CN106455575A - Active compound combinations - Google Patents

Active compound combinations Download PDF

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Publication number
CN106455575A
CN106455575A CN201580025270.0A CN201580025270A CN106455575A CN 106455575 A CN106455575 A CN 106455575A CN 201580025270 A CN201580025270 A CN 201580025270A CN 106455575 A CN106455575 A CN 106455575A
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plant
seed
spp
present
fructus
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Chinese (zh)
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U·沃申道夫-纽曼
S·希勒布兰德
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Bayer CropScience AG
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Bayer CropScience AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/08—Immunising seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Soil Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

The invention relates to active compound combinations, in particular a fungicidal composition, comprising (A) 2- {3-[2-(l- {[3,5-bis(difluoromethyl)-lH-pyrazol-l-yl]acetyl}piperidin-4-yl)-l,3-thiazol- 4-yl]-4,5-dihydro-l,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate, (B) fosetyl-aluminium and (C) 2,6-dimethyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrole-l,3,5,7(2H,6H)-tetrone, Propineb or Folpet. Moreover, the invention relates to a method for curatively or preventively controlling the phytopathogenic fungi of plants or crops, to the use of a combination according to the invention for the treatment of seed, to a method for protecting a seed and not at least to the treated seed.

Description

Active agent combinations
The present invention relates to active agent combinations, particularly Fungicidal composition, its comprise (A) 2- 3- [2-1- [3, 5- bis- (difluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidin-4-yl) -1,3- thiazole-4-yl] -4,5- dihydro -1,2- Azoles -5- base } -3- chlorphenyl methanesulfonates, (three (ethylphosphonic acid) aluminum, CAS 39148-24-8 is (by FR- for (B) phosethyl-Al Known to A-2254276)) and (C) 2,6- dimethyl -1H, 5H- [1,4] two thiophene English simultaneously [2,3-c:5,6-c'] two pyrroles -1,3, 5,7 (2H, 6H)-tetrones (CAS 16114-35-5, known to US 3364229 and WO 2010/043319), propineb ([[(1- methyl isophthalic acid, 2- ethane diyl) double [aminodithioformic acids]] (2-)] zinc ([[(1-methyl-1,2- Ethanediyl) bis [carbamodithioato]] (2-)] zinc) homopolymer, CAS 12071-83-9 is (by BE 611960 Known)) or folpet (N- (trichloro-methylthio) phthalimide, CAS 133-07-3, known to US 2553770).
Additionally, the present invention relates to being used for therapeutic ground or prophylactically prevent and treat the plant pathogenic fungi of plant or crop Method, the conjugate being related to the present invention is used for processing the purposes of seed, is related to protection of seed and is not limited solely to the seed processing Method.
Known compound 2- { 3- [2- (1- { [3,5- bis- (difluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidines -4- Base) -1,3- thiazole-4-yl] -4,5- dihydro -1,2- azoles -5- base } -3- chlorphenyl methanesulfonates has fungicidal properties (WO 2012/025557).However, the focus that oomycetes diseases are the activity profiles of this material are located.
In addition it has also been found that 2- 3- [2- (1- { [3,5- bis- (difluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidines - 4- yl) -1,3- thiazole-4-yl] -4,5- dihydro -1,2- azoles -5- base } -3- chlorphenyl methanesulfonates and other antifungal tie Close the synergistic combinations (WO 2013/127704) having obtained the plant pathogenic fungi for preventing and treating plant or crop.However, Oomycetes diseases are that the focus of the activity profile of this mixture are located.
Furthermore it is known that the phosphate ester phosphonic acids hydrogen ethyl ester of phosphonic acids and derivant (phosphonate ester) such as general entitled phosethyl-Al and Its derivant can be used for preventing and treating plant pathogenic fungi (Pesticide Manual, the 14th edition (2006) of plant and crop； " Modern Agrochemicals ", volume 4, the 3rd phase, in June, 2005；FR-A-2254276).However, these materials are low Activity under rate of application is not always enough.
It is known that compound 2,6- dimethyl -1H, 5H- [1,4] two thiophene English simultaneously [2,3-c:5,6-c '] two pyrroles -1,3,5, 7 (2H, 6H)-tetrones can be also suitably used for preventing and treating the plant pathogenic fungi (WO 2010/043319) of plant and crop.However, this A little activity under low rate of application for the material are not equally always enough.
It is known that compounds methyl zineb can be also suitably used for preventing and treating the plant pathogenic fungi (BE of plant and crop 611960).However, activity under low rate of application for this material is not equally always enough.
It is known that compound folpet can be also suitably used for preventing and treating the plant pathogenic fungi (US of plant and crop 2553770).However, activity under low rate of application for this material is not equally always enough.
In addition, because to modern antifungal apply environment and economic requirement improve constantly, for example, with regard to action spectrum, Toxicity, selectivity, rate of application, residue formed and favourable can preparative, and additionally because there may be problem, example As improved to the resistance of known reactive compound, so a lasting task is the new antifungal of exploitation, it is at least Some fields have the advantages that better than homologue known to it.
The present invention provides active agent combinations, and it at least achieves described purpose in some cases.
Surprisingly it has now been found that comprising following new active agent combinations
(A) 2- { 3- [2- (1- { [3,5- bis- (difluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidin-4-yl) -1,3- Thiazole-4-yl] -4,5- dihydro -1,2- azoles -5- base } -3- chlorphenyl methanesulfonates, and
(B) phosethyl-Al, and
(C) propineb, folpet or 2,6- dimethyl -1H, 5H- [1,4] two thiophene English simultaneously [2,3-c:5,6-c '] two Pyrroles -1,3,5,7 (2H, 6H)-tetrone
Not only there are very good fungicidal properties, but also display for plant pathogenic fungi to be prevented and treated and/ Or the cumulative enhancing of the action spectrum of microorganism and/or nuisance, and above all achieve cooperative effect, described cooperative effect Expand the sphere of action of compound (A), (B) and (C) in two ways.First, the rate of application of compound (A), (B) and (C) Reduce, effect simultaneously maintains like good.Secondly, in addition these three single compounds in the range of so low rate of application In the case of becoming nearly unavailable, this conjugate still achieves the phytopathogen control of height.On the one hand this make big Width extends the phytopathogen spectrum that can prevent and treat, and on the other hand improves safety in utilization.
However, except, in addition to the actual synergism in terms of Fungicidally active, the conjugate of the present invention also has it Its beat all advantageous feature, it is alternatively referred to as synergistic activity in a broad sense.The example of these advantageous feature that can be mentioned that is： Antifungal and/or insecticidal activity spectrum are extended to other plant pathogenic epiphyte and/or microorganism and/or nuisance, for example, expands Open up to resistant strain；Reduce the rate of application of active component；By means of the compositionss of the present invention, in addition single compound almost without Sufficient Pest control under the rate of application of effect；During preparing or apply when, for example grinding, screening, emulsifying, dissolving or During distribution, advantageous property；The light stability improved；More favourable degradability；The toxicology improved or ecotoxicology performance； The characteristic of the improvement of useful plant, including emerging, crop yield, more flourishing root system, tiller increase, increase plant height, more Big blade, less dead basal leaf, higher tiller, greener leaf color, less fertilizer needs, less seed needs Will, the tiller of more high yield, more prematurity, frumentum prematureness, less plant reversely (plant verse) (lodging), branch of raising Bar growth, the plant vigor improving and early stage rudiment；Or any other advantage familiar to the person skilled in the art.
The conjugate of the present invention can also provide improved systematicness by the reactive compound being used.Even if it is true that Some in the Fungicidal compounds being used do not have any systematicness or do not have gratifying systematicness, then at this In bright compositionss, these compounds still can show this characteristic.
Similarly, the conjugate of the present invention can make the persistency of the used anti-fungal efficacy of reactive compound increase Plus.
Another advantage of the conjugate of the present invention is to can achieve effect of increase.
In preferred embodiments, the active agent combinations of the present invention produce following characteristic in one or more：
The cumulative spectrum of spectrum, cooperative effect, the yield improving, more flourishing root system, greener leaf, tiller increase, increase Plant height, bigger blade, less dead basal leaf, higher tiller, less fertilizer need, more high yield point Tiller, more prematurity, frumentum earlier are ripe, less plant reversely, the shoot growth improving, the plant vigor improving, earlier Rudiment, improved systematicness, increased anti-fungal efficacy persistency, the attainable effect of increase.
It is also preferred that the active agent combinations of the present invention produce following characteristic：The cumulative enhancing of spectrum.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Cooperative effect.
It is also preferred that the active agent combinations of the present invention produce following characteristic：The yield improving.
It is also preferred that the active agent combinations of the present invention produce following characteristic：More flourishing root system.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Greener leaf.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Tiller increases.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Increased plant height.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Bigger blade.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Less dead basal leaf.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Higher tiller.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Less fertilizer needs.
It is also preferred that the active agent combinations of the present invention produce following characteristic：The tiller of more high yield.
It is also preferred that the active agent combinations of the present invention produce following characteristic：More prematurity.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Frumentum earlier is ripe.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Less plant is reverse.
It is also preferred that the active agent combinations of the present invention produce following characteristic：The shoot growth improving.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Rudiment earlier.
It is also preferred that the active agent combinations of the present invention produce following characteristic：The plant vigor improving.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Improved systematicness.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Increased anti-fungal efficacy is held Property long.
It is also preferred that the active agent combinations of the present invention produce following characteristic：Increase attainable effect.
For this ternary mixture, the weight ratio selecting active compound component is to produce required effect, for example collaborative Effect：
(A):(B):(C) it is 1:500:200 to 1:50:10；Preferably 1:200:180 to 1:100:25.
If being (C) 2,6- dimethyl -1H, 5H- [1,4] two thiophene English simultaneously [2,3-c:5,6-c '] two pyrroles -1,3,5,7 (2H, 6H)-tetrone, then most preferably weight ratio is for 1:200:40 to 1:150:30.
If (C) being propineb, then most preferably weight ratio is for 1:200:180 to 1:150:150.
If (C) being folpet, then most preferably weight ratio is for 1:200:150 to 1:150:100.
In the presence of compound (A), (B) or (C) can be with tautomeric form, this compound should be managed within a context Xie Wei, in appropriate circumstances, also includes corresponding tautomeric form, even if it is not specifically carried in each case And.
The compound (A), (B) or (C) with least one basic center can form such as acid-adducting salt, for example：With Strong inorganic acid, such as mineral acid, such as perchloric acid, sulphuric acid, nitric acid, nitrous acid, phosphoric acid or halogen acids；With strong organic carboxyl acid, for example The C of unsubstituted replacement (as halogen substiuted)1-C4Alkanoic acid such as acetic acid, saturation or undersaturated dicarboxylic acids for example oxalic acid, third Diacid, succinic acid, maleic acid, fumaric acid and phthalic acid, hydroxy carboxylic acid for example ascorbic acid, lactic acid, malic acid, tartaric acid and Citric acid, or benzoic acid；Or and organic sulfonic acid, the C of for example unsubstituted or substituted (as halogen substiuted)1-C4Alkanesulfonic acid or aryl Sulfonic acid, such as methanesulfonic acid or p-methyl benzenesulfonic acid.Have the compound (A) of at least one acid groups or compound (B) can, example As with alkali forming salt, such as slaine, such as alkali metal salt or alkali salt, such as sodium, potassium or magnesium salt；Or with ammonia or organic Amine forming salt, for example with morpholine, piperidines, pyrrolidine, single-, two- or three-low-grade alkylamine (as ethyl-, diethyl-, three second Base-or Dimethyl-propyl-amine) or single-, two- or three-hydroxy lower alkyl amine (as single-, two- or three-ethanolamine).Separately Outward, corresponding inner salt can optionally be formed.In the context of the present invention, the preferably favourable salt of agriculture chemistry.In view of trip Close relation between the compound (A) of form, (B) or (C) and its salt form, in the case of suitable and suitable, above Hereinafter any content being related to free compound (A), (B) or (C) or its salt is understood to also include respectively accordingly Salt or free compound (A), (B) or (C).This equivalent is also applied for the tautomer of compound (A), (B) or (C) And its salt.
Although the mixture of the present invention itself can be compositionss, the final compositionss using are generally by following system Standby：The compound of formula (A) is mixed with compound (B) and (C) and inert carrier, and if necessary, adds surfactant And/or another kind is for the auxiliary agent such as extender of preparation, and this mixture is configured to oil formulation, emulsifiable concentrate, can flow Dynamic preparation, wettable powder, water-dispersible granules, powder, granule etc..It is used alone or by adding another inert component And the preparation using can serve as pesticide.
Specifically other components of this final composition are described further below.
" compositionss " can be by following preparation：Prepare compound and compound (B) and (C) of formula (A) as described above, Then preparation of preparation or its diluent liquid.
For clarity, mixture (mixture) means the compound of formula (A) and the physical bond of compound (B) and (C) Thing (combination), and compositionss (composition) mean mixture and other additives for example surfactant, solvent, Carrier, pigment, defoamer, thickening agent and extender, are suitable for the conjugate of the form of agriculture chemistry application.
The invention still further relates to one kind is used for preventing and treating harmful microbe method, including making described harmful microorganism or its habitat Contact with above-mentioned composition.
The invention still further relates to a kind of method processing seed, contact with above-mentioned composition including making described seed.
Finally, the invention still further relates to the seed crossed with above-mentioned compositions-treated.
Therefore, the invention still further relates to being used for preventing and treating the compositionss of harmful microorganism, particularly harmful fungoid and antibacterial, its bag Containing effectively but the active component of the present invention of non-phytotoxic amount.These are preferably Fungicidal composition, and it comprises agriculturally to close Suitable auxiliary agent, solvent, carrier, surfactant or extender.
In the context of the present invention, " harmful microbe preventing and treating " refers to, compared with undressed plant, be harmful to The reduction of microbial infection, to be measured with fungicidal efficiency, reduces 25- preferably compared with undressed plant (100%) 50%, reduce 40-79% more preferably compared with undressed plant (100%)；Even further preferably, complete inhibition is harmful to Microbial infection (70-100%).Described preventing and treating can be curative, that is, be used for processing the plant infected, or protect Shield property, for protecting the plant not yet infected.
" effectively but non-phytotoxic amount " refers to enough to the fungal disease of preventing and treating plant in a satisfactory manner or completely Eradicate fungal disease and the amount of the present composition of any significant phytotoxicity symptom will not be caused simultaneously.Generally, should Rate of application can change in wider scope.It depends on several factors, funguses for example to be prevented and treated, plant, weather conditions and The composition of the present composition.
Suitable organic solvent includes institute's polarized and the non-polar organic solvent being generally used for preparing purpose.Preferably molten Agent is selected from ketone, such as methyl-isobutyl ketone and Ketohexamethylene；Amide, such as dimethylformamide and alkanoic acid amide, such as N, N- Dimethyldecamide and N, N- dimethyloctanamide；And circulus solvent, such as N- methyl-pyrrolidon, N- octyl group-pyrrole Pyrrolidone, N- dodecyl-ketopyrrolidine, N- octyl group-caprolactam, N- dodecyl-caprolactam and butyrolactone；And it is strong Polar solvent, such as dimethyl sulfoxide；And aromatic hydrocarbons, such as dimethylbenzene, SolvessoTM, mineral oil is (as white spirit (white Spirit), oil, alkylbenzene and bobbin oil)；And ester, such as Propyleneglycol-monomethylether acetass, dibutyl adipate, second The own ester of acid, heptyl acetate, tri-n-butyl citrate and n-butyl phthalate；And alcohol, such as benzylalcohol and 1- methoxyl group- 2- propanol.
According to the present invention, carrier is naturally occurring or synthetic organic or inorganic material, its mix with active component or combine with Preferably apply, be particularly applied to plant or plant part or seed.Carrier, it can be solid or liquid, typically inertia And should be suitable in agricultural.
Useful solid or liquid-carrier include：Such as ammonium salt and natural rock dust (such as Kaolin, clay, Talcum, white Chalk, quartz, attapulgite, montmorillonite or kieselguhr) and synthesis rock dust (silicon dioxide for example in small, broken bits, aluminium oxide and natural or conjunction The silicate becoming), resin, wax, solid fertilizer, water, alcohol (particularly butanol), organic solvent, mineral oil and vegetable oil and its spread out Biological.The mixture of these carriers equally can also be used.
Suitable solid packing and carrier include：Inorganic particle, such as carbonate, silicate, sulfate and oxide, its Particle mean size is 0.005 μm to 20 μm, preferably 0.02 μm to 10 μm, such as ammonium sulfate, ammonium phosphate, carbamide, Calcium Carbonate, sulphuric acid Calcium, magnesium sulfate, magnesium oxide, aluminium oxide, silicon dioxide, so-called fine-particle silicon dioxide, silica gel, naturally occurring or synthetic silicic acid Salt and aluminosilicate and plant product such as flour, wood powder/sawdust and cellulose powder.
The solid carrier of useful granule includes：The natural rock for example pulverized and be classified such as calcite, marble, floating Stone, meerschaum, dolomite, and the granule of the inorganic and organic powder of synthesis, and the granule of organic material, such as sawdust, coconut palm Shell, maize cob and tobacco rods.
The gaseous state extender of useful liquefaction or carrier are such liquid, and it is gas under standard temperature and normal pressure State, such as aerosol propellant such as halogenated hydrocarbons, and butane, propane, nitrogen and carbon dioxide.
In said preparation, it is possible to use viscosifier such as carboxymethyl cellulose, and powder, granule or latex form natural and Synthetic polymer, such as Radix Acaciae senegalis, polyvinyl alcohol and polyvinyl acetate, or natural phospholipid, such as cephalin and lecithin, with And synthetic phospholipid.Other additives can be mineral oil and vegetable oil.
If extender used is water, such as organic solvent can also be used as cosolvent.Useful liquid is molten Agent is mainly：Aromatic compounds, such as dimethylbenzene, toluene or alkylnaphthalene；Chlorinating aromatic compounds and chlorinated aliphatic hydrocarbons, such as chlorine Benzene, vinyl chloride or dichloromethane；Aliphatic hydrocarbon, such as hexamethylene or paraffin, such as mineral oil fractions, mineral oil and vegetable oil；Alcohol, such as Butanol or ethylene glycol and their ether and ester；Ketone, such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or Ketohexamethylene；Highly polar Solvent, such as dimethylformamide and dimethyl sulfoxide；And water.
The compositionss of the present invention also can comprise other components, such as surfactant.Useful surfactant is emulsifying Agent and/or foaming agent, there is ion or the dispersant of nonionic nature or the mixture of wetting agent or these surfactants. The example is polyacrylic salt, the salt of the salt of lignosulphonic acid, phenolsulfonic acid or LOMAR PWA EINECS 246-676-2, oxirane and fatty alcohol or and fat The condensation polymer of fat acid or fatty amine, the phenol (preferably alkyl phenol or aryl phenol) replacing, the salt of sulfosuccinate, taurine derive Thing (preferably taurine Arrcostab), the alcohol of polyethoxylated or the phosphate ester of phenol, the fatty ester of polyhydric alcohol and contain sulphuric acid The derivant of the compound of root, sulfonate radical and phosphate radical, such as alkylaryl polyglycol ether, alkylsulfonate, alkylsurfuric acid Salt, arylsulphonate, protein hydrolysate, lignin sulfite waste liquor and methylcellulose.If one of active component and/ Or one of inert carrier be insoluble in water and apply and carry out in water, then the presence of surfactant is necessary.Table The ratio of face activating agent is 5-40 weight % of the present composition.
Suitable surfactant (adjuvant, emulsifying agent, dispersant, protecting colloid, wetting agent and adhesive) includes all The polyalkylene glycol ethers of conventional ion and nonionic, such as ethoxylated nonylphenol, side chain or branched-chain alcoho, alkyl phenol With the product of the product, fatty acid amine and oxirane and/or expoxy propane of oxirane and/or expoxy propane, And fatty acid ester, alkylsulfonate, alkyl sulfate, alkyl ether sulfate, alkyl ether phosphate, aryl-sulfate, ethoxy Base aryl alkyl phenol, such as triphenylethylene base-phenol-ethoxylate and ethoxylation and propoxylated aryl alkyl Phenol such as sulphation or phosphorylation aryl alkane phenol-ethoxylate and-ethyoxyl and propoxylate.Other examples are natural and close The water-soluble polymer becoming, for example, lignosulphonates, gelatin, Radix Acaciae senegalis, phospholipid, starch, Hydrophobic Modified Starch and fiber Plain derivant, particularly cellulose esters and cellulose ether, and polyvinyl alcohol, polyvinyl acetate, Polyvinylpyrrolidone, poly- Acrylic acid, polymethylacrylic acid and (methyl) acrylic acid and the copolymer of (methyl) acrylate, and by alkali metal hydrogen-oxygen The methacrylic acid of compound neutralization and the copolymer of methacrylate, and the condensation of optionally substituted naphthalene sulfonate and formaldehyde Product.
Dyestuff, such as inorganic pigment can be used, such as ferrum oxide, titanium oxide and Prussian blue；And organic dyestuff, for example Alizarin dyes, azo dye and metallized phthalocyanine dye；And trace nutrient, such as ferrum, manganese, boron, copper, cobalt, molybdenum and zinc Salt.
May be present in the defoamer in preparation and include such as silicone emulsion, long-chain alcohol, fatty acid and its salt and fluorine-containing Organic substance and its mixture.
The example of thickening agent be polysaccharide, such as xanthan gum or aluminium-magnesium silicate, silicate, such as attapulgite, bentonite with And fine-particle silicon dioxide.
If appropriate it is also possible to there are other additional component, such as protecting colloid, binding agent, adhesive, thickening agent, touch Become material, penetrating agent, stabilizer, sequestering agent, chelating agent.Generally, active component can be generally used for preparation purpose appoint What solid or liquid additive combine.
According to its specific physically and/or chemically characteristic, the mixture of the present invention or compositionss can be used with itself Or the form of its preparation uses or uses for type of service prepared therefrom, for example aerosol, capsule suspension liquid, harl concentrate Thing, warm fog concentrate, encapsulating granule, granula subtilises, for processing the flowable concentrate of seed, ready to use solution, can dust powder Agent, emulsifiable concentrate, oil-in-water emulsion, water-in-oil emulsion, big granule, microgranule, oil dispersible powder, oil is miscible can Flowing concentrate, gas (under pressure), gas generate product, foam, paste, coated pesticidal seed, suspension-concentrates, outstanding breast Emulsion concentrate, solubility concentrate, suspension, wettable powders, soluble powder, powder and granule, water solublity and water Dispersion-ness particle agent or tablet, for processing the water solublity of seed and water-dispersible powder, wettable powder, being soaked with active component Microencapsulation in the natural product of stain and synthetic and polymeric material and seed coat material and ULV harl and Warm atomization preparation.
The compositionss of the present invention not only include being already prepared to using and can be utilized suitable device to be applied to plant or kind The preparation of son, and include the business concentrate of necessary dilute with water before use.Conventional administration is to dilute for example in water And subsequently spray gained spray liquid, dilute in oil after apply, do not dilute and directly apply, the soil of seed treatment or granule is applied With.
The mixture of the present invention, compositionss and preparation usually contain 0.05-99 weight %, 0.01-98 weight %, preferably The active component of 0.1-95 weight %, more preferably 0.5-90%, most preferably 10-70 weight %.For special applications for example In order to protect timber and derivative woodwork, the mixture of the present invention, compositionss and preparation usually contain 0.0001-95 weight Amount %, the preferably active component of 0.001-60 weight %.
The content of the active component in the administration form prepared by preparation can change in a wide range.In administration form The concentration of active component is usually 0.000001-95 weight %, preferably 0.0001-2 weight %.
Described preparation can be prepared in a way known, for example, pass through active component and at least one routine increment Agent, solvent or diluent, adjuvant, emulsifying agent, dispersant and/or binding agent or fixative, wetting agent, waterproofing agent, if appropriate If desiccant and UV stabilizer and dyestuff and pigment, defoamer, preservative, inorganic and organic thickening if appropriate Agent, adhesive, gibberellins and other processing aids are mixed with water conjunction.According to preparation type to be prepared, need other processing Step, for example, wet grinding, dry grinding and granulation.
The mixture of the present invention or compositionss can be existed or with its (commercially available) preparation with by these preparation systems with itself Standby exists as the type of service with the mixture of other (known) active component, and other (known) active component described such as kill Insecticide agent, attractant, sterilant, bactericide, acaricide, nematicide, antifungal, growth regulator, herbicide, fertilizer Material, safener and/or semiochemical.
With mixture or compositionss, the process of the present invention that plant and plant part are carried out directly is carried out or pass through Conventional treatment method acts on its environment, habitat or storage area and carries out, described conventional treatment method for example impregnates, sprays, Atomization, irrigation, evaporation, dusting, it is atomized, broadcasts sowing, foaming, being coated with, applying paving, pouring (immersion), drip irrigation and in propagating materialss In the case of, especially in the case of seed, process, crust, be coated with one layer also by dry seedses process, wet seed treatment, serosity Or multiple coatings etc..Described mixture or compositionss can also be applied by super-low capacity is mensuration, or by mixture or compositionss system Agent or active component are expelled in soil in itself.
Plant/crop protection
Described mixture or compositionss or compositionss have effective microbiocidal activity, and can be in crop protection and material It is used for preventing and treating harmful microorganism, such as funguses and antibacterial in protection.
The invention still further relates to for preventing and treating harmful microbe method it is characterised in that by the mixture of the present invention or combination Thing is applied to plant pathogenic fungi, plant-pathogenic antibacterial and/or its habitat.
Antifungal can be used for preventing and treating plant pathogenic fungi in crop protection.It is characterized in that to broad-spectrum plant disease Pathogenic fungi includes prominent effect of soil-borne disease substance, and it is specifically for infraclass：Plasmodiophoromycetes (Plasmodiophoromycetes), Oomycete (Peronosporomycetes) (synonym：Oomycete (Oomycetes)), Chytridiomycetes (Chytridiomycetes), Zygomycetes (Zygomycetes), Ascomycetes (Ascomycetes), Basidiomycetess And deuteromycetes (Deuteromycetes) (synonym (Basidiomycete)：Deuteromycetes (Fungi imperfecti)). Some antifungal are system activities and can be used as leaf, seed dressing or soil fungicide in plant protection.Additionally, they It is suitable for antifungal, it especially infects the wooden of plant or root.
Bactericide can be used for preventing and treating pseudomonadaceae (Pseudomonadaceae), Rhizobiaceae in crop protection (Rhizobiaceae), enterobacteriaceae (Enterobacteriaceae), Corynebacteriaceae (Corynebacteriaceae) and Streptomycetaceae (Streptomycetaceae).
The non-limiting example of the pathogen of fungal disease that can be processed according to the present invention includes：
The disease being led to by powdery mildew pathogen, described powdery mildew pathogen such as Blumeria (Blumeria), example As grass family dlumeria graminis (Blumeria graminis)；Podosphaera (Podosphaera), for example white cross hair list Softgel shell (Podosphaera leucotricha)；Sphaerotheca (Sphaerotheca), such as Herba Xanthii monofilament shell (Sphaerotheca fuliginea)；Uncinula (Uncinula), such as Fructus Vitis viniferae snag shell (Uncinula necator)；
The disease being led to by rust pathogen, described rust pathogen such as glue Rust (Gymnosporangium), example As brown size rest fungus (Gymnosporangium sabinae)；Camel spore rest fungus (Hemileia), such as coffee rust (Hemileia vastatrix)；Phakopsora (Phakopsora), such as Phakopsora pachyrhizi (Phakopsora ) and Herba podocarpii oxyphylli layer bacterium (Phakopsora meibomiae) pachyrhizi；Puccinia (Puccinia), such as concealment handle rust Bacterium (Puccinia recondita), leaf rust (P.triticina), puccinia graminis (P.graminis) or bar shaped handle rest fungus (P.striiformis)；Uromyces (Uromyces), such as wart top uromyce (Uromyces appendiculatus)；
The disease being led to by the pathogen from Oomycete, the pathogen such as white rust of described Oomycete belongs to (Albugo), Such as white rust (Albugo candida)；Bremia (Bremia), such as Caulis et Folium Lactucae sativae disk downy mildew (Bremia lactucae)； Peronospora (Peronospora), such as Semen Pisi sativi downy mildew (Peronospora pisi) or Peronospora parasitic (P.brassicae)；Epidemic disease Mould genus (Phytophthora), such as phytophthora infestans (Phytophthora infestans)；Plasmopara (Plasmopara), Such as Fructus Vitis viniferae single shaft mould (Plasmopara viticola)；The false frost of Pseudoperonospora (Pseudoperonospora), such as grass Mould (Pseudoperonospora humuli) or Pseudoperonospora cubensis (Pseudoperonospora cubensis)；Pythium (Pythium), such as Pythium ultimum (Pythium ultimum)；
By for example following leaf spot leading to and leaf blight, Alternaria (Alternaria), such as alternaria solani sorauer (Alternaria solani)；The raw tail spore (Cercospora beticola) of Cercospora (Cercospora), such as Radix Betae；Branch Spore belongs to (Cladiosporium), such as melon fruit fly (Cladiosporium cucumerinum)；Cochliobolus belongs to (Cochliobolus), such as standing grain cochliobolus (Cochliobolus sativus) (branch spore form (Conidia form)：Drechslera (Drechslera), synonym：Long compacted spore mould (Helminthosporium)), palace portion cochliobolus (Cochliobolus miyabeanus)；Colletotrichum (Colletotrichum), such as Kidney bean anthrax (Colletotrichum lindemuthianum)；Rust staining pathogenic bacteria belongs to (Cycloconium), for example Fructus oleae europaeae ring stalk spore bacterium (Cycloconium oleaginum)；Between seat shell belong to (Diaporthe), such as seat shell (Diaporthe citri) between Citrus； Elsinoe (Elsinoe), such as mandarin orange Elsinochrome (Elsinoe fawcettii)；Kind long spore belongs to (Gloeosporium), for example please the long spore of colour disk (Gloeosporium laeticolor)；Small cluster shell belongs to (Glomerella), Such as GLOMERFLLA CINGULATA (Glomerella cingulata)；Ball seat Pseudomonas (Guignardia), such as Fructus Vitis viniferae Guignardia (Guignardia bidwellii)；Leptosphaeria (Leptosphaeria), such as Cruciferae ball cavity bacteria (Leptosphaeria maculans), clever withered shell ball cavity bacteria (Leptosphaeria nodorum)；Ruin greatly shell to belong to (Magnaporthe), such as Lycoperdon polymorphum Vitt ruins greatly shell (Magnaporthe grisea)；Micro- spore belongs to (Microdochium), for example Avenge mould micro- spore (Microdochium nivale)；Mycosphaerella (Mycosphaerella), such as standing grain green-ball chamber bacterium (Mycosphaerella graminicola), Semen arachidis hypogaeae spherical cavity bacterium (M.arachidicola) and Fijian spherical cavity bacterium (M.fijiensis)；Dark mycosphaerella (Phaeosphaeria), such as Semen Tritici aestivi phaeosphaeria nodorum (Phaeosphaeria nodorum)；Nuclear cavity Pseudomonas (Pyrenophora), for example, justify nuclear cavity bacteria (Pyrenophora teres), couchgrass nuclear cavity bacteria (Pyrenophora tritici repentis)；Ramularia (Ramularia), for example, give birth to Ramularia (Ramularia collo-cygni)、Ramularia areola；Beak genuss (Rhynchosporium), such as rye (Secale cereale L.) beak spore (Rhynchosporium secalis)；Septoria (Septoria), such as Septoria apii (Septoria apii), Fructus Lycopersici esculenti septoria musiva (Septoria lycopersii)；Core coral Pseudomonas (Typhula), such as meat spore core coral bacterium (Typhula incarnata)；Venturia (Venturia), such as venturia inaequalis (Venturia inaequalis)；
By for example following root leading to and stem disease evil, corticium (Corticium), such as standing grain photovoltaicing leather bacteria (Corticium graminearum)；Fusarium (Fusarium), such as Fusarium oxysporum (Fusarium oxysporum)；Gaeumannomyces (Gaeumannomyces), such as gaeumannomyce (Gaeumannomyces graminis)；Rhizoctonia (Rhizoctonia), Such as Rhizoctonia solani Kuhn (Rhizoctonia solani)；For example led to by rice corruption pathogenic bacteria (Sarocladium oryzae) Broom Thamnidium (Sarocladium) disease；The genus sclerotium for example being led to by rice pyrenomycetes (Sclerotium oryzae) (Sclerotium) disease；Tapesia belongs to, such as Tapesia acuformis；Thiclaviopsis (Thielaviopsis), example As mould in Nicotiana tabacum L. root-rot (Thielaviopsis basicola)；
By for example following fringe leading to and panicle (inclusion Cob Maydis) disease, Alternaria, such as Alternaria；Bent Mould genus (Aspergillus), such as Aspergillus flavus (Aspergillus flavus)；Cladosporium (Cladiosporium), such as branch Shape cladosporium (Cladiosporium cladosporioides)；Claviceps (Claviceps), such as Claviceps purpurea (Claviceps purpurea)；Fusarium (Fusarium), such as fusarium culmorum (Fusarium culmorum)；Red Mould Pseudomonas (Gibberella), such as Gibberella zeae (Gibberella zeae)；Little setting-out shell belongs to (Monographella), example As avenged rotten bright shuttle spore (Monographella nivalis)；Septoria (Septoria), such as septoria musiva (Septoria nodorum)；
The disease being led to by smut, for example, axle Ustilago (Sphacelotheca), such as Sorghum vulgare Pers. silk smut-fungi (Sphacelotheca reiliana)；Tilletia (Tilletia), such as Semen Tritici aestivi net bunt powder bacterium (Tilletia Caries), T. contraversa (T.controversa)；Urocystis (Urocystis), for example hidden bar smut (Urocystis occulta)；Ustilago (Ustilago), such as naked smut (Ustilago nuda), U.nuda tritici；
By for example following fruit rot leading to, aspergillus, such as Aspergillus flavus；Botrytis (Botrytis), such as ash Botrytis (Botrytis cinerea)；Penicillium (Penicillium), such as penicillium expansum (Penicillium ) and penicillium purpurogenum (P.purpurogenum) expansum；Sclerotinia belongs to (Sclerotinia), such as sclerotinite (Sclerotinia sclerotiorum)；Verticillium (Verticillium), such as Huang withers and takes turns branch spore (Verticillium alboatrum)；
Rotten, mouldy, withered, corrupt and disease of dampinging off, Alternaria are passed by for example following seed leading to and soil (Alternaria), for example led to by Alternaria brassicicola (Alternaria brassicicola)；Aphanomyces (Aphanomyces), for example led to by Semen Pisi sativi silk capsule mould (Aphanomyces euteiches)；Ascochyta (Ascochyta), for example led to by Radix Crotalariae szemoensiss Ascochyta tini (Ascochyta lentis)；Aspergillus, for example, led by Aspergillus flavus Cause；Cladosporium (Cladosporium), for example, led to by multi-trunk natalensis (Cladosporium herbarum)；Cochliobolus belongs to (Cochliobolus), for example led to by standing grain cochliobolus (Cochliobolus sativus)；(conidial form：De Shi Mould genus (Drechslera), Bipolaris (Bipolaris) synonym：Helminthosporium (Helminthosporium))；Anthrax Pseudomonas (Colletotrichum), for example, led to by hair core anthrax (Colletotrichum coccodes)；Fusarium (Fusarium), for example led to by fusarium culmorum (Fusarium culmorum)；Gibberella belongs to (Gibberella), for example Led to by Gibberella zeae (Gibberella zeae)；Shell ball spore belongs to (Macrophomina), such as by Kidney bean shell ball spore bacterium (Macrophomina phaseolina) leads to；Little setting-out shell belongs to (Monographella), such as by the rotten little setting-out shell of snow (Monographella nivalis) leads to；Penicillium (Penicillium), such as by penicillium expansum (Penicillium Expansum) lead to；Phoma (Phoma), for example, led to by Cruciferae black shin bacterium (Phoma lingam)；Phomopsis Belong to (Phomopsis), for example, led to by Semen sojae atricolor Phomopsis (Phomopsis sojae)；Phytophthora (Phytophthora), example As led to by Phytophthora cactorum (Phytophthora cactorum)；Nuclear cavity Pseudomonas (Pyrenophora), such as by wheat and barley nuclear cavity bacteria (Pyrenophora graminea) leads to；Pyricularia Sacc. (Pyricularia), such as by Magnaporthe grisea (Pyricularia Oryzae) lead to；Rotten mold genus (Pythium), for example, led to by Pythium ultimum (Pythium ultimum)；Rhizoctonia, example As led to by Rhizoctonia solani Kuhn (Rhizoctonia solani)；Rhizopus (Rhizopus), such as by rice rhizopus (Rhizopus Oryzae) lead to；Bulbil belongs to (Sclerotium), for example, led to by Sclerotium rolfsii (Sclerotium rolfsii)；Shell Pin spore belongs to (Septoria), for example, led to by phaeosphaeria nodorum (Septoria nodorum)；Core coral Pseudomonas (Typhula), example As led to by meat spore core coral bacterium (Typhula incarnata)；Take turns mould Pseudomonas (Verticillium), such as by verticillium dahliae (Verticillium dahliae) leads to；
By such as Nectria (Nectria), such as a kind of fruit, such as apple, pear, etc. does what cancer clump red shell bacterium (Nectria galligena) led to Cancer (cancers) and witches' broom；
By such as chain sclerotinia sclerotiorum belong (Monilinia), it is withered that such as drupe chain sclerotinia sclerotiorum (Monilinia laxa) leads to Wither disease；
By such as Exobasidium (Exobasidium), such as eggplant outer cross-arming bacteria (Exobasidium vexans)；Exoascus (Taphrina) leaf blotch or leaf curl that, for example lopsided external capsule bacterium (Taphrina deformans) leads to.
By the decline disease of for example following xylophyta (Wooden Plant) leading to, such as by rhizopus lattice spore bacterium (Phaeomoniella clamydospora), Phaeoacremonium aleophilum and Fomitiporia Eschka (Esca) disease that mediterranea leads to；The Fructus Vitis viniferae apical dieback for example being led to by Fructus Vitis viniferae apical dieback bacterium (Eutypa lata) Sick (Eutypa dyeback)；The Ganoderma disease for example being led to by long and narrow spore Ganoderma (Ganoderma boninense)；For example by wood Rigidoporus (Rigidoporus) disease that Rigidoporus duruss (Rigidoporus lignosus) lead to；
By such as Botrytis (Botrytis), such as the pathogen of Botrytis cinerea (Botrytis cinerea) leads to flower and kind The disease of son；
By such as Rhizoctonia (Rhizoctonia), such as Rhizoctonia solani Kuhn (Rhizoctonia solani)；Long compacted spore Mould genus (Helminthosporium), the plant tuber that for example the compacted spore of eggplant length (Helminthosporium solani) leads to Disease；
By such as knee Pseudomonas (Plamodiophora), such as mustard belongs to plasmodiophora brassicae (Plamodiophora brassicae) The clubroot leading to.
The disease being caused by bacterial pathogens, described bacterial pathogens such as xanthomonas (Xanthomanas), such as water Rice bacterial leaf spot Xanthomonas campestris (Xanthomonas campestris pv.oryzae)；Rhodopseudomonass (Pseudomonas), such as Pseudomonas syringae angular leaf spot of cucumber pvs oryzae and oryzicola (Pseudomonas syringae pv.lachrymans)；Erwinia Belong to (Erwinia), such as solution Erzvinia amylovora (Erwinia amylovora).
Following soybean diseases preferably can be prevented and treated：
By the fungal disease on for example following leaf, stem, pod and the seed leading to：Rod method leaf spot (Alternaria Spec.atrans tenuissima), anthrax (Colletotrichum gloeosporoides dematium Var.truncatum), brown spot (Soybean Brown Spot line septoria musiva (Septoria glycines)), tail spore leaf spot and leaf blight (Kikuchi tail spore (Cercospora kikuchii)), choanephora leaf blight (Choanephora infundibulifera Trispora (synonym)), dactuliophora leaf spot (Dactuliophora glycines), downy mildew (northeast downy mildew (Peronospora manshurica)), drechslera epidemic disease (Drechslera glycini), Frogeye Leaf Spot (Semen sojae atricolor Tail spore (Cercospora sojina)), leptosphaerulina leaf spot (Leptosphaerulina trifolii), leaf Point mould (phyllostica) leaf spot (the raw phyllosticta (Phyllosticta sojaecola) of Semen sojae atricolor), pod and cane blight (Semen sojae atricolor Pod stalk withered rotten disease (Phomopsis sojae)), powdery mildew (Microsphaera diffusa), pyrenochaeta leaf spot (Pyrenochaeta glycines), rhizoctonia ground epidemic disease, leaf blight (foliage blight) and damping-off (web Blight) (Rhizoctonia solani Kuhn), rust (Phakopsora pachyrhizi (Phakopsora pachyrhizi, Phakopsora Meibomiae), shot hole (Semen sojae atricolor crust circle spore (Sphaceloma glycines)), (handle of crawling is mould for stemphylium leaf blight (Stemphylium botryosum)), target spot (target spot) (Corynespora cassicola (Corynespora cassiicola)).
By the fungal disease on for example following root and stem foot leading to：Black root rot (Calonectria Crotalariae), charcoal rot (Kidney bean shell ball spore bacterium (Macrophomina phaseolina)), fusarium epidemic disease or wilting, root Rotten and pod and root neckrot rotten (sharp fusarium (Fusarium oxysporum), straight beak fusarium (Fusarium orthoceras), F.semitectum (Fusarium semitectum), Herba Equiseti Hiemalises' fusarium (Fusarium equiseti)), mycoleptodiscus root Maize ear rot (Mycoleptodiscus terrestris), neocosmospora (Neocosmopspora vasinfecta), pod And cane blight (seat shell (Diaporthe phaseolorum) between Kidney bean), stem canker (Semen sojae atricolor north stem canker (Diaporthe phaseolorum var.caulivora)), phytophthora maize ear rot (male greatly phytophthora (Phytophthora Megasperma)), brown stem rot (brown stem rot bacterium (Phialophora gregata)), (melon and fruit corruption is mould for rotten mould maize ear rot (Pythium aphanidermatum), abnormal female corruption mould (Pythium irregulare), pythium debaryanum (Pythium Debaryanum), P. myriotylum (Pythium myriotylum), Pythium ultimum (Pythium ultimum)), rhizoctonia root Maize ear rot, stem rot and damping off (Rhizoctonia solani Kuhn (Rhizoctonia solani)), sclerotinite stem rot (sclerotinite (Sclerotinia sclerotiorum)), sclerotinite southern blight (sclerotinia Southern Blight) (Sclerotinia rolfsii), thielaviopsis sp root rot (Nicotiana tabacum L. root-rot mould (Thielaviopsis basicola)).
The Fungicidal mixture of the present invention or compositionss can be used for therapeutic or protectiveness/preventative preventing and treating plant-pathogenic Funguses.Therefore, the invention still further relates to prevent and treat plant pathogenic fungi by using the active component or compositionss of the present invention Therapeutic and protectiveness method, the active component of the described present invention or compositionss are applied to seed, plant or plant part, really Reality or the soil of plant growing.
The fact that described active component is tolerated well by plant under the concentration needed in controlling plant diseases makes it possible to Process aerial partss, propagating materialss and seed and the soil of plant.
According to the present invention it is possible to process all of plant and plant part.Plant refers to all plants and plant population, example Wild plant as desired and undesirable, cultivar and plant variety are (regardless of whether be subject to plant variety or plant breeder Rights protection).Cultivar and plant variety can be the plants being obtained by Sterile culture and breeding method, and methods described can With by one or more biological technique method for example by using dihaploid, protoplast fusion, random and orthomutation, Molecule or genetic marker or assisted by biological engineering and gene engineering method or supplement.Plant part refers to all of plant Part and plant organ, such as branch, leaf, Hua Hegen above and below the ground, wherein lists such as leaf, needle, stem, branch, flower, son real Body, fruit and seed and root, bulb and rhizome.Crop and trophism and genitality propagating materialss, such as cutting, bulb, Rhizome, long flagellum and seed fall within plant part.
The mixture of the present invention or compositionss, when they are tolerated well by plant, have favourable Homoiotherm poison Property and tolerated well by environment, it is suitable to protect plant and plant organ, improves yield, improves the quality harvesting material.It Be preferably used as crop production compositions.They are to usual sensitive and resistant species and growth all or some stage tool Active.
Following major crop plants can be included according to the plant that the present invention is processed：Corn and soybean, Herba Medicaginiss, Cotton Gossypii, to Day certain herbaceous plants with big flowers, Btassica Brassica campestris L (Brassica oil seeds) such as colea (Brassica napus) (such as canola (canola), oil seed rape (rapeseed)), Radix Brassicae rapae (Brassica rapa), Caulis et Folium Brassicae junceae (B.juncea) (such as (field) mustard Dish) and Ethiopia Caulis et Folium Brassicae junceae (Brassica carinata), Palmae (Arecaceae sp.) (such as Elaeis guineensis Jacq., Cortex cocois radiciss), Oryza sativa L., Semen Tritici aestivi, Radix Betae, Caulis Sacchari sinensis, Herba bromi japonici, rye (Secale cereale L.), Fructus Hordei Vulgaris, Semen setariae and Sorghum vulgare Pers., black Semen Tritici aestivi, Caulis et Folium Lini, nut, Fructus Vitis viniferae and liana And the various fruits and vegetables from various plant classification groups, such as Rosaceae (Rosaceae sp.) (such as a kind of fruit, such as apple, pear, etc. such as Herba Marsileae Quadrifoliae Fruit and pears, and drupe such as Fructus Pruni (apricots), Fructus Pruni pseudocerasi, almond (almonds), Fructus Pruni salicinae and Fructus Persicae, and berry such as Fructus Fragariae Ananssae, tree The certain kind of berries, red and Ribes nigrum L. and ribes grossularia (gooseberry)), Ribesioidae sp., Juglandaceae (Juglandaceae sp.), Betulaceae (Betulaceae sp.), paint Ochnaceae (Anacardiaceae sp.), Fagaceae (Fagaceae sp.), Moraceae (Moraceae sp.), Oleaceae (Oleaceae sp.) (such as Chinese olive tree), Actinidiaceae (Actinidaceae sp.), Camphor tree Section (Lauraceae sp.) (such as American Avocado Tree book, xylocinnamomum, Camphora), Musaceae (Musaceae sp.) (such as Banana tree and big Any of several broadleaf plants), Rubiaceae (Rubiaceae sp.) (such as coffee), Theaceae (Theaceae sp.) (such as tea), Sterculiaceae (Sterculiceae sp)., Rutaceae (Rutaceae sp.) (such as Fructus Citri Limoniae, Fructus Citri junoriss, Citrus and grapefruit)；Solanaceae (Solanaceae sp.) (such as Fructus Lycopersici esculenti, Rhizoma Solani tuber osi, Fructus Piperiss, Fructus Capsici, Fructus Solani melongenae, Nicotiana tabacum L.), Liliaceae (Liliaceae sp.), Compositae (Compositae sp.) (such as Caulis et Folium Lactucae sativae, arithoke and Herba Cichorii include root Herba Cichorii, Lettuce or common Herba Cichorii), umbrella shape Section (Umbelliferae sp.) (such as Radix Dauci Sativae, parsley, Herba Apii graveolentiss and celeriac), Cucurbitaceae (Cucurbitaceae sp.) (such as Fructus Cucumidis sativi includes Gherkin, Fructus Cucurbitae moschatae, Citrullus vulgariss, calabash and Fructus Melo), Herba Alii fistulosi section (Alliaceae sp.) (such as Folium Allii tuberosi and ocean Herba Alii fistulosi), Cruciferae (Cruciferae sp.) (such as white cabbage, red cabbage, Caulis et Folium Brassicae capitatae, cauliflower, Brassica oleracea L.var.gemmifera Zenk., little Bai Dish, kohlrabi, Radix Raphani, Wasabia japonic (Euterma Wasabi), Herba Oenanthes Javanicae and Chinese cabbage), pulse family (Leguminosae sp.) (for example Semen arachidis hypogaeae, Semen Pisi sativi, Seem Lablab Album and Kidney bean such as Semen Glyciness and Semen Viciae fabae), Chenopodiaceae (Chenopodiaceae sp.) (such as Swiss chard, fodder beet, Herba Spinaciae, sweet Dish root), flax family (Linaceae) (Linaceae sp.) (such as Fructus Cannabiss (hemp)), Cannabaceae (Cannabeacea sp.) (such as Fructus Cannabiss (cannabis)), Malvaceae (Malvaceae sp.) (such as Flos abelmoschi manihot, cocoa powder), Papaveraceae (Papaveraceae) is (for example Poppy flower), Asparagaceae (Asparagaceae) (such as Germinatus Phragmitiss)；Ornamental plant in useful plant and garden and tree Wood, including turf, lawn, meadow and Flos Chrysanthemi (Stevia rebaudiana)；And the gene of these plants in each case Modified types.Particularly preferred plant is Semen sojae atricolor.
Especially, the mixture of the present invention and compositionss are suitable to prevent and treat following plant disease：
White rust belongs to (Albugo spp.) (white rust), in ornamental plant, vegetable crop (such as Candida albicans (A.candida)) and on Helianthi (such as tragopogon pratensis l. white rust (A.tragopogonis))；Alternaria (Alternaria Spp.) (diplostomiasis, black speck), in vegetable, Brassica campestris L, (for example alternaria brassica (A.Brassicola) or mustard belong to rod method (A.brassicae)), Radix Betae (such as thin Alternaria alternata (A.tenuis)), fruit, Oryza sativa L., Semen sojae atricolor and Rhizoma Solani tuber osi be (for example, Alternaria solani sorauer (A.solani) or mutually every rod method (A.alternata)) and Fructus Lycopersici esculenti (for example, alternaria solani sorauer (A.solani) or Mutually every rod method (A.alternata)) Alternaria (Alternaria spp.) (blackhead) on upper and Semen Tritici aestivi；Radix Betae and Aphanomyces (Aphanomyces spp.) on vegetable；Ascochyta (Ascochyta spp.) in frumentum and vegetable, example As the big wheat husk two spore (A.hordei) on the wheat shell two spore (A.tritici) (shell two spore leaf blight) and Fructus Hordei Vulgaris on Semen Tritici aestivi； Bipolaris (Bipolaris spp.) and Drechslera kind (Drechslera spp.) (epigamouss：Cochliobolus belongs to (Cochliobolus spp.)), such as leaf spot on Semen Maydiss (the compacted spore of umbilicuss (D.maydis) and Semen Maydiss life umbilicuss in Semen Maydiss Compacted spore (B.zeicola)), such as the clever shape speckle (wheat root-rot Bipolaris (B.sorokiniana)) in frumentum and such as Oryza sativa L. Oryza sativa L. Bipolaris (B.oryzae) above and on turfgrass；Wheat powdery mildew in frumentum (such as Semen Tritici aestivi or Fructus Hordei Vulgaris) (Blumeria graminis) (old name：Erysiphe) graminis) (powdery mildew)；Botryosphaeria on vine (Botryosphaeria spp.) (' Si Laike dead arm disease ') (for example setting flower lichens Fructus Vitis viniferae seat chamber bacterium (B.obtusa))；Fructus Vitis viniferae Spore bacterium (Botrytis cinerea) (epigamouss：Botrytis cinerea (Botryotinia fuckeliana):Gray mold, ash is rotten Disease), in soft fruit and apple class fruit (especially Fructus Fragariae Ananssae), vegetable (especially Caulis et Folium Lactucae sativae, Radix Dauci Sativae, Herba Apii graveolentis and Brassica oleracea L.var.capitata L.), On Brassica campestris L, flower, vine, forest crop and Semen Tritici aestivi (ear mycete)；Caulis et Folium Lactucae sativae disk on Caulis et Folium Lactucae sativae obstructs mould (Bremia lactucae) (downy mildew)；Long beak shell on broad leaf tree and coniferous tree belongs to (Ceratocystis spp.) (same to Ophiostoma) (blue-stain fungi (blue stain fungus)), such as long beak shell of the elm on elm (C.ulmi) (Dutch elm disease)；Cercospora (Cercospora spp.) (brown spot (Cereospora leat spot)), in Semen Maydiss (such as Semen Maydiss tail spore (C.zeae- Maydis)), Oryza sativa L., Radix Betae (such as Radix Betae tail spore (C.beticola)), Caulis Sacchari sinensis, vegetable, coffee, Semen sojae atricolor (such as Semen sojae atricolor (C.sojina) or C.kikuchil) and on Oryza sativa L.；Cladosporium (Cladosporium spp.), in Fructus Lycopersici esculenti (such as Fructus Lycopersici esculenti leaf mold Pathogenic bacteria (C.fulvum)：Leaf muld of tomato) and frumentum on, such as multi-trunk natalensis (C.herbarum) (ear rot) on Semen Tritici aestivi； Clavicipitaceae (Claviceps purpurea) (ergot) in frumentum；It is (asexual that cochliobolus belongs to (Cochliobolus spp.) Type：Helminthosporium (Helminthosporium) or Bipolaris (Bipolaris)) (tikka), in Semen Maydiss (such as round spot rotation spore Chamber bacterium (C.carbonum)), frumentum (such as standing grain cochliobolus (C.sativus), phorozoon：Semen Tritici aestivi is bipolar mould (B.sorokiniana)：Clever shape speckle) and Oryza sativa L. (for example, palace portion cochliobolus (C.miyabeanus), phorozoon：The compacted spore of rice length (H.oryzae) on)；Colletotrichum (colletotrichum spp.) (epigamouss：Small cluster shell belongs to (Glomerella spp.)) (black rot), in Cotton Gossypii (such as Cotton Gossypii anthrax (C.gossypii)), Semen Maydiss (such as Sorghum vulgare Pers. anthrax (C.graminicola)：Stem rot and black rot), soft fruit, Rhizoma Solani tuber osi (such as Rhizoma Solani tuber osi anthrax (C.coccodes)：Droop), beans (such as Kidney bean anthrax (C.lindemuthianum)) and Semen sojae atricolor (such as Semen sojae atricolor charcoal Cellulitis bacterium (C.truncatum)) on；Corticium (Corticium spp.) on Oryza sativa L., for example, C.sasakii (banded sclerotial blight)； How main rod spore mould (Corynespora cassiicola) (leaf spot) on Semen sojae atricolor and ornamental plant；Rust staining pathogenic bacteria belongs to (Cycloconium spp.), such as the C.oleaginum on Fructus Canarii albi；Cylindrocarpon (Cylindrocarpon spp.) (such as water Fruit tree cancer (cancer) or the Blackfoot Disease of vine, epigamouss：Nectria kind (Nectria spp.) or Neonectria Spp.), in fruit tree, vine (such as C.liriodendn；Epigamouss：Neonectria liriodendri, Blackfoot Disease) and On many ornamental trees；Dematophora necatrix (epigamouss on Semen sojae atricolor：Lineae ablicantes plumage bacterium (Rosellinia Necatrix)) (root/stem rot)；Between seat shell belong to (Diaporthe spp.) such as Semen sojae atricolor on Kidney bean between seat shell (D.phaseolorum) (stem disease)；Drechslera (Drechslera spp.) (same to Helminthosporium (Helminthosporium), epigamouss：Nuclear cavity Pseudomonas (Pyrenophora)), in Semen Maydiss, frumentum, such as Fructus Hordei Vulgaris (for example D.teres, net blotch) and Semen Tritici aestivi (such as D.tritici-repentis：DTR leaf spot), on Oryza sativa L. and turfgrass；Vine On Eschka disease (eutypa dieback, apoplexy), by speckle thermophilic indigo plant spore pore fungi (Formitiporia punctata) (with speckle hole pin Shelf funguses (Phellinus punctata)), F mediterranea.Phaeomoniella chlamydospora (old name Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and/or tree flower lichens Fructus Vitis viniferae seat Chamber bacterium (Botryosphaeria obtusa) leads to；Elsinoe (Elsinoe spp.), in pomaceous fruits fruit (E.pyri) With soft fruit (E.veneta：Black rot) and vine (Fructus Vitis viniferae Elsinochrome (E.ampelina)：Black rot) on；Water Rice leaf smut (Entyloma oryzae) (leaf smut) on rice；Attached ball spore Pseudomonas (Epicoccum on Semen Tritici aestivi Spp.) (blackhead disease)；Erysiphe (Erysiphe spp.) (powdery mildew), in Radix Betae (Radix Betae powdery mildew (E.betae)), vegetable Dish (such as pea powdery mildew (E.pisi)), such as cucumber variety (such as Compositae powdery mildew (E.cichoracearum)) and volume In heart vegetable kind, such as Brassica campestris L (such as Cruciferae powdery mildew (E.cruciferarum))；Eutypa fata(Eutypa Slightly withered, the phorozoon of cancer or top：Cytosporina lata, with Libertella blepharis), in fruit tree, Fructus Vitis viniferae On rattan and many ornamental trees；Prominent umbilicuss Helminthosporium (Exserohilum spp.) (same to Helminthosporium (Helminthosporium Spp.)), on Semen Maydiss (the prominent compacted spore of the umbilicuss (E.turcicum) of such as Semen Maydiss)；Fusarium (Fusarium on various plants Spp. (epigamouss：Gibberella belongs to (Gibberella)) (droop, root and stem rot), such as frumentum (such as Semen Tritici aestivi or Fructus Hordei Vulgaris) On Fusarium graminearum (F.Graminearum) or fusarium culmorum (F.culmorum) (root rot and Yin Ding), on Fructus Lycopersici esculenti Fusarium oxysporum (F.oxysporum), the Fusariumverticillioides on Fusarinm solani (F.solani) and Semen Maydiss on Semen sojae atricolor (F.verticillioides)；Gaeumannomyces graminis (Gaeumannomyces in frumentum (such as Semen Tritici aestivi or Fructus Hordei Vulgaris) and Semen Maydiss Graminis) (entirely eat)；Gibberella belongs to (Gibberella spp.), in frumentum (such as Gibberella zeae bacterium (G.zeae)) and Oryza sativa L. (such as Gibberella fujikuroi (G.fujikuroi)：Bakanae disease) on；Enclosing on vine, apple class fruit and other plant Cotton small cluster shell (G.gossypii) on small cluster shell (Glomerella cingulata) and Cotton Gossypii；Seed dyeing on Oryza sativa L. Complex (grainstaining complex)；Fructus Vitis viniferae Guignardia (Guignardia bidwellii) (black corruption on vine Disease)；Glue Rust (Gymnosporangium spp.) on Rosaceae and Juniperus rigida Sieb.et Zucc., such as (pears become rusty the G.sabinae on pears Disease)；Helminthosporium (Helminthosporium spp.) (same Drechslera on Semen Maydiss, frumentum and Oryza sativa L. (Drechslera), epigamouss：Cochliobolus belongs to (Cochliobolus))；Hunchbacked spore rust belongs to (Hemileia spp.), such as coffee Coffee rust (H.vastatrix) (coffee leaf rust) on coffee；Isariopsis clavispora on vine (with grape branch spore)；Kidney bean shell ball spore (Macrophomina phaseolina) (same Macrophomina on Semen sojae atricolor and Cotton Gossypii Phaseoli) (root/stem rot)；The withered bacterium of the mould leaf of snow (Microdochium nivale) in frumentum (such as Semen Tritici aestivi or Fructus Hordei Vulgaris) (same to Fusarium nivale (Fusarium nivale)) (pink snow mold)；Microsphaera diffusa on Semen sojae atricolor is (white Powder disease)；Drupe chain sclerotinia sclerotiorum in chain sclerotinia sclerotiorum belong (Monilinia spp.), such as drupe and other Rosaceae (M.laxa.), Zheng Mei Australia type drupe chain sclerotinia sclerotiorum (M.fructicola) and the raw chain sclerotinia sclerotiorum (M.fructigena) of fruit (are bloomed Branch rot (blossom and twig blight))；Mycosphaerella on frumentum, Fructus Musae, soft fruit and Semen arachidis hypogaeae Standing grain green-ball chamber bacterium (M.graminicola) (phorozoon on (Mycosphaerella spp.), such as such as Semen Tritici aestivi：Wheat shell pin Spore (Septoria tritici), septoria musiva leaf spot) or Fructus Musae on Fijian spherical cavity bacterium (M.fijiensis) (Xin Jiadong Disease)；Peronospora kind (Peronospora spp.) (downy mildew), in Brassica oleracea L.var.capitata L. (such as Semen Brassicae Campestriss downy mildew (P.brassicae)), oil Dish (such as Peronospora parasitic (P.parasitica)), plant bulbs (such as Herba Alii fistulosi downy mildew (P.destructor)), Nicotiana tabacum L. (Nicotiana tabacum L. Downy mildew (P.tabacina)) and Semen sojae atricolor (such as P.manshuricav) on；Phakopsora pachyrhizi (Phakopsora on Semen sojae atricolor ) and P.meibomiae (soybean rust) pachyrhizi；Saksenaea (Phialophora spp.), in for example in vine (example As P.tracheiphila and P.tetraspora) and Semen sojae atricolor (such as P.gregata：Stem disease) on；On Brassica campestris L and Brassica oleracea L.var.capitata L. Radix Betae Phoma sp (P.betae) (leaf spot) on Caulis et Folium Brassicae capitatae Phoma sp (Phomalingam) (root and stem rot) and Radix Betae；Intend stem The mould genus of point (Phomopsis spp.), in Helianthi, vine (such as P.viticola：Dead arm disease) and Semen sojae atricolor (such as stem is routed Infectionss/stem wilt：P.phaseoli, epigamouss：Stem canker (Diaporthe phaseolorum)) on；Beautiful another name for Sichuan Province on Semen Maydiss Broomcorn millet section chytrid (Physoderma maydis) (brown spot)；Phytophthora (Phytophthora spp.) on various plants is (withered Wither disease, root, leaf, stem and fruit rot), such as in Fructus Capsici and cucumber variety (such as phytophthora blight of pepper (P.capsici)), Semen sojae atricolor (such as soyabean phytophthora (P.megasperma), same to soybean phytophthora (P.sojae)), Rhizoma Solani tuber osi and Fructus Lycopersici esculenti (such as phytophthora infestans (P.infestans), late blight and brown rot) and broad leaf tree (such as Oak Tree phytophthora (P.ramorum) Oak Tree sudden death) on；The volume heart Plasmodiophora brassica bacteria (Plasmodiophora brassicae) (clubroot) on dish, Brassica campestris L, Radix Raphani and other plant；Single shaft is mould Belong to (Plasmopara spp.), for example, the Fructus Vitis viniferae on vine gives birth to single shaft mould (P.viticola) (vine downy mildew, downy mildew Disease) and Helianthi on Helianthi single shaft mould (P.halstedii)；Rosaceae, Flos lupuli (Flos Humuli Lupuli), pomaceous fruits fruit and soft fruit On Podosphaera (Podosphaera spp.) (powdery mildew), such as the white cross hair list softgel shell on Fructus Mali pumilae (P.leucotricha)；Many Acarasiales belong to (Polymyxa spp.), such as in frumentum such as Fructus Hordei Vulgaris and Semen Tritici aestivi (Polymyxa Graminis (P.graminis)) and on Radix Betae (Polymyxa betae (P.betae)), and the Disease thus propagated；Frumentum, for example Paving hair on Semen Tritici aestivi or Fructus Hordei Vulgaris intends little tail spore (Pseudocercosporella herpotrichoides), and (eye spot/stem breaks Split, epigamouss：Tapesia yallundae)；Pseudoperonospora (Pseudoperonospora) (downy mildew) on various plants, Such as Fructus Cucumidis sativi vacation downy mildew (P.cubensis) on cucumber variety or the P.humili on Flos lupuli (Flos Humuli Lupuli)；On vine Pseudopezicula tracheiphila (angle leaf scorch is withered, phorozoon Saksenaea vasiformis (Phialophora))；Handle on various plants Semen Tritici aestivi handle rest fungus on Rust (Puccinia spp.) (rust), such as frumentum such as Semen Tritici aestivi, Fructus Hordei Vulgaris or rye (Secale cereale L.) (P.triticina) (brown rust of wheat), bar shaped handle rest fungus (P.striiformis) (yellow rust). Fructus Hordei Vulgaris handle rest fungus (P.hordei) (short leaf rust), puccinia graminis (P.graminis) (stalk rust) or Puccinia recondita (P.recondita) are (black Wheat leaf rust), the Puccinia kuehnii on Caulis Sacchari sinensis and such as Germinatus Phragmitiss (such as Germinatus Phragmitiss handle rest fungus (P.asparagi)) (P.kuehnii)；Semen Tritici aestivi macula lutea nuclear cavity bacteria (Pyrenophora tritici-repentis) (phorozoon on Semen Tritici aestivi： Drechslera tritici-repentis) round nuclear cavity bacteria (P.teres) (net blotch) on (being filled with leaf spot) or Fructus Hordei Vulgaris； Pyricularia Sacc. (Pyricularia spp.), such as water Magnaporthe grisea (the P.oryzae) (epigamouss on Oryza sativa L.：Pyricularia oryzae (Magnaporthe grisea). rice blast) and turfgrass and frumentum on Pyricularia oryzae (P.grisea)；Pythium (Pythium spp.) (damping off), in turfgrass, Oryza sativa L., Semen Maydiss, Semen Tritici aestivi, Cotton Gossypii, Brassica campestris L, Helianthi, Radix Betae, vegetable and its On its plant (such as Pythium ultimum (P.ultimum) or melon and fruit corruption mould (P.aphanidermatum))；Ramularia (Ramularia spp.), the such as R.collo-cygni (post is every spore leaf and turfgrass/physiology leaf spot) on Fructus Hordei Vulgaris and Radix Betae On Radix Betae post every spore (R.beticola)；Cotton Gossypii, Oryza sativa L., Rhizoma Solani tuber osi, turfgrass, Semen Maydiss, Brassica campestris L, Rhizoma Solani tuber osi, Radix Betae, vegetable With the Rhizoctonia (Rhizoctonia spp.) on various other plants, the such as Rhizoctonia solani Kuhn (R.solani) on Semen sojae atricolor (root and stem rot), the Rhizoctonia solani Kuhn (R.solani) (banded sclerotial blight) on Oryza sativa L. or the Rhizoctonia cerealis on Semen Tritici aestivi or Fructus Hordei Vulgaris (R.cerealis) (sharp eyespot)；Rhizopus stolonifer (Rhizopus on Fructus Fragariae Ananssae, Radix Dauci Sativae, Brassica oleracea L.var.capitata L., vine and Fructus Lycopersici esculenti Stolonifer) (soft rot)；Rye (Secale cereale L.) beak spore (Rhynchosporium secalis) (leaf on Fructus Hordei Vulgaris, rye (Secale cereale L.) and Triticale hexaploide Lart. Speckle)；Sheath rot of rice plant bacterium (Sarocladium oryzae) on Oryza sativa L. and S.attenuatum (sheath maize ear rot)；Sclerotinia (Sclerotinia spp.) (stem rot or white rot), in vegetable and field crops such as Brassica campestris L, Helianthi (such as sclerotium cup fungi (Sclerotinia sclerotiorum)) and Semen sojae atricolor (such as S.rolfsii) on；Septoria on various plants (Septoria spp.), such as the Soybean Brown Spot line septoria musiva (S.glycines) (tikka) on Semen sojae atricolor, the wheat shell pin on Semen Tritici aestivi (S.nodorum is (same for phaeosphaeria nodorum on spore (S.tritici) (spot blight (Septoria leaf blotch)) and frumentum Wheat leaf spoting bacteria (Stagonospora nodorum)) (tikka and clever shape speckle)；Fructus Vitis viniferae snag shell (Uncinula on vine Necator) (same to grape powdery mildew (Erysiphe necator) (powdery mildew, phorozoon：Oidium tuckeri)； Setospaeria spp. (tikka), in Semen Maydiss, (such as S.turcicum, with Semen Maydiss length compacted spore (Helminthosporium Turcicum)) and on turfgrass；Axle Ustilago (Sphacelotheca spp.) (head smut), in Semen Maydiss (such as Semen Maydiss Silk axle smut (S.reiliana)：Grain of rice dust-brand (kernel smut)), on Semen setariae and Caulis Sacchari sinensis；Fructus Cucumidis sativi on cucumber variety is white Powder pathogenic bacteria (Sphaerotheca fuliginea) (powdery mildew)；Spongospora subterranea (Spongospora on Rhizoma Solani tuber osi Subterranea) (powdery scab) and the Disease thus propagated；Shell many born of the same parents Pseudomonas (Stagonospora in frumentum Spp.), for example (leaf spot and clever shape speckle, the epigamouss of the grain husk withered shell many born of the same parents bacterium (S.nodorum) on Semen Tritici aestivi：The withered ball cavity bacteria of grain husk (Leptosphaeria nodorum) [same to phaeosphaeria nodorum (Phaeosphaeria nodorum)])；Ma Ling on Rhizoma Solani tuber osi Potato cancerous protuberance pathogenic bacteria (Synchytrium endobioticum) (wart of potatoes)；Exoascus (Taphrina spp.), example As Lee external capsule bacterium (T.pruni) (Lee on the lopsided external capsule bacterium (T.deformans) (leaf curl) and Fructus Pruni salicinae (pi um) in Fructus Persicae Rim of the mouth bag disease (plum-pocketdisease))；Thiclaviopsis on Nicotiana tabacum L., melonidum fruit, vegetable crop, Semen sojae atricolor and Cotton Gossypii (Thielaviopsis spp.) (black root rot), such as T.basicola (with grace secretly interior spore (Chalara elegans))； Tilletia on Tilletia (Tilletia spp.) (wheat and barley or bunt) in frumentum, such as Semen Tritici aestivi (T.tritici) (same to Tilletia caries (T.caries), the bunt of wheat) and T. contraversa (T.controversa) (dwarf bunt)；Meat spore core coral bacterium (Typhula incarnata) (ash snow on Fructus Hordei Vulgaris or Semen Tritici aestivi Mildew)；Urocystis (Urocystis spp.), such as recessive bar smut (U.occulta) (the black powder of stalk on rye (Secale cereale L.) Disease)；Uromyces (Uromyces spp.) (rust), in vegetable plant such as beans (such as wart top uromyce (U.appendiculatus), with Kidney bean uromyce (U.phaseolI)) and Radix Betae (such as Radix Betae uromyce (U.betae) on)；Ustilago (Ustilago spp.) (smut), in frumentum (for example naked smut (U.nuda) and U.avaenae), Semen Maydiss (such as Ustilago maydis (U.maydis)：Smut of maize) and Caulis Sacchari sinensis on；Venturia (Venturia spp.) (crust), on Fructus Mali pumilae (such as apple black star bacteria (V.inaequalis)) and pears；And various plant Verticillium (Verticillium on if tree and ornamental trees, vine, soft fruit, vegetable and field crops Spp.) (leaf and branch are withered), the such as Verticilliumdahliae (V.dahliae) on Fructus Fragariae Ananssae, Brassica campestris L, Rhizoma Solani tuber osi and Fructus Lycopersici esculenti.
The mixture of the present invention and compositionss are particularly preferred for the following plant disease of preventing and treating：Soybean diseases：Semen sojae atricolor purpura Pathogenic bacteria (Cercospora kikuchii), Semen sojae atricolor Elsinochrome (Elsinoe glycines), seat shell soya bean varieties (Diaporthe phaseolorum var.sojae), Soybean Brown Spot line septoria musiva (Septaria glycines), Semen sojae atricolor greyness Pathogenic bacteria (Cercospora sojina), Pachyrrhyizus erosuss layer pound bacterium (Phakopsora pachyrhizi), pathogen of soybean root rot Leaf spot (Corynespora embraced by (Phytophthora sojae), Rhizoctonia solani Kuhn (Rhizoctonia solani), rod ) and sclerotinite (Sclerotinia sclerotiorum) casiicola.
Plant health
The mixture of the present invention and compositionss are suitable for strengthening plant health.
Strengthen the plant growing that plant health should mean the mixture of the present invention or compositionss can serve as being defined as below to adjust Section agent, the plant strengthening/induction of resistance compound with being defined as follows, the plant physiology being defined as below for impact, and For improving the crop yield being defined as below.
Plant growth regulating
In some cases, the mixture of the present invention or compositionss can also be used as weeding with specific concentration or rate of application Agent, safener, growth regulator or the reagent improving plant property, or it is used as microbicide, such as antifungal, antifungal Agent, bactericide, the antiviral compositionss of viroid (include antagonism) or as antagonism MLO (mycoplasma-like organism(MLO) organism) and The compositionss of RLO (rickettsia-like organism organism).If appropriate, they are also used as synthesizing the centre of other active component Body or precursor.
The active component of the mixture of the present invention or compositionss has intervened the metabolism of plant, and is therefore also used as Growth regulator.
Plant growth regulator can play various effects to plant.The effect of this material depends primarily on and development of plants rank The time of application of Duan Xiangguan, and additionally depend on the amount of the active component being applied to plant or its environment and apply type.Every In the case of kind, growth regulator should have the effect being especially desired to crop plants.
Plant growth regulating compound can be used for for example suppressing nourishing and growing of plant.This growth inhibited is economical interest , such as in the case of grass because its therefore can in ornamental garden, park and sports facility, roadside, on airport or Reduce mowing frequency in fruit crop.It is also important that near roadside and pipeline or aerial cable or fairly common It is not intended to the growth of suppression draft and xylophyta in the region of vigorous plant growing.
It is also important that growth regulator is used for suppressing the longitudinal growth of frumentum.This reduces or completely eliminates in harvesting The risk of plant lodging before.Additionally, in the case of frumentum, growth regulator can strengthen stem, it also offsets lodging.Use Growth regulator allows to increase yield using higher fertilizer volume to shorten and to strengthen stem, falls without cereal crops Any risk of volt.
In many crop plants, suppression is nourished and grown and is allowed more dense plantation, therefore can be obtained based on soil surface Higher yield.Another advantage of the relatively plantlet obtaining by this way is that crop is easier to cultivate and harvests.
Suppression phytonutritive plant growth can also lead to output increased, because nutrient and assimilation quotient are compared to the battalion of plant Foster part is more beneficial for flower and fruit is formed.
Generally, growth regulator can also be used for promoting vegetative growth.When harvesting phytonutritive plant part, so can be non- Chang Youyi.However, promoting vegetative growth that genitality can also be promoted to grow, because forming more assimilation quotients, lead to more Or bigger fruit.
In some cases, output increased can be realized by adjusting the metabolism of plant, and give birth in trophism simultaneously Then there is no any detectable change in length.Additionally, growth regulator can be used for changing the composition of plant, this is permissible in turn Lead to the improvement of the quality of product of harvesting.For example, it is possible to increase the sugared content in Radix Betae, Caulis Sacchari sinensis, Fructus Ananadis comosi and citrus fruit, Or increase the protein content in Semen sojae atricolor or frumentum.Can also be suppressed using growth regulator for example before harvesting or after harvesting The degraded of the sugar in required composition such as Radix Betae or Caulis Sacchari sinensis.Can be with the production of actively impact secondary plant composition or elimination.One Individual example is the flowing stimulating latex in rubber tree.
Under the influence of growth regulator, parthenocarpous fruit can be formed.Furthermore, it is possible to the sex of impact flower.Can also produce Raw pollen sterile, it is extremely important in the breeding and production of hybrid seed.
The branch of plant can be controlled using growth regulator.On the one hand, by destroying apical dominance, go back and Developing restraint Combine, the growth of side shoot can be promoted, this is especially possibly in demand in the culture of ornamental plant.However, it is another Aspect is it is also possible to suppress the growth of side shoot.This effect is particularly advantageous for example in the cultivation of Nicotiana tabacum L. or the cultivation of Fructus Lycopersici esculenti.
The amount of leaf on plant under the influence of growth regulator, can be controlled, so that realizing plant in the desired time Disleave.This disleave plays a major role in the mechanical harvesting of Cotton Gossypii, but is also beneficial to be easy to harvest in other crops, example As in vinegrowing.The disleave that plant can also be carried out is with the transpiration of reduction plant before plant transplanting.
Growth regulator is equally applicable to adjust cracking of fruit.On the one hand, precocious cracking of fruit can be prevented.The opposing party Face is it is also possible to promote cracking of fruit or even flower abortion to realize the quality (" desaturation (thinning) ") needing, thus eliminating (substituting (" alternation ")).Substitute and be understood to mean that some Fruit types provide very not year by year for endogenous cause The feature of same yield.Finally, can reduce, in harvesting, the power separating required for fruit using growth regulator, to allow Mechanical harvesting or be easy to manually harvest.
Growth regulator can be also used for harvesting before or after realize harvested material faster or delay one-tenth Ripe.This is particularly advantageous, because its permission is optimized and revised to the market demand.Additionally, in some cases, growth regulator can To improve fruit color.In addition, growth regulator can also be used for concentrating maturation in certain time period.This determines in single operation In for example in the case of Nicotiana tabacum L., Fructus Lycopersici esculenti or coffee complete mechanical or manual harvesting prerequisite.
By using growth regulator, the seed of plant or the dormancy of bud can also be affected so that plant such as Fructus Ananadis comosi or Ornamental plant in nursery germinates when they are generally not inclined to such, rudiment or bloom.There is frost risk Region is it may be necessary to postpone sprouting or rudiment of seed by growth regulator, thus avoiding the infringement being led to by late frost.
Finally, growth regulator can induce the resistance to frost, arid or the high salinity of soil for the plant.This allows to It is generally not suitable for cultivated plant in the region of this purpose.
Induction of resistance
The reactive compound of the present invention also shows potent potentiation in plant.Therefore, they can be used for transferring and plant The defence of the invasion and attack to undesirable microorganism for the thing.
In the present context, plant enhancing (induction of resistance) material is understood to mean that and can stimulate plant as follows System of defense those materials, that is, when subsequently with undesirable microbial inoculant, so that the development of plants processing is gone out to this The resistance of slightly biological height.
The reactive compound of the present invention is further adapted for improving the yield of crop.Additionally, they show toxicity the quilt of reduction Plant tolerates well.
Additionally, in the context of the present invention, plant physiology effect includes following：
Abiotic stress tolerance, uses including restorative, the water after temperature tolerance, drought tolerance and drought stress Efficiency (related to the water consumption reducing), resistance to overhead flooding injury, ozone stress and UV toleration, to chemicals such as heavy metal, salt, pesticide The toleration of (safener) etc..
Biotic toleration, including the fungus resistant improving and the resistance to nematicide, virus and antibacterial improving.At this In the context of invention, biotic toleration preferably includes the fungus resistant improving and the resistance to nematicide improving
Increased plant vigor, include plant quality and seed vitality, reduction stand unsuccessfully (stand failure), The photosynthetic efficiency of the outward appearance, the restorative, afforestation effect of improvement improving and improvement improved.
Effect to phytohormone and/or functional enzyme
Impact to growth regulator (accelerator), including germinateing earlier, more preferably emerge, more flourishing root system and/or change Kind root growth, increased tillering ability, the tiller of more high yield, more prematurity, increased plant height and/or Biomass, stem Shortening, the improvement of branch growth, core/spike number mesh, spike number mesh/square metre, stolon number and/or spend number, the harvest index, more improving Big leaf, less dead basal leaf, improved phyllotaxy, more early ripe/more precocity fruiting, uniformly ripening, increased kernel grouting Time, more preferable result, bigger fruit/vegetable size, rudiment resistance and reduction lodging.
The yield improving, refer to the total biomass of per hectare, output per hectare, core/fruit weight, seed sizes and/or Hectare weight and the product quality of raising, including
The machinability improved, is related to distribution of sizes (core, fruit etc.), uniformly ripening, grain moisture, preferably grinds Property, preferably wine brewing property, preferably the property brewageed, increase fruit juice yield, harvesting property, digestibility, sedimentation value, Falling Number, Pod stability, storage stability, improve fibre length/intensity/uniformity, breast increase and/or meet ensiling letting animals feed Suitable quality, to culinary art and frying adaptability；
Also include the marketability improved, be related to fruit/grain quality, the distribution of sizes (core, fruit etc.) improved, increase Storage/storage period, firmness/softness, taste (fragrance, quality etc.), grade (size, shape, berry number etc.), every grout leaking The number of really/fruit, brittleness, freshness, by wax covering, the frequency of disorder, color etc.；
Also include increase required composition, for example protein content, fatty acid, oil content, oil quality, aminoacid composition, Sugared content, acid content (pH), sugar/acid ratio rate (Brix), polyphenol, content of starch, nutritional quality, glutelin content/index, energy Content, taste etc..
And also including the unwanted composition that reduces, for example less mycotoxin, less aflatoxin, soil are smelly Gourmet powder level, phenol fragrance, laccase (lacchase), polyphenol oxidase and peroxidase, nitrate content etc..
Sustainable agriculture, including nutrientuse efficiency, particularly nitrogen (N)-utilization ratio, phosphorus (P)-utilization ratio, water conservancy Transpiration, Repiration and/or the CO with efficiency, improving2Assimilation ratio, more preferable dross, Ca- metabolism of improvement etc..
Delay senility, including improving plant physiology, it for example showed in the longer seed-filling period, led to higher Yield, longer plant greenery color duration and therefore include color (green), water content, drying etc..Therefore, at this In the context of invention it has been found that, the concrete application of the present invention of active compound allows to extend greenery area Persistent period, this delays the maturation (old and feeble) of plant.For peasant, the seed-filling period that major advantage is longer leads to Higher yield.For peasant, also there is the greater flexibility based on collecting time.
Wherein " sedimentation value " is measuring of protein quality, and is described in the standard time according to Zeleny (Zeleny value) Interim is suspended in the precipitation degree of the flour in lactic acid solution.This is considered measuring of baking propertiess.Flour is molten in lactic acid The swelling fraction of glutelin in liquid affects the sedimentation rate of flour suspension.Higher glutelin content and more preferable qualities of gluten Cause slower sedimentation and higher Zeleny test value.The sedimentation value of flour depends on aleuronat and forms, and mainly Related to the volume of protein content, wheat hardness and pan and burner hearth surface packing.Compared to SDS settling volume, bread The higher dependency that block amasss and Zeleny settling volume between is likely due to protein content impact volume and Zeleny Value (Czech J.Food Sci.Vol.21, No.3：91-96,2000) both.
Additionally, " Falling Number " mentioned in this article is measuring of the baking quality of frumentum particularly Semen Tritici aestivi.Falling Number Test shows to have occurred and that rudiment damages.This means the change of physical property of the Starch Fraction to wheat seed Occur.Wherein, Falling Number instrument is by measuring the flour and water paste resistance to whereabouts plunger come analysis of viscosity.Its occur when Between (in seconds) be referred to as falling fall number.Falling Number result is recorded as the index of enzymatic activity in Semen Tritici aestivi or flour sample, and result with With the second, the time of meter represents.High Falling Number (for example, higher than 300 seconds) represents the Semen Tritici aestivi of minimum enzymatic activity and better quality Or flour.Low Falling Number (for example, less than 250 seconds) represents high enzymatic activity and the germinate Semen Tritici aestivi damaging or flour.
Term " more flourishing root system "/" root growth of improvement " refers to longer root system, deeper root growth, faster root Growth, higher root do/fresh weight, higher root volume, bigger root surface area, bigger root diameter, higher root stability, More root branches, higher root approximate number and/or more tip of a root, and can pass through with suitable method and image analysis program (such as WinRhizo) to measure to analyze root construction.
Term " crop water application efficiency " technically refers to the agricultural product quality of the water being consumed of per unit, and in warp The value of the product that the water volume being consumed of per unit produces is referred on Ji.And can be for example with the biology of yield/ha, plant Amount, thousand nuclear masses and spike number/m2To measure.
Term " nitrogen use efficiency " technically refers to the agricultural product quality of the nitrogen being consumed of per unit, and economically Refer to the value of the product that the nitrogen being consumed of per unit produces, reflection picked-up and utilization ratio.
The color of improvement/improvement in greening and improve photosynthetic efficiency and aging delay can use known to technology Such as HandyPea system (Hansatech) is measuring.Fv/Fm is widely used in the maximum representing photosynthetical system II (PSII) The parameter of sub- efficiency.This parameter is broadly considered the selectivity instruction of plant photosynthesis performance, and healthy sample generally obtains big About 0.85 maximum Fv/Fm value.If sample is exposed to certain form of biological or abiotic stress factor, and (it reduces The Photochemical quenching ability of the energy in PSII), then it will be observed that the value lower than these.Fv/Fm is expressed as variable fluorescence Property (Fv) and maximum fluorescence value (Fm) ratio.The instruction that performance index is mainly sample vigor (see, for example, Advanced Techniques in Soil Microbiology, 2007,11,319-341；Applied Soil Ecology, 2000,15, 169-182).
The delay of the color of improvement/improvement in greening and the photosynthetic efficiency improved and aging can also be net by measurement Photosynthetic rate (Pn), measurement chlorophyll content (for example passing through the pigment extraction method of Ziegler and Ehle), measurement Photochemical Efficiency (Fv/Fm ratio), measure shoot growth and final root and/or canopy Biomass, measure tiller density and root mortality rate to comment Valency.
In the context of the present invention, preferably improve plant physiology effect, it is selected from：Enhanced root growth/more flourishing Root system, the greening improving, the water application efficiency (related to the water consumption reducing) improving, the nutritional utilization efficiency, especially of improvement Yield including nitrogen (the N)-service efficiency improved, the aging of delay and raising.
In improving yield, the improvement of the preferably improvement of sedimentation value and Falling Number and protein and sugared content is outstanding It is for the plant selected from frumentum (preferably wheat).
Preferably, the new application of the Fungicidal composition of the present invention is related to following combination purposes：A) have or do not having Preventative and/or therapeutic ground controlling pathogenic fungi by means and/or nematicide in the case of resistant management, and b) the root life that improves At least one in long, improvement greening, the yield of the water application efficiency improving, the aging postponing and raising.To group root b) The raising of system, particularly preferably strengthens root system, water application efficiency and N- utilization ratio.
Seed treatment
Present invention additionally comprises the method processing seed.
The invention still further relates to having passed through the seed that one of aforementioned paragraphs method was processed.The seed of the present invention is used for protecting Seed exempts from the method for harmful microorganism infringement.In these methods, at using the active component with least one present invention The seed of reason.
The mixture of the present invention or compositionss can be also suitably used for processing seed.Most of by harmful organisms cause to work The infringement of thing plant is to be caused by the infecting of seed during storing or after planting and during and after plant germination 's.Because just especially sensitive in the root of growing plants and branch, and even less infringement leads to the death of plant, institute Particularly critical with this stage.Therefore, to protect seed and germination plant significant by using suitable compositionss.
Plant pathogenic fungi is prevented and treated by the seed of process plant known for a long time, and be constantly to change The theme entering.However, the process of seed brings a series of problems that can not always solve in a satisfactory manner.For example, The method expecting to develop protection seed and germination plant, the method make after planting or after plant emergence need not or at least notable Reduce extra applying crop production compositions.Also want to optimize the amount of used active component, to plant with germinateing for seed What thing offer was as best as possible protects the infringement so as to from plant pathogenic fungi, but plant will not be made to be subject in itself simultaneously The infringement of the active component being used.Especially, process the method for seed it is also contemplated that the intrinsic antifungal of transgenic plant is special Property, so that seed and the best protection of germination plant are realized with minimum crop production compositions consumption.
Therefore, the invention still further relates to by protected with the compositions-treated seed of the present invention seed and germination plant from The method of plant pathogenic fungi infringement.The invention still further relates to the present composition is used for processing seed to protect seed and germination The purposes that plant encroaches on from plant pathogenic fungi.The invention still further relates to the compositions-treated of the present invention to protected from The seed of plant pathogenic fungi infringement.
After harm is emerged, the preventing and treating of the plant pathogenic fungi of plant is mainly passed through with crop protection compositions-treated soil The aerial partss of earth and plant are carrying out.It is contemplated that crop production compositions may to environment and human and animal's health Produce impact, therefore make great efforts to reduce the applied amount of active component.
One of the advantages of the present invention is, the special system performance of the mixture of the present invention and compositionss means to use this A little mixture and compositions-treated seed not only protect seed itself, but also protect emerge after obtained plant from plant Pathogenic epiphyte is encroached on.In this way, it is possible to save immediately treat crop at seeding time or afterwards soon.
It also hold that advantageously, the mixture of the present invention or compositionss especially can also be made together with transgenic seed With in this case, being given expression to by the plant of this seed growth and have effective protein to nuisance.By with originally The mixture of invention or the such seed of compositions-treated, only expressing protein, such as insecticidal proteins can be to prevent and treat some insects. It was unexpectedly determined that being observed that further cooperative effect in this case, this coordinating effect adds additional and prevents The effectiveness of pest infestation.
It is any used in agricultural, greenhouse, forestry or gardening and vinegrowing that the compositionss of the present invention are applied to protection The seed of plant variety.Especially, this is following seed：Frumentum (for example Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), black Semen Tritici aestivi, Sorghum vulgare Pers./millet and Herba bromi japonici), Semen Maydiss, Cotton Gossypii, Semen sojae atricolor, rice, Rhizoma Solani tuber osi, Helianthi, Kidney bean, coffee, Radix Betae (such as sugar beet and fodder beet), Semen arachidis hypogaeae, Brassica campestris L, Semen Papaveriies, Fructus Canarii albi, Cortex cocois radiciss, cocoa, Caulis Sacchari sinensis, Nicotiana tabacum L., vegetable (as Fructus Lycopersici esculenti, Fructus Cucumidis sativi, Bulbus Allii Cepae and Caulis et Folium Lactucae sativae), turf and sight Reward property plant (also seeing below).The seed of frumentum (such as Semen Tritici aestivi, Fructus Hordei Vulgaris, rye (Secale cereale L.), black Semen Tritici aestivi and Herba bromi japonici), Semen Maydiss and Oryza sativa L. Process is particular importance.It is particularly preferably the seed of Semen sojae atricolor.
Also as described below, being particular importance with the mixture or compositions-treated transgenic seed of the present invention.This relates to And the plant seed containing at least one heterologous gene that can express the polypeptide with insecticidal properties or protein.Transgenic kind Heterologous gene in son can for example derive from following kinds of microorganism：Such as bacillus cereuss (Bacillus), root nodule bacteria (Rhizobium), pseudomonass (Pseudomonas), husky thunder bacterium (Serratia), Trichoderma spp. (Trichoderma), stick-like bacillus (Clavibacter), sacculus mould (Glomous) or viscous broom mould (Gliocladium).These heterologous genes are preferred from spore bar Pseudomonas, in this case gene outcome be effective against European corn borer and/or western corn rootworm.Described heterologous gene is more excellent Choosing is derived from bacillus thuringiensiss (Bacillus thuringiensis).
In the context of the present invention, the present composition individually or is applied to seed in the form of suitable preparation.Excellent Selection of land, seed its sufficiently stable with processed in the state of not damaging in processing procedure.Generally, can harvesting and Any time between sowing processes seed.It is usually used and separate and by cob, shell, stem, epidermis, hair or sarcocarp from plant The seed sorting out.It is, for example possible to use having harvested, having cleaned and the seed that be less than 15 weight % has been dried to moisture.Or Person, it is possible to use after the drying for example with water process and and then after drying seed.
When processing seed it is often necessary to attentional selection is applied to the amount of the present composition of seed and/or other adds Plus the amount of agent is so that the germination of seed is without prejudice, or the plant generating is without prejudice.This point is especially in certain rate of application Under there is the active component of phytotoxic effects in the case of must keep firmly in mind.
The compositionss of the present invention can directly be applied, that is, do not contain any other component and not yet dilute.Generally, it is preferred to close Compositionss are applied to seed by suitable dosage form.Suitable preparation and method for seed treatment are those skilled in the art Known, and be documented in such as documents below：US 4,272,417、US 4,245,432、US 4,808,430、US 5, 876,739、US 2003/0176428A1、WO 2002/080675、WO 2002/028186.
Mixture that can be used according to the invention or compositionss can be converted into conventional Seed dressing formulations, for example solution, emulsion, Suspension, powder, foam, serosity or other seed coating composition, and ULV preparation.
These preparations are to mix with conventional additives and prepare in known manner by by active component or mixture, described As a example conventional additives as conventional extender and solvent or diluent, dyestuff, wetting agent, dispersant, emulsifying agent, defoamer, Preservative, secondary thickening agent, adhesive, gibberellins and water.
May be present in the useful dyestuff in Seed dressing formulations that can be used according to the invention is all dyes being usually used in this purpose Material.The pigment being slightly soluble in water can be used, or water-soluble dyestuff.Example is included with dyestuff known to following title：Rhodamine B, C.I. pigment red 112 and C.I. solvent red 1.
May be present in the useful wetting agent in Seed dressing formulations that can be used according to the invention to be all promotion moistenings and lead to It is usually used in the material of active agrochemicals component preparation.Preferably use alkylnaphthalene sulfonate, for example diisopropyl naphthalene sulfonate or Diisobutyl naphthalene.
May be present in the useful dispersant in Seed dressing formulations that can be used according to the invention and/or emulsifying agent is conventional using In all nonionics of active agrochemicals component preparation, anion and cation dispersing agent.Nonionic or the moon preferably can be used Ionic dispersants or the mixture of nonionic or anionic dispersing agents.Suitable non-ionic dispersing agent is particularly including epoxy second Alkane/propylene oxide block polymer, alkyl phenol polyglycol ether and triphenyl vinyl phenol polyglycol ether and its phosphorylation or sulfur The derivant of acidifying.Suitable anionic dispersing agents especially lignosulphonates, polyacrylate and arylsulphonate/formaldehyde contracting Compound.
May be present in the defoamer in Seed dressing formulations that can be used according to the invention is to be usually used in active agrochemicals composition The all foam inhibition material of preparation.Preferably use silicone antifoam agent and magnesium stearate.
It is available in agrochemical composition for may be present in the preservative in Seed dressing formulations that can be used according to the invention All substances in this purpose.Example includes Dichlorophenol and benzyl alcohol hemiformal.
The secondary thickening agent that may be present in Seed dressing formulations that can be used according to the invention is in agrochemical composition Can be used for all substances of this purpose.Preferably example includes cellulose derivative, acrylic acid derivative, xanthan gum, modified viscous Silicon dioxide native and in small, broken bits.
May be present in the binding agent in Seed dressing formulations that can be used according to the invention is to can be used for owning in product of dressing seed Traditional binders.Preferably example includes Polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose (tylose).
May be present in gibberellins in Seed dressing formulations that can be used according to the invention be preferably gibberellins A1, A3 (=red mould Acid), A4 and A7；Particularly preferably use gibberellin.Gibberellins are known (referring to R.Wegler " Chemie der”[Chemistry of the Crop Protection Compositions and Pesticides], volume 2, Springer Verlag, 1970,401-412 Page).
Seed dressing formulations used according to the invention can be used directly or be used for processing wide scope after water in advance dilution Different seeds, including the seed of transgenic plant.In this case, in the interaction with the material formed by expression In also can produce extra cooperative effect.
For with can be used according to the invention Seed dressing formulations or by add water and preparation prepared therefrom processes kind Son, all mixed cells being generally used for dressing seed are all useful.Specifically, seed dressing program is to put in blender by seed, Add specific the desired amount of Seed dressing formulations with itself or after prior dilute with water, mix every kind of material until preparation uniform It is distributed on seed.If appropriate, subsequently it is dried process.
Mycotoxin (Mycotoxins)
Additionally, the process of the present invention can reduce the mould bacterium in harvested material and food prepared therefrom and feedstuff The content of element.Mycotoxin is especially including but not limited to following：Deoxynivalenol (deoxynivalenol) (DON), nivalenol (nivalenol), 15-Ac-DON, 3-Ac-DON, T2- and HT2- toxin, fumonisins (fumonisins), 6-(10-hydroxy-6-oxo-trans-1-undecenyl)-.beta.-resorcylic acid lactone (zearalenon), moniliformin (moniliformin), fusarine (fusarin), Diacetoxysciroenol (diaceotoxyscirpenol) (DAS), beauvericin (beauvericin), enniatin (enniatin), layer go out fusanin (fusaroproliferin), fusarenol, ochratoxin (ochratoxins), Clavacin (patulin), peptide (ergot alkaloids) and aflatoxin (aflatoxins), these poison Element can be produced by for example following funguses：Fusarium (Fusarium spec.), such as fusarium acuminatum (F.acuminatum), Asia Fusariumsp (F.asiaticum), fusarium avenaceum (F.avenaceum), gram ground Fusarium spp. (F.crookwellense), yellow fusarium (F.culmorum), Fusarium graminearum (wheat scab) (F.graminearum (Gibberella zeae)), fusarium equiseti (F.equiseti), F.fujikoroi, Fructus Musae Fusarium spp. (F.musarum), Fusarium oxysporum (F.oxysporum), proliferation Fusarium spp. (F.proliferatum), Fusarlum poae (F.poae), F.pseudograminearum, fusarium sambucinum (F.sambucinum), Fusarlum scripi (F.scirpi), half-naked reaping hook Bacterium (F.semitectum), Fusarinm solani (F.solani), Fusarium sporotrichioides (F.sporotrichoides), F.langsethiae, glue fusarium oxysporum (F.subglutinans), three line Fusariumsps (F.tricinctum), fusarium moniliforme (F.verticillioides) etc., and aspergillus (Aspergillus spec.) such as Aspergillus flavus (A.flavus), parasitic song Mould (A.arasiticus), A.Nomius, Aspergillus ochraceus (A.ochraceus), Aspergillusclavatus (A.clavatus), aspergillus terreus (A.terreus), aspergillus versicolor (A.versicolor), Penicillium (Penicillium spec.) is as mould in pure green cyan (P.verrucosum), pure green cyan mould (P.viridicatum), Penicillium citrinum (P.citrinum), penicillium expansum (P.expansum), penicillium claviformae (P.claviforme), penicillium roqueforti (P.roqueforti), Claviceps (Claviceps Spec.) as Claviceps purpurea (C.purpurea), spindle Clavicipitaceae (C.fusiformis), Claviceps paspali (C.paspali), C.africana, Stachybotrys (Stachybotrys) and other.
Material protection
The mixture of the present invention or compositionss can be also used for protection materials, for safeguard industries material from harmful micro- life The infringement of thing (such as funguses and insecticide) and destruction.
Additionally, the mixture of the present invention or compositionss individually or with other active ingredient combinations can be used as antifouling composition.
Industrial materials in this context are understood to mean the non-living material prepared in industry.For example, By the mixture of the present invention or compositionss protect the industrial materials changing against microorganism or destroying can for adhesive, glue, Paper, wallpaper and paper, fabric, woollen blanket, leather, timber, fiber and tulle fabric (tissue), paint vehicle and plastic, cold But lubricant and can be by the other materials of microbial infection or destruction.The production equipment that can be destroyed by microbial growth and building A part, for example cooling water circulation, cooling and heating system and heating ventilation and air-conditioning unit are it is also possible in material to be protected In the range of refer to.Industrial materials in the scope of the invention preferably include adhesive, sizing material, paper and card, leather, timber, paint vehicle, cold But lubricant and heat-transfer fluid, more preferably timber.
The mixture of the present invention or compositionss can prevent adverse effect, for example corruption, decline, variable color, decolouring or mycete Formed.
In the case of processing timber, the compound/composition of the present invention can be also used for opposing be easy on timber or The fungal disease of growth inside.Term " timber " refers to all types of woodworks, and the institute of the such timber for building There are processing type, such as solid wood, high density timber, laminated wood (timber and clamping plate.The method for the treatment of in accordance with the present invention timber is main It is to contact one or more compound of the present invention or the compositionss of the present invention；This includes for example directly applying, sprays, soaks Stain, injection or any other suitable mode.
In addition, the compound of the present invention can be used for protecting the object contacting with saline or brackish water from pollution, described thing Body especially shell, sieve, net, building, mooring equipment and signaling system.
The method of the present invention for preventing and treating harmful fungoid can also be used for protection storage goods.Storage goods is understood as Refer to plant or the natural materials of animal origin or the converted productss of its natural origin, expect digital preservation for which.Plant comes Source such as plant or plant part, such as stem, leaf, tuber, seed, fruit, grain storage goods can be in fresh harvesting Or protected after by (pre-) drying, moistening, pulverizing, grinding, compacting or roasting.Storage goods also include timber, not plus Work, such as building timber, electric pole and fence, or final product form, such as furniture.The storage goods of animal origin is such as beast Skin, leather, leather and fur and hair.The active component of the present invention can prevent adverse effect, as corrupt, rotten, variable color, colour fading or mycete Formed.
Industrial materials degraded or the microorganism of change can be made to include such as antibacterial, funguses, yeast, algae and cement biology Body.The mixture of the present invention or compositionss preferred pair funguses, particularly mycete, wooden stain fungus and domestomycetes (ascomycetess (Ascomycetes), basidiomycetes (Basidiomycetes), Fungi Imperfecti (Deuteromycetes) and zygomycete (Zygomycetes)) and to cement organism and algae there is effect.Example includes the microorganism with subordinate：Alternaria, Such as alternaria tenuis (Alternaria tenuis)；Eurotium (Aspergillus), such as aspergillus niger (Aspergillus niger)；Black wool Pseudomonas (Chaetomium), such as chaetomium globosum (Chaetomium globosum)；Powder lead fungi belongs to (Coniophora), such as cellar fungus (Coniophora puetana)；Lentinus Edodess Pseudomonas (Lentinus), such as Lentinus tigrinus Bacterium (Lentinus tigrinus)；Penicillium (Penicillium), such as Penicillum glaucum (Penicillium glaucum)；Polyporuses (Polyporus), such as variable color polypor (Polyporus versicolor)；Aureobasidium (Aureobasidium), such as aureobasidium pullulanses (Aureobasidium pullulans)；Core stem point belongs to (Sclerophoma), such as Sclerophoma pityophila；Trichoderma (Trichoderma), such as Trichoderma viride (Trichoderma viride)；Long beak shelly belongs to (Ophiostoma spp.), and Ceratocystis fimbriata Strainses belong to (Ceratocystis ), spp. Humicola (Humicola spp.), Peter's shell belongs to (Petriella spp.), pieces mould genus (Trichurus ), spp. Coriolus Qu61 (Coriolus spp.), viscous gill fungus belongs to (Gloeophyllum spp.), pleurotus (Pleurotus Spp.), transverse hole fungus belong to (Poria spp.), and imperial cyprid belongs to (Serpula spp.) and Tyromyces (Tyromyces spp.), Cladosporium (Cladosporium spp.), paecilomyces (Paecilomyces spp.), Mucor (Mucor spp.), angstrom Uncommon Bordetella (Escherichia), such as escherichia coli (Escherichia coli)；Rhodopseudomonass (Pseudomonas), Such as pseudomonas aeruginosa (Pseudomonas aeruginosa)；Staphylococcus (Staphylococcus), for example golden yellow Color staphylococcuses (Staphylococcus aureus), Candida (Candida spp.) and Saccharomyces (Saccharomyces spp.), such as saccharomyces cerevisiae (Saccharomyces cerevisae).
Antifungal activity
Additionally, the mixture of the present invention or compositionss also have extraordinary antifungal activity.They have non-constant width Antifungal activity is composed, and (for example anti-candida belongs to for particularly anti-dermatophyte and yeast, mycete and diphasic fungi (Candida), as Candida albicans (C.albicans), Candida glabrata (C.glabrata)) and anti-acrothesium floccosum (Epidermophyton floccosum), aspergillus such as aspergillus niger and Aspergillus fumigatus, trichophyta belongs to such as trichophyton (T.mentagrophytes), Microsporon (Microsporon) such as Canis sporidiole bacteria (M.canis) and Du's big belly difficult to understand are little Pityrosporion ovale (M.audouinii).Enumerate these funguses to be in no way intended to constitute the restriction that the funguses being covered are composed, and be only Illustrative.
Therefore, the mixture of the present invention or compositionss can be used in medical treatment and non-medical applications.
Genetic modified organism
As described above, all plants and its part can be processed according to the present invention.In preferred embodiments, to wild Floristics and Plant cultivars or obtained by standard biologic breeding method (such as hybridization or protoplast fusion) Plant, and its part processed.In another preferred embodiment, to by gene engineering method (if appropriate Being combined with conventional method) transgenic plant that obtains and Plant cultivars (genetic modified organism) and its part processed. Term " part " or " part of plant " or " plant part " are explained above.It is highly preferred that according to the present invention to commercially available can The plant of Plant cultivars that are obtaining or being currently in use is processed.Plant cultivars are understood to mean and have often passed through Rule breeding, by mutation or the plant with new features (" character ") that obtained by recombinant DNA technology.They can be cultivation Kind, mutation, biotype or genotype.
Treatment in accordance with the present invention method can be used for processing genetic modified organism (GMO), such as plant or seed.Gene is repaiied Decorations plant (or transgenic plant) are the plants in genome for its heterologous gene stable integration.Statement " heterologous gene " is basic On refer to such a gene, it provides beyond plant or assembles, and is introducing Matrix attachment region, Chloroplast gene or line grain During body genome, (can use by expression protein interested or polypeptide or by making other genes present in plant For example antisense technology, co-suppression technology, RNA interference-RNAi- technology or microRNA-miRNA technology) lower or silence and give institute Conversion plant is new or the agronomy of improvement or other characteristics.Heterologous gene in genome is also referred to as transgenic.By it The transgenic of the ad-hoc location definition in Plant Genome is referred to as conversion or transgenic event.
The plant preferably being processed according to the present invention and Plant cultivars include all plants with genetic stockss, It is particularly advantageous, useful that described genetic stockss give these plants (no matter obtaining) by breeding and/or biotechnological ways Character.
Further preferably the plant being processed according to the present invention and Plant cultivars have to one or more biotic Resistance, that is, described plant show to animal and microbial pests (for example to nematicide, insecticide, demodicid mite, plant pathogenic fungi, Antibacterial, virus and/or viroid) preferably resist.
Can be also that one or more abiotic stress is had according to the plant that the present invention is processed and Plant cultivars Those resistant plants.Abiotic stress conditions may include such as arid, low temperature exposure, beat exposure, osmotic stress, flood, increasing Plus Soil salinity, increased mineral exposure, ozone exposure, bloom exposure, nitrogen nutrition thing limited availability, phosphorus nutrients have Limit availability, keep away shade.
Can be also the yield that those are characterised by improving according to the plant that the present invention is processed and Plant cultivars Plant.In described plant, the yield of increase can be owing to, for example, the plant physiology function of improvement, g and D such as water Divide utilization ratio, water retaining efficiency, the nitrogen utilization improving, the carbon assimilation improving, the photosynthesis improving, the germination effect of increase Rate and hasting of maturity.In addition yield also can be affected by improved plant structure (under stress and non-stress conditions), including But it is not limited to control of blooming, seedling vigor, plant size, internode number and distance, the root life bloomed ahead of time, hybrid seed is produced Length, seed size, fruit size, the seed number of pod size, pod number or spike number, each pod or fringe, seed quality, raising Seed plumpness, reduce seed dispersal, reduce pod dehiscence and lodging resistance.Other yield characteristics include seed group Become, such as carbohydrate content, and composition such as Cotton Gossypii or starch, protein content, oil content and composition, nutriture value Value, the minimizing of anti-nutrient compounds, improved machinability and more preferable storage stability.
Can be the hybridization having shown hybrid vigor or heterosis, hybrid vigor feature according to the plant that the present invention is processed Plant, described hybrid vigor or heterosis, hybrid vigor typically result in higher yield, higher vigor, higher health degree and preferably To biological and abiotic stress resistance).
(for example can be lost by Plant Biotechnology method according to the plant that the present invention is processed or Plant cultivars Pass engineering to obtain) be herbicide tolerant plants, i.e. the plant of one or more given herbicide of tolerance.Such plant can With by gene transformation, or obtained by the plant selecting to comprise the mutation giving such herbicide tolerant.
Also (for example can be lost by Plant Biotechnology method according to the plant that the present invention is processed or Plant cultivars Pass engineering to obtain) it is insect resistant transgenic plant, there is the plant of resistance to the infringement of some targeted insects.Such plant Thing can be obtained by gene transformation, or is obtained by selecting the plant comprising the mutation giving such insect-resistant.
The plant that also can be processed according to the present invention or Plant cultivars are (by Plant Biotechnology method such as base Because engineering obtains) to abiotic stress, there is toleration.Such plant can be obtained by gene transformation, or is wrapped by selection Obtain containing the plant of mutation giving such stress tolerance.
The plant that also can be processed according to the present invention or Plant cultivars are (by Plant Biotechnology method such as base Because engineering obtains) show the amount of change, quality and/or the bin stability of harvesting product and/or the specific one-tenth of harvesting product Divide the characteristic changing.
(it can by Plant Biotechnology method for example for the plant that also can be processed according to the present invention or plant cultivars Genetic engineering obtain) be the fiber properties with change plant, such as vegetable lamb.Such plant can be turned by gene Change, or obtained by selecting the plant of the mutation containing the fiber properties giving this change.
Can also (it can pass through Plant Biotechnology method according to the plant that the present invention is processed or plant cultivars For example genetic engineering obtain) be the oily distribution characteristicss with change plant, the Brassica plantss of such as Brassica campestris L or correlation.So Plant can obtain by gene transformation or by selecting the plant of mutation containing the oily distribution characteristicss giving this change.
Also can (it can pass through Plant Biotechnology method example according to the plant that the present invention is processed or Plant cultivars As genetic engineering obtain) be the seed holding feature with change plant, the Brassica plantss of such as Brassica campestris L or correlation.Such Plant can pass through gene transformation, or by selecting containing the mutant giving the seed holding feature so changing to obtain, and wrap Include the plant as having the rapeseed plant postponing or reducing seed holding.
Also can (it can pass through Plant Biotechnology method example according to the plant that the present invention is processed or Plant cultivars As genetic engineering obtains) it is the plant translating rear protein modification pattern with change, such as tobacco plant.
Rate of application and time
When the mixture that the present invention is used or compositionss are as antifungal, according to applying type, rate of application can be Change in wider scope.The rate of application of the active component of the present invention is
In the case of processing plant part such as blade：0.1 to 10000g/ha, preferably 10 to 1000g/ha, more excellent Select 10 to 800g/ha, even more preferably 50 to 300g/ha (by water or drip irrigation apply in the case of it might even be possible to reduce Rate of application, particularly when using inert base such as asbestos or perlite)；
In the case of seed treatment：2 to 200g every 100kg seed, preferably 3 to 150g every 100kg seed, more preferably 2.5 to 25g every 100kg seed, even more preferably 2.5 to 12.5g every 100kg seed；
In the case of soil treatment：0.1 to 10000g/ha, preferably 1 to 5000g/ha.
These rate of application are only exemplary, are not intended to limit the present invention.
Therefore, the mixture of the present invention or compositionss can be used for protecting the plants from described pathogen invasion after the treatment For a period of time.The time providing protection is generally continuing 1 to 28 day with after described mixture or compositions-treated plant, and preferably 1 To 14 days, more preferably 1 to 10 day, most preferably 1 to 7 day, or last up to 200 days after seed treatment.
The processing method of the present invention also provides by simultaneously, individually or sequentially in the way of using or administered compound (I) and And/or (III) (II).If in sequentially mode, applying single active component in different time, then in the rational short time Interior, such as apply them one by one in a few houres or several days.Preferably, administered compound (A) and (B's) and/or (C) is suitable Ordered pair is not critical in the enforcement present invention.
Listed plant can particularly advantageously be processed with the mixture of the present invention or compositionss according to the present invention.Activity becomes Point or the above-mentioned preferred scope of compositionss be also applied for the process of these plants.Especially emphasize the chemical combination with specifically referring to herein Thing or compositions-treated plant.
Embodiment
The excellent Fungicidally active of the active compound combinations of the present invention is confirmed by following examples.Although individually Reactive compound shows weak Fungicidally active, but described compositionss have the activity simply adding sum beyond activity.
When the Fungicidally active of active compound combinations exceedes and is administered alone during the summation of the activity of reactive compound, Then the cooperative effect of antifungal exists all the time.The expection activity of the given combination of two kinds of reactive compounds can be calculated as below (ginseng See Colby, S.R., " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22)：
If
X is the effect when the rate of application with m ppm (or g/ha) applies reactive compound A,
Y is the effect when the rate of application with n ppm (or g/ha) applies reactive compound B,
Z is the effect when the rate of application with r ppm (or g/ha) applies reactive compound B,
E1It is the effect when respectively reactive compound A and B being applied with the rate of application of m and n ppm (or g/ha), and
E2It is ought be respectively with m, the rate of application of n and r ppm (or g/ha) applies effect during reactive compound A, B and C,
Then
And for ternary mixture：
The degree of effect is represented with %.0% represents the effect corresponding to tester, and 100% effect represents and do not observe To disease.
If the Fungicidally active of reality exceedes value of calculation, the activity of compositionss is superadditivity, and that is, cooperative effect is deposited ?.In this case, the effect actually observing have to be larger than the Expected Results value (E) being calculated by above-mentioned formula.
Another kind of method of confirmation cooperative effect is the method for Tammes (referring to " Isoboles, a graphic Representation of synergism in pesticides " in Neth.J.Plant Path., 1964,70,73- 80).
The present invention is illustrated with the following examples.However, the invention is not restricted to embodiment.
Embodiment A：The internal preventive trial (Fructus Lycopersici esculenti) that Phytophthora (Phytophthora) is tested
Solvent：The acetone of 24.5 weight portions
The dimethyl acetylamide of 24.5 weight portions
Emulsifying agent：The alkylaryl polyglycol ether of 1 weight portion
In order to prepare the appropriate formulation of reactive compound, by the solvent of the reactive compound of 1 weight portion and described amount and breast Agent mixes, and with water, concentrate is diluted to desired concn.In order to test prophylactic activity, with active agent preparations with described Rate of application sprays germling plant.After sprinkling coating is dried, with the aqueouss of phytophthora infestans (Phytophthora infestans) Spore suspension inoculates described plant.Then this plant is placed in about 20 DEG C and relative atmospheric humidity is in 100% incubation cabinet.
Evaluate this test within 3 days after inoculation.0% represents the effect corresponding to untreated control thing, and 100% effect table Show and disease is not observed.Following table clearly illustrates, the activity being observed of the active compound of the present invention is more than meter , that is, there is cooperative effect in the activity calculated.
Table A -1：Internal preventive trial (Fructus Lycopersici esculenti) to Phytophthora test
* the activity of measured value=actual measurement
* value of calculation=using Colby formula calculate activity
The activity of * * difference=actual measurement and the difference of the activity calculating
Table A -2：Internal preventive trial (Fructus Lycopersici esculenti) to Phytophthora test
* the activity of measured value=actual measurement
* value of calculation=using Colby formula calculate activity
The activity of * * difference=actual measurement and the difference of the activity calculating
Embodiment B：The internal preventive trial (Fructus Mali pumilae) that Venturia (Venturia) is tested
Solvent：The acetone of 24.5 weight portions
The dimethyl acetylamide of 24.5 weight portions
Emulsifying agent：The alkylaryl polyglycol ether of 1 weight portion
In order to prepare the appropriate formulation of reactive compound, by the solvent of the reactive compound of 1 weight portion and described amount and breast Agent mixes, and with water, concentrate is diluted to desired concn.In order to test prophylactic activity, with active agent preparations with described Rate of application sprays germling plant.After sprinkling coating is dried, with the pathogenic agent of venturia inaequalis (Venturia inaequalis) Aqueouss conidial suspension inoculate described plant, be then in 100% incubation cabinet in about 20 DEG C and relative atmospheric humidity Keep 1 day.Then described plant is placed in about 21 DEG C of greenhouses with relative atmospheric humidity about 90%.
Evaluate this test within 10 days after inoculation.0% represents the effect corresponding to untreated control thing, and 100% effect Represent and disease is not observed.Following table clearly illustrates, the activity being observed of the active compound of the present invention is more than , that is, there is cooperative effect in the activity calculating.
Table B-1:Internal preventive trial (Fructus Mali pumilae) to Venturia test
* the activity of measured value=actual measurement
* value of calculation=using Colby formula calculate activity
* * difference=actual measurement activity and the difference calculating activity

Claims (8)

1. Synergistic fungicidal active combinations, it comprises
(A) 2- 3- [2- (1- { [3,5- bis- (difluoromethyl) -1H- pyrazol-1-yl] acetyl group } piperidin-4-yl) -1,3- thiazole - 4- yl] -4,5- dihydro -1,2- azoles -5- base } -3- chlorphenyl methanesulfonates, and
(B) phosethyl-Al, and
(C) propineb, folpet or 2,6- dimethyl -1H, 5H- [1,4] two thiophene English simultaneously [2,3-c:5,6-c '] two pyrroles- 1,3,5,7 (2H, 6H)-tetrones.
2. the active agent combinations of claim 1 are used for preventing and treating the purposes of undesired plant pathogenic fungi.
3. the active agent combinations of claim 1 are used for processing the purposes of seed.
4. the active agent combinations of claim 1 are used for processing the purposes of transgenic plant.
5. the active agent combinations of claim 1 are used for processing the purposes of the seed of transgenic plant.
6. the seed being processed with the active agent combinations of claim 1.
7. it is used for preventing and treating the method for undesired plant pathogenic fungi the reactive compound it is characterised in that by claim 1 Conjugate is applied to undesired plant pathogenic fungi and/or its habitat and/or seed.
8. it is used for preparing the method for Fungicidal composition it is characterised in that by the active agent combinations of claim 1 and increasing Amount agent and/or surfactant mixing.
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Citations (5)

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US4698334A (en) * 1977-01-14 1987-10-06 Rhone-Poulenc Agrochimie Fungicidal compositions based on alkyl phosphites
WO2003017762A2 (en) * 2001-08-24 2003-03-06 Bayer Cropscience Ag Fungicidal active-ingredient combinations
WO2011035834A1 (en) * 2009-09-02 2011-03-31 Bayer Cropscience Ag Active compound combinations
CN102595905A (en) * 2009-09-14 2012-07-18 拜尔农作物科学股份公司 Synergistic fungicidal combinations containing a dithiino-tetracarboxamide fungicide
WO2013127704A1 (en) * 2012-02-27 2013-09-06 Bayer Intellectual Property Gmbh Active compound combinations containing a thiazoylisoxazoline and a fungicide

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US4698334A (en) * 1977-01-14 1987-10-06 Rhone-Poulenc Agrochimie Fungicidal compositions based on alkyl phosphites
WO2003017762A2 (en) * 2001-08-24 2003-03-06 Bayer Cropscience Ag Fungicidal active-ingredient combinations
WO2011035834A1 (en) * 2009-09-02 2011-03-31 Bayer Cropscience Ag Active compound combinations
CN102595905A (en) * 2009-09-14 2012-07-18 拜尔农作物科学股份公司 Synergistic fungicidal combinations containing a dithiino-tetracarboxamide fungicide
WO2013127704A1 (en) * 2012-02-27 2013-09-06 Bayer Intellectual Property Gmbh Active compound combinations containing a thiazoylisoxazoline and a fungicide

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