CN106396398A - Ceramic tile with pink-enhancing colored glaze layer and preparation method thereof - Google Patents
Ceramic tile with pink-enhancing colored glaze layer and preparation method thereof Download PDFInfo
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- CN106396398A CN106396398A CN201610797823.0A CN201610797823A CN106396398A CN 106396398 A CN106396398 A CN 106396398A CN 201610797823 A CN201610797823 A CN 201610797823A CN 106396398 A CN106396398 A CN 106396398A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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Abstract
The invention provides a ceramic tile with a pink-enhancing colored glaze layer and a preparation method thereof. The ceramic tile with the pink-enhancing colored glaze layer comprises a blank layer, a printed layer and a pink-enhancing colored glaze layer from the bottom to the top, wherein the pink-enhancing colored glaze layer is formed by spraying pink-enhancing colored glaze; the pink-enhancing colored glaze comprises the following components in parts by mass: 12 parts of high-boron calcium transparent frit, 0.1-10 parts of color-complementing pigment, 1.3 parts of carboxymethyl cellulose, 45 parts of ethylene glycol and 40 parts of water; the high-boron calcium transparent frit comprises the following chemical components in parts by weight of oxides: 6 parts of Na2O, 12 parts of CaO, 7 parts of ZnO, 8 parts of B2O3, 3 parts of Al2O3 and 54 parts of SiO2; the color-complementing pigment is one or a combination of several of known ceramic glaze pigment. Through the preparation method provided by the invention, a high-gray and bright color which cannot be achieved through the conventional ink jetting process can be complemented, and thus the quality of a product is improved.
Description
Technical field
The present invention relates to architectural pottery production field, more particularly, to a kind of have the Ceramic Tiles increasing pink blossom glaze layer and its preparation
Method.
Background technology
Stamp is the Main Means of architectural pottery product incrustation.Stamp can be divided mainly into screen printing, roller printing
With ink-jet printed.Printing technology can make product surface have abundant textured pattern decorative effect, and improving product business is additional
Value.Ink-jet printed at present have become as main flow, but limited to by ink-jet technology and equipment and ink, much colors of higher gray scale
Ink-jet printer is ensureing definition and also can not reach on the premise of steady production at present.
Content of the invention
The present invention is directed to the technical problem propose in prior art, and the present invention provides a kind of pottery having and increasing pink blossom glaze layer
Brick, it includes from the bottom to top：Green body layer, printed layer and increasing pink blossom glaze layer, described increasing pink blossom glaze layer increases pink blossom glaze shape by charity
Become, described increasing pink blossom glaze is calculated with mass fraction, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-
10 parts, carboxymethylcellulose calcium：1.3 part, ethylene glycol：45 parts, water：40 parts；
The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including following component：Na2O:
6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Described complementary color colorant is one or more combination of known pottery glaze stain.
Preferably, in above-mentioned Ceramic Tiles, it is also covered with one layer of protection fancy glaze layer, described protection flower on increasing pink blossom glaze layer
Glaze is clear frit.
Preferably, in above-mentioned Ceramic Tiles, between green body layer and printed layer, it is additionally provided with cover coat.
Preferably, in above-mentioned Ceramic Tiles, it is additionally provided between green body layer and printed layer and brightens layer, brightening layer is by charity
Brighten glaze formation, brighten glaze and calculated with mass fraction, it includes following component：Clear frit：50 parts, zirconium silicate：50
Part, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
The present invention also provides the preparation method of the above-mentioned Ceramic Tiles having and increasing pink blossom glaze layer, and it comprises the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) on brightening layer, decalcomania layer is formed using known stamp mode；
Step 3) charity increasing pink blossom glaze in decalcomania layer, formed and increase pink blossom glaze layer, increase pink blossom glaze in terms of mass fraction
Calculate, including following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, second
Glycol：45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including as follows
Component：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color colorant is known
One or more of ceramic glaze stain combination；
Step 4) enter kiln and fire；
Step 5) base substrate after burning till is polished and edging process, obtain ceramic brick product.
Preferably, in above-mentioned preparation method, in step 3) and step 4) between also include charity protect glaze step, protect
Shield glaze is clear frit.
Preferably, step 1) and step 2) between also include printing and brighten the step that layer is brightened in glaze formation, the increasing of use
The component of white glaze material is calculated with mass fraction, including following component：Clear frit：50 parts, zirconium silicate：50 parts, print cream：65 parts,
Sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
Preferably, in above-mentioned preparation method, printing number of times >=2 time brightening glaze are printed.
Preferably, in above-mentioned preparation method, step 5) firing temperature be 1175～1185 DEG C, firing period is 60～
70min.
Compared to the prior art, the present invention provide method, the high gray scale that existing ink-jetting process cannot be able to be obtained and
Gorgeous color carries out complementary color, lifts product property.
Brief description
Fig. 1 is the sectional view of the Ceramic Tiles that the embodiment of the present invention 1 provides；
Fig. 2 is the sectional view of the Ceramic Tiles that the embodiment of the present invention 2 provides；
Fig. 3 is the sectional view of the Ceramic Tiles that the embodiment of the present invention 3 provides；
Fig. 4 is the sectional view of the Ceramic Tiles that a preferred embodiment of the invention provides；
Fig. 5 is the sectional view of the Ceramic Tiles that the embodiment of the present invention 4 provides；
Fig. 6 is the sectional view of the Ceramic Tiles that the embodiment of the present invention 5 provides.
Description of reference numerals：1- green body layer；2- cover coat；3- brightens layer；4- decalcomania layer；5- increases pink blossom glaze layer；6-
Help color fancy glaze layer；7- protects fancy glaze layer；8- mineral crystal fancy glaze layer.
Specific embodiment
Below by accompanying drawing and some embodiments, this patent to be described.It is to be appreciated that the following drawings is merely illustrative,
Do not draw in strict accordance with ratio, under projecting some technical characteristics, have zooming in or out of local.
Embodiment 1
Referring to the drawings 1, the present embodiment provide a kind of there are the Ceramic Tiles brightening layer, it includes from the bottom to top：Green body layer 1,
Cover coat 2, brighten layer 3 and decalcomania layer 4, brightening layer 3 is to brighten glaze by silk screen printing to be formed, and brightens the thickness of layer 3
Spend for 0.2-1.2mm.
Its preparation method is as follows：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) billet surface by drench glaze by way of cover-coat enamel known to charity, formed cover coat；
Step 3) printed on cover coat using silk screen printing mode and brighten glaze, formed and brighten layer；
Step 4) on brightening layer, printed layer is formed using known stamp mode；
Step 5) enter kiln and fire；
Step 6) base substrate after burning till is polished and edging process, obtain ceramic brick product.
Wherein, the blank formulation in described step 1 is the body recipe of common glazed ceramic brick, provides an example here
The formula of property.For ensureing the flatness of product and ripple glaze deformation, base substrate aluminum content 21% about, whiteness at 35 degree about,
It is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts, Guangxi
White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet ball grinding
Mode, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content is 6
～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%, 100
0～6% below mesh, remaining is -60～+100 mesh.
Cover-coat enamel formula is to ensure product sintering temperature, brick, the common porcelain glazed ceramic brick of effect fancy glaze stereoeffect
Conventional cover-coat enamel, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts, calcined kaolin：
7 parts, aluminum oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, zirconium silicate：20 parts, CNH00058：10～15 parts, sodium humate：
0.2, carboxymethylcellulose calcium:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4～5 hours；Cover-coat enamel
Proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel covers to base substrate,
Reduce the impact to glaze paint for the impurity in base substrate.
Brighten glaze, it is calculated with mass fraction, and it includes following component：Clear frit：50 parts, zirconium silicate：50 parts, print
Cream：65 parts, sodium tripolyphosphate：0.3 part, water：35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
Here zirconium silicate is to brighten Main Ingredients and Appearance, and it is coordinated with the clear frit of speciality, adjusts it using print cream
Printing effect, to reach the effect that base substrate is preferably brightened.Here print cream is the print of commercially available traditional regulation glaze charity effect
Cream, its exemplary group is divided into, and calculates according to the mass fraction：Methyl：1.3 parts, ethylene glycol：35 parts, water：35 parts, preservative：0.001
Part.This brightens glaze, and using clear frit and zirconium silicate as Main Ingredients and Appearance, wherein clear frit is to firing temperature and sintering effect
It is adjusted, zirconium silicate is brightened, combined by both, on the premise of production cost is relatively low, so that the base substrate after burning is had
Higher whiteness, and can be with effective control blank deformation by way of screen printing.
Embodiment 2
Referring to the drawings 2, a kind of Ceramic Tiles, it includes from the bottom to top：Green body layer 1, cover coat 2, brighten layer 3, decalcomania
Layer 4 and increasing pink blossom glaze layer 5.
Here form the increasing pink blossom glaze increasing pink blossom glaze layer 5 with mass fraction calculating, including following component：High boron is calcareous transparent
Frit：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：40 parts；
The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including following component：Na2O:
6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Described complementary color colorant is one or more combination of known pottery glaze stain.
Preparation method, increases the step that charity increases pink blossom glaze on the basis of embodiment 1.
It is to be appreciated that cover coat 2 and brighten layer 3 and can not carry out charity here, the ceramic brick product effect certainly obtaining
Corresponding decline.
The charity thickness increasing pink blossom glaze layer is 0.2-0.8mm.
Embodiment 3
Referring to the drawings 3, a kind of Ceramic Tiles, it includes from the bottom to top：Green body layer 1, cover coat 2, brighten layer 3, decalcomania
Layer 4 and help color fancy glaze layer 6.
Here formed and help the color fancy glaze that helps of color fancy glaze layer 6 to calculate with mass fraction, including following component：Including such as the following group
Point：100 parts of high zinc matter frit, prints 130 parts of cream, 0.3 part of sodium tripolyphosphate, 40 parts of water；
The chemical constituent of described high zinc matter frit is calculated with oxide weight number, including following component：
SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
It is to be appreciated that cover coat 2 and brighten layer 3 and can not carry out charity here, the ceramic brick product effect certainly obtaining
Corresponding decline.It is, of course, also possible in decalcomania layer 4 and helping between color fancy glaze layer 6 and also to include increasing pink blossom glaze layer 5, its structure is such as
Accompanying drawing 4.
The thickness helping color fancy glaze layer is 0.2-0.8mm.
Embodiment 4
Referring to the drawings 5, in the present embodiment, in one layer of protection fancy glaze of billet surface charity, form protection fancy glaze layer 7, this
In protection fancy glaze be known clear frit.
Certainly, need exist for illustrating, protection fancy glaze layer 7 charity is on decalcomania layer 4.
Embodiment 5
Referring to the drawings 6, the present embodiment provides a preferred embodiment of the invention in detail, a kind of Ceramic Tiles, and it is by lower
Structure be：Including green body layer 1, cover coat 2, brighten glaze layer 3, decalcomania layer 4, increase pink blossom glaze layer 5, help color fancy glaze layer 6,
Protection glaze layer 7 and mineral crystal fancy glaze layer 8.
Its preparation technology comprises the steps：
The present invention also provides a kind of production technology of Ceramic Tiles, and it comprises the steps：
Step 1) base raw material through dispensing, ball milling be obtained slurry, then remove iron, sieve, old, powder by spraying after sieve,
Prepared blank；
Step 2) by press, blank is pressed, prepare base substrate；
Step 3) base substrate is put into dry kiln it is dried；
Step 4) carry out charity cover-coat enamel by the way of drenching glaze；
Step 5) glaze is brightened using serigraphy brightened；
Step 6) carry out decorating stamp by ink-jet printing apparatus；
Step 7) color that pink blossom glaze compensates needs reinforcement is increased by serigraphy；
Step 8) help color fancy glaze to help color development by serigraphy；
Step 9) protect glaze layer that ink-jetting pattern is protected by serigraphy；
Step 10) pass through serigraphy mineral crystal fancy glaze；
Step 11) enter kiln and be fired；
Step 12) polishing；
Step 13) edging, quality restriction, packaging obtain final product.
Wherein, the blank formulation in described step 1 is the body recipe of common glazed ceramic brick, provides an example here
The formula of property.For ensureing the flatness of product and ripple glaze deformation, base substrate aluminum content 21% about, whiteness at 35 degree about,
It is as follows that its formula presses mass fraction：Yichuan sand：20 parts, Ganzhou low temperature potassium sodium sand：15 parts, mud is washed in Qianshan：16～20 parts, Guangxi
White mud：8 parts, 3 parts of the white mud in Ji'an, Guangchang potassium sand：31 parts, Fuzhou City's bentonite：1 part, black talc：2～3 parts.Using wet ball grinding
Mode, Ball-milling Time 11～12 hours；After slurry fineness was 250 mesh sieves, tail over as 1.6～2.0 grams；Blank moisture content is 6
～6.5%, its grain composition：More than 20 mesh 0～1.5%, -20～+40 mesh 30～60%, -20～+60 mesh 72～88%, 100
0～6% below mesh, remaining is -60～+100 mesh.
Baking temperature in step 3 is 100～160 DEG C, and arid cycle is 50～70min.Drying is to remove base substrate
In unnecessary moisture content, this guarantee product quality, be typically dried process.
Cover-coat enamel formula in step 4 is to ensure product sintering temperature, brick, the common ceramic glaze of effect fancy glaze stereoeffect
The conventional cover-coat enamel of surface ceramic tile, as follows by mass fraction：Potassium feldspar：25 parts, quartz：15～30 parts, nepheline：15～25 parts, forge
Burn kaolin：7 parts, aluminum oxide：10 parts, wollastonite：4 parts, zinc oxide：1 part, zirconium silicate：20 parts, CNH00058：10～15 parts,
Sodium humate：0.2, carboxymethylcellulose calcium:0.2 part, sodium tripolyphosphate：0.15 part, by the way of wet ball grinding, ball milling 4～5
Hour；Cover-coat enamel proportion 1.75～1.85g/cm3, the flow velocity 30-35 second, after crossing 325 mesh sieves, tail over as 3～4 grams.Cover-coat enamel is to base substrate
Covered, reduced the impact to glaze paint for the impurity in base substrate.
Brighten fancy glaze in described step 5,80 mesh full impregnated nets are printed using silk-screen printing technique, print twice brighten fancy glaze, burn
After one-tenth, in 60-68 degree, Yin Sandao brightens fancy glaze to finished product whiteness, and in 72-78 degree, Yin Sidao brightens fancy glaze to finished product whiteness, and finished product is white
Degree is in 80-83 degree.Brighten fancy glaze as follows by mass fraction：Clear frit:50 parts, zirconium silicate：50 parts, print cream:65 parts, trimerization phosphorus
Sour sodium：0.3 part, water：35 parts.The glaze slip using after ball milling needs to reach following requirement：325 mesh sieves tail over 0.05-0.1%, than
1.55-1.58 gram/cc of weight.The composition of clear frit is following (calculating of oxide mass number):Na2O:5 parts, CaO:9
Part, ZnO:8,Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.Print cream is that common fancy glaze print cream (is chosen as Dow in the present embodiment
The DS4003 of science and technology), it is counted as point as follows according to the mass fraction：Carboxymethylcellulose calcium：1.3 parts, ethylene glycol：35 parts, water：35 parts,
Preservative：0.001 part.
Brighten mode in view of glaze for glazed tile, can by improve base substrate whiteness and raising cover-coat enamel whiteness reach similar
Effect, brightens mode around these three in experimentation and does a lot of work.
The serial example 1 of contrast：Under the experiment condition of fixing step 2,3,4,5,6,7,8,9,10,11,12,13, only to step
Base substrate whiteness in rapid 1 is adjusted, and draws following table：
Base substrate is the basis of product, and its deformation has a direct impact to follow-up finished product glacing flatness and ripple glaze, by adopting
Selected raw material can improve finished product whiteness to a certain extent, but raw material is required too high.Also indivedual enterprises are had to be to reach in industry
To preferable base substrate whiteness, to be realized by slow burning (reducing more than half yield), thus can relax to base substrate composition
Require, the problems such as without excessively considering the deformation producing due to due to base substrate composition, a large amount of blank raw materials using high whiteness,
But because yield is too low, cost input is too big, also do not reach preferable whiteness simultaneously.Adjust the mode of whiteness using body recipe
Sexual valence is poor.
The serial example 2 of contrast：Under the experiment condition of fixing step 1,2,3,5,6,7,8,9,10,11,12,13, only to step
Cover-coat enamel formula in rapid 4 is adjusted, simultaneously remaining component in fixing step 4, only the zirconium silicate to impact whiteness most critical
Number be adjusted, draw following table：
| Zirconium silicate number in cover-coat enamel | Finished product whiteness | Cost | Finished product deforms (mm) |
| 10 | 42 | 0.6 yuan/square metre | Positive and negative 0.1 |
| 20 | 51 | 1.2 yuan/square metre | Positive 0.2 |
| 30 | 56 | 1.8 yuan/square metre | Positive 0.4 |
| 40 | 60 | 2.4 yuan/square metre | Positive 0.55 |
| 60 | 65 | 3.6 yuan/square metre | Positive more than 0.8 |
Because the coefficient of expansion of zirconium silicate is less, if excessive add the deformation that can have a strong impact on product in cover-coat enamel so that producing
Product increasingly encircle with the increase adding zirconium silicate amount, product.Simultaneously in cover-coat enamel after addition is a certain amount of, the impact to whiteness is got over
Come weaker, and the glaze volume of cover-coat enamel is relatively thick, so this scheme is also with high costs in the case of not reaching preferable whiteness,
But comparatively brightened using cover-coat enamel plus zirconium silicate and either will be better than for the lifting of whiteness still becomes present aspect
Increase the input of base substrate whiteness and the effect of generation.
The serial example 3 of contrast：Under the experiment condition of fixing step 1,2,3,4,6,7,8,9,10,11,12,13, only to step
Rapid 5 brighten glaze is adjusted, and draws following table：
By the research of three of the above mode, we can draw, brightens fancy glaze layer come improving product by serigraphy
The technical scheme of whiteness, to consider from the whitening effect that can reach, production stability, product quality and integrated cost hence it is evident that
Better than the technical scheme lifting whiteness in terms of base substrate and cover-coat enamel.Preferable whiteness can be reached moreover it is possible to ensure the deformation of product
Deng in product in, external quality, and Optimum cost.This also exactly the present invention program advantage be located, by change tradition
Improve base substrate whiteness using drenching glaze mode, glaze layer is thicker and is difficult to adjust, the scheme that the present invention provides, there is provided a kind of suitable
Silk screen printing brighten glaze, it is used for ceramic tile production, can be reached different white by way of printing the different numbers of plies
Degree effect, makes process window more wide in range, is issued to best effect in the minimum situation of cost.
Increasing pink blossom glaze in step 7, using silk-screen printing technique, prints the set floral pattern consistent with ink-jetting pattern texture
(depending on meshcount is according to the required depth heightening the color and clear patterns degree, mesh number scope in 80-250 mesh, in this product
Use 160 mesh effect nets.Bigger using meshcount, pattern definition is higher, but the amplitude that can heighten the color is less；
And use silk screen mesh number less, then the definition of pattern and fine and smooth degree are lower, but the effect that heightens the color can be higher) so that
The color that InkJet printing processes do not reach can be compensated by increasing powder craft, thus reaching more abundant, face true to nature
Color effect.In product development and production process, can according to product need adjust silk-screen patterns and colorant proportioning, thus reaching
To the various patterns wanted and color.It is as follows that increasing pink blossom glaze presses mass fraction：The calcareous clear frit of high boron：12 parts, Jin Zong：3.3
Part, reddish brown：0.6 part, parcel is red：3 parts, parcel is yellow：0.6 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts, water：40 parts.
Here the calcareous frit of high boron is calculated with oxide mass number：Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3
Part, SiO2:54 parts.Need exist for illustrating, Jin Zong, reddish brown, parcel is red and parcel Huang is the inorganic pigment of glaze, its select and
Proportioning, to need the color increasing powder as reference, is mated according to actual toning experience.Ink-jet can be realized using increasing pink blossom glaze
The unapproachable gray scale of stamp.
Help color fancy glaze in step 8,140 mesh full impregnated nets are printed using silk-screen printing technique, for ensureing fancy glaze uniform fold, no
Can cause because of the thickness difference helping color fancy glaze helps aberration different thus producing two tone colour, and the full impregnated net using print twice 140 mesh to enter
Row is complementary.Help color fancy glaze as follows by mass fraction：High zinc matter frit:100 parts, DS4003 (the print cream of Dow):130 parts, trimerization：
0.3 part, water：40 parts.325 mesh sieves tail over as 0.1-0.2%, and proportion is 1.32-1.35 gram/cc.High zinc matter frit with
Chemical oxide mass fraction calculates：SiO2:53 parts, ZnO:21 parts, K2O:4 parts, Al2O3:7 parts, MgO:3 parts, CaO:3.5 part.
Under the experiment condition of fixing step 1,2,3,4,5,6,7,9,10,11,12,13, only step 8 is adjusted,
Show that print helps color fancy glaze and not printing to help color fancy glaze to contrast：Coloring intensity lifting more than 10%, so can save the ink of costliness
And colorant, advantageously reduce production cost.
Protection glaze layer in described step 9, prints 80 mesh full impregnated nets using silk-screen printing technique or carries veined effect net,
Textured effect net would generally be nested flower with the inkjet printing pattern of the step 6 of as described before, and according to protection glaze thickness
Thin needs select print 1-3 road silk screen fancy glaze, for ensureing the needs of later stage cold working polishing, generally select using print 3 road silk screens
Fancy glaze, by print clear frit or complete throw glaze and other effects glaze so that ink-jetting pattern be difficult to be worn during routine use or
Be conducive to this series of products is carried out with the cold work in later stage.It is as follows that protection glaze fancy glaze presses mass fraction：DJY801-G2 is (big
The low-temperature transparent protection glaze of border science and technology):70 parts, DJY801-121 (the temperature resistant transparent protection glaze of big border science and technology):30 parts, DS4003
(the print cream of Dow):47 parts, sodium tripolyphosphate：0.3 part, water：25 parts.250 mesh sieves tail over 0.7-1.0%, proportion 1.60-1.63
Gram/cc.This protection glaze layer can also be other clear frits or entirely throw glaze.
DJY801-G2 composition is calculated as follows by the mass fraction of oxide：SiO2:67 parts, Al2O3:14 parts, CaO:12 parts,
B2O3:5 parts.DJY801-121 composition is calculated as follows by oxide mass number：SiO2:51 parts, Al2O3:15,K2O part:2,
Na2O:5 parts, MgO:3.2 parts, CaO:10 parts, B2O3:8 parts.
Mineral crystal fancy glaze in step 10, prints 60 mesh effect nets, this effect net pattern texture using silk-screen printing technique
It is mutually matched (set flower) with the inkjet printing pattern of as described before step 6, in the place printing to mineral crystal fancy glaze, mineral crystal
Fancy glaze can be merged with following fancy glaze, and (high temperature viscosity of mineral crystal fancy glaze is relatively low, and metal oxide content is higher and molten
Also ratio is relatively low to melt temperature, can melt and arrange following glaze layer during burning till) so that this local pattern sink (under
Sunken effect can ensure that the pattern of mineral crystal, effect will not be disposed when product is carried out with cold working polishing), produce simultaneously
Raw mineral crystal effect.It is as follows that mineral crystal fancy glaze formula presses mass fraction：100 parts of mineral crystal dry granular, clear frit 0-50 part
(needing to change according to calcining system), print cream (the print cream of Dow) 60-80 (reach need according to formula change adjustment usage amount
The fancy glaze proportion wanted) part, 0.2 part of carboxymethylcellulose calcium, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70
～80%, remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal
Fancy glaze thickeies effect net by 60 mesh together and is printed.Mineral crystal dry granular is as follows with chemical oxide composition：SiO2:8 parts,
Al2O3:3 parts, B2O3:20 parts, Fe2O3：9 parts, MnO:46 parts, TiO2:8 parts.
Clear frit is calculated with oxide component, and its chemical constituent is as follows：SiO2:55 parts, Al2O3:14 parts, K2O:2 parts,
Na2O:6 parts, MgO:2 parts, CaO:10 parts, B2O3:8 parts.
Firing temperature in step 11 is 1175～1185 DEG C, and firing period is 60～70min.
Polishing edging is the common process of Production of Ceramics, and correspondence carries out selecting here.
Embodiment 6
In the present embodiment, give this product with negative ion health function.
Anion is a kind of negatively charged gas ion of in the air.Various gas componants in air are not exclusively to divide
Submode exists, and a portion is existed with the free state of ion.Wherein electronegative molecule or particulate (be commonly called as bearing from
Son) human body synthesis and vitamin storage can not only be facilitated, the physiological activity of strengthening and human activin, to human body and other biological
Vital movement has highly important impact, and therefore it is otherwise known as " air vitamin ".
In the prior art, be typically employed in composition of raw materials and add a certain proportion of tourmaline powder, using when temperature and
When pressure changes, electric heating difference and voltage difference can be caused between tourmaline crystal, this electrostatic potential difference can be up to 1.0 ×
106EV, this energy be enough to make air ionize, and is converted into negative aeroion.But the main component because of tourmaline powder is
The aluminium that is characterized with boracic, sodium, iron, the silicate material of lithium circulus, a large amount of introducings in base substrate can cause blank deformation,
And introduce in glaze, also the characteristic of glaze can be produced with certain impact, especially for marzacotto, thus while there being correlation
Functional product occurs, but overall performance not up to optimum.
Pin in this regard, the present embodiment provide corresponding solution, because tourmaline powder need and air contact could produce right
The effect answered.Therefore, in the present embodiment, the component of mineral crystal fancy glaze is improved, introduce tourmaline powder wherein
With improvement component, it is allowed to both there is abundant brilliant flower decorative effect, with more negative ion health function.
Concrete scheme is as follows：
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, tourmaline powder
1-3 part, light rare earth oxide 0.01-0.05 part, 20 parts of clear frit (corresponding firing temperature is suitably selected), print cream
(the print cream of Dow) 60-80 (reaching the fancy glaze proportion of needs according to formula change adjustment usage amount) part, carboxymethylcellulose calcium
0.2 part, water 25-40 part, the particle diameter of mineral crystal dry granular：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze ratio
Weigh 1.6～1.7g/cm3, after crossing 320 mesh sieves, tail over as 0.1 gram.Mineral crystal fancy glaze thickeies effect net by 60 mesh together and enters
Row printing.
The use number of clear frit can be 0-50 part, and it uses root in order to adjust firing temperature and effect, marzacotto
Suitably adjusted according to firing temperature and service condition.
This programme adds a small amount of tourmaline powder and micro light rare earth oxide in mineral crystal fancy glaze, so that
Its electrostatic potential difference lifting, can be issued to higher anion releasing effect in less consumption.
The process being provided using such as embodiment 3, prepared Ceramic Tiles, under 25 degrees Celsius, relative humidity 60%
Under the conditions of test, anion-generating capacity be 1800-2000/cm3.Because producing anion needs in the larger ring of relative humidity
Border, therefore such brick is suitable for using in the larger space of the humidity such as bathroom.
Certainly, tourmaline can also be replaced using Strange ice stone, opal or rare talent's stone here.Because generation provided above
The material of anion has considerable influence to the firing temperature of base substrate and blank deformation, and in the present invention, the mineral being used are brilliant
Body fancy glaze contains substantial amounts of metallic element, and the glaze that it can arrange below in sintering forms depression, so both can report barrier
The anion effect layer being formed will not be skimmed when follow-up rubbing down is processed, and meanwhile, this being applied in combination also makes Ceramic Tiles produce
The anti-pollution characteristic of product and finished product deformation all control in less scope, essentially identical with un-added effect.
And adopt traditional the tradition anion powder such as tourmaline is used as added material, add in conventional glaze,
The addition reaching the negative ion concentration of the present invention is needed to need to increase 1.5-2 times.So anion powder burns till to glaze
Effect has considerable influence, and then affects anti-pollution characteristic and the deformation of finished product.
Embodiment 7
In the present embodiment, give this product antibacterial functions, in traditional handicraft, product surface material introduces antibacterial
Agent is conventional selection.The antiseptics such as example common silver, copper, zinc.But because product needed passes through high temperature sintering, this can be to product
Antibacterial effect produce deleterious effect, in this regard, people select using above antiseptic phosphate.But be given with prior art
Scheme from the point of view of, all cannot solve the problems, such as the deformation of products after there is good antibacterial effect very well.
Pin, in this regard, the present invention introduces a certain amount of antibacterial components in above mineral crystal fancy glaze, is spent using mineral crystal
The a large amount of metallic elements containing in glaze, glaze can melt at a lower temperature, concave downward, it is to avoid follow-up rubbing down is to antibacterial
The destruction of layer, the metallic element simultaneously containing in mineral crystal fancy glaze is also so that the antibacterial effect of its antiseptic is enhanced.
It is as follows that the present embodiment provides mineral crystal fancy glaze formula to press mass fraction：100 parts of mineral crystal dry granular, antiseptic
1.5 parts, 10 parts of clear frit (corresponding firing temperature suitably selected), print cream (the print cream of Dow) 60-80 (according to formula
Change adjustment usage amount is reaching the fancy glaze proportion of needs) part, 0.2 part of carboxymethylcellulose calcium, water 25-40 part, mineral crystal does
The particle diameter of grain：80～120 mesh account for 70～80%, and remainder is by 120 mesh, fancy glaze proportion 1.6～1.7g/cm3, cross 320 mesh sieves
Afterwards, tail over as 0.1 gram.
Antiseptic is the mixture of silver orthophosphate and basic zirconium phosphate, and the mass percent of silver orthophosphate is 85-95%, balance of phosphoric acid
Zirconium.In high temperature sintering, silver orthophosphate and basic zirconium phosphate are combined, and silver ion will go in the layer structure of basic zirconium phosphate, part
Bedded zirconium phosphate crystal defect is repaired, part replaces zirconium ion, thus defining the mixed crystal knot of silver orthophosphate and basic zirconium phosphate
Structure, has low cost, the feature of durable antibacterial effect, and it has no adverse effects to the colour generation of color development metal oxide.
Embodiment 8
In the present embodiment, essentially identical with embodiment 7 preparation technology, institute's difference is that antiseptic is chosen as aoxidizing
Silver, the number that it accounts in mineral crystal fancy glaze is 5 parts.After configuring in proportion, by this mineral crystal with antibacterial effect
Fancy glaze charity is carrying out the billet surface of printing ornament, tests its effect after sintering, has preferable killing effect to bacterium, but
Its colour generation has a small amount of deviation with default.
Embodiment 9
In the present embodiment, essentially identical with embodiment 7 preparation technology, institute's difference is that antiseptic is chosen as aoxidizing
Copper, the number that it accounts in mineral crystal fancy glaze is 1.5 parts.After configuring in proportion, by this mineral crystalline substance with antibacterial effect
Body fancy glaze charity, in the billet surface carrying out printing ornament, is tested its effect, and it is compared with embodiment 5 after sintering, colour generation
Partially deep, antibacterial effect is slightly poor.
Embodiment 10
In the present embodiment, essentially identical with embodiment 7 preparation technology, institute's difference is that antiseptic is chosen as phosphoric acid
Silver, and it is not added with basic zirconium phosphate.After configuring in proportion, this mineral crystal fancy glaze charity with antibacterial effect is being carried out stamp
The billet surface of decoration, tests its effect, and it is compared with embodiment 5 after sintering, colour generation slightly deviation, the holding of antibacterial effect
Continuous property is slightly poor.
The above-mentioned description to embodiment is to be understood that and use invention for ease of those skilled in the art.
Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein general
Principle is applied in other embodiment without through performing creative labour.Therefore, the invention is not restricted to above-described embodiment, ability
, according to the announcement of the present invention, the improvement made without departing from scope and modification all should be the present invention's for field technique personnel
Within protection domain.
Claims (8)
1. a kind of have the Ceramic Tiles increasing pink blossom glaze layer, and it includes from the bottom to top：Green body layer, printed layer and increasing pink blossom glaze layer, its
It is characterised by, described increasing pink blossom glaze layer increases pink blossom glaze by charity and formed, described increasing pink blossom glaze is calculated with mass fraction, including such as
Lower component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：45 parts,
Water：40 parts；
The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including following component：Na2O:6 parts,
CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；
Described complementary color colorant is one or more combination of known pottery glaze stain.
2. a kind of as claimed in claim 1 have the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that in described increasing pink blossom glaze layer
It is also covered with one layer of protection fancy glaze layer, described protection fancy glaze is clear frit.
3. a kind of as claimed in claim 1 have the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that described green body layer and stamp
It is provided with cover coat between layer.
4. a kind of as claimed in claim 1 have the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that described green body layer and stamp
It is additionally provided between layer and brightens layer, the described layer that brightens is to brighten glaze by charity to be formed, and the described glaze that brightens is with mass fraction
Calculate, it includes following component：Clear frit：50 parts, zirconium silicate：50 parts, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：
35 parts；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
5. a kind of preparation method with the Ceramic Tiles increasing pink blossom glaze layer, it comprises the steps：
Step 1) make adobe from known ceramic body powder punching press；
Step 2) on brightening layer, decalcomania layer is formed using known stamp mode；
Step 3) charity increasing pink blossom glaze in decalcomania layer, formed and increase pink blossom glaze layer, increase pink blossom glaze and calculated with mass fraction, wrap
Include following component：The calcareous clear frit of high boron：12 parts, complementary color colorant 0.1-10 part, carboxymethylcellulose calcium：1.3 parts, ethylene glycol：
45 parts, water：40 parts；The chemical constituent of the calcareous clear frit of described high boron is calculated with oxide weight number, including following component：
Na2O:6 parts, CaO:12 parts, ZnO:7 parts, B2O3:8 parts, Al2O3:3 parts, SiO2:54 parts；Described complementary color colorant is known pottery
One or more combination of glaze stain；
Step 4) enter kiln and fire；
Step 5) base substrate after burning till is polished and edging process, obtain ceramic brick product.
6. as claimed in claim 5 a kind of preparation method with the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that described step
Rapid 3) and step 4) between also include charity protect glaze step, described protection glaze be clear frit.
7. as claimed in claim 5 a kind of preparation method with the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that described step
Rapid 1) and step 2) between include print brighten glaze formation brighten layer step, the described component brightening glaze is with mass fraction
Calculate, including following component：Clear frit：50 parts, zirconium silicate：50 parts, print cream：65 parts, sodium tripolyphosphate：0.3 part, water：35
Part；
The chemical constituent of described clear frit is calculated with oxide weight number, including following component：
Na2O:5 parts, CaO:9 parts, ZnO:8 parts, Al2O3:8 parts, B2O3:2 parts, SiO2:60 parts.
8. as claimed in claim 7 a kind of preparation method with the Ceramic Tiles increasing pink blossom glaze layer it is characterised in that described print
System brightens printing number of times >=2 time of glaze.
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| CN111807701A (en) * | 2020-07-08 | 2020-10-23 | 佛山市东鹏陶瓷有限公司 | Preparation method of high-strength ceramic glazed tile and prepared high-strength ceramic glazed tile |
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