CN103756119A - Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof - Google Patents
Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof Download PDFInfo
- Publication number
- CN103756119A CN103756119A CN201310752753.3A CN201310752753A CN103756119A CN 103756119 A CN103756119 A CN 103756119A CN 201310752753 A CN201310752753 A CN 201310752753A CN 103756119 A CN103756119 A CN 103756119A
- Authority
- CN
- China
- Prior art keywords
- potter
- power cable
- cable sheath
- clay
- sheath material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Insulated Conductors (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides an argil-modified low-smoke zero-halogen power cable sheath material which comprises the following components in parts by mass: 40-70 parts of ethylene-vinyl acetate copolymer, 20-40 parts of linear low-density polyethylene, 10-20 parts of high-molecular compatilizer, 130-160 parts of flame retardant, 5-20 parts of synergistic flame retardant, 2-4 parts of surface treating agent, 0.5-1 part of antioxidant, 5-7 parts of carbon black masterbatch and 1-4 parts of processing aid, wherein the flame retardant contains barium sulfate, and the synergistic flame retardant contains argil. The invention also provides a preparation method of the power cable sheath material.
Description
Technical field
The present invention relates to a kind of cable jacket material, relate more specifically to the field of low-smoke non-halogen flame-retardant power cable sheath material.
Background technology
The fire retardant material of domestic wires and cables industry mostly is Halogen fire retardant material in the past, and some efficient fire retardant, although can bring higher flame retardant properties, it otherwise need to the composite use of halogenated flame retardant, mostly is imported materials and items, and cost this respect seldom has producer to accept.During traditional Halogen material combustion, discharge a large amount of dense smoke and corrodibility halogenide, to human body and environment, all can cause damage.At present the CABLE MATERIALS of high flame resistance is to adopt high method of filling mostly, but high filling brought mechanical property poor, resistance to cracking can be poor etc. many problems, cracking, electric leakage in use, brought hidden danger to public safety.
In sum, this area lacks low smoke and zero halogen power cable sheath material and manufacture method thereof, requires this material to have higher flame retardant effect, mechanical property and good electric property, and especially its cost is lower, and green, environmental protection, and processing characteristics is good.
Summary of the invention
The first object of the present invention is to obtain a kind of low smoke and zero halogen power cable sheath material of potter's clay modification, this material has higher flame retardant effect, mechanical property and good electric property, especially its cost is lower, and green, environmental protection, and processing characteristics is good.
The second object of the present invention is to obtain a kind of manufacture method of low smoke and zero halogen power cable sheath material of potter's clay modification, this material has higher flame retardant effect, mechanical property and good electric property, especially its cost is lower, and green, environmental protection, and processing characteristics is good.
A first aspect of the present invention provides a kind of low smoke and zero halogen power cable sheath material of potter's clay modification, it comprises following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
In a specific embodiment of the present invention, it is comprised of following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
In a specific embodiment of the present invention, wherein, in described ethylene-vinyl acetate copolymer, the mass percentage content of its vinyl acetate is 20～40%, and melting index is 3～7g/min.
In a specific embodiment of the present invention, wherein, described high molecular weight compatibilizer is one or both in maleic anhydride graft terpolymer EP rubber, maleic anhydride grafted polyethylene or maleated ethylene vinyl acetate copolyme; Preferably, described high molecular weight compatibilizer is maleated ethylene vinyl acetate copolyme.
In a specific embodiment of the present invention, wherein, described surface treatment agent is one or both in stearic acid, Zinic stearas or silane coupling agent;
Preferably, the surface treatment agent of employing is silane coupling agent.
In a specific embodiment of the present invention, wherein, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, 4, one or more in 4 '-thiobis (6-tertiary butyl meta-cresol), β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) positive octadecyl ester of propionic acid, Tyox B or thio-2 acid two (18) ester;
Preferably, the oxidation inhibitor of employing is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5: 7).
In a specific embodiment of the present invention, wherein, described processing aid is a kind of in paraffin, polyethylene wax or ethylene bis stearic acid amide;
Preferably, the processing aid of employing is polyethylene wax.
In a specific embodiment of the present invention, wherein, described fire retardant is barium sulfate and the coordinating of other flame retardant compositions, and wherein said other fire retardants are selected from one or more in aluminium hydroxide, magnesium hydroxide.
In a specific embodiment of the present invention, wherein, described synergistic flame retardant is potter's clay, or the coordinating of potter's clay and other synergistic flame retardants, and described synergistic flame retardant is selected from one or more in zinc oxide, polynite.
In a specific embodiment of the present invention, the CABLE MATERIALS of preparation is by JB/T10707 standard.
In a specific embodiment of the present invention, the cable that the CABLE MATERIALS of preparation obtains is fire-retardant by the bunchy C class in IEC60332-3-24.
A second aspect of the present invention provides the preparation method of the low smoke and zero halogen power cable sheath material of a kind of potter's clay modification of the present invention, and described method comprises the steps:
Supply raw materials; Comprise:
Ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay;
Raw material is prepared burden by the proportioning of each component, together put into the abundant mixing that high-speed mixer carries out 5 ± 1min, then add successively twin screw and single screw extrusion machine to carry out extruding pelletization; The temperature of screw rod is: 110～130 ℃ of feeding sections, 125～145 ℃ of transportation sections, 135～160 ℃ of fluxing zones, 130～150 ℃ of heads.
Embodiment
The inventor is through extensive and deep research, has higher flame retardant effect, mechanical property and the cable sheath material formula of electric property preferably by improving preparation technology, having obtained, and is surprised to find that processing characteristics is excellent especially.Completed on this basis the present invention.
Technical conceive of the present invention is as follows:
The invention discloses a kind of low smoke and zero halogen power cable sheath material and manufacture method thereof of potter's clay modification, the massfraction ratio that this CABLE MATERIALS forms is: 40～70 parts of ethylene-vinyl acetate copolymers, 20～40 parts of linear low density polyethylenes, 10～20 parts of high molecular weight compatibilizers, 130～160 parts of fire retardants, 5～20 parts of synergistic flame retardants, 2～4 parts of surface treatment agents, 0.5～1 part, oxidation inhibitor, 5～7 parts of black masterbatchs, 1～4 part of processing aid; Characteristics and advantages of the present invention is: good flame retardant properties, resistance toheat, mechanical property, resistance to cracking energy, not halogen-containing preferably, low cigarette, low toxicity, environmental friendliness.
In the present invention, term " contains " or " comprising " represents that various compositions can be applied in mixture of the present invention or composition together.Therefore, term " mainly by ... form " and " by ... composition " be included in that term " contains " or in " comprising ".
Below describe in detail to various aspects of the present invention:
The low smoke and zero halogen power cable sheath material of potter's clay modification
A first aspect of the present invention provides a kind of low smoke and zero halogen power cable sheath material of potter's clay modification, it comprises following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
At present the CABLE MATERIALS of high flame resistance is to adopt high method of filling mostly, but high filling brought mechanical property poor, resistance to cracking can be poor etc. many problems, cracking, electric leakage in use, brought hidden danger to public safety.And that the present invention adopts between fire retardant and synergistic flame retardant is collaborative, coordinate ethylene-vinyl acetate copolymer, linear low density polyethylene, make the flame retardant properties of gained resistance sheath material good, and good mechanical property, resistance to cracking can be also very good.
The CABLE MATERIALS of preparation of the present invention can be passed through JB/T10707 standard.
In addition the cable that the CABLE MATERIALS that, prepared by the present invention obtains is fire-retardant by the bunchy C class in IEC60332-3-24.
The present invention possesses following characteristics and advantages simultaneously: higher mechanical property (in optimum embodiment, tensile strength reaches 12.5MPa); Good flame retardant properties; There is good resistance to cracking energy (150 ℃ of thermal shock tests), low cigarette, low toxicity, environmental protection; The formula of this CABLE MATERIALS, through a series of adjustment, has good melting index in addition, and hardness and moment of torsion are more suitable, have good processing characteristics.
In a specific embodiment of the present invention, it is comprised of following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
In a specific embodiment of the present invention, wherein, in described ethylene-vinyl acetate copolymer, the mass percentage content of its vinyl acetate is 20～40%, and melting index is 3～7g/min.Described embodiment makes processing characteristics better.
Preferably, described high molecular weight compatibilizer is one or both in maleic anhydride graft terpolymer EP rubber, maleic anhydride grafted polyethylene or maleated ethylene vinyl acetate copolyme.
In a specific embodiment of the present invention, in order to coordinate with other components better, wherein, described high molecular weight compatibilizer is maleated ethylene vinyl acetate copolyme.
In a specific embodiment of the present invention, in order to coordinate with other components better, wherein, described surface treatment agent is one or both in stearic acid, Zinic stearas or silane coupling agent;
Preferably, the surface treatment agent of employing is silane coupling agent.
In a specific embodiment of the present invention, in order to coordinate with other components better, wherein, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, 4, one or more in 4 '-thiobis (6-tertiary butyl meta-cresol), β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) positive octadecyl ester of propionic acid, Tyox B or thio-2 acid two (18) ester.
Preferably, the oxidation inhibitor of employing is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5: 7).Described embodiment and other component synergetic propertyes are better.
In a specific embodiment of the present invention, in order to coordinate with other components better, wherein, described processing aid is a kind of in paraffin, polyethylene wax or ethylene bis stearic acid amide.
Preferably, the processing aid of employing is polyethylene wax.
In a specific embodiment of the present invention, wherein, described fire retardant is is barium sulfate and the coordinating of other flame retardant compositions, and wherein said other fire retardants are selected from one or more in aluminium hydroxide, magnesium hydroxide.Preferably, the addition that described barium sulfate accounts for described fire retardant is 0.3～15%, with the total weight of fire retardant, and preferably 5～8%.
In a specific embodiment of the present invention, wherein, described synergistic flame retardant is potter's clay, or the coordinating of potter's clay and other synergistic flame retardants, and described synergistic flame retardant is selected from one or more in zinc oxide, polynite.
Preparation method
A second aspect of the present invention provides the preparation method of the low smoke and zero halogen power cable sheath material of a kind of potter's clay modification of the present invention, and described method comprises the steps:
Supply raw materials; Comprise:
Ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay;
Raw material is prepared burden by the proportioning of each component, together put into the abundant mixing that high-speed mixer carries out 5 ± 1min, then add successively twin screw and single screw extrusion machine to carry out extruding pelletization; The temperature of screw rod is: 110～130 ℃ of feeding sections, 125～145 ℃ of transportation sections, 135～160 ℃ of fluxing zones, 130～150 ℃ of heads.
Described twin screw and single screw extrusion machine all well known to a person skilled in the art.
Preferred embodiment
A low smoke and zero halogen power cable sheath material for potter's clay modification, the component that it comprises following massfraction:
Wherein:
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described ethylene-vinyl acetate copolymer, the mass percentage content of its vinyl acetate is 20～40%, melting index is 3～7g/min.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described high molecular weight compatibilizer is one or both in maleic anhydride graft terpolymer EP rubber, maleic anhydride grafted polyethylene or maleated ethylene vinyl acetate copolyme.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described fire retardant is one or more in aluminium hydroxide, magnesium hydroxide or barium sulfate.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described synergistic flame retardant is one or more in zinc oxide, potter's clay, polynite.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described surface treatment agent is one or both in stearic acid, Zinic stearas or silane coupling agent.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, 4, one or more in 4 '-thiobis (6-tertiary butyl meta-cresol), β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) positive octadecyl ester of propionic acid, Tyox B or thio-2 acid two (18) ester.
The low smoke and zero halogen power cable sheath material of described a kind of potter's clay modification, described processing aid is a kind of in paraffin, polyethylene wax or ethylene bis stearic acid amide.
The present invention presses following step manufacture:
Raw material is prepared burden by the proportioning of each component, together put into the abundant mixing that high-speed mixer carries out 5min, then add successively twin screw and single screw extrusion machine to carry out extruding pelletization.The temperature of screw rod is: 110～130 ℃ of feeding sections, 125～145 ℃ of transportation sections, 135～160 ℃ of fluxing zones, 130～150 ℃ of heads.
most preferred embodiment of the present invention
In most preferred embodiment of the present invention, the high molecular weight compatibilizer of employing is maleic anhydride grafted polyethylene; The synergistic flame retardant adopting is potter's clay; The surface treatment agent adopting is silane coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5:7); The processing aid adopting is polyethylene wax.
This embodiment has been chosen suitable ethylene-vinyl acetate copolymer and surface treatment agent, uses barium sulfate to strengthen mechanical property, has also added appropriate synergistic flame retardant, obtains a kind of low smoke and zero halogen power cable sheath material and manufacture method thereof of potter's clay modification.Compare with other material, the present invention possesses following characteristics and advantages simultaneously: higher mechanical property (tensile strength reaches 12.5MPa); Good flame retardant properties; There is good resistance to cracking energy (150 ℃ of thermal shock tests), low cigarette, low toxicity, environmental protection; The formula of this CABLE MATERIALS, through a series of adjustment, has good melting index in addition, and hardness and moment of torsion are more suitable, have good processing characteristics.
As no specific instructions, various raw material of the present invention all can obtain by commercially available; Or prepare according to the ordinary method of this area.Unless otherwise defined or described herein, the familiar same meaning of all specialties used herein and scientific words and those skilled in the art.In addition any method similar or impartial to described content and material all can be applicable in the inventive method.
Other aspects of the present invention, due to disclosure herein, are apparent to those skilled in the art.
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment are only not used in and limit the scope of the invention for the present invention is described.The experimental technique of unreceipted actual conditions in the following example, measures according to national standard conventionally.If there is no corresponding national standard, according to general international standard, normal condition or the condition of advising according to manufacturer, carry out.Unless otherwise indicated, otherwise all umbers are weight part, and all per-cents are weight percentage, and described polymericular weight is number-average molecular weight.
Unless otherwise defined or described herein, the familiar same meaning of all specialties used herein and scientific words and those skilled in the art.In addition any method similar or impartial to described content and material all can be applicable in the inventive method.
Embodiment
Embodiments of the invention and comparative example formula for raw stock are in Table 1.
Table 1 this low smoke and zero halogen power cable sheath material embodiment and comparative example formula (umber)
Wherein:
The high molecular weight compatibilizer that comparative example 1 adopts is maleic anhydride grafted polyethylene; The synergistic flame retardant adopting is potter's clay; The surface treatment agent adopting is silane coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester; The processing aid adopting is paraffin and ethylene bis stearic acid amide (proportioning is 1: 1).
The high molecular weight compatibilizer that embodiment 1 adopts is maleic anhydride grafted polyethylene; The synergistic flame retardant adopting is potter's clay; The surface treatment agent adopting is silane coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester; The processing aid adopting is paraffin and ethylene bis stearic acid amide (proportioning is 1: 1).
The high molecular weight compatibilizer that embodiment 2 adopts is maleated ethylene vinyl acetate copolyme; The synergistic flame retardant adopting is potter's clay, zinc oxide and polynite; The surface treatment agent adopting is aluminate coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5: 7); The processing aid adopting is paraffin and polyethylene wax (proportioning is 1: 1).
The high molecular weight compatibilizer that embodiment 3 adopts is maleic anhydride grafted polyethylene; The synergistic flame retardant adopting is potter's clay and zinc oxide; The surface treatment agent adopting is silane coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5: 7); The processing aid adopting is paraffin and polyethylene wax (proportioning is 1: 1).
The high molecular weight compatibilizer that comparative example 2 adopts is maleic anhydride grafted polyethylene; The surface treatment agent adopting is silane coupling agent and Zinic stearas (proportioning is 5: 1); The oxidation inhibitor adopting is β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) positive octadecyl ester of propionic acid; The processing aid adopting is paraffin.
The high molecular weight compatibilizer that embodiment 4 adopts is maleic anhydride grafted polyethylene; The synergistic flame retardant adopting is potter's clay; The surface treatment agent adopting is silane coupling agent; The oxidation inhibitor adopting is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5: 7); The processing aid adopting is polyethylene wax.
Embodiment and comparative example all adopt following manufacture method:
Raw material is prepared burden by the proportioning of each component, together put into the abundant mixing that high-speed mixer carries out 5min, then add successively twin screw and single screw extrusion machine to carry out extruding pelletization.The temperature of screw rod is: 110～130 ℃ of feeding sections, 125～145 ℃ of transportation sections, 135～160 ℃ of fluxing zones, 130～150 ℃ of heads.
The CABLE MATERIALS performance of embodiment and comparative example is in Table 2.
The performance of each embodiment of table 2 and comparative example CABLE MATERIALS
Wherein embodiment 4 is most preferred embodiment, and its performance is separately in Table 3.
The performance of table 3 embodiment 4
| Sequence number | Performance | Unit | Embodiment 5 |
| 1 | Tensile strength | MPa | 12.54 |
| 2 | Elongation at break | % | 155.92 |
| 3 | Air heat ageing test (100 ℃, 168h) | / | / |
| 3.1 | Tensile strength retention rate | % | 97.1 |
| 3.2 | Reserved elongation at break | % | 93.8 |
| 4 | Melting index | g/10min | 8.4 |
| 5 | Density | g/cm3 | 1.521 |
| 6 | Thermal shock test (150 ℃, 1h) | / | By |
| 7 | The burning of IEC60332-3-24 bunchy | / | C class |
| 8 | Low temperature brittleness (25 ℃) | Failure number | 4/30 |
| 9 | Volume specific resistance (20 ℃) | Ω·m | 1.08*10 12 |
| 10 | Dielectric strength | MV/m | 25 |
| 11 | Smoke density (nonflame) | / | 137 |
| 12 | Oxygen index | % | 39 |
| 13 | Halogen acid gas content | mg/g | 1.1 |
| 14 | PH value | / | 5.6 |
| 15 | Specific conductivity | μs/mm | 1 |
| 16 | Poison exponent | / | 1.8 |
The foregoing is only preferred embodiment of the present invention, not in order to limit essence technology contents scope of the present invention, essence technology contents of the present invention is to be broadly defined in the claim scope of application, any technology entity or method that other people complete, if defined identical with the claim scope of application, also or a kind of change of equivalence, all will be regarded as being covered by among this claim scope.
All documents of mentioning in the present invention are all quoted as a reference in this application, just as each piece of document, are quoted as a reference separately.In addition should be understood that, after having read foregoing of the present invention, those skilled in the art can make various changes or modifications the present invention, these equivalent form of values fall within the application's appended claims limited range equally.
Claims (10)
1. the low smoke and zero halogen power cable sheath material of a potter's clay modification, it comprises following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
2. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, it is comprised of following component: ethylene-vinyl acetate copolymer, linear low density polyethylene, high molecular weight compatibilizer, fire retardant, synergistic flame retardant, surface treatment agent, oxidation inhibitor, black masterbatch and processing aid, and the massfraction of each component is:
Wherein, in described fire retardant, contain barium sulfate;
Described synergistic flame retardant contains potter's clay.
3. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, in described ethylene-vinyl acetate copolymer, the mass percentage content of its vinyl acetate is 20～40%, melting index is 3～7g/min.
4. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, described high molecular weight compatibilizer is one or both in maleic anhydride graft terpolymer EP rubber, maleic anhydride grafted polyethylene or maleated ethylene vinyl acetate copolyme;
Described high molecular weight compatibilizer is maleated ethylene vinyl acetate copolyme.
5. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, described surface treatment agent is one or both in stearic acid, Zinic stearas or silane coupling agent;
Preferably, the surface treatment agent of employing is silane coupling agent.
6. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, described oxidation inhibitor is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, 4, one or more in 4 '-thiobis (6-tertiary butyl meta-cresol), β-(4-hydroxyl-3,5-di-tert-butyl-phenyl) positive octadecyl ester of propionic acid, Tyox B or thio-2 acid two (18) ester;
Preferably, the oxidation inhibitor of employing is four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester and Tyox Bs (proportioning is 5:7).
7. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, described processing aid is a kind of in paraffin, polyethylene wax or ethylene bis stearic acid amide;
Preferably, the processing aid of employing is polyethylene wax.
8. the low smoke and zero halogen power cable sheath material of potter's clay modification as claimed in claim 1, wherein, described fire retardant is barium sulfate and the coordinating of other flame retardant compositions;
Wherein said other fire retardants are selected from one or more in aluminium hydroxide, magnesium hydroxide.
9. the low smoke and zero halogen power cable sheath material of potter's clay modification according to claim 1, wherein, described synergistic flame retardant is potter's clay, or the coordinating of potter's clay and other synergistic flame retardants, and described synergistic flame retardant is selected from one or more in zinc oxide, polynite.
10. according to a preparation method for the low smoke and zero halogen power cable sheath material of a kind of potter's clay modification described in claim 1～9 Arbitrary Term, described method comprises the steps:
Raw material as claimed in claim 1 is provided;
Raw material is prepared burden by the proportioning of each component, together put into the abundant mixing that high-speed mixer carries out 5 ± 1min, then add successively twin screw and single screw extrusion machine to carry out extruding pelletization; The temperature of screw rod is: 110～130 ℃ of feeding sections, 125～145 ℃ of transportation sections, 135～160 ℃ of fluxing zones, 130～150 ℃ of heads.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310752753.3A CN103756119A (en) | 2013-12-31 | 2013-12-31 | Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310752753.3A CN103756119A (en) | 2013-12-31 | 2013-12-31 | Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103756119A true CN103756119A (en) | 2014-04-30 |
Family
ID=50523455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310752753.3A Pending CN103756119A (en) | 2013-12-31 | 2013-12-31 | Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103756119A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140600A (en) * | 2014-08-11 | 2014-11-12 | 江苏德威新材料股份有限公司 | Halogen-free environment-friendly high-speed elevator compensation chain material and application thereof |
| CN104530547A (en) * | 2014-12-19 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | Thermoplastic low-smoke halogen-free high-flame-retardant material for automobile wire and preparation method of material |
| CN105713291A (en) * | 2016-04-29 | 2016-06-29 | 上海工程技术大学 | Insulating material for preparing aerial insulated cable and preparation method thereof |
| CN108641175A (en) * | 2018-05-31 | 2018-10-12 | 安徽电信器材贸易工业有限责任公司 | A kind of wearable lightweight Cable jacket materials and preparation method thereof |
| CN108727676A (en) * | 2017-04-17 | 2018-11-02 | 江苏宝源高新电工有限公司 | A kind of sheath and the general fireproofing cable material without halide and preparation method thereof that insulate |
| CN109810397A (en) * | 2019-02-02 | 2019-05-28 | 上海国缆检测中心有限公司 | A kind of electric railway low-smoke halogen-free flame-retardant sheath material and preparation method thereof |
| CN111303528A (en) * | 2020-04-20 | 2020-06-19 | 杭州美临塑业有限公司 | Halogen-free low-smoke high-flame-retardant high-oxygen-insulation cable material for power cable and preparation method thereof |
| CN112662042A (en) * | 2020-12-21 | 2021-04-16 | 常州市沃科科技有限公司 | B1-grade low-smoke halogen-free cable sheath material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102209752A (en) * | 2008-09-16 | 2011-10-05 | 联合碳化化学及塑料技术有限责任公司 | Crack-resistant, flame retardant, halogen-free, cable assembly and coating composition |
| CN103044758A (en) * | 2012-12-21 | 2013-04-17 | 上海至正道化高分子材料有限公司 | Thermoplastic water-resistant low-smoke halogen-free flame retardant cable material and manufacturing method thereof |
-
2013
- 2013-12-31 CN CN201310752753.3A patent/CN103756119A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102209752A (en) * | 2008-09-16 | 2011-10-05 | 联合碳化化学及塑料技术有限责任公司 | Crack-resistant, flame retardant, halogen-free, cable assembly and coating composition |
| CN103044758A (en) * | 2012-12-21 | 2013-04-17 | 上海至正道化高分子材料有限公司 | Thermoplastic water-resistant low-smoke halogen-free flame retardant cable material and manufacturing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 山西省化工研究所: "《塑料橡胶加工助剂》", 31 October 2002, article "陶土", pages: 590-594 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140600A (en) * | 2014-08-11 | 2014-11-12 | 江苏德威新材料股份有限公司 | Halogen-free environment-friendly high-speed elevator compensation chain material and application thereof |
| CN104140600B (en) * | 2014-08-11 | 2016-06-29 | 江苏德威新材料股份有限公司 | A kind of halogen-free environmental high-speed elevator compensation chain material and application thereof |
| CN104530547A (en) * | 2014-12-19 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | Thermoplastic low-smoke halogen-free high-flame-retardant material for automobile wire and preparation method of material |
| CN105713291A (en) * | 2016-04-29 | 2016-06-29 | 上海工程技术大学 | Insulating material for preparing aerial insulated cable and preparation method thereof |
| CN108727676A (en) * | 2017-04-17 | 2018-11-02 | 江苏宝源高新电工有限公司 | A kind of sheath and the general fireproofing cable material without halide and preparation method thereof that insulate |
| CN108641175A (en) * | 2018-05-31 | 2018-10-12 | 安徽电信器材贸易工业有限责任公司 | A kind of wearable lightweight Cable jacket materials and preparation method thereof |
| CN109810397A (en) * | 2019-02-02 | 2019-05-28 | 上海国缆检测中心有限公司 | A kind of electric railway low-smoke halogen-free flame-retardant sheath material and preparation method thereof |
| CN111303528A (en) * | 2020-04-20 | 2020-06-19 | 杭州美临塑业有限公司 | Halogen-free low-smoke high-flame-retardant high-oxygen-insulation cable material for power cable and preparation method thereof |
| CN112662042A (en) * | 2020-12-21 | 2021-04-16 | 常州市沃科科技有限公司 | B1-grade low-smoke halogen-free cable sheath material and preparation method thereof |
| CN112662042B (en) * | 2020-12-21 | 2023-06-20 | 常州市沃科科技有限公司 | B1-level low-smoke halogen-free cable sheath material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103756119A (en) | Argil-modified low-smoke zero-halogen power cable sheath material and preparation method thereof | |
| CN103044758A (en) | Thermoplastic water-resistant low-smoke halogen-free flame retardant cable material and manufacturing method thereof | |
| CN102250409B (en) | Synergistic flame-retardant low-smoke halogen-free polyolefin cable material and preparation method thereof | |
| CN103739928A (en) | High-performance low smoke zero halogen power cable sheath material adopting silicon resin to enhance efficiency and preparation method thereof | |
| JP4074681B2 (en) | Flame retardant halogen-free composition | |
| CN104479232B (en) | A kind of 125 DEG C of low flue unhalogen flame-retarded ethylpropyl rubber CABLE MATERIALSs and preparation method thereof | |
| CN103275385B (en) | Nuclear power Halogen-free low-smoke flame-retardant cable sheath material and preparation method thereof | |
| CN102485782B (en) | Crosslinked, oil-resistant, low temperature-resistant, low-smoke, halogen-free and flame-retardant cable material and its preparation method | |
| CN103205053B (en) | Nano-modified low-shrinkage low-smoke halogen-free and flame-retardant polyolefin cable material and preparation thereof | |
| CN106380869A (en) | 125-degree irradiation-crosslinked elastomer cable material used for new energy automobile high-voltage cable and manufacture method of elastomer cable material | |
| CN103739927B (en) | Temperature resistant grade is low-smoke zero-halogen cable material formula and the preparation method of 150 DEG C | |
| CN109651691B (en) | Low-temperature-resistant oil-resistant torsion-resistant low-smoke halogen-free flame-retardant wind energy cable sheath material and preparation method and application thereof | |
| CN105504480A (en) | Oil-resistant irradiation-crosslinking low-smoke halogen-free flame-retardant polyolefin material for locomotive wires and cables | |
| CN104177695A (en) | Crosslinked halogen-free flame-retardant cable material | |
| CN110903538A (en) | 90-DEG C cracking-resistant moisture-proof flame-retardant polyethylene cable material and preparation method thereof | |
| CN104744791B (en) | A kind of low smoke halogen-free fire retardant polyolefin cable material and preparation method thereof | |
| CN104231420B (en) | 105 DEG C of temperature resistant grade irradiated crosslinking low-smoke halogen-free flame-retardant isolating material and preparation method thereof | |
| CN103012946A (en) | 150 DEG C irradiation crosslinking low-smoke non-halogen flame-retardant cable material | |
| CN104292601A (en) | Oil-proof low-smoke and non-halogen fire-retardant cable material and preparation method thereof | |
| CN105086128A (en) | 125 DEG C irradiation cross-linking low-smoke halogen-free flame-retardant polyolefin cable material | |
| CN100363415C (en) | Low smoke non-halogen fire retarding expansive polyolefins electronic wire material and preparation process thereof | |
| CN105348630A (en) | Thermoplastic non-halogen low-smoke flame-resistant material with high oxygen index and strong self-extinguishing property for electric wire and cable and preparation method of material | |
| CN104945705A (en) | Oil-resistant thermoplastic low-smoke zero-halogen flame-retardant polyolefin cable material and preparation method thereof | |
| JP6344200B2 (en) | Flame retardant resin composition and flame retardant insulated wire / cable | |
| CN109627565A (en) | 150 DEG C of heatproof of low-smoke zero-halogen cable material formula and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 201108 Shanghai Yuanjiang Industrial Zone Xhenzhuang Road No. 5050 Applicant after: SHANGHAI ZHIZHENG DAOHUA POLYMER MATERIALS CO., LTD. Address before: 201108 Shanghai city Minhang District Yuanjiang Industrial Zone Xhenzhuang Road No. 5050 Applicant before: Origianl Dow Advanced Compounds (Shanghai) Co., Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: ORIGIANL DOW ADVANCED COMPOUNDS (SHANGHAI) CO., LTD. TO: SHANGHAI ORIGINALDOW ADVANCED COMPOUNDS CO., LTD. |
|
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140430 |
|
| RJ01 | Rejection of invention patent application after publication |