CN106367747A - Antiquing coloring method for bronze ware - Google Patents
Antiquing coloring method for bronze ware Download PDFInfo
- Publication number
- CN106367747A CN106367747A CN201610786128.4A CN201610786128A CN106367747A CN 106367747 A CN106367747 A CN 106367747A CN 201610786128 A CN201610786128 A CN 201610786128A CN 106367747 A CN106367747 A CN 106367747A
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- CN
- China
- Prior art keywords
- bronze
- bronze ware
- coloring
- ware
- wooden case
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/52—Treatment of copper or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an antiquing coloring method for bronze ware. The antiquing coloring method is characterized by including the following steps that (1) coloring pretreatment is carried out, and specifically, a mixture composed of carborundum, with the weight percentage being 34%-60%, and activating fluid is sprayed to the surface of the bronze ware which is ground and subjected to finishing; (2) the bronze ware subjected to coloring pretreatment is placed in a wood box without a bottom, a mixture composed of copper sulfate, ammonium chloride and loess with the weight ratio of 0.1:1:(100-150) is poured into the wood box till a bronze body of the bronze ware is covered, and then clear water is poured in a permeating mode; and (3) a box opening of the wood box is tightly covered with plastic cloth and a wood cover to form an airtight environment, the oxygen content in the wood box is controlled to be 0.1-0.2 mg/L, and the bronze ware is taken out after being stored for at least ten days. By means of the method, a bronzed rust layer can be formed on the surface of the bronze ware, and the antique historical bitterness is shown.
Description
Technical field
The present invention relates to bronze surface handling process technical field, modelled after an antique more particularly, to a kind of bronze ware
Color method.
Background technology
Bronze ware has the history of 4,000 sexcentenaries in China, and unearthed has weapons, sacrificial vessel, drinking vessel etc..With increasingly
The excavation of many bronze ware is unearthed, and bronze ware is increasingly liked by people, and the bronze ware due to being unearthed belongs to history relic, is subject to
State guarantee is it is impossible to put on display or as collectibles collection, be only fabricated to by imitated method imitated in common museum
Product are put on display and are collected, and in order to meet this demand, many enterprises start to produce imitated bronze ware product both at home and abroad, but existing at present
Some surface antique-imitation technologies still can not reproduce the romantic charm of ancient culture well it is impossible to preferably meet the demand of people.
Content of the invention
For problems of the prior art, it is an object of the invention to provide a kind of antique coloring side of bronze ware
Method, the method can make bronze surface form copper-colored embroidery layer, assumes vicissitudes sense of the remote past.
The technical solution adopted in the present invention is: a kind of method of bronze ware antique coloring, comprises the following steps:
Step (1): coloring pre-treatment: the mixing of the corundum being 34%～60% with percentage by weight and activating solution formation
Thing sprays to the bronze surface after polishing, refine；
Step (2): the bronze ware carrying out after pre-treatment is positioned in bottomless wooden case, pours weight percent into toward in wooden case
Extremely bury bronze copper body than the mixture of copper sulfate, ammonium chloride and loess formation for 0.1:1:100～150, pour supernatant water and ooze
Thoroughly；
Step (3): with Polypropylence Sheet and wooden cover, wooden case case lid is sternly formed closed environment, control in wooden case oxygen content extremely
0.1～0.2mg/l, takes out after preserving at least 10 days.
The invention has the benefit that the antique coloring method of the bronze ware of the present invention can make bronze surface form bronze
The embroidery layer of color, bright in colour abundant, assume vicissitudes sense of the remote past, and bronze surface is smooth, does not fade, the side of the present invention
Method is simple to operate, low cost, market application are wide.
Specific embodiment
Describe the present invention with reference to specific embodiment, the description of this part is only exemplary and explains
Property, should there is not any restriction effect to protection scope of the present invention.
A kind of method of bronze ware antique coloring of the present invention, comprises the following steps:
Step (1): coloring pre-treatment: the mixing of the corundum being 34%～60% with percentage by weight and activating solution formation
Thing sprays to the bronze surface after polishing, refine；Process before coloring can remove very thin outside bronze ware metal surface
Oxide-film, make metal surface activation, to ensure the strong bonded of dyed layer and parent metal, can effectively improve product surface put down
Whole degree.
Step (2): the bronze ware carrying out after pre-treatment is positioned in bottomless wooden case, pours weight percent into toward in wooden case
Extremely bury bronze copper body than the mixture of copper sulfate, ammonium chloride and loess formation for 0.1:1:100～150, pour supernatant water and ooze
Thoroughly；
Step (3): with Polypropylence Sheet and wooden cover, wooden case case lid is sternly formed closed environment, control in wooden case oxygen content extremely
0.1～0.2mg/l, takes out after preserving at least 10 days.
In technique scheme, described activating solution is the sulfuric acid solution of concentration 50～100mol/l.
In technique scheme, described particles of silicon carbide mesh number is 100～150 mesh.
In described step (3), the oxygen content in wooden case can be controlled by adding deoxidizer.
Described deoxidizer is iron powder, sulphite, carborundum or carbide.
Embodiment 1
The corundum that 3.4kg granule mesh number is 100 mesh and 10kg concentration is taken to be 50mol/l sulfuric acid solution mixing and stirring
Form mixed liquor, then with mixed liquor, the bronze surface after polishing, refine is sprayed；The bronze ware after pre-treatment will be carried out
It is positioned in bottomless wooden case, pour the mixture of 0.1 part of copper sulfate, 10 parts of ammonium chloride and 1000 parts of loess toward in wooden case into covering
Bury bronze copper body, pour supernatant water infiltration；Add appropriate iron powder to make Control for Oxygen Content in wooden case reach in 0.1mg/l in wooden case to detest
Case lid is sternly formed closed environment with Polypropylence Sheet and wooden cover, takes out after preserving 10 days by oxygen condition.The bronze ware that will take out
The product loess on clean water surface, the present embodiment product surface forms one layer of copper-colored embroidery layer, bright in colour abundant, is in
Existing vicissitudes sense of the remote past, smooth surface is smooth not to fade.
Embodiment 2
The corundum that 6kg granule mesh number is 150 mesh and 10kg concentration is taken to be 100mol/l sulfuric acid solution mixing and stirring
Form mixed liquor, then with mixed liquor, the bronze surface after polishing, refine is sprayed；The bronze ware after pre-treatment will be carried out
It is positioned in bottomless wooden case, pour the mixture of 0.1 part of copper sulfate, 10 parts of ammonium chloride and 1500 parts of loess toward in wooden case into covering
Bury bronze copper body, pour supernatant water infiltration；Appropriate carborundum is added so that Control for Oxygen Content in wooden case is reached in 0.1mg/l in wooden case
Case lid is sternly formed closed environment with Polypropylence Sheet and wooden cover, takes out after preserving 15 days by anaerobic state.The bronze that will take out
The device product loess on clean water surface, the present embodiment product surface forms one layer of copper-colored embroidery layer, bright in colour abundant,
Assume vicissitudes sense of the remote past, smooth surface is smooth not to fade.
Embodiment 3
The corundum that 5kg granule mesh number is 120 mesh and 10kg concentration is taken to be 60mol/l sulfuric acid solution mixing and stirring shape
Become mixed liquor, then with mixed liquor, the bronze surface after polishing, refine is sprayed；The bronze ware carrying out after pre-treatment is put
It is placed in bottomless wooden case, the mixture pouring 0.1 part of copper sulfate, 10 parts of ammonium chloride and 1200 parts of loess toward in wooden case into is to burial
Bronze copper body, pours supernatant water infiltration, adds appropriate sulphite so that Control for Oxygen Content in wooden case is reached in 0.2mg/l in wooden case
Case lid is sternly formed closed environment with Polypropylence Sheet and wooden cover, takes out after preserving 14 days by anaerobic state.The bronze that will take out
The device product loess on clean water surface, the present embodiment product surface forms one layer of copper-colored embroidery layer, bright in colour abundant,
Assume vicissitudes sense of the remote past, smooth surface is smooth not to fade.
The above is only presently preferred embodiments of the present invention, not makes any limit to the technical scope of the present invention
System, therefore any trickle amendment, equivalent variations and modification that every technical spirit according to the present invention is made to above example, all
Still fall within the range of technical scheme.
Claims (5)
1. a kind of method of bronze ware antique coloring is it is characterised in that comprise the following steps:
Step (1): coloring pre-treatment: the mixture pair of the corundum being 34%～60% with percentage by weight and activating solution formation
Bronze surface after polishing, refine is sprayed；
Step (2): the bronze ware carrying out after pre-treatment is positioned in bottomless wooden case, pouring percentage by weight into toward in wooden case is
The mixture that the copper sulfate of 0.1:1:100～150, ammonium chloride and loess are formed, to burying bronze copper body, pours supernatant water infiltration；
Step (3): with Polypropylence Sheet and wooden cover, wooden case case lid is sternly formed closed environment, control in wooden case oxygen content to 0.1～
0.2mg/l, takes out after preserving at least 10 days.
2. bronze ware antique coloring as claimed in claim 1 method it is characterised in that: described activating solution for concentration be 50～
The sulfuric acid solution of 100mol/l.
3. bronze ware antique coloring as claimed in claim 1 method it is characterised in that: described particles of silicon carbide mesh number is
100～150 mesh.
4. bronze ware antique coloring as claimed in claim 1 method it is characterised in that: in described step (3), can be by adding
Killing is controlling the oxygen content in wooden case.
5. bronze ware antique coloring as claimed in claim 4 method it is characterised in that: described deoxidizer be iron powder, sulfurous
Hydrochlorate or carborundum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786128.4A CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786128.4A CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106367747A true CN106367747A (en) | 2017-02-01 |
| CN106367747B CN106367747B (en) | 2019-06-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610786128.4A Expired - Fee Related CN106367747B (en) | 2016-08-31 | 2016-08-31 | The antique coloring method of bronze ware |
Country Status (1)
| Country | Link |
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| CN (1) | CN106367747B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106985593A (en) * | 2017-02-22 | 2017-07-28 | 河北晨阳工贸集团有限公司 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1167042A (en) * | 1997-03-24 | 1997-12-10 | 薛发伟 | Technology for making imitation of bronze ware |
| CN1749441A (en) * | 2004-09-16 | 2006-03-22 | 张役 | Surface treating method for copper made wind instrument |
| CN1853960A (en) * | 2005-04-29 | 2006-11-01 | 湖北省荆州市郢都青铜艺术研究所 | Bronze surface antique-imitation technology |
| CN101109079A (en) * | 2007-08-23 | 2008-01-23 | 黄炜棠 | Hot tinting method on copper surface |
| CN101130869A (en) * | 2007-09-20 | 2008-02-27 | 吴江市天地人真空炉业有限公司 | Chemical tinting method for bronze color of copper |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN103397317A (en) * | 2013-07-25 | 2013-11-20 | 山西宇达集团有限公司 | Coloring rust-proof test solution for bronze sculpture and coloring method thereof |
-
2016
- 2016-08-31 CN CN201610786128.4A patent/CN106367747B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1167042A (en) * | 1997-03-24 | 1997-12-10 | 薛发伟 | Technology for making imitation of bronze ware |
| CN1749441A (en) * | 2004-09-16 | 2006-03-22 | 张役 | Surface treating method for copper made wind instrument |
| CN1853960A (en) * | 2005-04-29 | 2006-11-01 | 湖北省荆州市郢都青铜艺术研究所 | Bronze surface antique-imitation technology |
| CN101109079A (en) * | 2007-08-23 | 2008-01-23 | 黄炜棠 | Hot tinting method on copper surface |
| CN101130869A (en) * | 2007-09-20 | 2008-02-27 | 吴江市天地人真空炉业有限公司 | Chemical tinting method for bronze color of copper |
| CN102268666A (en) * | 2011-07-21 | 2011-12-07 | 洛阳粤钰青铜器有限公司 | Rusting solution and method for forming green rust on surface of bronze ware |
| CN103397317A (en) * | 2013-07-25 | 2013-11-20 | 山西宇达集团有限公司 | Coloring rust-proof test solution for bronze sculpture and coloring method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 李震，贾文忠: "《青铜器修复与鉴定》", 30 April 2012, 北京：文物出版社 * |
| 河南省文物考古研究所: "《古代青铜器修复与保护技术》", 30 June 2014, 郑州：大象出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106985593A (en) * | 2017-02-22 | 2017-07-28 | 河北晨阳工贸集团有限公司 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
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| Publication number | Publication date |
|---|---|
| CN106367747B (en) | 2019-06-11 |
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