CN106396818A - Ecological mineral solution fertilizer for food crops as well as preparation and use methods thereof - Google Patents
Ecological mineral solution fertilizer for food crops as well as preparation and use methods thereof Download PDFInfo
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- CN106396818A CN106396818A CN201611187042.6A CN201611187042A CN106396818A CN 106396818 A CN106396818 A CN 106396818A CN 201611187042 A CN201611187042 A CN 201611187042A CN 106396818 A CN106396818 A CN 106396818A
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- mineral solution
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
- A01C21/005—Following a specific plan, e.g. pattern
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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Abstract
The invention discloses an ecological mineral solution fertilizer for food crops as well as preparation and use methods thereof. The formula raw material of the fertilizer is a natural ore which is a mixture of medical stone, smithsonite, pyrolusite, copper concentrate and paigeite. The preparation method comprises the following steps: crushing the natural ore into powder; performing vibration screening, suspended separation, soaking dissolution, boiling reaction, aging extraction and filtration to prepare a multi-element mineral solution; then performing energy-gathered shearing by virtue of an ultrasonic field driven by an alternating magnetic field; and finally, performing aging filtration, purification and filling to prepare the ecological mineral solution fertilizer for the food crops. The ecological mineral solution fertilizer for the food crops, disclosed by the invention, at least contains 20 types of metallic ions, the content of a main component meets a standard of the Ministry of Agriculture for an NY1428-2010 microelement water-soluble fertilizer, and the fertilizer has multiple functions of having a high energy state and high activity, activating and catalyzing vitality of crops, and the like.
Description
Technical field
The present invention relates to a kind of trace element water-soluble fertilizer, particularly a kind of cereal crops ecological mineral solution fertilizer and its system
Standby and using method.
Background technology
Cereal crops have upper state, high activity with ecological mineral solution fertilizer, have multiple work(such as activation, catalysis vitality
Can, crop photosynthesis can be promoted, strengthen metabolism, resist disease pest and poor environment harm, increase crop yield, improve
Quality.Famous American scientist Lan Nasi Pauling doctor claims that " all diseases all cause due to a lack of trace quantity mineral substance element, not micro-
Amount mineral element, vitamin cannot act on enzyme, and life only vanishes into thin air ".Set great store by military affairs or martial arts and think in scientist open country island：The micro unit of life power
Element is extremely close with the life relation of people, " lacks work bad, is not unlikely to survive." due to the life power element with modern
Constantly reduce with life-related element, so that human diseases is got more and more, or even cause to obtain obstinate after being ill.
It is known that the nutrient on the person derives from food.Such as ferrum is people's necessary life power element, also all
Know that the comparision contents of ferrum in Herba Spinaciae are high, but in our Herba Spinaciaes that eat now, the content of ferrum only has the Herba Spinaciae of the fifties in last century to contain
/ 20th of iron, other vegetables also have similar situation with foods such as grains." soil is the mother of food ", through chemically examining soil,
The final cause that in food, these life power elements reduce is the minimizing of these life power trace element in soil.
The grain of China always eats yield by 32055.5 ten thousand tons of 1980, increases to 60702.6 ten thousand tons within 2014, per hectare
Per unit area yield brings up to 5892 kilograms by 2734 kilograms, increased 2 times.Often producing 100 kilograms of corn kernels needs to absorb from soil
2.13 kilograms of nitrogen, 1.1 kilograms of phosphorus, 1.51 kilograms of potassium.The nutrient plundered in soil, mainly to supplement by application fertilizer.
The usage amount of China's chemical fertilizer, by 1269.4 ten thousand tons of 1980, increases to 5995.9 ten thousand tons in 2014, increased 4.7 times, wherein,
Nitrogenous fertilizer increases to 2392.9 ten thousand tons from 934.2 ten thousand tons, and phosphate fertilizer increases to 845.3 ten thousand tons from 273.3 ten thousand tons, and potash fertilizer is from 34.6 ten thousand tons
Increase to 641.9 ten thousand tons, compound fertilizer increases to 2115.8 ten thousand tons from 27.2 ten thousand tons.The appearance of chemical fertilizer and be continuously increased use, promotees
Enter crop yield to increase substantially, substantially met the demand of having enough to eat and wear of burgeoning population existence substantially, also brought meanwhile
Very important negative effect.
It is that soil nutrient is unbalance first.People obtain substantial amounts of crop products when, soil not only consume a large amount of nitrogen,
Phosphorus, potassium nutrition, are also consumed by a large amount of mine trace element nutrients.And the administration of chemical fertilizer, only to soil refilled merely nitrogen, phosphorus,
Potassium three elements etc., fail to supplement mine trace element.Soil nutrient is unbalance to directly affect the micronutrient levelss of crop products,
The quality leading to crop products reduces.Two is that soil physico-chemical property degenerates.The administration of a large amount of chemical fertilizer, makes Soil structure hardened,
Secondary salinization increases, and soil microorganism is deficient, contaminated soil, pollutes (underground) water.Solution is to enrich enough to soil
Humus, with organic agriculture fertilizer (compost) replace chemical fertilizer.
It is worth mentioning that present fertilizer, the farm manure either piled up, or the fertilizer of plant produced, all
It is with lacking the straw of mineral trace element or the domestic animals and fowls feces with lacking the forage feed of mineral trace element
Process.Mineral trace element can not be supplemented with this fertilizer comprehensively.
, with soil for this, soil is with rock as mother for grain.Accordingly, it would be desirable to ask for mineral trace element from natural crystal, exploitation is ground
Make the mineral trace element new product of wide spectrum and be extensively applied, this has become raising crop yield further, and
Fundamentally improve the important channel of crops quality.
Applicant once adopted granted patent (patent No. ZL 00121456.X, patent name：Ecological mineral solution and its system
Preparation Method) ecological mineral solution that produces attempts being applied to agriculture aspect.But, the production technology of above-mentioned patent and ore system
Standby mineral solution out, finds its iron content 2.19g/l, manganese 0.15g/l, boron 0.002g/l, copper 5.1ug/ml, zinc through authority's detection
596.1ug/ml, molybdenum 0.02ug/ml, total 7.96g/l, away from the ministry standard of the Ministry of Agriculture's " trace element water-soluble fertilizer "《NY
1428～2010》Differ greatly.Therefore, the needs that ecological dynamic element cannot meet agricultural production are prepared using prior art.Mesh
Before, need a kind of new cereal crops ecological mineral solution of research and development badly fertile.
The purpose of the present invention is to take out molten polynary mineral solution from natural crystal in original ecological mineral solution, in alternating intense magnetic field
Shearing activation Process ba- sis on, carried out deep research and development, all significant improvement has been done to raw material and process it is therefore intended that
Develop the agricultural series of products of life power element, that is, cereal crops are fertile with ecological mineral solution, and provide its supporting preparation to make
Use method.
For realizing above-mentioned technical purpose, the present invention adopts the following technical scheme that：
A kind of cereal crops are fertile with ecological mineral solution, be liquid aqueous solution it is characterised in that：Wherein at least contains 20 kinds of gold
Belong to ion, its formula material is natural crystal, described natural crystal is Maifanitum, smithsonite, pyrolusite, copper concentrate and paigeite
Mixture, in described natural crystal, the weight ratio of contained component and each component is：Maifanitum 10～20%；Smithsonite 20～
30%；Pyrolusite 20～30%；Copper concentrate 20～30%；Paigeite 5～10%, limestone 0～10%, the liquid 250 made
The pH of times diluent is 3.0～3.5.
Wherein, when described cereal crops are used for maize planting, Maifanitum, Pedicellus et Pericarpium Trapae in described natural crystal with ecological mineral solution is fertile
The weight ratio of zinc ore, pyrolusite, copper concentrate and paigeite is：Maifanitum 20%；Smithsonite 30%；Pyrolusite 20%；Copper concentrate
20%；Paigeite 10%.
Wherein, when cereal crops are used for rice cultivation with ecological mineral solution is fertile, preferably Maifanitum, smithsonite, pyrolusite, copper
The weight ratio of concentrate and paigeite is：Maifanitum 15%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite
10%；Limestone 10%.
Further, described cereal crops with ecological mineral solution fertile for wheat planting when, preferably Maifanitum, smithsonite,
The weight ratio of pyrolusite, copper concentrate and paigeite is：Maifanitum 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；
Paigeite 10%.
The present invention the fertile preparation method of above-mentioned cereal crops ecological mineral solution is also provided it is characterised in that：Will be natural
Ore is ground into powder, sequentially passes through shaking-sieving, the separation that suspends, reaction is boiled in immersion dissolving, ageing extracts and filters, makes
Polynary mineral solution, the ultrasonic field being then passed through alternating intense magnetic field driving carries out cumulative shearing, finally aged filtration, purification and filling
Dress, the cereal crops making finished product are fertile with ecological mineral solution.
Preferably, described immersion dissolving is boiled in reaction, and the immersion lytic agent of use is sulphuric acid and the concentration of concentration 98%
36% hydrochloric acid；The addition volume of the sulphuric acid of described concentration 98% is equivalent to 2 times of natural crystal volume of mixture；Concentration 36%
Hydrochloric acid addition volume identical with the volume of natural crystal mixture.
Preferably, described immersion dissolving is boiled in reaction, and stirring immersion 10～16 hours boils 3～5 hours.
Additionally, above-mentioned preparation method prepare pulverizer, the selecting crude drugs with winnower screen cloth that production line includes laying successively and sequentially connecting
Jarring machine, boil dissolving retort, pressure filter, ageing retort, energy-gathering device, manganese sand filter, purification pot and finished pot, institute
State to boil and sulfuric acid storage tank and hydrochloric acid tank are connected respectively on dissolving retort, described pressure filter connects Solid state fermentation system.
Finally, the present invention also provides the cereal crops fertile use of ecological mineral solution prepared using above-mentioned preparation method
Method it is characterised in that：
(1) maize planting：
Respectively spray once in seedling stage (5-7 leaf), jointing stage, trumpet period, use ecological ore deposit molten with cereal crops for every mu every time
Liquid fertilizer 100ml sprays to water 60L；
(2) rice cultivation：
Rice seedling bed using method：Respectively apply once in 1 leaf 1 heart stage, 2 leaf 1 heart stage, every square metre of seedbed is used with cereal crops every time
Ecological mineral solution fertilizer 1ml, sprinkles to 1000 times of water and pours；
Honda using method：In period of seedling establishment, jointing stage, boot stage each spray once, every time every mu with cereal crops ecology
Mineral solution fertilizer 100ml sprays to water 60L；
(3) plant Semen Tritici aestivi：
In tillering stage, jointing stage, pustulation period each spray once, every time every mu with cereal crops ecological mineral solution fertilizer 100ml
Water 60L is sprayed.
Compared with prior art, the present invention has integrally made two to improve greatly below：
First, adjustment variety of raw material and formula design
The present invention carries out screening study to basic material, selected the Maifanitum of rich in mineral substances trace element, smithsonite,
Formula material based on pyrolusite, copper concentrate, paigeite, preparation rich in mineral substances trace element agricultural type ecological dynamic element,
It is fundamentally to solve the problems, such as that micronutrient levelss are low to provide material base；
Wherein, smithsonite mainly provides zinc element, the zinc in smithsonite, and part can be replaced by ferrum or manganese, or a small amount of
Magnesium, calcium, cadmium, copper, cobalt or lead replaced, it is similar with most carbonate minerals, is dissolved in hydrochloric acid and can produce bubble.Smithsonite
One kind that hardness is higher, proportion is larger is belonged in calcite group；
Pyrolusite, main component is manganese dioxide, is a kind of common manganese mineral, containing manganese 63.19%, is important manganese ore
Stone.Miao Autonomous County of Songtao of Tong Ren District of Guizhou Province city is general to feel that manganese ore verifies 1.92 hundred million tons of manganese resource amount, can be rated as Asia first；
Copper concentrate is that low-grade cupric tcrude ore processes, through ore-dressing technique, the concentrate reaching certain mass index, can be straight
Connect for smeltery's copper metallurgy.Copper concentrate major part is the secondary mineral again through reduction for the original sulfides oxidation Decomposition, contains
Copper component is high, is most important copper metallurgy Ore.Yunnan Province of China Dongchuan copper etc. has a large amount of copper concentrates；
Paigeite is the raw material refining boron, rich in boron and ferrum；
Limestone contains abundant calcium constituent, also silicon, ferrum, magnesium, aluminum etc.；
Maifanitum is a kind of natural silicate mineral, and main chemical compositions are inorganic aluminosilicates, including
SiO2、Al2O3、Fe2O3、FeO、MgO、CaO、K2O、Na2O、TiO2、P2O5, MnO etc., also containing the whole constants units needed for animal
Element, trace element and rare earth element, such as K, Na, Ca, Mg, Cu, Mo etc., as many as about 58 kinds.
Due to employing copper, ferrum, manganese, zinc, crude boron stone on the basis of Maifanitum it is ensured that the source of this 5 kinds of elements, for carrying
Copper, ferrum, manganese, zinc, the content of boron element reach Ministry of Agriculture's " trace element water-soluble fertilizer " in high Ore preparation ecological dynamic element
Ministry standard《NY1428～2010》Requirement index, there is provided material base ensure.
In formula design, creatively select Maifanitum 10～20%, smithsonite 20～30%, pyrolusite 20～
30%th, copper concentrate 20～30%, the Ore of paigeite 5～10% weight ratio are configured, the cereal crops ecology ore deposit of preparation
In solution fertilizer, copper, ferrum, manganese, zinc, boron, the content of molybdenum element are all improved, and have reached the requirement of Ministry of Agriculture's ministry standard, i.e. copper
The content sum of Cu+ ferrum Fe+ manganese Mn+ zinc Zn+ boron+molybdenum Mu reaches 100g/L.The highest content of trace element of the present invention reaches
144.5g/L.
2nd, the improvement of production technology
(1) adjustment soak species and concentration：Coordinating 36% concentrated hydrochloric acid with high concentration 98% concentrated sulphuric acid is high concentration strong acid
As soaking solution, the micronutrient levelss in product can be directly adjacent to and reach the requirement of Ministry of Agriculture's ministry standard for mixing, and
If utilizing the dilute hydrochloric acid of prior art 2～10% concentration, dilute sulfuric acid, citric acid one of which dilute concentration acid soak Ore,
The Ore putting into same ratio wherein prepares water-soluble fertilizer, is detected, result shows that the concentration of soaking solution is too dilute, micro
Constituent content seldom, and needs concentration it is impossible to reach the requirement of Ministry of Agriculture's ministry standard；
(2) change stirring to soak and boiling time：By stirring immersion 3～5 hours, it is adjusted to stirring immersion 10～16 little
When；By boiling time by 2～5 hours, it is adjusted to and boils 3～5 hours, the response time lengthens；Prove through repetition test, prolongation is stirred
Mix immersion reaction and boiling time, breeze just can be made fully to dissolve, effectively improve micronutrient levelss.
The cereal crops of the present invention fertile functional component of ecological mineral solution and content such as table 1：
Table 1. the cereal crops fertile functional component of ecological mineral solution and content
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 30000～35000 | Ferrum | 15000～23000 |
| Manganese | 19000～23000 | Zinc | 29000～34000 |
| Calcium | 300～400 | Cobalt | 5～10 |
| Phosphorus | 1000～1450 | Nickel | 5～10 |
| Magnesium | 3200～4200 | Molybdenum | 800～1000 |
| Potassium | 1400～2000 | Lithium | 300～400 |
| Sodium | 150～200 | Vanadium | 40～60 |
| Selenium | 30～50 | Silicon | 360～480 |
| Barium | 180～230 | Titanium | 800～1400 |
| Aluminum | 11000～15000 | Boron | 3000～4000 |
Through Beijing fertilizer quality supervision and inspection station and the detection of National Geology test center, this mineral solution mineral is micro
The content of element meets the ministry standard of " trace element water-soluble fertilizer " of the Ministry of Agriculture《NY1428～2010》Regulation, copper Cu+ ferrum
The content sum of Fe+ manganese Mn+ zinc Zn+ boron+molybdenum Mu reaches 100g/L.In the report of spectrum Buddhist nun's test, copper+ferrum+manganese+zinc+boron
+ molybdenum content adds up to 153.47g/L.Cu >=20g/L in product of the present invention, Fe >=5g/L, Mn >=30g/L, Zn >=44g/L, B >=
2g/L, the highest content of trace element reaches 144.5g/L.
Compared with prior art, the present invention has following technical advantage：
First, cereal crops with ecological mineral solution fertilizer dissolved with the catalysis promoting during life chemistry, activation dynamic
Power groups of elements, they all presented in water-complex ion, e.g., Cu++,Fe++,Mn++, Zn++,Mo++,Ti++Deng containing d rail
The element ion in road, these ions can be acted on hydrone, forms chelation structure so as to there be comparatively gentle surface charge close
Degree；
2nd, these elements all have d orbital electron or unoccupied orbital, when above-mentioned element reaches finite concentration, cause electronics to turn
Move, produce hydroxyl radical free radical, can degrade toxic organic compound, precipitation of heavy metals；
3rd, under conditions of oxygen concentration is higher, automatically generate ecological oxygen, strengthen the metabolism of crop；
4th, cereal crops ecological mineral solution fertilizer has upper state, and the cascaded structure of water clusters is cut off, and forms little point
Sub- water, is easily absorbed by plant roots stem and leaf；
5th, the mineral trace element content in product can be effectively improved, cereal crops ore deposit contained by ecological mineral solution fertilizer
Material trace element species is many, has the linear water aggressiveness of the cut formation of metal cation of the affine scale value of different electric charges
Length, regularity are different, play different effects to different cytons.These elements enter plant body in can accomplish each department its
Duty, metabolic balance, robust plant, leaf color is beautiful, and mouthfeel improves, quality improving；
6th, using method is simple, easy to utilize；
7th, obvious effect of increasing production：
Through to the cereal crops fertile extensive experimentation of ecological mineral solution and application, can supplement crop growthing development must
The various trace elements needing, it is possible to increase crop yield, its obvious effect of increasing production, improve crop quality simultaneously.Carry from various places
For test report see, fertile with ecological mineral solution using cereal crops, Semen Tritici aestivi averagely increases production 7.4%, highest volume increase 20.4%；Water
Rice seedlings Tian Nengzhuan root key Seedling, prevents and treats damping-off effect and reaches 95%；Rice on honda can improve resists chilling injury ability, average increasing
Produce 18.6%, highest volume increase 28.6%；Semen Maydiss sprayed in seedling stage and jointing stage, averagely increased production 7.9%, highest volume increase 12.6%；
Semen sojae atricolor was sprayed in early flowering season and fruiting period, averagely increased production 10.8%, highest volume increase 20.9%.
1. Jilin Province's clay fertilizer stands in Xin Jia village of Lishu County little Kuan township and has done rice test, in period of seedling establishment, jointing stage, pustulation period
Each spray that a cereal crops ecological mineral solution is fertile, the Oryza sativa L. performance of sprinkling is turned green, and fast, tiller is early, growth is vigorous, is supplying water
Show especially prominent in the case of fertilizer deficiency.Show early jointing, early booting, grouting fast, ripe early during reproductive growth
2-3 days, increase mass of 1000 kernel, increase production 27.5%；
2. Heilongjiang Province Sui Ling county agricultural technology extension center carries out spraying cereal crops ecological mineral solution in corn field
Fertile test, respectively in Maize at Seedling Stage, jointing stage each sprinkling once, every mu with cereal crops ecological mineral solution fertilizer 100ml to water
500 times, carry out foliage spray, effect of increasing production reaches 14.6-18.8%；
3. agricultural technology extension master station of autonomous prefecture of Yanbian, Jilin Province Korean nationality 2014 is in Yanji Chaoyang Chuan Zhen too East Village
Carry out the cereal crops ecological mineral solution fertilizer Applied D emonstration of 75 mu of Oryza sativa L., survey 533 kilograms of per mu yield, than conventional cultivation volume increase
16.5%；
4th, prolong side Dongcheng nuisanceless Special Agriculture Product company limited by the organic rice planted using this water-soluble fertilizer respectively at
2009 and the product quality inspection of 2010 Nian Song Korean Autonomous Prefecture of Yanbian are checked, and in rice kernel detection report, apply mineral solution
Fertile organic rice is more much higher than the content of mineral substances of unused organic rice, wherein manganese 9.5>6.3；Lithium 0.08>0.002；Zinc
15.2>9.1；Selenium 0.03>0.005；Cobalt 0.07>0.02；Ferrum 2.7<2.8；Calcium 95.5>54.2；Chromium 0.53>0.04.Unit：μg/
kg.
Additionally, the water-soluble fertilizer that this patent is related to is also very notable for the effect of Radix Ginseng.Radix Ginseng is well-known " northeast
One of three essentials-essence ", in decades, Radix Ginseng industry development is swift and violent, make can cultivated ginseng forest land resource almost exhausted, in old ginseng 30
It is the how many years final conclusions having descended that Radix Ginseng can not be planted in year again, and renovation and utilization old ginseng plantation Radix Ginseng is extremely urgent, and Radix Ginseng is even
Work is the significant technology issues also could not being fully solved in the world.Applicant is being investigated on the spot and is being seeked advice from famous both at home and abroad
On the basis of experts and scholars, in autumn in 2011 to autumn in 2013, in Shi Miao village of Ji'an City linen thread township of Jilin Province, use cereal crops
Carry out old ginseng Radix Ginseng continuous cropping test with ecological mineral solution fertilizer, after 2 years, Radix Ginseng survival rate reaches more than 70%, achieves breakthrough
The achievement of property.
Brief description
By the detailed description made in conjunction with the following drawings, above-mentioned and/or other aspects of the present invention and advantage will become
Become apparent from and be easier to understand, these accompanying drawings simply schematically, are not intended to limit the present invention, wherein：
Fig. 1 is cereal crops ecological mineral solution fertilizer preparation technology schematic flow sheet.
Reference：1- pulverizer, 2- selecting crude drugs with winnower screen cloth jarring machine, 3- boil dissolving retort, 4- sulfuric acid storage tank, 5- hydrochloric acid
Storage tank, 6- pressure filter, 7- ageing retort, 8- energy-gathering device, 9- manganese sand filter, 10- purification pot, 11- finished pot, 12- give up
Slag disposal system.
Specific embodiment
Hereinafter, cereal crops ecological mineral solution fertilizer and its preparation using method of the present invention are described with reference to the accompanying drawings
Embodiment.
The embodiment that here is recorded is the specific specific embodiment of the present invention, for the design of the present invention is described, all
It is explanatory and exemplary, should not be construed as the restriction to embodiment of the present invention and the scope of the invention.Except here record
Implement exception, those skilled in the art can also be based on the application claims and description disclosure of that using aobvious
The other technical schemes being clear to, these technical schemes include any obvious using making of the embodiment that here is recorded
The technical scheme of substitutions and modifications.
The present invention relates to a kind of cereal crops are fertile with ecological mineral solution, it at least contains 20 metal ion species, and its formula is former
Expect for natural crystal, described natural crystal is Maifanitum, smithsonite, the mixture of pyrolusite, copper concentrate and paigeite.As this
The optimal technical scheme of invention, in described natural crystal, raw material components and each components by weight are：Maifanitum 10～20%；Pedicellus et Pericarpium Trapae
Zinc ore 20～30%；Pyrolusite 20～30%；Copper concentrate 20～30%；Paigeite 5～10%, limestone 0～10%.
If Fig. 1 is cereal crops ecological mineral solution fertilizer preparation technology schematic flow sheet.According to the preparation of preparation technology flow process
Cereal crops are fertile with ecological mineral solution, use pulverizer 1 first by skies such as Maifanitum, smithsonite, pyrolusite, copper concentrate, paigeites
So Ore is ground into powder, chooses 60 mesh powder through selecting crude drugs with winnower screen cloth jarring machine 2, then percentage by weight is respectively Maifanitum 10
～20%, smithsonite 20～30%, pyrolusite 10～20%, copper concentrate 20～30%, the ratio of paigeite 5～10% puts into boils
Mix in boil-off solution retort 3, add and be equivalent to the sulphuric acid of concentration 98% of 2 times of ore volume and isopyknic with natural crystal
The hydrochloric acid of concentration 36%, adds in retort 3 by acid storage tank 4,5, and stirring immersion 10～16 hours is boiled 3～5 hours, carried out
Dissolving, through pressure filter 6 solid-liquid separation, solution loads ageing retort 7 and is aged, the high-energy ultrasonic being driven by alternating intense magnetic field
Field 8, the ball of string structure shearing, smashing cereal crops ecological mineral solution fertilizer stock solution improves energy state, through manganese sand filter 8 mistake
Filter, purification pot 9 purifies, and delivers to finished product storage tank 10, line 11 to be filled fill.With reference to embodiment, present invention is had
Body explanation：
Embodiment 1
Prepare Semen Maydiss special cereal crops ecological mineral solution fertile, with pulverizer 1 by Maifanitum, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite are ground into powder, choose 60 mesh powder through selecting crude drugs with winnower screen cloth jarring machine 2, then divide weight %
Not Wei Maifanitum 20%, smithsonite 30%, pyrolusite 20%, copper concentrate 20%, the ratio of paigeite 10% puts into boils dissolving
Mix in retort 3, add and be equivalent to the sulphuric acid of concentration 98% of 2 times of ore volume and the salt of the isopyknic concentration of Ore 36%
Acid adds in retort 3 by acid storage tank 4,5, stirring immersion 10～16 hours, boils 3～5 hours, is dissolved, through filter pressing
Machine 6 solid-liquid separation, solution loads ageing retort 7 and is aged, the high-energy ultrasonic field energy-gathering device 8 being driven by alternating intense magnetic field,
The ball of string structure shearing, smashing cereal crops ecological mineral solution fertilizer stock solution improves energy state, filters through manganese sand filter 9, purifies
Tank 10 purifies, and delivers to finished product storage tank 11, line fill to be filled.The Semen Maydiss special cereal crops fertile functional component of ecological mineral solution
And content such as table 2：
Table 2. Semen Maydiss special the cereal crops fertile functional component of ecological mineral solution and content
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 19000～25000 | Ferrum | 7600～12000 |
| Manganese | 28000～36000 | Zinc | 48000～56000 |
| Calcium | 250～450 | Sodium | 260～320 |
| Phosphorus | 900～1500 | Nickel | 15～30 |
| Magnesium | 2500～4000 | Molybdenum | 800～1000 |
| Potassium | 2400～3700 | Lithium | 80～400 |
| Selenium | 30～50 | Silicon | 360～480 |
| Barium | 180～230 | Titanium | 800～1400 |
| Aluminum | 11000～15000 | Boron | 3000～4000 |
The special cereal crops of Semen Maydiss of present invention preparation are fertile micro rich in copper, ferrum, manganese, zinc, boron, molybdenum etc. with ecological mineral solution
Element, reaches the technical specification with regard to trace element water-soluble fertilizer for the Ministry of Agriculture, and the content of wherein zinc element is higher, contributes to preventing and treating
The generation of the grey seedling diseases of Semen Maydiss being led to due to excessive application of phosphoric acid diammonium with spread.
Embodiment 2
The preparation special cereal crops of Oryza sativa L. are fertile with ecological mineral solution, with pulverizer 1 by Maifanitum, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite, limestone are ground into powder, choose 60 mesh powder through selecting crude drugs with winnower screen cloth jarring machine 2, then by wheat
Meal stone 15%, smithsonite 25%, pyrolusite 20%, copper concentrate 20%, paigeite 10%, the ratio (weight %) of limestone 10%
Input is boiled in dissolving retort 3 and is mixed, and adds concentration 98% sulphuric acid being equivalent to 2 times of ore volume and Ore isopyknic dense
Spend 36% hydrochloric acid and add in retort 3 by acid storage tank 4,5, stirring immersion 10～16 hours, boil 3～5 hours, dissolved,
Through pressure filter 6 solid-liquid separation, solution loads ageing retort 7 and is aged, and the high-energy ultrasonic field being driven by alternating intense magnetic field is gathered
Energy device 8, the ball of string structure shearing, smashing cereal crops ecological mineral solution fertilizer stock solution improves energy state, through manganese sand filter 9
Filter, purification pot 10 purifies, and delivers to finished product storage tank 11, line fill to be filled.The special cereal crops of Oryza sativa L. are fertile with ecological mineral solution
Functional component and content such as table 3：
Table 3. Oryza sativa L. special the cereal crops fertile functional component of ecological mineral solution and content
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 18000～25000 | Ferrum | 8000～14000 |
| Manganese | 34000～41000 | Zinc | 48000～52000 |
| Calcium | 1200～1500 | Sodium | 260～320 |
| Phosphorus | 1000～1500 | Nickel | 15～30 |
| Magnesium | 2000～4000 | Molybdenum | 800～1000 |
| Potassium | 2000～3000 | Lithium | 180～400 |
| Selenium | 30～50 | Silicon | 1800～2800 |
| Barium | 200～230 | Titanium | 1200～1400 |
| Aluminum | 8800～12000 | Boron | 4000～6000 |
The special cereal crops of Oryza sativa L. of present invention preparation ecological mineral solution fertilizer is not only rich in copper, ferrum, manganese, zinc, boron, molybdenum etc.
Trace element, reaches the technical specification with regard to trace element water-soluble fertilizer for the Ministry of Agriculture, and the content of wherein element silicon is higher, contributes to
Improve the growth promoter of Oryza sativa L. and resistant to lodging, resistances against diseases, thus improving yield.
Embodiment 3
Prepare Semen Tritici aestivi special cereal crops ecological mineral solution fertile, with pulverizer 1 by Maifanitum, smithsonite, pyrolusite, copper
The natural crystals such as concentrate, paigeite, limestone are ground into powder, choose 60 mesh powder through selecting crude drugs with winnower screen cloth jarring machine 2, then by wheat
Meal stone 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Ratio (weight %) input of paigeite 10% is boiled molten
Mix in solution retort 3, add concentration 98% sulphuric acid and the isopyknic concentration of Ore 36% hydrochloric acid being equivalent to 2 times of ore volume
Add in retort 3 by acid storage tank 4,5, stirring immersion 10～16 hours, boil 3～5 hours, dissolved, through pressure filter 6
Solid-liquid separation, solution loads ageing retort 7 and is aged, and the high-energy ultrasonic field energy-gathering device 8 being driven by alternating intense magnetic field is cut
The ball of string structure cutting, smashing cereal crops ecological mineral solution fertilizer stock solution improves energy state, filters through manganese sand filter 9, purifies
Tank 10 purifies, and delivers to finished product storage tank 11, line fill to be filled.The fertile functional component of the special ecological mineral solution of Semen Tritici aestivi and content such as table
4：
Table 4. Semen Tritici aestivi special the cereal crops fertile functional component of ecological mineral solution and content
| Element | Content (mg/l) | Element | Content (mg/l) |
| Copper | 16000～24000 | Ferrum | 9000～12000 |
| Manganese | 34000～41000 | Zinc | 42000～52000 |
| Calcium | 400～500 | Sodium | 260～360 |
| Phosphorus | 1000～1500 | Nickel | 25～50 |
| Magnesium | 2600～4000 | Molybdenum | 1800～3000 |
| Potassium | 1500～3000 | Lithium | 280～400 |
| Selenium | 30～60 | Silicon | 380～580 |
| Barium | 200～280 | Titanium | 9800～1400 |
| Aluminum | 9800～15000 | Boron | 4000～6000 |
The cereal crops of present invention preparation are rich in the trace element such as copper, ferrum, manganese, zinc, boron, molybdenum with ecological mineral solution is fertile, reach
To the Ministry of Agriculture with regard to the technical specification of trace element water-soluble fertilizer, it is widely used in Cereal, legume and tuber crops.
Additionally, sum up in experimentation cereal crops ecological mineral solution fertile preferably use method, see table 5：
Table 5. cereal crops preferably use method with ecological mineral solution fertilizer
Points for attention：
(1) this product can not replace chemical fertilizer.
(2) this product can not with combined use of pesticides, with spray insecticide interval 5 days used above.
(3) this product is nontoxic to people, animal, using safety.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention.The present invention also can make multiple
Content mineral solution trace element water-soluble is fertile, is widely used in melon and fruit class, solanaceous vegetables, root vegetableses and the various fruit and vegerable of leaf vegetabless, also may be used
Foliage spray for fruit tree and pouring root etc..All any modifications made within the spirit and principles in the present invention, equivalent,
Improve etc., should be included within the scope of the present invention.
Claims (9)
1. a kind of cereal crops are fertile with ecological mineral solution, be liquid aqueous solution it is characterised in that：Its formula material is natural ore
Stone, in described natural crystal, the weight ratio of contained component and each component is：10～20% Maifanitums, 20～30% smithsonite, 20
The limestone of～30% pyrolusite, 15～20% copper concentrates, 5～10% paigeites and 0～10%；250 times that make liquid dilute
Releasing liquid pH is 3.0～3.5.
2. cereal crops according to claim 1 with ecological mineral solution fertile it is characterised in that：Described cereal crops are ecological
Mineral solution is fertile to be used for maize planting, Maifanitum, smithsonite, pyrolusite in described natural crystal, the weight of copper concentrate and paigeite
Than for：Maifanitum 20%；Smithsonite 30%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%.
3. cereal crops according to claim 1 with ecological mineral solution fertile it is characterised in that：Described cereal crops are ecological
Mineral solution is fertile to be used for rice cultivation, the weight of Maifanitum, smithsonite, pyrolusite, copper concentrate and paigeite in described natural crystal
Than for：Maifanitum 15%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%；Limestone 10%.
4. cereal crops according to claim 1 with ecological mineral solution fertile it is characterised in that：Described cereal crops are ecological
Mineral solution fertilizer is used for planting Semen Tritici aestivi, the weight of Maifanitum, smithsonite, pyrolusite, copper concentrate and paigeite in described natural crystal
Than for：Maifanitum 25%；Smithsonite 25%；Pyrolusite 20%；Copper concentrate 20%；Paigeite 10%.
5. the fertile preparation method of ecological mineral solution of the cereal crops described in a kind of claim 1-4 any one, its feature exists
In：Natural crystal is ground into powder, sequentially pass through shaking-sieving, suspend separate, soak dissolving boil reaction, ageing extract and
Filter, make polynary mineral solution, the ultrasonic field being then passed through alternating intense magnetic field driving carries out cumulative shearing, finally aged mistake
Filter, purification and fill, the cereal crops making finished product are fertile with ecological mineral solution.
6. cereal crops according to claim 5 with the fertile preparation method of ecological mineral solution it is characterised in that：Described immersion
Dissolving is boiled in reaction, and the lytic agent that soaks of use is the sulphuric acid of concentration 98% and the hydrochloric acid of concentration 36%；Described concentration 98%
The addition volume of sulphuric acid be equivalent to 2 times of natural crystal volume of mixture；The addition volume of the hydrochloric acid of concentration 36% with natural
The volume of ore mix is identical.
7. cereal crops according to claim 5 with the fertile preparation method of ecological mineral solution it is characterised in that：Described immersion
Dissolving is boiled in reaction, stirring immersion 10～16 hours, boils 3～5 hours.
8. the fertile preparation method of ecological mineral solution of the cereal crops according to claim 5～7 any one, its feature exists
In：In preparation application prepare the pulverizer (1) that production line includes laying successively and sequentially connect, selecting crude drugs with winnower screen cloth jarring machine (2),
Boil dissolving retort (3), pressure filter (6), ageing retort (7), energy-gathering device (8), manganese sand filter (9), purification pot
(10) and finished pot (11), described boiling connects sulfuric acid storage tank (4) and hydrochloric acid tank (5) in dissolving retort (3) respectively, described
Pressure filter (6) connects Solid state fermentation system (12).
9. a kind of cereal crops prepared using the preparation method described in claim 8 are with the fertile user of ecological mineral solution
Method it is characterised in that：
(1) maize planting：
In seedling stage (5-7 leaf), jointing stage, trumpet period is each sprays once, every time every mu fertile with cereal crops ecological mineral solution
100ml sprays to water 60L；
(2) rice cultivation：
Rice seedling bed using method：Respectively apply once in 1 leaf 1 heart stage, 2 leaf 1 heart stage, every square metre of seedbed is ecological with cereal crops every time
Mineral solution fertilizer 1ml, sprinkles to 1000 times of water and pours；
Honda using method：In period of seedling establishment, jointing stage, boot stage, respectively spray once, uses ecological ore deposit molten with cereal crops for every mu every time
Liquid fertilizer 100ml sprays to water 60L；
(3) plant Semen Tritici aestivi：
In tillering stage, jointing stage, pustulation period each spray once, every time every mu with cereal crops ecological mineral solution fertilizer 100ml to water
60L sprays.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111886994A (en) * | 2020-07-08 | 2020-11-06 | 北京大学 | Method for promoting crop growth and reducing insect pests |
| CN114642101A (en) * | 2022-03-16 | 2022-06-21 | 聚宇能科技控股有限公司 | Method for treating compound raw materials for crops |
| CN114773126A (en) * | 2022-05-24 | 2022-07-22 | 张鹏 | Harmless extract capable of improving soil and improving yield and quality of plants as fertilizer |
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| CN1273816A (en) * | 2000-04-28 | 2000-11-22 | 北京金山四博科技开发有限公司 | Activated and concentrated liquid containing minerals and race elements and preparing process thereof |
| CN1335272A (en) * | 2000-07-24 | 2002-02-13 | 北京金山生态动力素制造有限公司 | Ecological mineral solution and its prepn |
| CN101503321A (en) * | 2009-03-12 | 2009-08-12 | 王君信 | Method for preparing microelement in compound fertilizer |
| CN102992841A (en) * | 2012-11-13 | 2013-03-27 | 阮喜英 | Natural microelement and rare earth element-containing plant nutrient solution and preparation method thereof |
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| CN1273816A (en) * | 2000-04-28 | 2000-11-22 | 北京金山四博科技开发有限公司 | Activated and concentrated liquid containing minerals and race elements and preparing process thereof |
| CN1335272A (en) * | 2000-07-24 | 2002-02-13 | 北京金山生态动力素制造有限公司 | Ecological mineral solution and its prepn |
| CN101503321A (en) * | 2009-03-12 | 2009-08-12 | 王君信 | Method for preparing microelement in compound fertilizer |
| CN102992841A (en) * | 2012-11-13 | 2013-03-27 | 阮喜英 | Natural microelement and rare earth element-containing plant nutrient solution and preparation method thereof |
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| CN111886994A (en) * | 2020-07-08 | 2020-11-06 | 北京大学 | Method for promoting crop growth and reducing insect pests |
| CN114642101A (en) * | 2022-03-16 | 2022-06-21 | 聚宇能科技控股有限公司 | Method for treating compound raw materials for crops |
| CN114773126A (en) * | 2022-05-24 | 2022-07-22 | 张鹏 | Harmless extract capable of improving soil and improving yield and quality of plants as fertilizer |
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| CN106396818B (en) | 2019-02-19 |
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