CN106366224A - 可热聚合的组合物、由此形成的组成液及其用途 - Google Patents
可热聚合的组合物、由此形成的组成液及其用途 Download PDFInfo
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- CN106366224A CN106366224A CN201610741431.2A CN201610741431A CN106366224A CN 106366224 A CN106366224 A CN 106366224A CN 201610741431 A CN201610741431 A CN 201610741431A CN 106366224 A CN106366224 A CN 106366224A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F120/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F120/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
本发明提供一种可热聚合的组合物,包含:(a)单体;(b)热起始剂;以及(c)塑化剂,其中所述单体包含单官能基丙烯酸酯类单体、多官能基丙烯酸酯类单体或其混合物。本发明亦提供一种由所述可热聚合的组合物经一无溶剂热聚合方法反应形成的组成液,其可应用于黏着、涂布或封装。
Description
技术领域
本发明是关于一种可热聚合的组合物及由此形成的组成液。本发明特别是关于一种可用于黏着、涂布或封装的组成液。
背景技术
随着信息产业快速发展,诸如移动电话、个人数字助理、笔记本电脑等电子产品已成为人们日常生活中的必需品。近年来业界更将触控面板(Touch Panel,TP)模块与显示面板模块(例如液晶模块(Liquid Crystal Module,LCM)整合),制作出可让使用者可直接在上面点选进行各项操作的触控式显示器,提供更便捷且人性化的操作模式。
为让触控式显示器更轻更薄且具有更好的视觉效果,业界不仅发展出各种迭层方式,也在贴合技术上力求突破。在贴合技术方面,全平面贴合(full lamination)使两层板之间完全被黏着剂层密合贴合,没有任何缝隙与空气,因此显示面板的背光能够比较顺利地穿透迭层,不会由于传递介质的折射率不同(玻璃保护层折射率约是1.52,空气折射率是约1)而发生折射现象,造成显示画面的亮度降低或产生迭影的情况。全平面贴合不仅能提供较高质量的画面、缩减触控式显示器整体的厚度,还可提高结合强度、耐冲击性,同时能有效降低显示面板产生的噪声对触控讯号所造成的干扰。
附图1和附图2为采用全平面贴合技术的触控式显示器贴合层示意图和剖面示意图。触控式显示器1包含触控面板10、黏着剂层12,以及显示面板20。其中,黏着剂层12包含液态光学胶(liquid optically clear adhesive,LOCA)14与可光固化之框胶16。
液态光学胶14,用来将触控面板10贴合至显示面板20上,通常具有较低黏度,才可在贴合过程中均匀流平,达到较佳的贴合性。较低黏度的液态光学胶14俗称水胶。框胶16通常具有高黏度,主要目的是用来防止液态光学胶14的溢胶情形,这在大吋面板的贴合尤其需要。框胶16还可阻挡液态光学胶14渗入液晶面板与边框之间的狭缝22,避免液晶受到污染。
进行贴合时,通常先将框胶16以边点胶边固化的方式,沿着显示面板20的边缘涂布一圈,形成一具有固定高度的阻挡墙。固化后的框胶16与显示面板20构成一可容纳液态光学胶14的凹槽。接着,将液态光学胶14以双Y字型或工字型的点胶路径涂布至凹槽内,然后进行上下面板的贴合。固化后的框胶16还可在贴合过程中,维持两面板间的固定间隙。
目前业界使用的液态光学胶14,依组成的高分子种类,可分为橡胶系和压克力系。橡胶系较早出现于市面上,包含例如聚异戊二烯(polyisoprene)、聚丁稀(polybutadiene)或聚氨酯(polyurethane)等弹性聚合物的组份,虽然具有优良的抗黄变性、弹性、高黏着力以及高折射率等优点,但原料较昂贵,重工时又容易有残胶,造成良率损失,因此总体量产成本偏高。
后来开发出的压克力系光学胶,包含例如聚丙烯酸酯(polyacrylate)的聚合物,同样具备高透明度、高黏着力、优良的抗黄变性的特点,但其原料价格较低,不留残胶易于重工,总体量产成本较低。因此,已有越来越多厂商选用压克力系黏着剂,作为贴合触控面板10与显示面板20的液态光学胶14。
目前,业界是针对不同产品与不同贴合机台的需求,开发出不同的液态光学胶14,例如具有特定介电系数或黏度范围的液态光学胶14,然后,再另外制作与液态光学胶14匹配的框胶16。
因此,为了简化制程、降低成本,并提供符合上述规格要求的液态光学胶和框胶,业界仍需一种改良的制备方法。本发明是经过广泛的研究与实验,发现利用无溶剂热聚合方法制备出各种不同黏度的黏着组合物,可分别符合液态光学胶和框胶的黏度规格,以符合环保且降低成本的要求,可有效解决先前技术中存在的问题。
发明内容
本发明首先提供一种可热聚合的组合物,其包含:
(a)单体;
(b)热起始剂;及
(c)塑化剂,
其中所述单体包含单官能基丙烯酸酯类单体、多官能基丙烯酸酯类单体或其混合物。
本发明又提供一种组成液,其是由上述的可热聚合的组合物经无溶剂热聚合方法反应而所形成。
本发明再提供一种黏着组合物,其包含上述的组成液。
上述的组成液是以无溶剂热聚合方法反应而形成,可制备出可调整黏度的黏着组合物,可应用于触控面板与显示面板,或其他材料表面之间的贴合、黏着。上述的组成液也可应用在涂布或封装材料领域中。
本发明与现有技术相比具有明显的优点和有益效果。借由上述技术方案,本发明的组成液,可以用相同的原料,分别制备出不同黏度的液态光学胶及与其匹配的框胶,至少具有下列优点:1)制程较简化且原料成本相对较低,2)制备出的液态光学胶及框胶没有兼容性问题,用于触控面板相关的涂布及贴合,可避免溢胶,并使框胶与水胶交界处不会产生界面,且3)可应用于光学组件中,例如可取代光学胶带,简化并改善现有制程并提高良率。
附图说明
所附图式是提供本发明更进一步的了解,并纳入并构成本说明书的一部分。所述附图式与说明书内容一同阐述的本发明实施例是有助于解释本发明的原理原则。在图式中:
图1为采用全平面贴合技术的触控式显示器的贴合层示意图。
图2为采用全平面贴合技术的触控式显示器的剖面示意图。
图中,1为触控式显示器,10为触控面板,20为显示面板,12为黏着剂层,12为液态光学胶,16为框胶。
应当注意的是,所有的图式皆为概略性的。为方便和在图纸上清晰起见,图式的相对尺寸和部分零件比例是以夸大或缩小规模呈现。相同的标号一般是用来于不同的实施例中指示相对应或类似的组件。
具体实施方式
在以下详细描述中,请参考附图,这些附图构成本揭露书的一部分,其中说明例示出本发明具体实施方案。这些实施方案被详细地描述以使本领域的技术人员能够实践本发明。当然,其他实施例也可以被利用,且在不脱离本发明的范围下,可以做出结构或组成上的不同变化。
因此,以下的详细描述,不应被视为具有限制意义,并且本发明的范围应由所附权利要求书所定义,其发明内容应同时考虑等效物的全部范围。
本发明首先提供一种可热聚合的组合物,包含:
(a)单体;
(b)热起始剂;以及
(c)塑化剂,
其中所述单体包含单官能基丙烯酸酯类单体、多官能基丙烯酸酯类单体或其混合物。
根据本发明一实施例,其中所述塑化剂的沸点高于所述热起始剂的热聚合引发温度。
根据本发明一实施例,其中所述塑化剂的用量以所述可热聚合的组合物总重量计不小于30%。
根据本发明一实施例,所述可热聚合的组合物中所包含的组份(a),包含丙烯酸酯类单体,其中所述丙烯酸酯类单体包含单官能基丙烯酸酯类单体、多官能基丙烯酸酯类单体或其混合物。
根据本发明一实施例,上述的单官能基丙烯酸酯类单体是选自由甲基丙烯酸甲酯(methyl methacrylate,MMA)、甲基丙烯酸丁酯、2-苯氧基乙基丙烯酸酯(2-phenoxy ethylacrylate)、乙氧化2-苯氧基乙基丙烯酸酯(ethoxylated 2-phenoxy ethyl acrylate)、2-(2-乙氧基乙氧基)乙基丙烯酸酯(2-(2-ethoxyethoxy)ethyl acrylate)、环三羟甲基丙烷甲缩醛丙烯酸酯(cyclic trimethylolpropane formal acrylate)、β-羧乙基丙烯酸酯(β-carboxyethyl acrylate)、3,3,5-三甲基环己基丙烯酸酯(3,3,5-trimethyl cyclohexaneacrylate)、邻苯基苯氧基乙基丙烯酸酯(Ortho-phenyl phenoxy ethyl acrylate)、2-(对-异丙苯基-苯氧基)-乙基丙烯酸酯(cumyl phenoxyl ethyl acrylate)、月桂酸甲基丙烯酸酯(lauryl methacrylate)、异辛基丙烯酸酯(isooctyl acrylate)、硬脂酸甲基丙烯酸酯(stearyl methacrylate)、异癸基丙烯酸酯(isodecyl acrylate)、异冰片基甲基丙烯酸酯(isoborny methacrylate)、芐基丙烯酸酯(benzyl acrylate)、2-羟基乙基甲基丙烯酸酯磷酸酯(2-hydroxyethyl metharcrylate phosphate)、己内酯基丙烯酸酯(caprolactone acrylate)、丙烯酸羟乙酯(hydroxyethyl acrylate,HEA)、甲基丙烯酸-2-羟基乙酯(2-hydroxyethyl methacrylate,HEMA)及其混合物所组成的群组。
根据本发明一实施例,上述的多官能基丙烯酸酯类单体是选自由3-羟-2,2-二甲基丙酸3-羟-2,2-二甲基丙酯二丙烯酸酯(hydroxypivalyl hydroxypivalatediacrylate)、1,6-己二醇二丙烯酸酯(1,6-hexanediol diacrylate)、乙氧化1,6-己二醇二丙烯酸酯(ethoxylated 1,6-hexanediol diacrylate)、二丙二醇二丙烯酸酯(dipropylene glycol diacrylate)、三环癸烷二甲醇二丙烯酸酯(Tricyclodecanedimethanol diacrylate)、乙氧化二丙二醇二丙烯酸酯(ethoxylated dipropyleneglycol diacrylate)、新戊二醇二丙烯酸酯(neopentyl glycol diacrylate)、丙氧化新戊二醇二丙烯酸酯(propoxylatedneopentyl glycol diacrylate)、乙氧化双酚A二甲基丙烯酸酯(ethoxylated bisphenol-A dimethacrylate)、2-甲基-1,3-丙二醇二丙烯酸酯(2-methyl-1,3-propanediol diacrylate)、乙氧化-2-甲基-1,3-丙二醇二丙烯酸酯(ethoxylated 2-methyl-1,3-propanediol diacrylate)、2-丁基-2-乙基-1,3-丙二醇二丙烯酸酯(2-butyl-2-ethyl-1,3-propanediol diacrylate)、乙二醇二甲基丙烯酸酯(ethylene glycol dimethacrylate;EGDMA)、二乙二醇二甲基丙烯酸酯(diethyleneglycol dimethacrylate)、三(2-羟乙基)异氰脲酸三丙烯酸酯(Tris(2-hydroxy ethyl)isocyanurate triacrylate)、季戊四醇三丙烯酸酯(pentaerythritol triacrylate)、乙氧化三羟甲基丙烷三丙烯酸酯(ethoxylatedtrimethylolpropane triacrylate)、丙氧化三羟甲基丙烷三丙烯酸酯(propoxylated trimethylolpropane triacrylate)、三羟甲基丙烷三甲基丙烯酸酯(trimethylolpropane trimethacrylate)、季戊四醇四丙烯酸酯(pentaerythritol tetraacrylate)、乙氧化季戊四醇四丙烯酸酯(ethoxylatedpentaerythritol tetraacrylate)、双-三羟甲基丙烷四丙烯酸酯(ditrimethylolpropanetetraacrylate)、丙氧化季戊四醇四丙烯酸酯(propoxylated pentaerythritoltetraacrylate)、二季戊四醇六丙烯酸酯(dipentaerythritol hexaacrylate)、三丙二醇二甲基丙烯酸酯(tripropylene glycol dimethacrylate)、1,4-丁二醇二甲基丙烯酸酯(1,4-butanediol dimethacrylate)、1,6-己二醇二甲基丙烯酸酯(1,6-hexanedioldimethacrylate)、烯丙基化二甲基丙烯酸环己酯(allylated cyclohexyldimethacrylate)、二甲基丙烯酸异氰脲酸酯(isocyanurate dimethacrylate)、乙氧基化三羟甲基丙烷三甲基丙烯酸酯(ethoxylatedtrimethylolpropane trimethacrylate)、丙氧基化甘油三甲基丙烯酸酯(propoxylated glycerol trimethacrylate)、三(丙烯氧乙基)异氰脲酸酯(tris(acryloxyethyl)isocyanurate)、三羟甲基丙烷三丙烯酸酯(trimethylolpropane triacrylate)及其混合物所组成的群组。
根据本发明一实施例,选用的单体为具特定黏度的胶液,其黏度在室温下(25℃)小于10,000cps,较佳小于1,000cps,优选小于100cps。
根据本发明一实施例,所述单体的用量以所述可热聚合的组合物总重量计为5%至69.99%,较佳为10%至59.99%。
根据本发明一实施例,是选用己内酯基丙烯酸酯(caprolactone acrylate)做为所述单体。
本发明提供的可热聚合的组合物中所包含的组份(a),可视需要另包含乙烯基系单体,其限制条件为乙烯基系单体不包含丙烯酸基单体。上述的乙烯基系单体可包含例如,但不限于,苯乙烯类单体、N-乙烯基单体(N-vinyl monomers),或其混合物。须注意的是,于本文中,所谓“苯乙烯类单体”是包含苯乙烯及其衍生物。
根据本发明一实施例,上述的苯乙烯类单体是选自由苯乙烯、4-氯-α-甲基苯乙烯(4-chloro-α-methylstyrene)、α-甲基苯乙烯、4-甲基苯乙烯、α-乙基苯乙烯、4-乙基苯乙烯、3-甲基苯乙烯、4-丙基苯乙烯、4-环己基苯乙烯、二乙烯基苯、3-甲氧基-α-硝基苯乙烯(3-methoxy-α-nitrostyrene)、硝基苯乙烯、氟苯乙烯、溴苯乙烯、氯苯乙烯、氯甲基苯乙烯、氨基苯乙烯(aminostyrene)、4-甲氧基苯乙烯、4-乙氧基苯乙烯、羟基苯乙烯(hydroxystyrene)、乙酰氧基苯乙烯(acetoxystyrene)、1-乙烯基萘(1-vinylnaphthalene)、2-乙烯基萘(2-vinylnaphthalene)、4-十二烷基苯乙烯、2-乙基-4-苯甲基苯乙烯、4-(苯基丁基)苯乙烯及其组合所组成的群组。较佳系使用低极性之苯乙烯类单体,其实例包含:苯乙烯、α-甲基苯乙烯、4-甲基苯乙烯、α-乙基苯乙烯、4-乙基苯乙烯、3-甲基苯乙烯、4-丙基苯乙烯,4-十二烷基苯乙烯、4-甲氧基苯乙烯、4-乙氧基苯乙烯及其混合物所组成的群组。根据本发明的一较佳实施例,是使用苯乙烯做为乙烯基系单体。
根据本发明一实施例,上述的N-乙烯基单体(N-vinyl monomers)是选自由N-乙烯基咔唑(N-vinylcarbazole),N-乙烯基吲哚衍生物(N-vinylindole derivatives),N-乙烯基吡咯烷酮(N-vinylpyrrolidone),N-乙烯基己内酰胺(N-vinylcaprolactam),N-乙烯基甲酰胺(N-vinylformamide),N-乙烯基乙酰胺衍生物(N-vinylacetoamide derivatives),N-乙烯基(NA)邻苯二甲酰亚胺(N-vinyl(na)phthalimides),N-乙烯基咪唑盐(N-vinylimidazolium salts),N-乙烯基三唑(N-vinyltriazoles)及其混合物所组成的群组。
根据本发明一实施例,当所述可热聚合的组合物中所包含的组份(a)另包含乙烯基系单体时,其中的丙烯酸酯类单体和乙烯基系单体加入反应器的顺序并无特殊限制,可一同加入或分开加入反应器进行热聚合反应。
本发明提供的可热聚合的组合物中所包含的组份(b)可为热分解型起始剂,但并不限于此。根据本发明一实施例,上述的热起始剂是选自由过氧化苯(Benzoyl peroxide)、过氧化氢异丙苯(Cumyl hydroperoxide)、过氧化二异丙苯(Dicumyl peroxide)、第三丁基过氧化氢(tert-Butyl hydroperoxide)、过氧化第三丁基顺丁烯二酸(tert-Butylmonoperoxymaleate)、二乙酰过氧化物(acetyl peroxide)、月桂酰过氧化物(Dilauroylperoxide)、上述过氧化物中一或多者与胺酸(amino acid)或磺酸(sulfonic acid)的混合物、上述过氧化物中一或多者与含钴化合物的混合物、偶氮二异丁腈(AIBN)及上述物质的混合物所组成的群组。
本发明的热起始剂的用量并无特殊限制,可依据选用的单体种类及用量,和预订达到的聚合度,视需要进行调整。根据本发明的一实施例,所述热起始的用量以所述可热聚合的组合物的总重量计为0.001%至5%。根据本发明的一实施例,所述热起始的分解温度(引发温度)约是-10℃至200℃。
根据本发明的一实施例,是选用月桂酰过氧化物作为所述热起始剂,其分解温度约是70℃至80℃。
本发明提供的可热聚合的组合物中所包含的组份(c)塑化剂,需具备耐高温、不易挥发的特性,且所述塑化剂的沸点高于所述热起始剂的热聚合引发温度。更进一步优选条件为塑化剂的沸点及裂解温度高于热起始剂的热聚合引发温度,以避免塑化剂发生沸腾或裂解。本发明的塑化剂是取代传统有机溶剂,作为热聚合反应的介质。以塑化剂取代传统有机溶剂,可免除溶剂热聚合反应中溶剂逸散和后续从产物中去除有机溶剂的步骤。由于不需要额外的处理、回收步骤,较符合环保与降低成本的要求。
本发明的塑化剂的用量必须足够,才可均匀混合组成单体和热起始剂,促进聚合反应,以及避免反应过程中黏度过高造成反应或散热不均匀的问题。根据本发明一实施例,所述塑化剂的用量以所述可热聚合的组合物的总重量计,为30%至95%,较佳为40%至90%。
根据本发明一实施例,所述塑化剂是选自由邻苯二甲酸酯、脂肪族二元酸酯、磷酸酯、苯多酸酯、芴系二酯(fluorene-containing diester)、烷基磺酸酯、多元醇酯、环氧化合物及其混合物所组成的群组。根据本发明一较佳实施例,塑化剂是选自邻苯二甲酸酯、磷酸酯及其混合物所组成的群组。
上述的邻苯二甲酸酯较佳为邻苯二甲酸二甲酯(C6H4(COOCH3)2)、邻苯二甲酸二乙酯(C6H4(COOC2H5)2)、邻苯二甲酸二丙烯酯(C6H4(COOCH2CH=CH2)2)、邻苯二甲酸二丙酯(C6H4(COOCH2CH2CH3)2)、邻苯二甲酸二丁酯(C6H4[COO(CH2)3CH3]2)、邻苯二甲酸二异丁酯(C6H4[COOCH2CH(CH3)2]2)、邻苯二甲酸二戊酯(C6H4[COO(CH2)4CH3]2)、邻苯二甲酸二环己酯(C6H4(COOC6H11)2)、邻苯二甲酸丁酯苯甲酯(CH3(CH2)3OOCC6H4COOCH2C6H5)、邻苯二甲酸二己酯(C6H4[COO(CH2)5CH3]2)、邻苯二甲酸二异庚酯(C6H4[COO(CH2)4CH(CH3)2]2)、邻苯二甲酸二(2-乙基)己酯(C6H4[COOCH2CH(C2H5)(CH2)3CH3]2)、邻苯二甲酸二正辛酯(C6H4[COO(CH2)7CH3]2)、邻苯二甲酸二异辛酯(C6H4[COO(CH2)5CH(CH3)2]2)、邻苯二甲酸二异壬酯(C6H4[COO(CH2)6CH(CH3)2]2)、邻苯二甲酸二异癸酯(C6H4[COO(CH2)7CH(CH3)2]2)、邻苯二甲酸双十一烷基酯(C6H4[COO(CH2)10CH3]2)或其混合物;更佳为邻苯二甲酸二甲酯(C6H4(COOCH3)2)、邻苯二甲酸二乙酯(C6H4(COOC2H5)2)、邻苯二甲酸二丙烯酯(C6H4(COOCH2CH=CH2)2)、邻苯二甲酸丁酯苯甲酯(CH3(CH2)3OOCC6H4COOCH2C6H5)、邻苯二甲酸二异壬酯(C6H4[COO(CH2)6CH(CH3)2]2)及其混合物所组成的群组。
上述的磷酸酯较佳是选自由磷酸三苯酯(triphenyl phosphate(TPP))、磷酸三甲苯酯(tricresyl phosphate(TCP))、磷酸三异丙基苯酯(tri(isopropylphenyl)phosphate)、磷酸甲苯二苯酯(cresyl diphenyl phosphate)、间苯二酚四苯基二磷酸酯(tetraphenyl resorcinol diphosphate)、双酚A双(二苯基磷酸酯)(tetraphenyl 4,4'-(propane-2,2-diyl)bis(4,1-phenylene)diphosphate)及其混合物所组成的群组。
根据本发明一较佳实施例,选用的塑化剂为双酚A双(二苯基磷酸酯),折射率约1.6,其结构式如下:
本发明又提供一种组成液,其是由上述的可热聚合的组合物经一无溶剂热聚合方法反应所形成。
本发明所述的无溶剂热聚合方法,包含下列步骤:
(1)在一脱氧环境下,于一反应器中提供一单体与一塑化剂,搅拌并加热至一预定温度,形成第一溶液;
(2)将一含热起始剂的第二溶液,在一脱氧环境下滴入所述反应器中,与第一溶液混合,形成一可热聚合的组合物;以及
(3)使所述可热聚合的组合物在所述热起始剂的引发下进行一热聚合反应,形成组成液。
适用于所述无溶剂热聚合方法的单体、热起始剂和塑化剂的物质可参考前文,故不再赘述。
上述步骤(1)的预定温度是取决于单体和热起始剂的搭配。根据本发明实施例,所述预定温度介于80℃~300℃之间。根据本发明一较佳实施例,上述步骤(1)的塑化剂的用量以第一溶液总重量计不小于40%。
上述步骤(2)中,可预先将热起始剂溶解于另一部分的单体或塑化剂,以形成含热起始剂的第二溶液,目的是便于滴入反应器中。所述的热起始剂为容易受热分解成自由基(即初级自由基)的化合物,例如但不限制于热分解型或氧化还原分解型,可为任何本发明所属技术领域中具有通常知识者所熟知者,其例如可为过氧化物或偶氮化物。
上述步骤(3),由所述热起始剂引发所述可热聚合的组合物中的单体进行热聚合反应而形成聚合物。所述组成液包含聚合物和塑化剂。
上述步骤(3),于热聚合反应后,塑化剂的含量以反应器中组成液的总重量计不小于30%。
根据本发明一实施例,上述组成液的黏度可介于1,000cps到2,000,000cps之间,较佳为1,500cps到250,000cps之间。
本发明再提供一种黏着组合物,其包含上述的组成液。详言之,本发明提供的黏着组合物包含:
(i)组成液;
(ii)单官能基单体、多官能基单体或其混合物;
(iii)光起始剂;以及
(iv)第二塑化剂。
根据本发明一实施例,组份(i)的组成液,其为聚合物和塑化剂的组成液,其用量以所述黏着组合物总重量计为20%至90%,较佳为40至85%,更佳为50%至80%。
根据本发明一实施例,适量的组份(ii)可用以稀释黏着组合物黏度,制备出符合不同产品需求的黏着组合物,应用范围较广泛。
根据本发明一实施例,所述黏着组合物所包含的组份(ii)中的单官能基单体或多官能基单体是选自由2-苯氧基乙基丙烯酸酯(2phenoxy ethyl acrylate)、月桂酸甲基丙烯酸酯(lauryl methacrylate)、异癸基丙烯酸酯(isodecyl acrylate)、异冰片基甲基丙烯酸酯(isoborny methacrylate)、三羟甲基丙烷三甲基丙烯酸酯(trimethylolpropanetrimethacrylate)、季戊四醇四丙烯酸酯(pentaerythritol tetraacrylate)、乙氧基化三羟甲基丙烷三甲基丙烯酸酯(ethoxylated trimethylol propane trimeth acrylate)、丙氧基化甘油三甲基丙烯酸酯(propoxylated glycerol trimethacrylate)、三羟甲基丙烷三丙烯酸酯(trimethylolpropane triacrylate)及其混合物所组成的群组。
可用于本发明的市售单官能基单体或多官能基单体包括:由Eternal公司生产,商品名为EM223、EM328、EM2308、EM231、EM219、EM90、EM70、EM235、EM2381、EM2382、EM2383、EM2384、EM2385、EM2386、EM2387、EM331、EM3380、EM241、EM2411、EM242、EM2421或EM265等。
根据本发明一实施例,所述单官能基单体或多官能基单体的用量以所述黏着组合物的总重量计为5%至80%,较佳为5%至40%,更佳为5%至30%。
所述黏着组合物所包含的组份(iii)的光起始剂并无特殊限制,是经光照射后会产生自由基(free radical),而透过自由基起始聚合反应者。光起始剂的用量,可视需要依所述黏着组合物中包含的单体/聚合物的种类及用量进行调整。一般而言,光起始剂的用量以所述黏着组合物总重量计为0.1至5%,较佳为0.5至3%。
根据本发明一实施例,适用于所述黏着组合物的光起始剂,可包含,但不限于,二苯甲酮(benzophenone)、二苯乙醇酮(benzoin)、2-羟基-2-甲基-1-苯基丙-1-酮(2-hydroxy-2-methyl-1-phenyl-propan-1-one)、2,2-二甲氧基-1,2-二苯基乙-1-酮(2,2-dimethoxy-1,2-diphenylethan-1-one)、1-羟基环己基苯基酮(1-hydroxy cyclohexylphenyl ketone)、2,4,6-三甲基苯甲酰基二苯基膦氧化物(2,4,6-trimethylbenzoyldiphenyl phosphine oxide),或它们的混合物。根据本发明一较佳实施例,选用的光起始剂是为二苯甲酮、1-羟基环己基苯基酮,或者为2,4,6-三甲基苯甲酰基二苯基膦氧化物。
所述黏着组合物所包含的组份(iv)的第二塑化剂的种类是为本发明所属技术领域中具有通常知识者所熟知,可与前述的可热聚合之组合物所包含的组份(c)的塑化剂可相同或不同。根据本发明一实施例,所述第二塑化剂是选自由邻苯二甲酸酯、脂肪族二元酸酯、磷酸酯、苯多酸酯、烷基磺酸酯、多元醇酯、环氧化合物及其混合物所组成的群组。根据本发明一较佳实施例,所述第二塑化剂是选自由邻苯二甲酸酯、磷酸酯及其混合物所组成的群组。
根据本发明一实施例,所述第二塑化剂的用量以所述黏着组合物的总重量计为约1至约60%,较佳约为5至约50%,更佳约为10至约40%。
本发明其中一项应用,例如所述黏着组合物是做为贴合触控面板与显示面板的液态光学胶(LOCA)时,所述黏着组合物所包含的塑化剂及第二塑化剂,还具有调整所述黏着组合物折射率的功能。根据本发明一实施例,可选用具有1.48以上折射率的塑化剂及第二塑化剂,帮助所述黏着组合物在固化后具有与玻璃较相近的折射率。另外,塑化剂及第二塑化剂还可增加黏着组合物固化后的柔软度和可挠性。
本发明提供的黏着组合物可视需要包含任何熟悉此项技术者已知的添加剂,其例如但不限于共起始剂(synergist)、增敏剂(sensitizer)、偶合剂、分散剂(dispersingagent)、润湿剂、增稠剂(thickening agent)、消泡剂、链转移剂(chain transfer agent)、抗黄变剂或摇变剂等。
本发明提供的黏着组合物,或包含上述的聚合物的胶液,可应用于黏着、涂布或封装的材料领域。常见的应用为例如,但不限于,液态光学胶(LOCA)、感压胶(PSA)、可剥胶(stripper)。本发明可藉由简单的制程,得到黏度范围广泛的黏着组合物或胶液,符合不同应用的需求。
本发明提供的黏着组合物可使用任何本发明所属技术领域中具有通常知识者所熟知的方法,涂布于一组件上,并与另一组件进行贴合,随后照射能量射线加以固化。举例言之,可使用本发明的黏着组合物将触控面板中作为传感器用的ITO膜或ITO玻璃与玻璃基板或保护盖板(cover lens)贴合,或将作为传感器用的ITO膜或ITO玻璃与另一ITO膜或ITO玻璃贴合,或将触控面板与LCD面板模块贴合。
实施例
名词表
测试方法:
黏度:以Brookfield LV黏度计,在25℃下测试组成液的黏度。
测试结果:
上述所得的测试结果纪录于表1-3。
实施例a1~a8
实施例a1
根据以下步骤进行操作:
1.制备第一溶液:反应槽中加入200g单体a与250g塑化剂d,充分混合后,进行除氧脱泡接着加热升温至120℃。
2.制备第二溶液:50g单体a与0.2g热起始剂i充分混合后进行除氧脱泡。
3.之后滴加入第二溶液于反应槽中,滴加速度控制在0.1-5.0cc/min,滴加完成后再反应0.5-4.0hr后中止反应。
实施例a2~a8
根据以下描述的方式制备实施例a2~a8的可热聚合的组合物。其操作步骤如实施例a1的方法,惟组成是如表1所列进行调整。
表1
由实施例a1-a3可知组份中起始剂浓度越高,所得到聚合物和塑化剂的组成液黏度也越高。由实施例a1、a8可知组份中选用不同种类单体皆可实施本发明的制备方法得到所述组成液。由实施例a2、a4、a5可知组份中不同种类塑化剂皆可制备本发明的组成液。由实施例a6、a7可知将各组份等比例放大仍可制备本发明的组成液。
实施例b1~b12
实施例b1
根据以下步骤进行操作:
1.制备第一溶液:反应槽中加入150g单体c与300g塑化剂f,充分混合后,进行除氧脱泡接着加热升温至120℃。
2.制备第二溶液:300g单体c与0.06g热起始剂i充分混合后进行除氧脱泡。
3.之后滴加入第二溶液于反应槽中,滴加速度控制在0.1-5.0cc/min,滴加完成后再反应0.5-4.0hr后中止反应。
实施例b2~b12
根据以下描述的方式制备实施例b2~b12的可热聚合的组合物。其操作步骤如实施例b1的方法,惟组成是如表2所列进行调整。
表2
由实施例b1-b3可知组份中起始剂浓度越高所得到的组成液黏度也越高。由实施例b4-b7可知组份中所添加起始剂浓度越高所得到的组成液黏度也越高。由实施例b1、b7、b8可知组份中所反应槽单体量(浓度)越低所得到的组成液黏度越高。由实施例b10、b11可知反应物总量与所添入起始剂浓度相同条件下,反应槽单体量越多黏度越高。
实施例c1~c4
实施例c1
根据以下步骤进行操作:
1.制备第一溶液:反应槽中加入100g单体a,100g单体b与250g塑化剂d,充分混合后,进行除氧脱泡接着加热升温至120℃。
2.制备第二溶液:25g单体a,25g单体b与与0.1g热起始剂i充分混合后进行除氧脱泡。
3.之后滴加入第二溶液于反应槽中,滴加速度控制在0.1-5.0cc/min,滴加完成后再反应0.5-4.0hr后中止反应。
实施例c2~c4
根据以下描述的方式制备实施例c2~c4的可热聚合之组合物。其操作步骤如实施例c1的方法,惟组成是如表3所列进行调整。
表3
由实施例c1-c3可知组份中选用不同种类塑化剂皆可本发明的制备方法得到所述组成液。由实施例a1、c1、c4可知组份中无论选择单种、两种或三种单体的混合皆可制备本发明的组成液。
根据上述本发明提供的无溶剂热聚合方法,可以用相同的原料,分别制备出不同黏度的液态光学胶及与其匹配的框胶,应用于光学组件中。比起习知的方法,不仅制程较简化,而且制备出的液态光学胶及框胶没有兼容性问题,同时具有相近的折射率等光学特性。本发明提供的无溶剂热聚合方法以单体(monomer)为起始原料,比起习知方法中使用寡聚物(oligomer)作为起始原料,成本也相对较低。
本发明提供的无溶剂热聚合方法,不仅具有简化的步骤、较低制作成本的特点,还可得到黏度范围广泛的产物胶液,可符合贴合、涂布或封装领域中不同的需求。
以上所述仅为本发明的较佳实施例,凡依本发明申请专利范围所做的均等变化与修饰,皆应属本发明的涵盖范围。
Claims (10)
1.一种可热聚合的组合物,其特征在于,包含:
(a)单体;
(b)热起始剂;以及
(c)塑化剂,
其中所述单体包含单官能基丙烯酸酯类单体、多官能基丙烯酸酯类单体或其混合物。
2.如权利要求1所述的可热聚合的组合物,其特征在于,其中所述塑化剂的沸点高于所述热起始剂的热聚合引发温度。
3.如权利要求1所述的可热聚合的组合物,其特征在于,其中所述塑化剂的用量以所述可热聚合的组合物的总重量计不小于30%。
4.如权利要求1所述的可热聚合的组合物,其特征在于,其中所述塑化剂选自由邻苯二甲酸酯、脂肪族二元酸酯、磷酸酯、苯多酸酯、芴系二酯、烷基磺酸酯、多元醇酯、环氧化合物及其混合物所组成的群组。
5.如权利要求4所述的可热聚合的组合物,其特征在于,其中所述磷酸酯选自由磷酸三苯酯、磷酸三甲苯酯、磷酸三异丙基苯酯、磷酸甲苯二苯酯、间苯二酚四苯基二磷酸酯、双酚A双(二苯基磷酸酯)及其混合物所组成的群组。
6.如权利要求1所述的可热聚合的组合物,其特征在于,其中所述热起始剂选自由过氧化苯、过氧化氢异丙苯、过氧化二异丙苯、第三丁基过氧化氢、过氧化第三丁基顺丁烯二酸、二乙酰过氧化物、月桂酰过氧化物、偶氮二异丁腈及其混合物所组成的群组。
7.如权利要求1所述的可热聚合的组合物,其特征在于,其中所述单体另包含乙烯基系单体,其限制条件为乙烯基系单体不包含丙烯酸基单体。
8.一种组成液,其是由权利要求1至7中任一项所述的可热聚合的组合物经无溶剂热聚合方法反应所形成。
9.如权利要求8所述的组成液,其特征在于,其中所述无溶剂热聚合方法,包含下列步骤:
在一脱氧环境下,于一反应器中提供单一单体与一塑化剂,搅拌并加热至一预定温度,形成一第一溶液;
将一含热起始剂的第二溶液,在一脱氧环境下,滴入所述反应器中,与所述第一溶液混合形成一可热聚合之组合物;以及
使所述可热聚合之组合物在所述热起始剂的引发下进行一热聚合反应,形成所述组成液。
10.一种黏着组合物,其包含如权利要求8至9中任一项所述的组成液。
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CN111073525A (zh) * | 2019-12-31 | 2020-04-28 | 道生天合材料科技(上海)有限公司 | 一种低模量柔性丙烯酸酯胶粘剂及其制备方法 |
CN111826090A (zh) * | 2020-01-16 | 2020-10-27 | 东莞市派乐玛新材料技术开发有限公司 | 一种无界线全贴合框胶、无界线全贴合面胶和显示面板 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4298519A (en) * | 1978-05-30 | 1981-11-03 | Akzo N.V. | Plasticizer-containing thermocurable composition |
EP0219857B1 (en) * | 1985-10-25 | 1992-01-08 | W.R. Grace & Co.-Conn. | Storage stable (meth)acrylate plastisols |
KR20100047090A (ko) * | 2008-10-27 | 2010-05-07 | 임진익 | 경조직 포매용 아크릴 레진의 조성 |
CN101939391A (zh) * | 2007-12-28 | 2011-01-05 | E.I.内穆尔杜邦公司 | 可热固化和光化固化的粘合剂组合物 |
CN102153953A (zh) * | 2010-12-31 | 2011-08-17 | 长兴化学工业股份有限公司 | 可光固化的粘着组合物 |
CN102898962A (zh) * | 2012-08-01 | 2013-01-30 | 长兴化学工业股份有限公司 | 双固化粘着组合物 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3862021A (en) * | 1972-02-17 | 1975-01-21 | Asahi Chemical Ind | Polymerizable compositions and laminated articles bonded |
US4605465A (en) * | 1982-04-26 | 1986-08-12 | W. R. Grace & Co. | UV and thermally curable, thermoplastic-containing compositions |
DE3739690A1 (de) * | 1987-11-24 | 1989-06-08 | Hoechst Ag | Stabilisierte arzneistoffe, verfahren zu ihrer herstellung sowie stabile arzneizubereitungen |
US7968661B2 (en) * | 2005-12-28 | 2011-06-28 | 3M Innovative Properties Company | Method of free radically polymerizing vinyl monomers |
BRPI0822882A2 (pt) * | 2008-06-11 | 2015-07-07 | Denki Kagaku Kogyo Kk | Composição curável |
CN102300888B (zh) * | 2008-12-17 | 2014-09-17 | 3M创新有限公司 | 含有机硅的共聚物的本体聚合 |
JP5648494B2 (ja) * | 2011-01-25 | 2015-01-07 | 住友化学株式会社 | 粘着剤シート、粘着剤付き光学フィルム及び光学積層体 |
-
2015
- 2015-12-31 TW TW104144787A patent/TWI668285B/zh active
-
2016
- 2016-08-25 US US15/246,553 patent/US20170190877A1/en not_active Abandoned
- 2016-08-26 CN CN201610741431.2A patent/CN106366224B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4298519A (en) * | 1978-05-30 | 1981-11-03 | Akzo N.V. | Plasticizer-containing thermocurable composition |
EP0219857B1 (en) * | 1985-10-25 | 1992-01-08 | W.R. Grace & Co.-Conn. | Storage stable (meth)acrylate plastisols |
CN101939391A (zh) * | 2007-12-28 | 2011-01-05 | E.I.内穆尔杜邦公司 | 可热固化和光化固化的粘合剂组合物 |
KR20100047090A (ko) * | 2008-10-27 | 2010-05-07 | 임진익 | 경조직 포매용 아크릴 레진의 조성 |
CN102153953A (zh) * | 2010-12-31 | 2011-08-17 | 长兴化学工业股份有限公司 | 可光固化的粘着组合物 |
CN102898962A (zh) * | 2012-08-01 | 2013-01-30 | 长兴化学工业股份有限公司 | 双固化粘着组合物 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073525A (zh) * | 2019-12-31 | 2020-04-28 | 道生天合材料科技(上海)有限公司 | 一种低模量柔性丙烯酸酯胶粘剂及其制备方法 |
CN111826090A (zh) * | 2020-01-16 | 2020-10-27 | 东莞市派乐玛新材料技术开发有限公司 | 一种无界线全贴合框胶、无界线全贴合面胶和显示面板 |
CN111826090B (zh) * | 2020-01-16 | 2022-06-03 | 东莞市派乐玛新材料技术开发有限公司 | 一种无界线全贴合框胶、无界线全贴合面胶和显示面板 |
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