CN106750938A - A kind of wear-resisting inexpensive long service life cable material - Google Patents

A kind of wear-resisting inexpensive long service life cable material Download PDF

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CN106750938A
CN106750938A CN201611181903.XA CN201611181903A CN106750938A CN 106750938 A CN106750938 A CN 106750938A CN 201611181903 A CN201611181903 A CN 201611181903A CN 106750938 A CN106750938 A CN 106750938A
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parts
resisting
wear
service life
long service
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唐亮
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Anhui Xinli Cable Material Co Ltd
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Anhui Xinli Cable Material Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Excavating Of Shafts Or Tunnels (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
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Abstract

The invention discloses the wear-resisting inexpensive long service life cable material of one kind, its raw material includes by weight:30 40 parts of polypropylene, 10 20 parts of polyvinyl chloride, 5 15 parts of epoxy resin, 12 parts of β AEEAs, 13 parts of carboxymethylcellulose calcium, 13 parts of epoxy aliphatic acid methyl ester, 26 parts of modified alta-mud, 12 parts of talcum powder, 58 parts of nano-graphene, 12 parts of castor oil, 12 parts of diisononyl phthalate, 13 parts of disproportionated rosin, 12 parts of microcrystalline wax, 12 parts of tributyl 2-acetylcitrate, 0.5 1.2 parts of phosphite ester, 0.1 0.6 parts of Masterbatch, 12 parts of antioxidant, 13 parts of antistatic additive.The present invention has more excellent fast light, heat-resisting, ageing-resistant performance, while high mechanical strength, anti-wear performance is good, with low cost.

Description

A kind of wear-resisting inexpensive long service life cable material
Technical field
The present invention relates to plastics arts, more particularly to a kind of wear-resisting inexpensive long service life cable material.
Background technology
With the increasingly raising of the development and progress and living standard of society, requirement of the people to cable is increasingly It is high.Because plastics have the advantages that light weight, not corrosion, good insulating, plastics are used in many links of cable production. But the quality of many modified plastics on the market is unstable, its anti-wear performance is not good, easily abrasion, and reduction uses the longevity Life, and high cost.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of wear-resisting inexpensive long service life cable material Material, with more excellent fast light, heat-resisting, ageing-resistant performance, while high mechanical strength, anti-wear performance is good, with low cost.
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third Alkene 30-40 parts, polyvinyl chloride 10-20 parts, epoxy resin 5-15 parts, 1-2 parts of beta-hydroxyethyl ethylenediamine, carboxymethylcellulose calcium 1-3 Part, epoxy aliphatic acid methyl ester 1-3 parts, modified alta-mud 2-6 parts, talcum powder 1-2 parts, nano-graphene 5-8 parts, castor oil 1-2 Part, diisononyl phthalate 1-2 parts, disproportionated rosin 1-3 parts, microcrystalline wax 1-2 parts, tributyl 2-acetylcitrate 1-2 parts, Phosphite ester 0.5-1.2 parts, Masterbatch 0.1-0.6 parts, antioxidant 1-2 parts, antistatic additive 1-3 parts.
Preferably, antioxidant is polyphenol antioxidant 1010, polyphenol antioxidant 1076, thioether-type phenol antioxidants and thiobis One or more compositions in phenol antioxidant.
Preferably, antistatic additive is polyethylene glycol methacrylic acid copolymer body, polyether ester amides, polyether ester acetyl One or more compositions in amine, polyethylene glycol oxide and epoxypropane copolymerization thing.
Preferably, modified alta-mud is prepared using following technique:By bentonite, cetyl trimethylammonium bromide, water, nothing Water-ethanol is mixed, filtering, is dried to obtain pretreatment bentonite;By kaolin, sodium lignin sulfonate, aliphatic alcohol polyethenoxy Ether sodium sulfate, water are well mixed, heating water bath, then carry out ultrasonic disperse, are subsequently added into graphene oxide stirring, dry, pulverize Obtain pre-processing diatomite;Polysulfone resin, N, N- dimethyl acetamides are mixed, pretreatment bentonite, pretreatment is added Diatomite is mixed, and is instilled in distilled water, and immersion, filtering, crushing obtains modified alta-mud.
Preferably, modified alta-mud is prepared using following technique:By weight by 20-30 parts of bentonite, 0.5-0.8 parts ten Six alkyl trimethyl ammonium bromides, 100-140 part water, 30-50 parts of absolute ethyl alcohol are mixed, and filtering is dried to obtain pretreatment swollen Profit soil;By weight by 20-30 parts of kaolin, 5-15 parts of sodium lignin sulfonate, 1-2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 100-140 parts of water is well mixed, heating water bath, then carries out ultrasonic disperse, is subsequently added into 0.5-1.5 parts of graphene oxide stirring, Dry, pulverize and obtain pre-processing diatomite;By weight by 2-6 parts of polysulfone resin, 5-15 parts of N, the mixing of N- dimethyl acetamides Stirring, 15-35 parts of pretreatment bentonite of addition, 40-60 parts of pretreatment diatomite are mixed, and are instilled in distilled water, are soaked, mistake Filter, crushing obtains modified alta-mud.
Preferably, modified alta-mud is prepared using following technique:By weight by 20-30 parts of bentonite, 0.5-0.8 parts ten Six alkyl trimethyl ammonium bromides, 100-140 part water, 30-50 parts of absolute ethyl alcohol mix 1-3h, and whipping temp is 65-75 DEG C, Mixing speed is 600-700r/min, filtering, and 85-95 DEG C dries 30-80min, obtains pre-processing bentonite;By weight will 20-30 parts of kaolin, 5-15 parts of sodium lignin sulfonate, 1-2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 100-140 parts of water mixing Uniformly, heating water bath 1-2h, bath temperature is 70-80 DEG C, then carries out ultrasonic disperse 20-30min, is subsequently added into 0.5-1.5 parts Graphene oxide stirs 5-15min, and mixing speed is 800-1000r/min, dry, pulverize and obtains pre-processing diatomite;By weight By 2-6 parts of polysulfone resin, 5-15 parts of N, N- dimethyl acetamides mix 2-6h to amount part, and whipping temp is 70-80 DEG C, is added 15-35 parts of pretreatment bentonite, 40-60 parts of pretreatment diatomite mix 15-35min, instill in distilled water, soak 30- 40h, filtering, crushing obtains modified alta-mud.
Preferably, polypropylene, polyvinyl chloride, epoxy resin, the weight ratio of modified alta-mud are 32-38:15-17:8-12: 3-5。
Preferably, modified alta-mud, talcum powder, the weight ratio of nano-graphene are 3-5:1.3-1.7:6-7.
The present invention is obtained using conventional fabrication process.
In pretreatment diatomite of the invention, kaolin, sodium lignin sulfonate and sodium sulfate of polyethenoxy ether of fatty alcohol according to It is secondary that by after water-bath, ultrasonication, being acted on graphene oxide, not only absorption property is good, and high temperature resistant, acid-proof alkaline are good, Itself and pretreatment bentonite, polysulfone resin, N, N- dimethyl acetamides compatibility is good, mutual good dispersion;And pre-process swollen Profit soil stabilization is good, and high mechanical strength, heat endurance is good, wherein under certain process conditions, by cetyl trimethyl bromine Changing ammonium carries out intercalation to bentonite, increases bentonite bed spacing, and adsorption area is big, coordinates pretreatment diatomite, polysulfone resin to make With, and appropriate N is added, N- dimethyl acetamides, mutual intersolubility is good, enters the high temperature resistant of modified alta-mud, resistance to acids and bases One step strengthens;The present invention using modified alta-mud and polypropylene, polyvinyl chloride, epoxy resin effect, and with epoxyfatty acid first Ester, sodium carboxymethylcellulose are used in combination, and are uniformly dispersed each other, resistance to elevated temperatures of the invention are improved, while mechanical strength Height, anti-wear performance is good;The present invention is with castor oil, diisononyl phthalate, disproportionated rosin, microcrystalline wax, acetyl lemon Sour tributyl is plasticizer, not only small toxicity, and the present invention is had more excellent fast light, heat-resisting, ageing-resistant performance;This hair Bright use modified alta-mud, talcum powder, nano-graphene are improving the present invention as filler, phosphite ester as stabilizer On the basis of mechanical property, can effective reduces cost, while assigning the present invention excellent weatherability and lustrous surface.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third 30 parts of alkene, 20 parts of polyvinyl chloride, 5 parts of epoxy resin, 2 parts of beta-hydroxyethyl ethylenediamine, 1 part of carboxymethylcellulose calcium, epoxyfatty acid 3 parts of methyl esters, 2 parts of modified alta-mud, 2 parts of talcum powder, 5 parts of nano-graphene, 2 parts of castor oil, diisononyl phthalate 1 Part, 3 parts of disproportionated rosin, 1 part of microcrystalline wax, 2 parts of tributyl 2-acetylcitrate, 0.5 part of phosphite ester, 0.6 part of Masterbatch, antioxygen 1 part of agent, 3 parts of antistatic additive.
Embodiment 2
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third 40 parts of alkene, 10 parts of polyvinyl chloride, 15 parts of epoxy resin, 1 part of beta-hydroxyethyl ethylenediamine, 3 parts of carboxymethylcellulose calcium, epoxyfatty acid 1 part of methyl esters, 6 parts of modified alta-mud, 1 part of talcum powder, 8 parts of nano-graphene, 1 part of castor oil, diisononyl phthalate 2 Part, 1 part of disproportionated rosin, 2 parts of microcrystalline wax, 1 part of tributyl 2-acetylcitrate, 1.2 parts of phosphite ester, 0.1 part of Masterbatch, polyphenol 2 parts of antioxidant 1010,1 part of epoxypropane copolymerization thing.
Modified alta-mud is prepared using following technique:By bentonite, cetyl trimethylammonium bromide, water, absolute ethyl alcohol Mix, filtering is dried to obtain pretreatment bentonite;By kaolin, sodium lignin sulfonate, AEO sulfuric acid Sodium, water are well mixed, heating water bath, then carry out ultrasonic disperse, are subsequently added into graphene oxide stirring, dry, pulverize and obtain pre- Treatment diatomite;Polysulfone resin, N, N- dimethyl acetamides are mixed, pretreatment bentonite, pretreatment diatomite is added Mix, instill in distilled water, immersion, filtering, crushing obtains modified alta-mud.
Embodiment 3
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third 32 parts of alkene, 17 parts of polyvinyl chloride, 8 parts of epoxy resin, 1.8 parts of beta-hydroxyethyl ethylenediamine, 1.5 parts of carboxymethylcellulose calcium, epoxy fat 2.5 parts of fatty acid methyl esters, 3 parts of modified alta-mud, 1.7 parts of talcum powder, 6 parts of nano-graphene, 1.8 parts of castor oil, phthalic acid 1.3 parts of dinonyl, 2.5 parts of disproportionated rosin, 1.3 parts of microcrystalline wax, 1.8 parts of tributyl 2-acetylcitrate, phosphite ester 0.8 Part, 0.5 part of Masterbatch, 1,076 1 parts of polyphenol antioxidant, 0.3 part of thioether-type phenol antioxidants, polyethylene glycol metering system 2.5 parts of sour EVA.
Modified alta-mud is prepared using following technique:By weight by 25 parts of bentonites, 0.6 part of cetyl trimethyl bromine Change ammonium, 120 parts of water, 40 parts of absolute ethyl alcohols to mix, filtering is dried to obtain pretreatment bentonite;It is high by 25 parts by weight Ridge soil, 10 parts of sodium lignin sulfonates, 1.5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 120 parts of water are well mixed, heating water bath, then Ultrasonic disperse is carried out, 1 part of graphene oxide stirring is subsequently added into, be dry, pulverize and obtained pre-processing diatomite;By weight by 4 Part polysulfone resin, 10 parts of N, N- dimethyl acetamides are mixed, and add 25 parts of pretreatment bentonites, 50 parts of pretreatment diatomite Mix, instill in distilled water, immersion, filtering, crushing obtains modified alta-mud.
Embodiment 4
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third 38 parts of alkene, 15 parts of polyvinyl chloride, 12 parts of epoxy resin, 1.2 parts of beta-hydroxyethyl ethylenediamine, 2.5 parts of carboxymethylcellulose calcium, epoxy fat 1.5 parts of fatty acid methyl esters, 5 parts of modified alta-mud, 1.3 parts of talcum powder, 7 parts of nano-graphene, 1.2 parts of castor oil, phthalic acid 1.7 parts of dinonyl, 1.5 parts of disproportionated rosin, 1.5 parts of microcrystalline wax, 1.4 parts of tributyl 2-acetylcitrate, 1 part of phosphite ester, 0.3 part of Masterbatch, 1.7 parts of thiobisphenol antioxidant, 1 part of polyether ester amides, 0.5 part of polyether ester acetamide.
Modified alta-mud is prepared using following technique:By weight by 20 parts of bentonites, 0.8 part of cetyl trimethyl bromine Change ammonium, 100 parts of water, 50 parts of absolute ethyl alcohols and mix 1h, whipping temp is 75 DEG C, and mixing speed is 600r/min, filtering, 95 DEG C 30min is dried, obtain pre-processing bentonite;By weight by 30 parts of kaolin, 5 parts of sodium lignin sulfonates, 2 parts of poly alkyl alcohols Oxygen ethene ether sodium sulfate, 100 parts of water are well mixed, and heating water bath 2h, bath temperature is 70 DEG C, then carries out ultrasonic disperse 30min, 0.5 part of graphene oxide stirring 15min is subsequently added into, mixing speed is 800r/min, dry, pulverize and obtains pre-processing diatom Soil;By weight by 6 parts of polysulfone resins, 5 parts of N, N- dimethyl acetamides mix 6h, and whipping temp is 70 DEG C, adds 35 Part pretreatment bentonite, 40 parts of pretreatment diatomite mix 35min, instill in distilled water, and immersion 30h, filtering is crushed To modified alta-mud.
Embodiment 5
The wear-resisting inexpensive long service life cable material of one kind proposed by the present invention, its raw material includes by weight:Poly- third 35 parts of alkene, 16 parts of polyvinyl chloride, 10 parts of epoxy resin, 1.5 parts of beta-hydroxyethyl ethylenediamine, 2 parts of carboxymethylcellulose calcium, epoxidised fatty 2 parts of sour methyl esters, 4 parts of modified alta-mud, 1.5 parts of talcum powder, 6.5 parts of nano-graphene, 1.5 parts of castor oil, phthalic acid two 1.5 parts of different nonyl ester, 2 parts of disproportionated rosin, 1.4 parts of microcrystalline wax, 1.6 parts of tributyl 2-acetylcitrate, 0.9 part of phosphite ester, color 0.4 part of master batch, 1,010 0.5 parts of polyphenol antioxidant, 1,076 0.5 parts of polyphenol antioxidant, 0.5 part of thiobisphenol antioxidant, poly- second 0.5 part of allyl diglycol methacrylic acid copolymer body, 0.5 part of polyethylene glycol oxide, 1 part of epoxypropane copolymerization thing.
Modified alta-mud is prepared using following technique:By weight by 30 parts of bentonites, 0.5 part of cetyl trimethyl bromine Change ammonium, 140 parts of water, 30 parts of absolute ethyl alcohols and mix 3h, whipping temp is 65 DEG C, and mixing speed is 700r/min, filtering, 85 DEG C 80min is dried, obtain pre-processing bentonite;By weight by 20 parts of kaolin, 15 parts of sodium lignin sulfonates, 1 part of fatty alcohol Polyethenoxy ether sodium sulfate, 140 parts of water are well mixed, and heating water bath 1h, bath temperature is 80 DEG C, then carries out ultrasonic disperse 20min, is subsequently added into 1.5 parts of graphene oxide stirring 5min, and mixing speed is 1000r/min, dry, pulverize and is pre-processed Diatomite;By weight by 2 parts of polysulfone resins, 15 parts of N, N- dimethyl acetamides mix 2h, and whipping temp is 80 DEG C, plus Enter 15 parts of pretreatment bentonites, 60 parts of pretreatment diatomite and mix 15min, instill in distilled water, soak 40h, filtering, powder It is broken to obtain modified alta-mud.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.

Claims (8)

1. a kind of wear-resisting inexpensive long service life cable material, it is characterised in that its raw material includes by weight:Polypropylene 30-40 parts, polyvinyl chloride 10-20 parts, epoxy resin 5-15 parts, 1-2 parts of beta-hydroxyethyl ethylenediamine, carboxymethylcellulose calcium 1-3 parts, Epoxy aliphatic acid methyl ester 1-3 parts, modified alta-mud 2-6 parts, talcum powder 1-2 parts, nano-graphene 5-8 parts, castor oil 1-2 parts, It is diisononyl phthalate 1-2 parts, disproportionated rosin 1-3 parts, microcrystalline wax 1-2 parts, tributyl 2-acetylcitrate 1-2 parts, sub- Phosphoesterase 30 .5-1.2 parts, Masterbatch 0.1-0.6 parts, antioxidant 1-2 parts, antistatic additive 1-3 parts.
2. wear-resisting inexpensive long service life cable material according to claim 1, it is characterised in that antioxidant is anti-for polyphenol One or more groups in oxygen agent 1010, polyphenol antioxidant 1076, thioether-type phenol antioxidants and thiobisphenol antioxidant Compound.
3. wear-resisting inexpensive long service life cable material according to claim 1 or claim 2, it is characterised in that antistatic additive is Polyethylene glycol methacrylic acid copolymer body, polyether ester amides, polyether ester acetamide, polyethylene glycol oxide and propylene oxide copolymer One or more compositions in compound.
4. the wear-resisting inexpensive long service life cable material according to claim any one of 1-3, it is characterised in that modified swollen Profit soil is prepared using following technique:Bentonite, cetyl trimethylammonium bromide, water, absolute ethyl alcohol are mixed, filtering, It is dried to obtain pretreatment bentonite;Kaolin, sodium lignin sulfonate, sodium sulfate of polyethenoxy ether of fatty alcohol, water are well mixed, Heating water bath, then ultrasonic disperse is carried out, graphene oxide stirring is subsequently added into, dry, pulverize and obtain pre-processing diatomite;Will be poly- Sulphone resin, N, N- dimethyl acetamides are mixed, and add pretreatment bentonite, pretreatment diatomite to mix, and are instilled and are steamed In distilled water, immersion, filtering, crushing obtains modified alta-mud.
5. the wear-resisting inexpensive long service life cable material according to claim any one of 1-4, it is characterised in that modified swollen Profit soil is prepared using following technique:By weight by 20-30 parts of bentonite, 0.5-0.8 parts of cetyl trimethylammonium bromide, 100-140 parts of water, 30-50 parts of absolute ethyl alcohol are mixed, and filtering is dried to obtain pretreatment bentonite;By weight by 20-30 Part kaolin, 5-15 parts of sodium lignin sulfonate, 1-2 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 100-140 parts of water are well mixed, Heating water bath, then ultrasonic disperse is carried out, 0.5-1.5 parts of graphene oxide stirring is subsequently added into, dry, pulverize and obtain pre-processing silicon Diatomaceous earth;By weight by 2-6 parts of polysulfone resin, 5-15 parts of N, N- dimethyl acetamides are mixed, and add 15-35 parts of pretreatment Bentonite, 40-60 part of pretreatment diatomite is mixed, and is instilled in distilled water, and immersion, filtering, crushing obtains modified alta-mud.
6. the wear-resisting inexpensive long service life cable material according to claim any one of 1-5, it is characterised in that modified swollen Profit soil is prepared using following technique:By weight by 20-30 parts of bentonite, 0.5-0.8 parts of cetyl trimethylammonium bromide, 100-140 parts of water, 30-50 parts of absolute ethyl alcohol mix 1-3h, and whipping temp is 65-75 DEG C, and mixing speed is 600-700r/ Min, filtering, 85-95 DEG C dries 30-80min, obtains pre-processing bentonite;By weight by 20-30 parts of kaolin, 5-15 parts Sodium lignin sulfonate, 1-2 part sodium sulfate of polyethenoxy ether of fatty alcohol, 100-140 parts of water are well mixed, heating water bath 1-2h, water Bath temperature is 70-80 DEG C, then carries out ultrasonic disperse 20-30min, is subsequently added into 0.5-1.5 parts of graphene oxide stirring 5- 15min, mixing speed is 800-1000r/min, dry, pulverize and obtains pre-processing diatomite;By weight by 2-6 parts of polysulfones tree Fat, 5-15 part N, N- dimethyl acetamides mix 2-6h, and whipping temp is 70-80 DEG C, add 15-35 parts of pretreatment swelling Soil, 40-60 parts of pretreatment diatomite mix 15-35min, instill in distilled water, soak 30-40h, and filtering, crushing is obtained Modified alta-mud.
7. the wear-resisting inexpensive long service life cable material according to claim any one of 1-6, it is characterised in that poly- third Alkene, polyvinyl chloride, epoxy resin, the weight ratio of modified alta-mud are 32-38:15-17:8-12:3-5.
8. the wear-resisting inexpensive long service life cable material according to claim any one of 1-7, it is characterised in that modified swollen Profit soil, talcum powder, the weight ratio of nano-graphene are 3-5:1.3-1.7:6-7.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107446261A (en) * 2017-07-31 2017-12-08 安徽新智电力科技有限公司 Benzoic cable jacket material and preparation method thereof is incorporated based on ultrasonic state
CN107731411A (en) * 2017-10-09 2018-02-23 青海欧耐特线缆有限公司 A kind of graphene electric wire and its cabling device
CN110534249A (en) * 2019-07-29 2019-12-03 安徽电缆股份有限公司 A kind of coextrusion insulated irradiation crosslinking halogen-free low-smoke flame-retardant electrical cable of long life double layer
CN111171456A (en) * 2018-11-13 2020-05-19 联泓(江苏)新材料研究院有限公司 Polypropylene composite material and preparation method thereof
CN112679851A (en) * 2020-12-24 2021-04-20 中辰电缆股份有限公司 High-performance fatigue-resistant composite cable material and preparation method thereof
CN115627013A (en) * 2022-09-08 2023-01-20 苏州博大永旺新材股份有限公司 Rice hull powder biomass-based fully-degradable material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105061932A (en) * 2015-08-05 2015-11-18 安徽电信器材贸易工业有限责任公司 Blended easily torn electric wire cable material
CN105694266A (en) * 2014-11-24 2016-06-22 郑四珍 Preparation method of cable material with excellent insulating properties and conductivity
CN105924826A (en) * 2016-05-03 2016-09-07 安徽九华金润铜业有限公司 Cold and high temperature resistant PVC cable material
CN106009374A (en) * 2016-06-16 2016-10-12 苏州杰姆斯特机械有限公司 Ageing-resistant antistatic polyvinyl chloride cable material for car and preparation method of ageing-resistant antistatic polyvinyl chloride cable material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105694266A (en) * 2014-11-24 2016-06-22 郑四珍 Preparation method of cable material with excellent insulating properties and conductivity
CN105061932A (en) * 2015-08-05 2015-11-18 安徽电信器材贸易工业有限责任公司 Blended easily torn electric wire cable material
CN105924826A (en) * 2016-05-03 2016-09-07 安徽九华金润铜业有限公司 Cold and high temperature resistant PVC cable material
CN106009374A (en) * 2016-06-16 2016-10-12 苏州杰姆斯特机械有限公司 Ageing-resistant antistatic polyvinyl chloride cable material for car and preparation method of ageing-resistant antistatic polyvinyl chloride cable material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107446261A (en) * 2017-07-31 2017-12-08 安徽新智电力科技有限公司 Benzoic cable jacket material and preparation method thereof is incorporated based on ultrasonic state
CN107731411A (en) * 2017-10-09 2018-02-23 青海欧耐特线缆有限公司 A kind of graphene electric wire and its cabling device
CN107731411B (en) * 2017-10-09 2019-04-26 青海欧耐特线缆有限公司 A kind of graphene wire and cable cabling device and its application method
CN111171456A (en) * 2018-11-13 2020-05-19 联泓(江苏)新材料研究院有限公司 Polypropylene composite material and preparation method thereof
CN110534249A (en) * 2019-07-29 2019-12-03 安徽电缆股份有限公司 A kind of coextrusion insulated irradiation crosslinking halogen-free low-smoke flame-retardant electrical cable of long life double layer
CN112679851A (en) * 2020-12-24 2021-04-20 中辰电缆股份有限公司 High-performance fatigue-resistant composite cable material and preparation method thereof
CN115627013A (en) * 2022-09-08 2023-01-20 苏州博大永旺新材股份有限公司 Rice hull powder biomass-based fully-degradable material and preparation method thereof

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