CN106985593A - A kind of ironwork does old technology and its decorates the preparation method of sealing wax - Google Patents
A kind of ironwork does old technology and its decorates the preparation method of sealing wax Download PDFInfo
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- CN106985593A CN106985593A CN201710096960.6A CN201710096960A CN106985593A CN 106985593 A CN106985593 A CN 106985593A CN 201710096960 A CN201710096960 A CN 201710096960A CN 106985593 A CN106985593 A CN 106985593A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
- C09D7/44—Combinations of two or more thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/28—Acidic compositions for etching iron group metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
Old technology is done the invention discloses a kind of ironwork and its preparation method of sealing wax is decorated, and is related to sealing wax technical field.Doing old technology is：Ironwork is put in neutral or acid salt fog cabinet after surface sand-blasting process and carries out corrosion, is dried after clear water immersion afterwards, flushing, grinding process, spraying or dip-coating enamelled coating.Sealing wax component is：20 40% aqueous acrylic modified epoxy ester emulsions, 11 30% aqueous one-component polyaminoester emulsions, 3 20% aqueous PVDC emulsions, 0.1 1% nertralizer, 0 10% emulsified wax, 0.1 0.2% defoamer, 2 10% coalescents, 0.3 0.9% moistening flatting agent, 5 10% deionized waters, 0.5 1.0% thickener.This does old technology environmental protection, and cost is low, efficiency high；The sealing wax is good in rusty surface adhesive force, difficult for drop-off, both increases protection effect, ironwork is not only retained corrosion effect again, and with certain gloss, color and luster.
Description
Technical field
The present invention relates to sealing wax technical field, more particularly to do the handicrafts such as old ironwork and decoration sealing wax technology neck
Domain.
Background technology
Ironwork gets rusty easily, and is especially easier corrosion occur under damp and hot environment.And general ironwork is in the time
Long korneforos, corrosion occurs, or even by complete corrosion.In the modern life, people's often making artificially by some handicrafts
It gets rusty（Do old）, dense history vicissitudes sense is made it have, so as to reach the effect of decoration.But the ironwork after corrosion
Produce and do not allow easy to maintain after corrosion, and corrosion easily comes off, and has influence on aesthetic.It is general it is not only protected using coating more
Corrosion effect is stayed, and makes it have certain gloss, color and luster, so as to reach more preferable aesthetic.
But, the general method for handling corrosion, the comparatively laborious cycle is longer or does not reach environmental protection.And
The good ironwork of corrosion, due to the presence of corrosion, general coating is difficult, with good adhesive force, to hold very much on the surface of corrosion
It is easy to fall off, both influenceed attractive in appearance, again protection effect of the reduction to ironwork.
The content of the invention
Old technology is done the technical problem to be solved in the present invention is to provide a kind of ironwork and its decorates the preparation method of sealing wax,
The ironwork does old technology environmental protection, and cost is low, and efficiency is higher；The sealing wax has good adhesive force on the surface of corrosion, is difficult
Come off, both added the protection effect to ironwork, make to do again it is old after ironwork not only retain corrosion effect, and have it
There are certain gloss, color and luster, so as to reach more preferable aesthetic and environmental requirement.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of ironwork does old technology, including such as
Lower step：Ironwork is put in neutral salt fog chamber or acid salt fog cabinet after surface sand-blasting process and carries out corrosion, ironwork rust
Soaked after erosion with clear water, rinse after dry, using quartz sand sand paper or blasting treatment, grinding process is carried out to ironwork, finally
By ironwork spraying or dip-coating enamelled coating, produce ironwork and do old technology product.
It is preferred that, the pH value of the salting liquid before being atomized in neutral salt fog chamber is between 6.5~7.2 (35 DEG C), during corrosion
Temperature is 35-50 DEG C, and salting liquid is 3-15wt% sodium-chloride water solution；The pH value of salting liquid before being atomized in acid salt fog cabinet
Between 3.1-3.3 (35 DEG C), temperature during corrosion is 5-50 DEG C, and salting liquid is 3-15wt% sodium-chloride water solution.
A kind of ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：20-40%'s
Aqueous acrylic modified epoxy ester emulsion, 11-30% aqueous one-component polyaminoester emulsion, 3-20% aqueous PVDC emulsions,
0.1-1% nertralizer, 0-10% emulsified wax, 0.1-0.2% defoamer, 2-10% coalescents, 0.3-0.9% profit
Wet levelling agent, 5-10% deionized water, 0.5-1.0% thickener.
It is preferred that, ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight： 20-
40% aqueous acrylic modified epoxy ester emulsion, 11-30% aqueous one-component polyaminoester emulsion, 3-20% aqueous PVDC breasts
Liquid, 0.1-1% nertralizer, 3-10% emulsified wax, 0.1-0.2% defoamer, 2-10% coalescents, 0.3-0.9%
Moistening flatting agent, 5-10% deionized water, 0.5-1.0% thickener.
It is preferred that, aqueous acrylic modified epoxy ester emulsion is the WPA5812 of brilliant same moral Chemical Co., Ltd. of Foshan City；
Aqueous one-component polyaminoester emulsion is the D-60A aqueous polyurethane emulsions of Shanghai Run Dao trade Co., Ltds；Aqueous PVDC emulsions
For the WPA5060 of brilliant same moral Chemical Co., Ltd. of Foshan City；Emulsified wax is polypropylene wax emulsion.
It is preferred that, defoamer is the mixture of polyether siloxane copolymer class defoamer and organic silicon defoamer；Thickening
Agent is that polyurethane-type thickener and alkali soluble rise the mixture of type thickener.
It is further preferred that in defoamer polyether siloxane copolymer class defoamer and organic silicon defoamer weight ratio
For 1:1；In thickener polyurethane-type thickener and alkali soluble rise type thickener weight ratio be 1:1 to 2:1.
It is preferred that, coalescents are the coalescents of alcohol ester 12.
It is preferred that, moistening flatting agent is the moistening flatting agent of Siloxane-Oxyalkylene Copolymers class；Nertralizer is dimethyl ethanol
One or both of amine, multifunctional assistant AMP-95.
Above-mentioned ironwork does the preparation method of the decoration sealing wax of old technology product, comprises the following steps：
Step a, first enters portions of de-ionized water, the nertralizer of half quality, the moistening flatting agent of half quality, part defoamer
Row mixing, stirs；
Step b, adds into step a and the poly- ammonia of aqueous one-component is added under aqueous acrylic modified epoxy ester emulsion, stirring condition
Ester emulsion, aqueous PVDC emulsions, emulsified wax；Then coalescents, remaining nertralizer, remaining deionized water are added, is stirred
Mix uniform；Remaining defoamer, remaining moistening flatting agent are added, is stirred；Thickener adjustment viscosity is eventually adding, is stirred
Mix uniform, produce the decoration sealing wax that ironwork makees old technology product.
It is using the beneficial effect produced by above-mentioned technical proposal：
（1）The present invention carries out corrosion from salt mist environment to ironwork（Artificially do old）Processing, the corrosion time, corrosion into degree
Taking human as control, old effect can be done to be reached in the short time, the raw material more importantly used is water, these are free of contamination for salt
Material, the solution of formation is free from environmental pollution, while the waste liquid produced may be reused, free from environmental pollution, operating environment is not yet
To health produce harm, can be repeatedly ironwork is handled, efficiency is higher；
（2）Sealing wax of the present invention has good adhesive force on the surface of corrosion, difficult for drop-off, has both added the protection to ironwork
Effect, make to do again it is old after ironwork not only retain corrosion effect, and certain gloss, color and luster are made it have, so as to reach
More preferable aesthetic and environmental requirement；
（3）Present invention collocation uses film forming matter aqueous acrylic modified epoxy ester emulsion, aqueous one-component polyaminoester emulsion, water
Property PVDC emulsions, emulsified wax and coalescents, can obtain the aqueous lacquer coat of high adhesion force, high glaze, high-decoration, and
And the water paint VOC≤80g/L wherein prepared, smell is very low, prevents from polluting environment；
（4）The film forming matters such as monocomponent polyurethane, PVDC, acrylic modified epoxy ester that the present invention is selected, with good attached
Put forth effort, and corrosion layer can be penetrated into, ultimately form the coating of densification, prevent water, oxygen from entering substrate surface, so as to press down
The further corrosion of base material processed.The smooth degree of coating, compact in paint film, good hand touch can be strengthened by adding emulsified wax, not shadow
The paint film transparency is rung, not only attractive in appearance but also scratch resistant effect is reached；
（5）The present invention is compounded from different types of defoamer, i.e., foam inhibitor is used with the collocation of foamicide, solves system
Air bubble problem；From different types of thickener compounding, the thixotropic property of system is solved；
（6）Nertralizer of the present invention is mainly raising system pH, to 8-9, and this scope pH value is not only able to make coating system stable,
And can suppress iron, steel substrate corrosion after spraying.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, this is opposed below in conjunction with embodiment
Invention is described in further detail.
The requirement of part material used in embodiments of the invention and manufacturer are as follows：
Aqueous acrylic modified epoxy ester emulsion is the WPA5812 of brilliant same moral Chemical Co., Ltd. of Foshan City；
Aqueous one-component polyaminoester emulsion is the D-60A aqueous polyurethane emulsions of Shanghai Run Dao trade Co., Ltds；
Aqueous PVDC (Vingon) emulsion is the WPA5060 of brilliant same moral Chemical Co., Ltd. of Foshan City；
Emulsified wax is polypropylene wax emulsion；Such as the EP15 of Co., Ltd of Shanghai Joule Wax Industry Co., Ltd；It has fusing point height, wearability
Good, particle diameter is tiny（Transparent micro emulsion）, good waterproof performance, hardness of film it is high, tack-free；
Defoamer is polyether siloxane copolymer class defoamer, such as（German Di Gao companies）Used additives Tego- is made in TEGO deaeration
902w, organic silicon defoamer, such as（German BIC Corp）BYK froth breaking effect auxiliary agent B two kinds of mixtures of YK-028, weight ratio
Example is 1:1 or so；
Thickener is the polyurethane-type thickener PS202 of polyurethane-type thickener, such as Ning Baidi groups of Italy, and alkali soluble rises type
Thickener, the alkali soluble of such as Ning Baidi groups of Italy rises two kinds of mixtures of type thickener ASE60, and part by weight scope is 1:1 to
2:1；
Coalescents are the coalescents of alcohol ester 12；Entitled 2,2,4- trimethyl -1, the 3- pentanediol mono isobutyrate of chemistry, is high
Boiling point environmental protection cosolvent, is purchased from Guangzhou Yu Tai Chemical Industry Science Co., Ltd；
Moistening flatting agent is the moistening flatting agent of Siloxane-Oxyalkylene Copolymers class；Such as（German enlightening is high）TEGO Tego-245,
One or both of Tego-270；
Nertralizer is one or both of dimethylethanolamine, multifunctional assistant AMP-95.
Embodiment 1
A kind of ironwork does old technology, comprises the following steps：Using the ironwork being typically molded, after surface sand-blasting process,
Be put in neutral or acid salt fog cabinet, the pH value of the salting liquid before being atomized in neutral salt fog chamber between 6.5~7.2 (35 DEG C),
Temperature during corrosion is 35-50 DEG C, and salting liquid is 3-15wt% sodium-chloride water solution；Salt before being atomized in acid salt fog cabinet is molten
The pH value of liquid is between 3.1-3.3 (35 DEG C), and temperature during corrosion is 35-50 DEG C, and salting liquid is 3-15wt% aqueous sodium chloride
Liquid.For example：The pH value of salting liquid before being atomized in neutral salt fog chamber is between 6.5~7.2 (35 DEG C), under the conditions of salt fog, iron
The easy corrosion of product, in general, under salt mist environment, corrosion degree passes through increase equivalent to the corrosion degree of outdoor placement 1 year
Salinity, raises temperature, reduces pH value（Use ackd salt fog chamber）, corrosion can be accelerated, according to exemplar corrosion effect come really
Determine time of the ironwork in salt mist environment, the ironwork that typically at 1-5 days or so, can be then up to corrosion requirement is used
Dried after clear water immersion, flushing, use the quartz sand sand paper of 100-800 mesh or blasting treatment, trickle polishing is carried out to exemplar
Processing, finally by ironwork spraying or one layer of sealing wax described below of dip-coating.
Above-mentioned ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：40% it is aqueous
Acrylic modified epoxy ester emulsion, 20% aqueous one-component polyaminoester emulsion, 15% aqueous PVDC emulsions, 0.6% neutralization
Agent, 10% emulsified wax, 0.2% defoamer, 7% coalescents, 0.9% moistening flatting agent, 5.3% deionized water,
1.0% thickener.
Above-mentioned ironwork does the preparation method of the decoration sealing wax of old technology product, comprises the following steps：
Step a, first enters portions of de-ionized water, the nertralizer of half quality, the moistening flatting agent of half quality, part defoamer
Row mixing, is stirred 15 minutes with 500r/min speed；
Step b, aqueous acrylic modified epoxy ester emulsion is added into step a, to add under 500r/min speed stirring condition
Enter aqueous one-component polyaminoester emulsion, aqueous PVDC emulsions, emulsified wax；Then coalescents, remaining nertralizer are added, is remained
Remaining deionized water, 900r/min speed is stirred 10 minutes；Remaining defoamer, remaining moistening flatting agent are added,
1200r/min speed is stirred 10 minutes；Thickener adjustment viscosity is eventually adding, 1000r/min speed is stirred 10 minutes, adjusted
Whole viscosity is to qualified（Generally apply at-four glasss 25 DEG C and test 60-85S）, produce the decoration sealing wax that ironwork makees old technology product.
Embodiment 2
Ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：22% water soluble acrylic acid changes
Property epoxy ester emulsion, 30% aqueous one-component polyaminoester emulsion, 20% aqueous PVDC emulsions, 0.1% nertralizer, 10% breast
Fossil waxes, 0.2% defoamer, 7.1% coalescents, 0.9% moistening flatting agent, 8.7% deionized water, 1.0% thickening
Agent.Decorate the preparation method be the same as Example 1 of sealing wax.
Embodiment 3
Ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：40% water soluble acrylic acid changes
Property epoxy ester emulsion, 30% aqueous one-component polyaminoester emulsion, 15% aqueous PVDC emulsions, 1% nertralizer, 0.2% disappear
Infusion, 7% coalescents, 0.8% moistening flatting agent, 5% deionized water, 1.0% thickener.Decorate the preparation side of sealing wax
Method be the same as Example 1.
Embodiment 4
Ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：40% water soluble acrylic acid changes
Property epoxy ester emulsion, 11% aqueous one-component polyaminoester emulsion, 20% aqueous PVDC emulsions, 1% nertralizer, 7.1% breast
Fossil waxes, 0.1% defoamer, 10% coalescents, 0.3% moistening flatting agent, 10% deionized water, 0.5% thickening
Agent.Decorate the preparation method be the same as Example 1 of sealing wax.
Embodiment 5
Ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：40% water soluble acrylic acid changes
Property epoxy ester emulsion, 30% aqueous one-component polyaminoester emulsion, 3% aqueous PVDC emulsions, 1% nertralizer, 3.9% emulsification
Paraffin, 0.2% defoamer, 10% coalescents, 0.9% moistening flatting agent, 10% deionized water, 1% thickener.Dress
Adorn the preparation method be the same as Example 1 of sealing wax.
Embodiment 6
Ironwork makees the decoration sealing wax of old technology product, is made up of the component of following percentage by weight：31.9% water soluble acrylic acid
Modified epoxy ester emulsion, 30% aqueous one-component polyaminoester emulsion, 20% aqueous PVDC emulsions, 1% nertralizer, 3% breast
Fossil waxes, 0.2% defoamer, 2% coalescents, 0.9% moistening flatting agent, 10% deionized water, 1% thickener.Dress
Adorn the preparation method be the same as Example 1 of sealing wax.
Table 1 is the decoration sealing wax test result that embodiments of the invention ironwork makees old technology product：
Sealing wax of the present invention has good adhesive force on the surface of corrosion, difficult for drop-off, has both added the protection effect to ironwork
Really, make to do again it is old after ironwork not only retain corrosion effect, and certain gloss, color and luster are made it have, so as to reach more
Good aesthetic and environmental requirement.
Claims (10)
1. a kind of ironwork does old technology, it is characterised in that：Comprise the following steps：
Ironwork is put in neutral salt fog chamber or acid salt fog cabinet after surface sand-blasting process and carries out corrosion, ironwork corrosion
Soaked afterwards with clear water, rinse after dry, using quartz sand sand paper or blasting treatment, grinding process is carried out to ironwork, finally will
Ironwork is sprayed or dip-coating enamelled coating, is produced ironwork and is done old technology product.
2. a kind of ironwork according to claim 1 does old technology, it is characterised in that
The pH value of salting liquid before being atomized in neutral salt fog chamber is between 6.5~7.2 (35 DEG C), and temperature during corrosion is 35-50
DEG C, salting liquid is 3-15wt% sodium-chloride water solution；
The pH value of salting liquid before being atomized in acid salt fog cabinet is between 3.1-3.3 (35 DEG C), and temperature during corrosion is 35-50
DEG C, salting liquid is 3-15wt% sodium-chloride water solution.
3. a kind of ironwork makees the decoration sealing wax of old technology product, it is characterised in that be made up of the component of following percentage by weight：
20-40% aqueous acrylic modified epoxy ester emulsion, 11-30% aqueous one-component polyaminoester emulsion, 3-20% aqueous PVDC
Emulsion, 0.1-1% nertralizer, 0-10% emulsified wax, 0.1-0.2% defoamer, 2-10% coalescents, 0.3-0.9%
Moistening flatting agent, 5-10% deionized water, 0.5-1.0% thickener.
4. a kind of ironwork according to claim 3 makees the decoration sealing wax of old technology product, it is characterised in that by weighing as follows
Measure the component composition of percentage：20-40% aqueous acrylic modified epoxy ester emulsion, 11-30% aqueous one-component polyurethane
Emulsion, 3-20% aqueous PVDC emulsions, 0.1-1% nertralizer, 3-10% emulsified wax, 0.1-0.2% defoamer, 2-
10% coalescents, 0.3-0.9% moistening flatting agent, 5-10% deionized water, 0.5-1.0% thickener.
5. a kind of ironwork according to claim 3 makees the decoration sealing wax of old technology product, it is characterised in that described aqueous
Acrylic modified epoxy ester emulsion is the WPA5812 of brilliant same moral Chemical Co., Ltd. of Foshan City；Aqueous one-component polyurethane breast
Liquid is the D-60A aqueous polyurethane emulsions of Shanghai Run Dao trade Co., Ltds；Aqueous PVDC emulsions are the brilliant same Dehua in Foshan City
The WPA5060 of work Co., Ltd；Emulsified wax is polypropylene wax emulsion.
6. a kind of ironwork according to claim 3 makees the decoration sealing wax of old technology product, it is characterised in that the froth breaking
Agent is the mixture of polyether siloxane copolymer class defoamer and organic silicon defoamer；Thickener be polyurethane-type thickener and
Alkali soluble rises the mixture of type thickener.
7. a kind of ironwork according to claim 6 makees the decoration sealing wax of old technology product, it is characterised in that the froth breaking
The weight ratio of polyether siloxane copolymer class defoamer and organic silicon defoamer is 1 in agent:1；Polyurethane-type increases in thickener
The rise weight ratio of type thickener of thick dose and alkali soluble is 1:1 to 2:1.
8. a kind of ironwork according to claim 3 makees the decoration sealing wax of old technology product, it is characterised in that the film forming
Auxiliary agent is the coalescents of alcohol ester 12.
9. a kind of ironwork according to claim 3 makees the decoration sealing wax of old technology product, it is characterised in that the wetting
Levelling agent is the moistening flatting agent of Siloxane-Oxyalkylene Copolymers class；Nertralizer is dimethylethanolamine, multifunctional assistant AMP-95
One or both of.
10. a kind of ironwork as described in claim any one of 3-9 does the preparation method of the decoration sealing wax of old technology product, its
It is characterised by：Comprise the following steps：
Step a, first enters portions of de-ionized water, the nertralizer of half quality, the moistening flatting agent of half quality, part defoamer
Row mixing, stirs；
Step b, adds into step a and the poly- ammonia of aqueous one-component is added under aqueous acrylic modified epoxy ester emulsion, stirring condition
Ester emulsion, aqueous PVDC emulsions, emulsified wax；Then coalescents, remaining nertralizer, remaining deionized water are added, is stirred
Mix uniform；Remaining defoamer, remaining moistening flatting agent are added, is stirred；Thickener adjustment viscosity is eventually adding, is stirred
Mix uniform, produce the decoration sealing wax that ironwork makees old technology product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096960.6A CN106985593A (en) | 2017-02-22 | 2017-02-22 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710096960.6A CN106985593A (en) | 2017-02-22 | 2017-02-22 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
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| CN106985593A true CN106985593A (en) | 2017-07-28 |
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| CN201710096960.6A Pending CN106985593A (en) | 2017-02-22 | 2017-02-22 | A kind of ironwork does old technology and its decorates the preparation method of sealing wax |
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