CN106366385A - Corrosion-resistant high-mechanical-strength cable insulation material - Google Patents

Corrosion-resistant high-mechanical-strength cable insulation material Download PDF

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CN106366385A
CN106366385A CN201610768331.9A CN201610768331A CN106366385A CN 106366385 A CN106366385 A CN 106366385A CN 201610768331 A CN201610768331 A CN 201610768331A CN 106366385 A CN106366385 A CN 106366385A
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parts
corrosion
lecithin
resistant high
modified
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李正祥
赵欣泰
张玉湘
杨永亮
高华
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Anhui Land Group Co Ltd
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Anhui Land Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/005Hydrogenated nitrile rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/38Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes condensation products of aldehydes with amines or amides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
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  • Health & Medical Sciences (AREA)
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  • Polymers & Plastics (AREA)
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  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a corrosion-resistant high-mechanical-strength cable insulation material which is prepared from the following raw materials in parts by weight: 20 to 30 parts of urea resin, 15 to 25 parts of ethylene octylene segmented copolymer, 20 to 40 parts of hydrogenated butadiene-acrylonitrile rubber, 1 to 2 parts of white factice, 3 to 7 parts of modified lecithin, 1.5 to 3 parts of castor oil, 0.5 to 1 part of cresyl diphenyl phosphate, 0.8 to 1.2 parts of benzyl butyl phthalate, 0.1 to 0.5 part of dioctyl phthalate, 6 to 14 parts of talcum powder, 8 to 12 parts of lignin, 6 to 12 parts of coconut fiber, 3 to 9 parts of asbestos, 6 to 10 parts of sea-foam stone powder, 1.5 to 2.5 parts of colorant, 1.5 to 3 parts of stabilizer, 1.5 to 2.5 parts of antistatic agent and 1.5 to 3 parts of 1010 antioxidant. The corrosion-resistant high-mechanical-strength cable insulation material is good in thermal stability, high in mechanical strength and excellent in corrosion resistance.

Description

A kind of corrosion-resistant high mechanical strength cable insulating material
Technical field
The present invention relates to field of cable technology, more particularly, to a kind of corrosion-resistant high mechanical strength cable insulating material.
Background technology
With rapid development of economy, the demand of cable insulating material increasing it is desirable to more and more higher, traditional cable Insulation Material is faced with huge challenge, electric wire as electric energy and information transfer body, in transportation, industrial mine, electricity The every field of the lives such as gas communication can see cable miscellaneous, and with the increase of cable status in life, it is exhausted Edge material quality is also increasingly subject to people's attention, and heat stability, mechanical strength and the corrosion resistance of current cable insulating material Demand can also be can not meet.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of corrosion-resistant high mechanical strength cable insulation Material, heat stability is good, high mechanical strength, excellent anti-corrosion performance.
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree Fat 20-30 part, ethylene octene block copolymer 15-25 part, hydrogenated nitrile-butadiene rubber 20-40 part, white factice 1-2 part, modified lecithin Fat 3-7 part, Oleum Ricini 1.5-3 part, phosphate toluene diphenyl ester 0.5-1 part, BBP(Butyl Benzyl Phthalate 0.8-1.2 part, adjacent benzene two Formic acid dioctyl ester 0.1-0.5 part, Pulvis Talci 6-14 part, lignin 8-12 part, cocoanut fiber 6-12 part, asbestos 3-9 part, meerschaum Powder 6-10 part, coloring agent 1.5-2.5 part, stabilizer 1.5-3 part, antistatic additive 1.5-2.5 part, 1010 antioxidant 1.5-3 parts.
Preferably, the weight of Lauxite, ethylene octene block copolymer, hydrogenated nitrile-butadiene rubber is than for 22-28:17-23: 25-35.
Preferably, the weight of white factice, modified lecithin, Oleum Ricini is than for 1.4-1.6:4-6:2-2.5.
Preferably, the weight of Pulvis Talci, lignin, cocoanut fiber, asbestos, sepiolite powder is than for 8-12:9-11:8-10: 5-7:7-9.
Preferably, modified lecithin adopts following technique preparation: sodium carboxymethyl cellulose, hyaluronic acid, water mixing are stirred Mix, add arginine mix and blend, regulation system ph value to 5.5-6, add 1- alkyl -3- (3- dimethyl aminopropyl) carbonization two Imines, the stirring of n- hydroxyl -7- azo BTA, add dehydrated alcohol to place and obtain modified carboxy methyl cellulose sodium;By ovum Phospholipid, dehydrated alcohol mix homogeneously, add Bacterial cellulose stirring, ultrasonic vibration, filter, it is water-soluble that procyanidin sent into by filter cake It is stirred at room temperature in liquid, modified carboxy methyl cellulose sodium, washing, lyophilization obtains modified lecithin.
Preferably, modified lecithin adopts following technique preparation: sodium carboxymethyl cellulose, hyaluronic acid, water mixing are stirred Mix 25-45min, add arginine mix and blend 35-65min, regulation system ph value to 5.5-6, add 1- alkyl -3- (3- bis- Methyl aminopropyl) carbodiimides, n- hydroxyl -7- azo BTA stirring 25-55min, whipping temp be 1.5-2.5 DEG C, add dehydrated alcohol to place 1-5h, obtain modified carboxy methyl cellulose sodium;By lecithin, dehydrated alcohol mix homogeneously, add Bacterial cellulose stirs 15-25h, and mixing speed is 300-360r/min, and whipping temp is 30-40 DEG C, ultrasonic vibration 45- 85min, ultrasonic power is 550-650w, filters, room temperature in filter cake feeding procyanidin aqueous solution, modified carboxy methyl cellulose sodium Stirring 2-4h, washing, lyophilization obtains modified lecithin.
Preferably, modified lecithin adopts following technique preparation: by weight by 10-20 part sodium carboxymethyl cellulose, 4-6 Part hyaluronic acid, 70-110 part water mix and blend 25-45min, add 0.3-0.7 part arginine mix and blend 35-65min, adjust Section system ph value, to 5.5-6, adds 0.4-0.6 part 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, 0.4-0.8 part N- hydroxyl -7- azo BTA stirs 25-55min, and whipping temp is 1.5-2.5 DEG C, adds 10-20 part dehydrated alcohol to put Put 1-5h, obtain modified carboxy methyl cellulose sodium;By weight by 3-7 part lecithin, 90-170 part dehydrated alcohol mix homogeneously, Add 12-16 part Bacterial cellulose stirring 15-25h, mixing speed is 300-360r/min, and whipping temp is 30-40 DEG C, ultrasonic Concussion 45-85min, ultrasonic power is 550-650w, filters, and the procyanidin water that 80-150 part concentration is 2-4g/l sent into by filter cake 2-4h is stirred at room temperature in solution, 15-25 part modified carboxy methyl cellulose sodium, washing, lyophilization obtains modified lecithin.
The present invention adopts conventional fabrication process to be obtained.
The present invention adopts hydrogenated nitrile-butadiene rubber, Lauxite, ethylene octene block copolymer mating reaction, mechanical strength Height, heat stability is good, and under modified lecithin effect, the compatibility is good, and white factice, Oleum Ricini mating reaction, and plasticization effect shows Write, mechanical strength further enhances;In the modified lecithin of the present invention, after lecithin is combined with Bacterial cellulose, procyanidin Further crosslinking is carried out to lecithin, after making crosslinking, lecithin is coated on Bacterial cellulose surface, not only there is the three-dimensional of uniqueness Nanostructured, and good with the compatibility of modified carboxy methyl cellulose sodium, mechanical performance can be effectively improved, lecithin is thin simultaneously Fungin surface distributed uniformly, and is diffused to the inside of Bacterial cellulose, overall crosslinked uniform, makes globality of the present invention Good, plasticization effect is excellent;And in modified carboxy methyl cellulose sodium, hyaluronic acid, sodium carboxymethyl cellulose synergism, can have Effect overcomes respective shortcoming, and not only mechanical performance is excellent, and has the excellent compatibility and between unclassified stores, and heat stability is high, with When not degradable, acid corrosion-resistant;Modified lecithin and dioctyl phthalate, BBP(Butyl Benzyl Phthalate, tricresyl phosphate two Phenyl ester carries out mating reaction, and resistance to thermo-oxidative stability is good, and mutual mixing uniformity is good, can be in the premise ensureing hardness of the present invention Under, strengthen the toughness of the present invention;Modified lecithin and lignin, Pulvis Talci, sepiolite powder, cocoanut fiber, asbestos mating reaction, Make the present invention not degradable, excellent anti-corrosion performance, mechanical performance further enhances.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree 20 parts of fat, 25 parts of ethylene octene block copolymer, 20 parts of hydrogenated nitrile-butadiene rubber, 2 parts of white factice, 3 parts of modified lecithin, Oleum Ricini 3 parts, 0.5 part of phosphate toluene diphenyl ester, 1.2 parts of BBP(Butyl Benzyl Phthalate, 0.1 part of dioctyl phthalate, Pulvis Talci 14 Part, 8 parts of lignin, 12 parts of cocoanut fiber, 3 parts of asbestos, 10 parts of sepiolite powder, 1.5 parts of coloring agent, 3 parts of stabilizer, antistatic additive 1.5 parts, 1,010 3 parts of antioxidant.
Embodiment 2
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree 30 parts of fat, 15 parts of ethylene octene block copolymer, 40 parts of hydrogenated nitrile-butadiene rubber, 1 part of white factice, 7 parts of modified lecithin, Oleum Ricini 1.5 parts, 1 part of phosphate toluene diphenyl ester, 0.8 part of BBP(Butyl Benzyl Phthalate, 0.5 part of dioctyl phthalate, Pulvis Talci 6 Part, 12 parts of lignin, 6 parts of cocoanut fiber, 9 parts of asbestos, 6 parts of sepiolite powder, 2.5 parts of coloring agent, 1.5 parts of stabilizer, antistatic 2.5 parts of agent, 1,010 1.5 parts of antioxidant.
Modified lecithin adopts following technique preparation: sodium carboxymethyl cellulose, hyaluronic acid, water mix and blend add Arginine mix and blend, regulation system ph value to 5.5-6, add 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, n- Hydroxyl -7- azo BTA stirs, and adds dehydrated alcohol to place and obtains modified carboxy methyl cellulose sodium;By lecithin, no Water-ethanol mix homogeneously, adds Bacterial cellulose stirring, ultrasonic vibration, filters, and filter cake sends into procyanidin aqueous solution, modified carboxylic It is stirred at room temperature in sodium carboxymethylcellulose pyce, washing, lyophilization obtains modified lecithin.
Embodiment 3
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree 22 parts of fat, 23 parts of ethylene octene block copolymer, 25 parts of hydrogenated nitrile-butadiene rubber, 1.6 parts of white factice, 4 parts of modified lecithin, Semen Ricini 2.5 parts of oil, 0.6 part of phosphate toluene diphenyl ester, 1.1 parts of BBP(Butyl Benzyl Phthalate, 0.2 part of dioctyl phthalate, Talcum 12 parts of powder, 9 parts of lignin, 10 parts of cocoanut fiber, 5 parts of asbestos, 9 parts of sepiolite powder, 1.8 parts of coloring agent, 2.5 parts of stabilizer, resist 1.8 parts of electrostatic agent, 1,010 2.5 parts of antioxidant.
Modified lecithin adopts the preparation of following technique: by weight by 10 parts of sodium carboxymethyl cellulose, 6 parts of hyaluronic acids, 70 parts of water mix and blend 45min, add 0.3 part of arginine mix and blend 65min, regulation system ph value to 5.5-6, add 0.4 Part 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, 0.8 part of n- hydroxyl -7- azo BTA stir 25min, Whipping temp is 2.5 DEG C, adds 10 parts of dehydrated alcohol to place 5h, obtains modified carboxy methyl cellulose sodium;By weight by 3 parts of ovum Phospholipid, 170 parts of dehydrated alcohol mix homogeneously, add 12 parts of Bacterial cellulose to stir 25h, and mixing speed is 300r/min, stirring Temperature is 40 DEG C, ultrasonic vibration 45min, and ultrasonic power is 650w, filters, and the procyanidin that 80 parts of concentration are 4g/l sent into by filter cake 4h is stirred at room temperature in aqueous solution, 15 parts of modified carboxy methyl cellulose sodium, washing, lyophilization obtains modified lecithin.
Embodiment 4
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree 28 parts of fat, 17 parts of ethylene octene block copolymer, 35 parts of hydrogenated nitrile-butadiene rubber, 1.4 parts of white factice, 6 parts of modified lecithin, Semen Ricini 2 parts of oil, 0.8 part of phosphate toluene diphenyl ester, 0.9 part of BBP(Butyl Benzyl Phthalate, 0.4 part of dioctyl phthalate, Pulvis Talci 8 Part, 11 parts of lignin, 8 parts of cocoanut fiber, 7 parts of asbestos, 7 parts of sepiolite powder, 2.2 parts of coloring agent, 2 parts of stabilizer, antistatic additive 2.2 parts, 1,010 2 parts of antioxidant.
Modified lecithin adopts the preparation of following technique: by weight by 20 parts of sodium carboxymethyl cellulose, 4 parts of hyaluronic acids, 110 parts of water mix and blend 25min, add 0.7 part of arginine mix and blend 35min, regulation system ph value to 5.5-6, add 0.6 Part 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, 0.4 part of n- hydroxyl -7- azo BTA stir 55min, Whipping temp is 1.5 DEG C, adds 20 parts of dehydrated alcohol to place 1h, obtains modified carboxy methyl cellulose sodium;By weight by 7 parts of ovum Phospholipid, 90 parts of dehydrated alcohol mix homogeneously, add 16 parts of Bacterial cellulose to stir 15h, and mixing speed is 360r/min, stirring temperature Spend for 30 DEG C, ultrasonic vibration 85min, ultrasonic power is 550w, filters, and the procyanidin that 150 parts of concentration are 2g/l sent into by filter cake 2h is stirred at room temperature in aqueous solution, 25 parts of modified carboxy methyl cellulose sodium, washing, lyophilization obtains modified lecithin.
Embodiment 5
A kind of corrosion-resistant high mechanical strength cable insulating material proposed by the present invention, its raw material includes by weight: ureaformaldehyde tree 25 parts of fat, 20 parts of ethylene octene block copolymer, 30 parts of hydrogenated nitrile-butadiene rubber, 1.5 parts of white factice, 5 parts of modified lecithin, Semen Ricini 2.3 parts of oil, 0.7 part of phosphate toluene diphenyl ester, 1 part of BBP(Butyl Benzyl Phthalate, 0.3 part of dioctyl phthalate, Pulvis Talci 10 parts, 10 parts of lignin, 9 parts of cocoanut fiber, 6 parts of asbestos, 8 parts of sepiolite powder, 2 parts of coloring agent, 2.2 parts of stabilizer, antistatic 2 parts of agent, 1,010 2.3 parts of antioxidant.
Modified lecithin adopts following technique preparation: by sodium carboxymethyl cellulose, hyaluronic acid, water mix and blend 35min, Add arginine mix and blend 50min, regulation system ph value to 5.5-6, add 1- alkyl -3- (3- dimethyl aminopropyl) carbonization Diimine, n- hydroxyl -7- azo BTA stirring 40min, whipping temp is 2 DEG C, adds dehydrated alcohol to place 3h, obtain Modified carboxy methyl cellulose sodium;By lecithin, dehydrated alcohol mix homogeneously, add Bacterial cellulose stirring 20h, mixing speed is 330r/min, whipping temp is 35 DEG C, ultrasonic vibration 80min, and ultrasonic power is 600w, filters, and procyanidin water sent into by filter cake 3h is stirred at room temperature in solution, modified carboxy methyl cellulose sodium, washing, lyophilization obtains modified lecithin.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (7)

1. a kind of corrosion-resistant high mechanical strength cable insulating material is it is characterised in that its raw material includes by weight: Lauxite 20-30 part, ethylene octene block copolymer 15-25 part, hydrogenated nitrile-butadiene rubber 20-40 part, white factice 1-2 part, modified lecithin 3-7 part, Oleum Ricini 1.5-3 part, phosphate toluene diphenyl ester 0.5-1 part, BBP(Butyl Benzyl Phthalate 0.8-1.2 part, O-phthalic Dioctyl phthalate 0.1-0.5 part, Pulvis Talci 6-14 part, lignin 8-12 part, cocoanut fiber 6-12 part, asbestos 3-9 part, sepiolite powder 6-10 part, coloring agent 1.5-2.5 part, stabilizer 1.5-3 part, antistatic additive 1.5-2.5 part, 1010 antioxidant 1.5-3 parts.
2. according to claim 1 corrosion-resistant high mechanical strength cable insulating material it is characterised in that Lauxite, ethylene are pungent Alkene block copolymer, the weight of hydrogenated nitrile-butadiene rubber are than for 22-28:17-23:25-35.
3. corrosion-resistant high mechanical strength cable insulating material according to claim 1 or claim 2 is it is characterised in that white factice, modified ovum Phospholipid, the weight of Oleum Ricini are than for 1.4-1.6:4-6:2-2.5.
4. according to any one of claim 1-3 corrosion-resistant high mechanical strength cable insulating material it is characterised in that Pulvis Talci, Lignin, cocoanut fiber, asbestos, the weight of sepiolite powder are than for 8-12:9-11:8-10:5-7:7-9.
5. according to any one of claim 1-4 corrosion-resistant high mechanical strength cable insulating material it is characterised in that modified lecithin Fat adopts following technique preparation: sodium carboxymethyl cellulose, hyaluronic acid, water mix and blend adds arginine mix and blend, adjusts Section system ph value, to 5.5-6, adds 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, n- hydroxyl -7- azo benzo three Nitrogen azoles stirs, and adds dehydrated alcohol to place and obtains modified carboxy methyl cellulose sodium;By lecithin, dehydrated alcohol mix homogeneously, plus Enter Bacterial cellulose stirring, ultrasonic vibration, filter, room in filter cake feeding procyanidin aqueous solution, modified carboxy methyl cellulose sodium Temperature stirring, washing, lyophilization obtains modified lecithin.
6. according to any one of claim 1-5 corrosion-resistant high mechanical strength cable insulating material it is characterised in that modified lecithin Fat adopts following technique preparation: sodium carboxymethyl cellulose, hyaluronic acid, water mix and blend 25-45min add arginine mixed Close stirring 35-65min, regulation system ph value to 5.5-6, add 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, n- Hydroxyl -7- azo BTA stirs 25-55min, and whipping temp is 1.5-2.5 DEG C, adds dehydrated alcohol to place 1-5h, obtains To modified carboxy methyl cellulose sodium;By lecithin, dehydrated alcohol mix homogeneously, add Bacterial cellulose stirring 15-25h, stirring Speed is 300-360r/min, and whipping temp is 30-40 DEG C, ultrasonic vibration 45-85min, and ultrasonic power is 550-650w, mistake Filter, is stirred at room temperature 2-4h in filter cake feeding procyanidin aqueous solution, modified carboxy methyl cellulose sodium, washing, and lyophilization obtains Modified lecithin.
7. according to any one of claim 1-6 corrosion-resistant high mechanical strength cable insulating material it is characterised in that modified lecithin Fat adopts following technique preparation: mixes 10-20 part sodium carboxymethyl cellulose, 4-6 part hyaluronic acid, 70-110 part water by weight Close stirring 25-45min, add 0.3-0.7 part arginine mix and blend 35-65min, regulation system ph value to 5.5-6, add 0.4-0.6 part 1- alkyl -3- (3- dimethyl aminopropyl) carbodiimides, 0.4-0.8 part n- hydroxyl -7- azo BTA Stirring 25-55min, whipping temp is 1.5-2.5 DEG C, adds 10-20 part dehydrated alcohol to place 1-5h, obtains modified carboxy methyl fine The plain sodium of dimension;By weight by 3-7 part lecithin, 90-170 part dehydrated alcohol mix homogeneously, 12-16 part Bacterial cellulose is added to stir Mix 15-25h, mixing speed is 300-360r/min, whipping temp is 30-40 DEG C, ultrasonic vibration 45-85min, ultrasonic power is 550-650w, filters, and 80-150 part concentration sent into by filter cake is the procyanidin aqueous solution of 2-4g/l, 15-25 part modified carboxy methyl 2-4h is stirred at room temperature in sodium cellulosate, washing, lyophilization obtains modified lecithin.
CN201610768331.9A 2016-08-30 2016-08-30 Corrosion-resistant high-mechanical-strength cable insulation material Pending CN106366385A (en)

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Cited By (1)

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CN108690288A (en) * 2018-05-30 2018-10-23 安徽渡江电缆集团有限公司 A kind of flame-proof cable sheath material that thermostabilization is high

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Application publication date: 20170201