CN101157575A - Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof - Google Patents

Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof Download PDF

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Publication number
CN101157575A
CN101157575A CNA2007100303714A CN200710030371A CN101157575A CN 101157575 A CN101157575 A CN 101157575A CN A2007100303714 A CNA2007100303714 A CN A2007100303714A CN 200710030371 A CN200710030371 A CN 200710030371A CN 101157575 A CN101157575 A CN 101157575A
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China
Prior art keywords
glaze
preparation
brick
ceramic
grail
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Pending
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CNA2007100303714A
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Chinese (zh)
Inventor
麦文英
汪加武
王礼
赵武臣
叶建明
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GUANGDONG OVERLAND CERAMICS CO Ltd
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GUANGDONG OVERLAND CERAMICS CO Ltd
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Priority to CNA2007100303714A priority Critical patent/CN101157575A/en
Publication of CN101157575A publication Critical patent/CN101157575A/en
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Abstract

The invention discloses a decoration level gravel hardening vitrified glaze tile comprising a ceramic tile substrate and primary coat glaze on the surface of the substrate; the invention is characterized in that the surface of the primary coat glaze is also provided with a surface hardspan prepared by dry grain cloth glaze. The invention also disclosed a preparation method which combines the techniques for the preparation of ceramic tile, polished tile and ceramic glazing tile, and carries the surface point polishing on the surface level gravel ceramic decoration glaze tile. The invention integrates the physical and chemical performance and the antifouling effect of the current vitrified polishing tile, thereby leading to the beautiful decoration effect and widening the scope of decoration applications.

Description

Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof
Technical field
The present invention relates to the ceramic production device field, more particularly relate to have the porcelain decorations glazed brick of better decorative effect.
Background technology
The ceramic glaze face brick is subjected to human consumer's favor always because its low water absorption, high strength, surface gloss are high, and its chemical ingredients, crystalline texture are all similar to lithotome, its surface decoration all is to be subject matter with imitative stone material all the time, its imitative stone level further improves in recent years, effect is become better and better, and contrasts other wall floor tile, has unrivaled excellent hot on material, yet it has the defective of raw materials cost height, high energy consumption, high pollution again.The half mute light brick of throwing is also arranged, as number of patent application be 200510035090.9, the applying date is 2005.06.13, name is called a kind of production technique of dummy porcelain polished tile and the patent application of polishing and grinding plant thereof, it discloses a kind of production technique and polissoir that matches with technology and grinding plant of dummy porcelain polished tile, in this technological process of production, after polishing process is arranged on drying process, before the firing process, have additional grinding step after firing process, described dry body polissoir and grinding plant adopt planetary structure.The polished brick in porcelain character surface of patent application preparation of the present invention shows as mute light or unglazed, though feel exquisiteness, can present adobe deep layer cloth decoration texture and adopt semipolish, but also can only show above-mentioned decorative effect, its material cost and production cost are still higher, therefore energy consumption is bigger, and not break away from the polished tile anti-fouling effect all the time bad for present ceramic tile production, and the not good enough defective of ornamental brick physicochemical property.
Summary of the invention
Purpose of the present invention is exactly that provide for the deficiency that solves prior art a kind of merged present polished brick in porcelain character physicochemical property and the ceramic glaze face brick is decorated anti-fouling effect characteristics, decorative effect perfection, the wider ornament layer gravel porcelain decorations glazed brick of decorative applications;
Another object of the present invention provides a kind of preparation method that can effectively energy-conservation, also effectively reduce raw materials cost and reduce the above-mentioned decoration layer grail vulcanized ceramic face glazing brick of processing waste.
The present invention adopts following technical solution to realize above-mentioned purpose: a kind of decoration layer grail vulcanized ceramic face glazing brick, it comprises ceramic tile basic unit and is positioned at the ground-coat enamel fancy glaze of substrate surface, it is characterized in that, also be provided with the surperficial sandy gravel stratum that is prepared from by dry granular cloth glaze on the surface of ground-coat enamel fancy glaze.
Decoration layer grail vulcanized ceramic face glazing brick of the present invention is to be prepared from by following processing method, and it is that order ceramic brick polishing brick and ceramic glaze face brick preparation technology are combined, and concrete technology is as follows:
A, blank forming, raw material is made material through the slurrying of ball ball milling, old, deironing, spraying and is made powder, after again through deironing, old after compression moulding;
B, glaze are decorated, and base substrate carries out glazing and decorates after drying;
C, the preparation of ground-coat enamel fancy glaze, through ball milling enamel frit makeing, deironing is stand-by with the glaze formula raw material;
D, roller printing will be blown powder through the base substrate in the b step, blow water and the ground-coat enamel fancy glaze that applies in the c step carries out roller printing;
The preparation of e, dry granular is made material with dry granular wine made of broomcorn millet side raw material after glaze slip sieves deironing, sieving through curing, to form qualified dry granular standby;
F, the dry granular in the e step is carried out the cloth glaze, burn till and form upper layer gravel;
G, the decorations of the upper layer gravel porcelain after burning till glazed brick carry out the surface point polished finish, get product after deburring.
As further specifying of such scheme, the dry granular composition of raw materials in the described e step is mainly based on the porcelain material, and adds wear-resisting high-temperature fusion raw material such as brown corundum, and also adding in the porcelain material has the strong albite mineral of fluxibility.
Upper layer gravel point polished finish in the described g step is to adopt the different processing of luminosity is carried out on the different surface of convex-concave, and sunk part adopts the polish-brush polishing, and the place that protrudes adopts high order to count the abrading block polishing.
Include useless ceramic tile, polishing slag in the described blank raw material.
The beneficial effect that the present invention adopts above-mentioned technical solution to reach is:
1, traditional polished tile is because of its process characteristic, need to consume a large amount of electric energy in the polishing process, and gravel technique for grinding of the present invention only needs 1/3rd of traditional polished tile product, has saved electric energy greatly, and the space of gravel hardening treatment of the present invention hold facility also has only traditional 1/3 simultaneously.
2, the waste material that produced of gravel of the present invention sclerosis polishing is less than 5% of traditional polished tile; Substantially Sewage treatment systems that need not be special is handled waste material, has both protected environment, has saved cost again; Its powdered frit loss simultaneously is few, can save 20% powdered frit.
3, used raw material can adopt the quality raw material much lower than polished tile in the product blank glaze formula of the present invention, and as adopting polishing slag in the polished tile production process etc., its raw materials cost has only 1/2~1/3 price of polished tile.
4, the present invention has adopted the gravel treatment technology that ornament layer is handled, and has improved the hardness and the wear resistance of brick face ornament layer, reaches the level of porcelain brick; And antifouling property has improved use properties greatly also than porcelain brick height;
5, the present invention is with glaze stamp and semipolish perfect adaptation, and experiment shows that its decorative effect has inferior light exquisiteness, flicker trickling, the gentle warm natural impression of tone, and the decoration gradation sense is strong, and decorative effect is abundant; The decoration technology characteristics of polished brick in porcelain character and ceramic glaze face brick have been merged in the present invention, make both decorative effects ideally unified, have improved the sense of reality and the class of product, and decorative applications is also more extensive.
Description of drawings
Fig. 1 is preparation technology's block diagram of the present invention;
Embodiment
As shown in Figure 1, decoration layer grail vulcanized ceramic face glazing brick of the present invention mainly is to form by following prepared, and it is order ceramic brick polishing brick and ceramic glaze face brick preparation technology are combined and to make, and concrete technology is as follows:
A, blank forming, at first carry out raw material by the prescription weighing, after the deironing of sieving that deironing, mud are old, the mud homogenizing is sieved of the slurrying of ball ball milling, mud, change the transfer jar over to, make material through spraying and make powder, after again through screening out the old back compression moulding of putting in storage of iron, powder; Be added with useless ceramic tile, polishing slag in the described blank raw material.
B, glaze are decorated, and base substrate carries out glazing and decorates after drying;
C, the preparation of ground-coat enamel fancy glaze, through ball milling enamel frit makeing, the glaze slip deironing is stand-by with the glaze formula raw material; The preparation of this ground-coat enamel fancy glaze is consistent with prior art, is not described further;
D, roller printing will be blown powder through the base substrate in the b step, blow water and the ground-coat enamel fancy glaze that applies in the c step carries out roller printing;
E, dry granular preparation, dry granular wine made of broomcorn millet side raw material after sieving deironing, is made glaze slip material, sieving through curing, to form qualified dry granular standby, wherein the size of dry granular is controlled at the 20-40 order and accounts for 70%, the 40-60 order accounts for 20%, for less than 20 orders and generally will not adopting greater than 60 purpose dry granulars, the size of the dry granular in this scope can make the brick body produce preferably decorative effect and be rich in gradation sense; The dry granular composition of raw materials is mainly based on the porcelain material, mainly be to improve particle wear resisting property and low-temperature sintering, for improving the transparency and the texture of dry granular, also adding has wear-resisting high-temperature fusion raw material such as brown corundum etc., and also adding in the porcelain material has the strong mineral such as albite of fluxibility.
F, the dry granular in the e step is carried out the cloth glaze, burn till and form upper layer gravel;
G, the decorations of the upper layer gravel porcelain after burning till glazed brick carry out the surface point polished finish, get product after deburring.The point polished finish is to adopt carrying out the different processing of luminosity in the different surface of convex-concave, sunk part adopts the polish-brush polishing, the place that protrudes adopts high order to count the abrading block polishing, adopt the point of this mode to polish the antifouling property that had both kept ornamental brick, have the good physical behavior of polished tile simultaneously again.
The present invention calcines granulation after adopting spraying drying again, a large amount of organic matters and crystal water have been discharged, make the dry granular compaction rate higher, significantly reduce the discharge of gas in the particle when burning till of product high temperature, in case in post-treatment grinding process split shed air holes, the decoration layer grail vulcanized ceramic face glazing brick of the processing that forms through above-mentioned prepared has decorative effect preferably, has preferable physicochemical property simultaneously, adopts porcelain decorations glazed brick of the present invention its performance index such as following table after testing:
Performance project Unit The national standard requirement Detected result
Water-intake rate Mean value≤0.5 0.10;.0.8-0.14
Wear resistance Change Report wear resistance rank and revolution 3 grades; 750 change
Stain resistance Be not less than 3 grades 5 grades
Strength at break N As thickness 〉=7.5mm, 〉=1300 2368.8
Modulus of rupture value MPa Mean value 〉=35 44.4;44.3-6.1
The external radiation exposure index Category-A finishing material I Ra≤1.3 0.52
The internal radiation index Category-A finishing material I r≤ little by 1.3 0.66
Smooth finish ≥55

Claims (7)

1. decoration layer grail vulcanized ceramic face glazing brick, it comprises ceramic tile basic unit and is positioned at the ground-coat enamel fancy glaze of substrate surface, it is characterized in that, also is provided with the surperficial sandy gravel stratum that is prepared from by dry granular cloth glaze on the surface of ground-coat enamel fancy glaze.
2. decoration layer grail vulcanized ceramic face glazing brick according to claim 1 is characterized in that, the size of the dry granular in the described surperficial sandy gravel stratum accounts for 70% for the 20-40 order, and the 40-60 order accounts for 20%.
3. the preparation method of claim 1 or 2 described decoration layer grail vulcanized ceramic face glazing bricks, it is characterized in that: it is that order ceramic brick polishing brick and ceramic glaze face brick preparation technology are combined, concrete technology is as follows:
A, blank forming, raw material is made material through the slurrying of ball ball milling, old, deironing, spraying and is made powder, after again through deironing, old after compression moulding;
B, glaze are decorated, and base substrate carries out glazing and decorates after drying;
C, the preparation of ground-coat enamel fancy glaze, through ball milling enamel frit makeing, deironing is stand-by with the glaze formula raw material;
D, roller printing will be blown powder through the base substrate in the b step, blow water and the ground-coat enamel fancy glaze that applies in the c step carries out roller printing;
The preparation of e, dry granular is made material with dry granular wine made of broomcorn millet side raw material after glaze slip sieves deironing, sieving through curing, to form qualified dry granular standby;
F, the dry granular in the e step is carried out the cloth glaze, burn till and form upper layer gravel;
G, the decorations of the upper layer gravel porcelain after burning till glazed brick carry out the surface point polished finish, get product after deburring.
4. the preparation method of decoration layer grail vulcanized ceramic face glazing brick according to claim 3, it is characterized in that, dry granular composition of raw materials in the described e step is mainly based on the porcelain material, and add wear-resisting high-temperature fusion raw material, in the porcelain material, also add the strong albite mineral of fluxibility are arranged, the size of described dry granular accounts for 70% for the 20-40 order, and the 40-60 order accounts for 20%.
5. the preparation method of decoration layer grail vulcanized ceramic face glazing brick according to claim 4 is characterized in that, described wear-resisting high-temperature fusion raw material adopts brown corundum.
6. the preparation method of decoration layer grail vulcanized ceramic face glazing brick according to claim 3, it is characterized in that, upper layer gravel point polished finish in the described g step is to adopt the different processing of luminosity is carried out on the different surface of convex-concave, sunk part adopts the polish-brush polishing, and the place that protrudes adopts high order to count the abrading block polishing.
7. the preparation method of decoration layer grail vulcanized ceramic face glazing brick according to claim 3 is characterized in that, includes useless ceramic tile, polishing slag in the described blank raw material.
CNA2007100303714A 2007-09-21 2007-09-21 Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof Pending CN101157575A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CNA2007100303714A CN101157575A (en) 2007-09-21 2007-09-21 Decoration layer grail vulcanized ceramic face glazing brick and preparation method thereof

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101905965B (en) * 2009-06-03 2012-07-25 佛山市简一陶瓷有限公司 Ceramic brick manufacturing process with concave-convex polished in-glaze decoration
CN102635214A (en) * 2012-05-10 2012-08-15 信益陶瓷(中国)有限公司 Universal ceramic tile used for wall surface and ground
CN102661451A (en) * 2012-05-05 2012-09-12 漳州日盛建筑陶瓷有限公司 Foaming ceramic thermal insulation pipe and preparation method thereof
CN102794950A (en) * 2012-07-21 2012-11-28 佛山瑭虹釉料科技有限公司 Once-fired color microcrystal brick and production process thereof
CN103291046A (en) * 2013-06-07 2013-09-11 张玉伟 Floor tile processing technology
CN103435369A (en) * 2013-08-12 2013-12-11 广东家美陶瓷有限公司 Method for manufacturing wear-resistant antiskid dry-particle ceramic tile
CN104150872A (en) * 2014-08-06 2014-11-19 苏州科德溯源仪器有限公司 Grapheme enhanced ceramic tile
CN105777089A (en) * 2016-04-01 2016-07-20 蒙娜丽莎集团股份有限公司 Light-permeable tile and preparation method thereof
CN106396398A (en) * 2016-08-31 2017-02-15 广东金意陶陶瓷有限公司 Ceramic tile with pink-enhancing colored glaze layer and preparation method thereof
CN106431502A (en) * 2016-09-03 2017-02-22 佛山市高明贝斯特陶瓷有限公司 Production process of tile with natural jade texture
CN109053226A (en) * 2018-08-27 2018-12-21 河源市东源鹰牌陶瓷有限公司 The method for preparing dumb light dry granular glazed tile
CN109849163A (en) * 2019-03-28 2019-06-07 江西和美陶瓷有限公司 The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101905965B (en) * 2009-06-03 2012-07-25 佛山市简一陶瓷有限公司 Ceramic brick manufacturing process with concave-convex polished in-glaze decoration
CN102661451A (en) * 2012-05-05 2012-09-12 漳州日盛建筑陶瓷有限公司 Foaming ceramic thermal insulation pipe and preparation method thereof
CN102635214A (en) * 2012-05-10 2012-08-15 信益陶瓷(中国)有限公司 Universal ceramic tile used for wall surface and ground
CN102794950A (en) * 2012-07-21 2012-11-28 佛山瑭虹釉料科技有限公司 Once-fired color microcrystal brick and production process thereof
CN102794950B (en) * 2012-07-21 2015-06-03 佛山瑭虹釉料科技有限公司 Once-fired color microcrystal brick and production process thereof
CN103291046B (en) * 2013-06-07 2015-07-01 张玉伟 Floor tile processing technology
CN103291046A (en) * 2013-06-07 2013-09-11 张玉伟 Floor tile processing technology
CN103435369A (en) * 2013-08-12 2013-12-11 广东家美陶瓷有限公司 Method for manufacturing wear-resistant antiskid dry-particle ceramic tile
CN104150872A (en) * 2014-08-06 2014-11-19 苏州科德溯源仪器有限公司 Grapheme enhanced ceramic tile
CN105777089A (en) * 2016-04-01 2016-07-20 蒙娜丽莎集团股份有限公司 Light-permeable tile and preparation method thereof
CN105777089B (en) * 2016-04-01 2018-08-28 蒙娜丽莎集团股份有限公司 A kind of transparent brick and preparation method thereof
CN106396398A (en) * 2016-08-31 2017-02-15 广东金意陶陶瓷有限公司 Ceramic tile with pink-enhancing colored glaze layer and preparation method thereof
CN106431502A (en) * 2016-09-03 2017-02-22 佛山市高明贝斯特陶瓷有限公司 Production process of tile with natural jade texture
CN109053226A (en) * 2018-08-27 2018-12-21 河源市东源鹰牌陶瓷有限公司 The method for preparing dumb light dry granular glazed tile
CN109849163A (en) * 2019-03-28 2019-06-07 江西和美陶瓷有限公司 The decorations brick of stereoscopic glaze made from leftover bits and pieces of material and its manufacturing method are scraped in a kind of utilization

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Open date: 20080409