CN106367747B - The antique coloring method of bronze ware - Google Patents
The antique coloring method of bronze ware Download PDFInfo
- Publication number
- CN106367747B CN106367747B CN201610786128.4A CN201610786128A CN106367747B CN 106367747 B CN106367747 B CN 106367747B CN 201610786128 A CN201610786128 A CN 201610786128A CN 106367747 B CN106367747 B CN 106367747B
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- China
- Prior art keywords
- bronze
- wooden case
- coloring
- wooden
- ware
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/52—Treatment of copper or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of methods of bronze ware antique coloring, characterized by comprising the following steps: step (1): coloring pre-treatment: the mixture that the diamond dust and activating solution that are 34%~60% with weight percent are formed sprays the bronze surface after polishing, refine；Step (2): the bronze ware after progress pre-treatment is placed in bottomless wooden case, and the mixture that the copper sulphate, ammonium chloride and loess that weight percent is 0.1:1:100~150 are formed is poured into wooden case and extremely buries bronze copper body, pours supernatant water infiltration；Step (3): sternly forming closed environment for wooden case case lid with plastic cloth and wooden cover, controls oxygen content in wooden case and takes out after saving at least 10 days to 0.1~0.2mg/L.This method can make bronze surface form bronze-colored embroidery layer, and vicissitudes sense of the remote past is presented.
Description
Technical field
The present invention relates to bronze surface treatment process technical field, more particularly, to a kind of the modelled after an antique of bronze ware
Color method.
Background technique
Bronze ware has the history of 4,000 sexcentenaries in China, and unearthed has weapons, sacrificial vessel, drinking vessel etc..With increasingly
The excavation of more bronze wares is unearthed, and bronze ware is increasingly liked by people, since unearthed bronze ware belongs to history relic, by
State guarantee can not be put on display in common museum or collect as collectibles, be only fabricated to by imitated method imitated
Product are put on display and collection, and in order to meet this demand, many enterprises start the imitated bronze ware product of production both at home and abroad, but existing at present
Some surface antique-imitation technologies cannot still reproduce the romantic charm of ancient culture well, cannot better meet the demand of people.
Summary of the invention
Aiming at the problems existing in the prior art, the purpose of the present invention is to provide a kind of antique coloring sides of bronze ware
Method, this method can make bronze surface form bronze-colored embroidery layer, and vicissitudes sense of the remote past is presented.
The technical scheme adopted by the invention is as follows: a kind of method of bronze ware antique coloring, comprising the following steps:
Step (1): coloring pre-treatment: the mixing that the diamond dust and activating solution for being 34%~60% with weight percent are formed
Object sprays the bronze surface after polishing, refine；
Step (2): the bronze ware after progress pre-treatment is placed in bottomless wooden case, weight ratio is poured into wooden case is
The mixture that copper sulphate, ammonium chloride and the loess of 0.1:1:100~150 are formed pours supernatant water infiltration to bronze copper body is buried；
Step (3): sternly forming closed environment for wooden case case lid with plastic cloth and wooden cover, controls in wooden case oxygen content extremely
0.1~0.2mg/L takes out after saving at least 10 days.
The invention has the benefit that the antique coloring method of bronze ware of the invention can make bronze surface form bronze
The embroidery layer of color, lovely luster is abundant, vicissitudes sense of the remote past is presented, and bronze surface is smooth, does not fade, side of the invention
Method is easy to operate, at low cost, market application is wide.
Specific embodiment
The present invention will be described in detail combined with specific embodiments below, and the description of this part is only exemplary and explains
Property, there should not be any restriction effect to protection scope of the present invention.
A kind of method of bronze ware antique coloring of the invention, comprising the following steps:
Step (1): coloring pre-treatment: the mixing that the diamond dust and activating solution for being 34%~60% with weight percent are formed
Object sprays the bronze surface after polishing, refine；Processing before coloring can remove very thin outside bronze ware metal surface
Oxidation film, make metal surface activation, to guarantee the firm connection of coloring layer and parent metal, it is flat that product surface can be effectively improved
Whole degree.
Step (2): the bronze ware after progress pre-treatment is placed in bottomless wooden case, weight ratio is poured into wooden case is
The mixture that copper sulphate, ammonium chloride and the loess of 0.1:1:100~150 are formed pours supernatant water infiltration to bronze copper body is buried；
Step (3): sternly forming closed environment for wooden case case lid with plastic cloth and wooden cover, controls in wooden case oxygen content extremely
0.1~0.2mg/L takes out after saving at least 10 days.
In above-mentioned technical proposal, the activating solution is the sulfuric acid solution of 50~100mol/L of concentration.
In above-mentioned technical proposal, the particles of silicon carbide mesh number is 100~150 mesh.
In the step (3), the oxygen content in wooden case can be controlled by addition deoxidier.
The deoxidier is iron powder, sulphite or calcium carbide.
Embodiment 1
Taking diamond dust that 3.4kg particle mesh number is 100 mesh and 10kg concentration is that 50mol/L sulfuric acid solution is mixed evenly
Mixed liquor is formed, then the bronze surface after polishing, refine is sprayed with mixed liquor；By the bronze ware after progress pre-treatment
It is placed in bottomless wooden case, 0.1 part of copper sulphate, 10 parts of ammonium chloride and 1000 parts of loess of mixture is poured into wooden case to covering
Bronze copper body is buried, supernatant water infiltration is poured；Appropriate iron powder is added into wooden case reaches Control for Oxygen Content in 0.1mg/L and detests
Case lid is sternly formed closed environment with plastic cloth and wooden cover, taken out after saving 10 days by oxygen condition.By the bronze ware of taking-up
The loess of product clear water clean the surface, the present embodiment product surface form one layer of bronze-colored embroidery layer, and lovely luster is abundant, is in
Existing vicissitudes sense of the remote past, surface is smooth not to fade.
Embodiment 2
Taking diamond dust that 6kg particle mesh number is 150 mesh and 10kg concentration is that 100mol/L sulfuric acid solution is mixed evenly
Mixed liquor is formed, then the bronze surface after polishing, refine is sprayed with mixed liquor；By the bronze ware after progress pre-treatment
It is placed in bottomless wooden case, 0.1 part of copper sulphate, 10 parts of ammonium chloride and 1500 parts of loess of mixture is poured into wooden case to covering
Bronze copper body is buried, supernatant water infiltration is poured；Appropriate silicon carbide is added into wooden case reaches Control for Oxygen Content in wooden case in 0.1mg/L
Case lid is sternly formed closed environment with plastic cloth and wooden cover, taken out after saving 15 days by anaerobic state.By the bronze of taking-up
The loess of device product clear water clean the surface, the present embodiment product surface form one layer of bronze-colored embroidery layer, and lovely luster is abundant,
Vicissitudes sense of the remote past is presented, surface is smooth not to fade.
Embodiment 3
Taking diamond dust that 5kg particle mesh number is 120 mesh and 10kg concentration is that shape is mixed evenly in 60mol/L sulfuric acid solution
The bronze surface after polishing, refine is sprayed at mixed liquor, then with mixed liquor；Bronze ware after progress pre-treatment is put
It is placed in bottomless wooden case, 0.1 part of copper sulphate, 10 parts of ammonium chloride and 1200 parts of loess of mixture is poured into wooden case to burial
Bronze copper body pours supernatant water infiltration, and appropriate sulphite is added into wooden case reaches Control for Oxygen Content in wooden case in 0.2mg/L
Case lid is sternly formed closed environment with plastic cloth and wooden cover, taken out after saving 14 days by anaerobic state.By the bronze of taking-up
The loess of device product clear water clean the surface, the present embodiment product surface form one layer of bronze-colored embroidery layer, and lovely luster is abundant,
Vicissitudes sense of the remote past is presented, surface is smooth not to fade.
The above is only presently preferred embodiments of the present invention, not makes any limit to technical scope of the invention
System, therefore any subtle modifications, equivalent variations and modifications to the above embodiments according to the technical essence of the invention,
It still falls within the scope of technical solution of the present invention.
Claims (5)
1. a kind of method of bronze ware antique coloring, which comprises the following steps:
Step (1): coloring pre-treatment: the mixture pair that the diamond dust and activating solution for being 34%~60% with weight percent are formed
Bronze surface after polishing, refine is sprayed；
Step (2): the bronze ware after progress pre-treatment is placed in bottomless wooden case, it is 0.1 that weight ratio is poured into wooden case:
The mixture that copper sulphate, ammonium chloride and the loess of 1:100~150 are formed pours supernatant water infiltration to bronze copper body is buried；
Step (3): sternly forming closed environment for wooden case case lid with plastic cloth and wooden cover, control in wooden case oxygen content to 0.1~
0.2mg/L takes out after saving at least 10 days.
2. the method for bronze ware antique coloring as described in claim 1, it is characterised in that: the activating solution be concentration be 50~
The sulfuric acid solution of 100mol/L.
3. the method for bronze ware antique coloring as described in claim 1, it is characterised in that: the particles of silicon carbide mesh number is
100~150 mesh.
4. the method for bronze ware antique coloring as described in claim 1, it is characterised in that:, can be by adding in the step (3)
Killing controls the oxygen content in wooden case.
5. the method for bronze ware antique coloring as claimed in claim 4, it is characterised in that: the deoxidier is iron powder or sulfurous
Hydrochlorate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786128.4A CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786128.4A CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106367747A CN106367747A (en) | 2017-02-01 |
| CN106367747B true CN106367747B (en) | 2019-06-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610786128.4A Expired - Fee Related CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
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| CN (1) | CN106367747B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106985593A (en) * | 2017-02-22 | 2017-07-28 | 河北晨阳工贸集团有限公司 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1167042A (en) * | 1997-03-24 | 1997-12-10 | 薛发伟 | Technology for making imitation of bronze ware |
| CN1749441A (en) * | 2004-09-16 | 2006-03-22 | 张役 | Surface treating method for copper made wind instrument |
| CN1853960A (en) * | 2005-04-29 | 2006-11-01 | 湖北省荆州市郢都青铜艺术研究所 | Bronze surface antique-imitation technology |
| CN101109079A (en) * | 2007-08-23 | 2008-01-23 | 黄炜棠 | Hot tinting method on copper surface |
| CN101130869A (en) * | 2007-09-20 | 2008-02-27 | 吴江市天地人真空炉业有限公司 | Chemical tinting method for bronze color of copper |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN103397317A (en) * | 2013-07-25 | 2013-11-20 | 山西宇达集团有限公司 | Coloring rust-proof test solution for bronze sculpture and coloring method thereof |
-
2016
- 2016-08-31 CN CN201610786128.4A patent/CN106367747B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1167042A (en) * | 1997-03-24 | 1997-12-10 | 薛发伟 | Technology for making imitation of bronze ware |
| CN1749441A (en) * | 2004-09-16 | 2006-03-22 | 张役 | Surface treating method for copper made wind instrument |
| CN1853960A (en) * | 2005-04-29 | 2006-11-01 | 湖北省荆州市郢都青铜艺术研究所 | Bronze surface antique-imitation technology |
| CN101109079A (en) * | 2007-08-23 | 2008-01-23 | 黄炜棠 | Hot tinting method on copper surface |
| CN101130869A (en) * | 2007-09-20 | 2008-02-27 | 吴江市天地人真空炉业有限公司 | Chemical tinting method for bronze color of copper |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN103397317A (en) * | 2013-07-25 | 2013-11-20 | 山西宇达集团有限公司 | Coloring rust-proof test solution for bronze sculpture and coloring method thereof |
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| CN106367747A (en) | 2017-02-01 |
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Granted publication date: 20190611 Termination date: 20190831 |