CN106467327A - 三元聚合物分子刷重金属捕捉剂的制备方法 - Google Patents
三元聚合物分子刷重金属捕捉剂的制备方法 Download PDFInfo
- Publication number
- CN106467327A CN106467327A CN201610857761.8A CN201610857761A CN106467327A CN 106467327 A CN106467327 A CN 106467327A CN 201610857761 A CN201610857761 A CN 201610857761A CN 106467327 A CN106467327 A CN 106467327A
- Authority
- CN
- China
- Prior art keywords
- side chain
- polymer
- chain
- ter
- heavy metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 137
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 42
- 239000002738 chelating agent Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920001021 polysulfide Polymers 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 238000005189 flocculation Methods 0.000 claims description 29
- 230000016615 flocculation Effects 0.000 claims description 29
- 229910052717 sulfur Inorganic materials 0.000 claims description 29
- 239000011593 sulfur Substances 0.000 claims description 29
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 28
- 230000015572 biosynthetic process Effects 0.000 claims description 23
- 238000003786 synthesis reaction Methods 0.000 claims description 23
- 238000006116 polymerization reaction Methods 0.000 claims description 21
- 229920002401 polyacrylamide Polymers 0.000 claims description 15
- -1 3,7- dithia -1- nonyl Chemical group 0.000 claims description 13
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 102000004377 Thiopurine S-methyltransferases Human genes 0.000 claims description 11
- 108090000958 Thiopurine S-methyltransferases Proteins 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 10
- 229920002189 poly(glycerol 1-O-monomethacrylate) polymer Polymers 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 125000000304 alkynyl group Chemical group 0.000 claims description 6
- 238000010550 living polymerization reaction Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 150000001540 azides Chemical class 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims description 4
- 229920002521 macromolecule Polymers 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 150000002924 oxiranes Chemical group 0.000 claims description 4
- 229920002454 poly(glycidyl methacrylate) polymer Polymers 0.000 claims description 4
- 150000003254 radicals Chemical group 0.000 claims description 4
- HRKQOINLCJTGBK-UHFFFAOYSA-N dihydroxidosulfur Chemical compound OSO HRKQOINLCJTGBK-UHFFFAOYSA-N 0.000 claims description 3
- 238000010526 radical polymerization reaction Methods 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000010323 ascorbic acid Nutrition 0.000 claims description 2
- 229960005070 ascorbic acid Drugs 0.000 claims description 2
- 239000011668 ascorbic acid Substances 0.000 claims description 2
- IVRMZWNICZWHMI-UHFFFAOYSA-N azide group Chemical group [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 238000007306 functionalization reaction Methods 0.000 claims description 2
- 229920001477 hydrophilic polymer Polymers 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000005266 side chain polymer Substances 0.000 claims description 2
- 229920001059 synthetic polymer Polymers 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 abstract description 10
- 230000002776 aggregation Effects 0.000 abstract description 6
- 238000004220 aggregation Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000003311 flocculating effect Effects 0.000 abstract description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 9
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 101710141544 Allatotropin-related peptide Proteins 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 6
- 229960000549 4-dimethylaminophenol Drugs 0.000 description 4
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WZRRRFSJFQTGGB-UHFFFAOYSA-N 1,3,5-triazinane-2,4,6-trithione Chemical compound S=C1NC(=S)NC(=S)N1 WZRRRFSJFQTGGB-UHFFFAOYSA-N 0.000 description 3
- 239000005077 polysulfide Substances 0.000 description 3
- 150000008117 polysulfides Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 2
- XZKFBZOAIGFZSU-UHFFFAOYSA-N 1-bromo-4-methylpentane Chemical compound CC(C)CCCBr XZKFBZOAIGFZSU-UHFFFAOYSA-N 0.000 description 2
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000001338 self-assembly Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N sodium azide Substances [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 2
- 235000019187 sodium-L-ascorbate Nutrition 0.000 description 2
- CNRZJYVUUWUCND-UHFFFAOYSA-N C(CSCCCSCC)S.C(C(=C)C)(=O)O Chemical compound C(CSCCCSCC)S.C(C(=C)C)(=O)O CNRZJYVUUWUCND-UHFFFAOYSA-N 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Removal Of Specific Substances (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610857761.8A CN106467327B (zh) | 2016-09-28 | 2016-09-28 | 四元聚合物分子刷重金属捕捉剂的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610857761.8A CN106467327B (zh) | 2016-09-28 | 2016-09-28 | 四元聚合物分子刷重金属捕捉剂的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106467327A true CN106467327A (zh) | 2017-03-01 |
CN106467327B CN106467327B (zh) | 2019-06-07 |
Family
ID=58230733
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610857761.8A Active CN106467327B (zh) | 2016-09-28 | 2016-09-28 | 四元聚合物分子刷重金属捕捉剂的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106467327B (zh) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698001A (zh) * | 2017-11-15 | 2018-02-16 | 顺德职业技术学院 | 新型阳离子染料絮凝剂及其制备方法及其应用 |
CN107828062A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 水溶性二元阳离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107828063A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 水溶性三元螯合聚合物分子刷染料捕捉剂及其制备方法及其应用 |
CN107828064A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 高效型染料絮凝剂及其制备方法及其应用 |
CN107857330A (zh) * | 2017-11-15 | 2018-03-30 | 顺德职业技术学院 | 水溶性二元螯合聚合物分子刷阳离子染料捕捉剂及其制备方法及其应用 |
CN107879450A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 水溶性三元聚合物分子刷阴离子染料捕捉沉降剂及其制备方法及其应用 |
CN107879453A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 新型鳌合型重金属捕捉剂及其合成方法及其应用 |
CN107879451A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 水溶性三元聚合物分子刷阳离子染料捕捉沉降剂及其制备方法及其应用 |
CN107879449A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 低成本螯合复合型重金属捕捉剂及其制备方法及其应用 |
CN107890856A (zh) * | 2017-11-15 | 2018-04-10 | 顺德职业技术学院 | 超快沉降型分子刷结构重金属捕捉剂及其制备方法及其应用 |
CN107892372A (zh) * | 2017-11-15 | 2018-04-10 | 顺德职业技术学院 | 水溶性四元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107903398A (zh) * | 2017-11-15 | 2018-04-13 | 顺德职业技术学院 | 水溶性三元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107902739A (zh) * | 2017-11-15 | 2018-04-13 | 顺德职业技术学院 | 水溶性二元螯合聚合物分子刷阴离子染料捕捉剂及其制备方法及其应用 |
CN107915297A (zh) * | 2017-11-15 | 2018-04-17 | 顺德职业技术学院 | 水溶性二元阴离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107935152A (zh) * | 2017-11-15 | 2018-04-20 | 顺德职业技术学院 | 超快沉降型复合型重金属捕捉剂及其生产方法及其应用 |
CN109775823A (zh) * | 2017-11-15 | 2019-05-21 | 顺德职业技术学院 | 新型阴离子染料絮凝剂及其制备方法及其应用 |
CN113354562A (zh) * | 2020-03-05 | 2021-09-07 | 中国科学院化学研究所 | 侧链高度有序排列的刷形聚合物及其制备方法和应用 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103936925A (zh) * | 2014-03-14 | 2014-07-23 | 厦门大学 | 一种具有离子响应和温度敏感性的无规共聚物的制备方法 |
-
2016
- 2016-09-28 CN CN201610857761.8A patent/CN106467327B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103936925A (zh) * | 2014-03-14 | 2014-07-23 | 厦门大学 | 一种具有离子响应和温度敏感性的无规共聚物的制备方法 |
Non-Patent Citations (1)
Title |
---|
常忆凌等: "《药剂学》", 31 July 2005 * |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698001A (zh) * | 2017-11-15 | 2018-02-16 | 顺德职业技术学院 | 新型阳离子染料絮凝剂及其制备方法及其应用 |
CN107828062A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 水溶性二元阳离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107828063A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 水溶性三元螯合聚合物分子刷染料捕捉剂及其制备方法及其应用 |
CN107828064A (zh) * | 2017-11-15 | 2018-03-23 | 顺德职业技术学院 | 高效型染料絮凝剂及其制备方法及其应用 |
CN107857330A (zh) * | 2017-11-15 | 2018-03-30 | 顺德职业技术学院 | 水溶性二元螯合聚合物分子刷阳离子染料捕捉剂及其制备方法及其应用 |
CN107879450A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 水溶性三元聚合物分子刷阴离子染料捕捉沉降剂及其制备方法及其应用 |
CN107879453A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 新型鳌合型重金属捕捉剂及其合成方法及其应用 |
CN107879451A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 水溶性三元聚合物分子刷阳离子染料捕捉沉降剂及其制备方法及其应用 |
CN107879449A (zh) * | 2017-11-15 | 2018-04-06 | 顺德职业技术学院 | 低成本螯合复合型重金属捕捉剂及其制备方法及其应用 |
CN107890856A (zh) * | 2017-11-15 | 2018-04-10 | 顺德职业技术学院 | 超快沉降型分子刷结构重金属捕捉剂及其制备方法及其应用 |
CN107892372A (zh) * | 2017-11-15 | 2018-04-10 | 顺德职业技术学院 | 水溶性四元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107903398A (zh) * | 2017-11-15 | 2018-04-13 | 顺德职业技术学院 | 水溶性三元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107902739A (zh) * | 2017-11-15 | 2018-04-13 | 顺德职业技术学院 | 水溶性二元螯合聚合物分子刷阴离子染料捕捉剂及其制备方法及其应用 |
CN107915297A (zh) * | 2017-11-15 | 2018-04-17 | 顺德职业技术学院 | 水溶性二元阴离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107935152A (zh) * | 2017-11-15 | 2018-04-20 | 顺德职业技术学院 | 超快沉降型复合型重金属捕捉剂及其生产方法及其应用 |
CN109775823A (zh) * | 2017-11-15 | 2019-05-21 | 顺德职业技术学院 | 新型阴离子染料絮凝剂及其制备方法及其应用 |
CN107879449B (zh) * | 2017-11-15 | 2019-11-08 | 顺德职业技术学院 | 低成本螯合复合型重金属捕捉剂及其制备方法及其应用 |
CN107935152B (zh) * | 2017-11-15 | 2019-11-08 | 顺德职业技术学院 | 超快沉降型复合型重金属捕捉剂及其生产方法及其应用 |
CN107890856B (zh) * | 2017-11-15 | 2019-11-26 | 顺德职业技术学院 | 超快沉降型分子刷结构重金属捕捉剂及其制备方法及其应用 |
CN107828064B (zh) * | 2017-11-15 | 2020-07-28 | 顺德职业技术学院 | 高效型染料絮凝剂及其制备方法及其应用 |
CN107828063B (zh) * | 2017-11-15 | 2020-07-31 | 顺德职业技术学院 | 水溶性四元螯合聚合物分子刷染料捕捉剂及其制备方法及其应用 |
CN107828062B (zh) * | 2017-11-15 | 2020-08-07 | 顺德职业技术学院 | 水溶性三元阳离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107903398B (zh) * | 2017-11-15 | 2020-08-07 | 顺德职业技术学院 | 水溶性四元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107879451B (zh) * | 2017-11-15 | 2020-09-01 | 顺德职业技术学院 | 水溶性四元聚合物分子刷阳离子染料捕捉沉降剂及其制备方法及其应用 |
CN107892372B (zh) * | 2017-11-15 | 2020-09-01 | 顺德职业技术学院 | 水溶性五元聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107879450B (zh) * | 2017-11-15 | 2020-09-01 | 顺德职业技术学院 | 水溶性四元聚合物分子刷阴离子染料捕捉沉降剂及其制备方法及其应用 |
CN107879453B (zh) * | 2017-11-15 | 2020-09-11 | 顺德职业技术学院 | 鳌合型重金属捕捉剂及其合成方法及其应用 |
CN107902739B (zh) * | 2017-11-15 | 2020-09-11 | 顺德职业技术学院 | 水溶性三元螯合聚合物分子刷阴离子染料捕捉剂及其制备方法及其应用 |
CN107915297B (zh) * | 2017-11-15 | 2020-09-11 | 顺德职业技术学院 | 水溶性三元阴离子型聚合物分子刷染料捕捉沉降剂及其制备方法及其应用 |
CN107857330B (zh) * | 2017-11-15 | 2020-09-18 | 顺德职业技术学院 | 水溶性三元螯合聚合物分子刷阳离子染料捕捉剂及其制备方法及其应用 |
CN107698001B (zh) * | 2017-11-15 | 2020-10-30 | 顺德职业技术学院 | 阳离子染料絮凝剂及其应用 |
CN113354562A (zh) * | 2020-03-05 | 2021-09-07 | 中国科学院化学研究所 | 侧链高度有序排列的刷形聚合物及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN106467327B (zh) | 2019-06-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106467327A (zh) | 三元聚合物分子刷重金属捕捉剂的制备方法 | |
CN106430499B (zh) | 三元聚合物分子刷重金属捕捉剂的制备方法 | |
Liu et al. | Synthesis of poly (dimethyldiallylammonium chloride-co-acrylamide)-graft-triethylenetetramine–dithiocarbamate and its removal performance and mechanism of action towards heavy metal ions | |
Donovan et al. | Sulfobetaine‐containing diblock and triblock copolymers via reversible addition‐fragmentation chain transfer polymerization in aqueous media | |
KR20170137220A (ko) | 금속 소거 중합체 및 그 용도 | |
Jiang et al. | Synthesis and property of poly (sodium 4-styrenesulfonate) grafted chitosan by nitroxide-mediated polymerization with chitosan-TEMPO macroinitiator | |
EP2738189B1 (en) | Amphiphilic macromolecule and use thereof | |
CA2842704A1 (en) | Amphiphilic macromolecule and use thereof | |
Yu et al. | Preparation of a cationic block copolymer composite coagulant TP (AM-DAC-PPFS) and its coagulation performance for treating oilfield sewage | |
CN104973673B (zh) | 一种重金属污水多功能处理剂及合成方法 | |
CN106496577B (zh) | 热敏型聚合物分子刷重金属捕捉剂的制备方法 | |
JP2013031838A (ja) | 有機/無機ハイブリッド高分子凝集剤 | |
Yang et al. | Removal of multiple heavy metal ions using a macromolecule chelating flocculant xanthated chitosan | |
Göktaş | Synthesis and characterization of temperature-responsive block copolymers using macromonomeric initiator | |
Dubey et al. | Synthesis of a copolymeric system and its flocculation performance for iron ore tailings | |
CN107879449A (zh) | 低成本螯合复合型重金属捕捉剂及其制备方法及其应用 | |
EP2738190A1 (en) | Amphiphilic macromolecule and use | |
CN106496576B (zh) | 酸敏型四元聚合物分子刷重金属捕捉剂的制备方法 | |
Shi et al. | Synthesis, characterization and scale inhibition performance evaluation of novel dendrimers with the initiator core of pentaerythritol derivative | |
JP2020517806A (ja) | 分岐ポリマー | |
CN107744798A (zh) | 生物质螯合改性重金属捕获剂及其制备方法及其应用 | |
CN106496574B (zh) | 热敏型重金属捕捉剂的制备方法 | |
CN106496575A (zh) | 酸敏型重金属捕捉剂的制备方法 | |
Emara et al. | Recycling of steel industry waste acid in the preparation of Fe3O4 nanocomposite for heavy metals remediation from wastewater | |
Vo et al. | Chemical and Photochemical Routes Toward Tailor-Made Polymer–Clay Nanocomposites: Recent Progress and Future Prospects |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Chen Yanwu Inventor after: Liu Feng Inventor after: Li Weishan Inventor after: Chen Xueyi Inventor after: Peng Qi Inventor after: Huo Yingpeng Inventor after: Lu Fenghui Inventor before: Liu Feng Inventor before: Li Weishan Inventor before: Chen Xueyi Inventor before: Peng Qi Inventor before: Huo Yingpeng Inventor before: Lu Fenghui Inventor before: Chen Yanwu |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231016 Address after: 230000 Room 203, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Hefei Jiuzhou Longteng scientific and technological achievement transformation Co.,Ltd. Address before: 528300 Desheng Road, Shunde District, Foshan, Guangdong, Daliang Patentee before: SHUNDE POLYTECHNIC |