only has higher thermal stability and fire resistance, while also overcoming the difficulty of poor water resistance.Although present invention solution
Low density polyethylene fire retardant of having determined is poor, the problem of poor water resistance, improves polyethylene safety coefficient in use, but
Be Low Density Polyethylene however for high pressure field direct current cables in running, the low conductivity characteristic of polyethylene is caused
The space charge of accumulated inside is difficult to spread, and causes the Severe distortion of local field strength, especially when there is temperature in oepration at full load
During Gradient Effect, this phenomenon is even more serious, when surface of insulating layer local field strength reaches certain value, will cause shelf depreciation,
The insulation ag(e)ing phenomenon such as resinification, substantially reduces the service life of cable, to this improve polyethylene anti-flaming, water resistance it is same
When, improve its insulating properties and particularly seem urgent.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided a kind of low-friction coefficient low smoke and zero halogen insulation is anti-
Protective material.
The present invention is achieved by the following technical solutions：
A kind of low-friction coefficient low smoke and zero halogen insulating protection material, is made up of the raw material of following weight portion：Low density polyethylene
It is alkene 40-45, APP 11-13, OP100.3-0.5, tetraethyl orthosilicate 12-15, glass dust 8-10, niobium dioxide 4-6, natural
Latex 2.2-2.5, antioxidant 1010 0.2-0.4, agar 2.3-2.5, Graphene 3-3.5, Calcium Carbonate 6.6-8, stearic acid
1.3-1.6, oxygen delignification 2.2-3, bastose 14-18, expoxy propane 2.4-3, polyphenylene oxide 24-28, appropriate dehydrated alcohol, go
Ion appropriate amount of water.
A kind of low-friction coefficient low smoke and zero halogen insulating protection material, is made up of step in detail below：
（1）By deionized water and dehydrated alcohol in mass ratio 1:2 are added in flask, warming while stirring to 40 DEG C, add poly- phosphorus
Sour ammonium stirring dissolves which, is slowly added to OP10, and with ammonia regulation system pH value 9-10, continues in the backward above-mentioned solution of dissolving
Stirring 10-20min, then tetraethyl orthosilicate is added in above-mentioned solution, after completion of dropping, continue reaction 2-3h, finally cool down
To room temperature, filter, be dried, wash and be put into dry product in baking oven；
（2）By expoxy propane and bastose stirring mixing, then stir in blender with polyphenylene oxide, antioxidant 1010, agar
Mix uniform, be then added to extruding pelletization in extruder, dry, extrusion temperature is 210-220 DEG C, screw speed 220-240 is stopped
Time 3-5min, pressure are 12-18MPa；
（3）The mixing of niobium dioxide, Calcium Carbonate and stearic acid is added in high-speed mixer, 100 DEG C is heated to, with 400 revs/min
After speed stirring 15min, add glass dust to continue to stir to obtain mixed-powder, the 8-9 times of anhydrous second measured will be added in natural emulsion
In alcohol, above-mentioned mixed-powder after stirring and dissolving, is added, stirred 40 minutes with 800 revs/min of rotating speed, be dried；
（4）By step（3）The product of preparation adds the 3-4 times of dimethylbenzene for measuring part, ultrasonic disperse 20-30min to add Graphene
Continue ultrasound uniform, scattered suspension is heated to into boiling under mechanical agitation, add 10% Low Density Polyethylene
Continue stirring 3h, be then added to dehydrated alcohol and deionized water volume ratio 1:In 1 solution, filter, be dried；
（5）By step（1）And step（2）The product of preparation is dried 5-6h in vacuum drying oven at 80 DEG C, after taking-up and step
（4）The product of preparation, remaining leftover materials temperature in double-roll rolling mill is 150 DEG C, and rotating speed is 60 revs/min of melt blending 10-
15min, it is compressing after in 80 DEG C of vacuum drying close annealing, short-circuit 24h, after room temperature is at the uniform velocity down to 5 DEG C/min.
It is an advantage of the invention that：The present invention is grafted bastose using polyphenylene oxide, strengthens the compatibility with polyethylene, and
Play a part of charcoal source in high temperature, and ammonium polyphosphate modifying generates intumescent carbon-coating together, is attached to material surface, prevent
Heat and the contact for having prevented with oxygen, reduce imflammable gas again diffuses speed, improve the anti-flammability of material
Can, intermolecular force is produced between the mixed-powder and Low Density Polyethylene of preparation, and eliminates compacting in vacuum drying oven
During the residual stress that produces, make the crystal habit of material more perfect, eliminate the internal sky for producing in Sample Preparation Procedure
Between electric charge, improve breakdown strength, play good insulating effect, and also enhance the property such as the wear-resisting of cable material, anti-attrition
Can, CABLE MATERIALS prepared by the present invention has an anti-ultraviolet aging function admirable, electrical insulating property, heat-resisting, corrosion-resistant, oil resistant, fire-retardant,
The advantages of fire protecting performance is higher, preparation method are simple, and process is easy to operate, accurate size, is worthy to be popularized.
Specific embodiment
A kind of low-friction coefficient low smoke and zero halogen insulating protection material, by following weight portion（Kilogram）Raw material make：
Low Density Polyethylene 40, APP 11, OP100.3, tetraethyl orthosilicate 12, glass dust 8, niobium dioxide 4, Heveatex 2.2,
Antioxidant 1010 0.2, agar 2.3, Graphene 3, Calcium Carbonate 6.6, stearic acid 1.3, oxygen delignification 2.2, bastose 14, ring
Ethylene Oxide 2.4, polyphenylene oxide 24, appropriate dehydrated alcohol, appropriate deionized water.
A kind of low-friction coefficient low smoke and zero halogen insulating protection material, is made up of step in detail below：
（1）By deionized water and dehydrated alcohol in mass ratio 1:2 are added in flask, warming while stirring to 40 DEG C, add poly- phosphorus
Sour ammonium stirring dissolves which, is slowly added to OP10, and with ammonia regulation system pH value 9, continues to stir in the backward above-mentioned solution of dissolving
10min is mixed, then tetraethyl orthosilicate is added in above-mentioned solution, after completion of dropping, continued reaction 2h, be finally cooled to room temperature,
Filter, be dried, wash and be put into dry product in baking oven；
（2）By expoxy propane and bastose stirring mixing, then stir in blender with polyphenylene oxide, antioxidant 1010, agar
Mix uniform, be then added to extruding pelletization in extruder, dry, extrusion temperature is 210 DEG C, screw speed 220, the time of staying
3min, pressure are 12MPa；
（3）The mixing of niobium dioxide, Calcium Carbonate and stearic acid is added in high-speed mixer, 100 DEG C is heated to, with 400 revs/min
After speed stirring 15min, add glass dust to continue to stir to obtain mixed-powder, the dehydrated alcohol of 8 times of amounts will be added in natural emulsion
In, above-mentioned mixed-powder is added after stirring and dissolving, is stirred 40 minutes with 800 revs/min of rotating speed, be dried；
（4）By step（3）The product of preparation adds the dimethylbenzene of 3 times of amount parts, ultrasonic disperse 20min to add Graphene continuation
It is ultrasonic uniform, scattered suspension is heated to into boiling under mechanical agitation, adds 10% Low Density Polyethylene to continue
Stirring 3h, is then added to dehydrated alcohol and deionized water volume ratio 1:In 1 solution, filter, be dried；
（5）By step（1）And step（2）The product of preparation is dried 5h in vacuum drying oven at 80 DEG C, after taking-up and step（4）
The product of preparation, remaining leftover materials temperature in double-roll rolling mill is 150 DEG C, and rotating speed is 60 revs/min of melt blending 10min,
In 80 DEG C of vacuum drying close annealing after compressing, short-circuit 24h, after room temperature is at the uniform velocity down to 5 DEG C/min.
The performance parameter of the cable material is as follows：
Percentage elongation：＞ 550%；Tensile strength：＞ 12MPa；Thermal impact：180 ± 1 DEG C/1h, do not ftracture；Limited oxygen index：
27%；Vertical combustion grade：V-0 levels.
Claims (2)
1. a kind of low-friction coefficient low smoke and zero halogen insulating protection material, it is characterised in that system is prepared by the raw material of following weight portion
Into：Low Density Polyethylene 40-45, APP 11-13, OP100.3-0.5, tetraethyl orthosilicate 12-15, glass dust 8-10, two
Niobium (Nb) boride 4-6, Heveatex 2.2-2.5, antioxidant 1010 0.2-0.4, agar 2.3-2.5, Graphene 3-3.5, Calcium Carbonate
6.6-8, stearic acid 1.3-1.6, oxygen delignification 2.2-3, bastose 14-18, expoxy propane 2.4-3, polyphenylene oxide 24-28, nothing
Appropriate water-ethanol, appropriate deionized water.
2. a kind of low-friction coefficient low smoke and zero halogen insulating protection material according to claim 1, it is characterised in that by following tool
Body step is made：
（1）By deionized water and dehydrated alcohol in mass ratio 1:2 are added in flask, warming while stirring to 40 DEG C, add poly- phosphorus
Sour ammonium stirring dissolves which, is slowly added to OP10, and with ammonia regulation system pH value 9-10, continues in the backward above-mentioned solution of dissolving
Stirring 10-20min, then tetraethyl orthosilicate is added in above-mentioned solution, after completion of dropping, continue reaction 2-3h, finally cool down
To room temperature, filter, be dried, wash and be put into dry product in baking oven；
（2）By expoxy propane and bastose stirring mixing, then stir in blender with polyphenylene oxide, antioxidant 1010, agar
Mix uniform, be then added to extruding pelletization in extruder, dry, extrusion temperature is 210-220 DEG C, screw speed 220-240 is stopped
Time 3-5min, pressure are 12-18MPa；
（3）The mixing of niobium dioxide, Calcium Carbonate and stearic acid is added in high-speed mixer, 100 DEG C is heated to, with 400 revs/min
After speed stirring 15min, add glass dust to continue to stir to obtain mixed-powder, the 8-9 times of anhydrous second measured will be added in natural emulsion
In alcohol, above-mentioned mixed-powder after stirring and dissolving, is added, stirred 40 minutes with 800 revs/min of rotating speed, be dried；
（4）By step（3）The product of preparation adds the 3-4 times of dimethylbenzene for measuring part, ultrasonic disperse 20-30min to add Graphene
Continue ultrasound uniform, scattered suspension is heated to into boiling under mechanical agitation, add 10% Low Density Polyethylene
Continue stirring 3h, be then added to dehydrated alcohol and deionized water volume ratio 1:In 1 solution, filter, be dried；
（5）By step（1）And step（2）The product of preparation is dried 5-6h in vacuum drying oven at 80 DEG C, after taking-up and step
（4）The product of preparation, remaining leftover materials temperature in double-roll rolling mill is 150 DEG C, and rotating speed is 60 revs/min of melt blending 10-
15min, it is compressing after in 80 DEG C of vacuum drying close annealing, short-circuit 24h, after room temperature is at the uniform velocity down to 5 DEG C/min.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610947680.7A CN106519382A (en) | 2016-10-26 | 2016-10-26 | Low-friction-factor low-smoke halogen-free insulation shielding material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610947680.7A CN106519382A (en) | 2016-10-26 | 2016-10-26 | Low-friction-factor low-smoke halogen-free insulation shielding material |
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| CN201610947680.7A Pending CN106519382A (en) | 2016-10-26 | 2016-10-26 | Low-friction-factor low-smoke halogen-free insulation shielding material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481715A (en) * | 2021-04-07 | 2021-10-08 | 北京理工大学 | Impregnation liquid for improving protective performance of fiber fabric and application thereof |
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|---|---|---|---|---|
| CN103865165A (en) * | 2014-03-21 | 2014-06-18 | 中利科技集团股份有限公司 | Low-smoke, halogen-free and flame retardant polyolefin cable material and preparation method thereof |
| CN105504473A (en) * | 2015-12-31 | 2016-04-20 | 天长市富信电子有限公司 | Sheath material for low-smoke halogen-free flame-retardant power line and preparation method thereof |
| CN105885162A (en) * | 2016-04-29 | 2016-08-24 | 安徽慧艺线缆集团有限公司 | Irradiation crosslinking polyethylene insulation single core cable for locomotive vehicle |
| CN105885178A (en) * | 2016-06-21 | 2016-08-24 | 南通志邦新材料科技有限公司 | Insulating composite material |
| CN105924715A (en) * | 2016-05-13 | 2016-09-07 | 芜湖诚通自动化设备有限公司 | High-temperature-resisting, insulating and inflaming-retarding power cable material and preparing method thereof |
| CN106009265A (en) * | 2016-06-14 | 2016-10-12 | 清华大学 | Preparation method of semiconductive shielding material for polypropylene insulation cables |
-
2016
- 2016-10-26 CN CN201610947680.7A patent/CN106519382A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865165A (en) * | 2014-03-21 | 2014-06-18 | 中利科技集团股份有限公司 | Low-smoke, halogen-free and flame retardant polyolefin cable material and preparation method thereof |
| CN105504473A (en) * | 2015-12-31 | 2016-04-20 | 天长市富信电子有限公司 | Sheath material for low-smoke halogen-free flame-retardant power line and preparation method thereof |
| CN105885162A (en) * | 2016-04-29 | 2016-08-24 | 安徽慧艺线缆集团有限公司 | Irradiation crosslinking polyethylene insulation single core cable for locomotive vehicle |
| CN105924715A (en) * | 2016-05-13 | 2016-09-07 | 芜湖诚通自动化设备有限公司 | High-temperature-resisting, insulating and inflaming-retarding power cable material and preparing method thereof |
| CN106009265A (en) * | 2016-06-14 | 2016-10-12 | 清华大学 | Preparation method of semiconductive shielding material for polypropylene insulation cables |
| CN105885178A (en) * | 2016-06-21 | 2016-08-24 | 南通志邦新材料科技有限公司 | Insulating composite material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481715A (en) * | 2021-04-07 | 2021-10-08 | 北京理工大学 | Impregnation liquid for improving protective performance of fiber fabric and application thereof |
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