CN106350942A - Bacteriostatic nonwovens capable of continuously releasing negative oxygen ions and preparation method thereof - Google Patents
Bacteriostatic nonwovens capable of continuously releasing negative oxygen ions and preparation method thereof Download PDFInfo
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- CN106350942A CN106350942A CN201610688881.XA CN201610688881A CN106350942A CN 106350942 A CN106350942 A CN 106350942A CN 201610688881 A CN201610688881 A CN 201610688881A CN 106350942 A CN106350942 A CN 106350942A
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
- D06M15/09—Cellulose ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a bacteriostatic nonwovens capable of continuously releasing negative oxygen ions and a preparation method thereof. The bacteriostatic nonwovens capable of continuously releasing negative oxygen ions is characterized by being prepared from, by weight, 1-2 parts of carboxymethyl chitosan zinc, 4-8 parts of nano-sized tourmaline powder, 1-2 parts of gelatin powder, 5-10 parts of polylactic acid, 1-2 parts of polyethylene glycol 200, 3-5 parts of activated carbon, 1-2 parts of kaolin, 4-8 parts of peppermint essence, 50-70 parts of isotatic polypropylene, 3-6 parts of kieselguhr, 1-2 parts of sodium dodecyl sulfate, a proper amount of carboxymethyl cellulose sodium and a proper amount of water. The addition of the nano-sized tourmaline powder in the nonwovens can achieve the effects of continuously releasing negative oxygen ions, when the nonwovens is applied to automotive interior, the in-vehicle space makes people feel cool, comfortable and refreshing, and the refreshing effect is remarkable due to the match of peppermint essence; coordinated with the added carboxymethyl chitosan zinc, the nonwovens can effectively inhibit the growth of bacteria.
Description
Technical field
The present invention relates to a kind of non-woven fabrics and preparation method thereof and in particular to a kind of can continuous releasing negative oxygen ion nonwoven
Cloth and preparation method thereof.
Background technology
Non-woven fabrics are a kind of non-weaving cloths, and it is directly to utilize high polymer section, chopped fiber or long filament that fiber is passed through gas
Stream or machinery become net, are then passed through spun lacing, acupuncture, or hot rolling and reinforce, and eventually pass the cloth of the no braiding of Final finishing formation.Tool
There is the tencel product of softness, ventilative and planar structure, advantage is not produce Soft flocks, tough, durable, as soft as silk,
It is one kind of reinforcing material, and the sensation of also cotton, have been widely used for automotive field.But stay in confined space for a long time
Interior, people can think that dizzy brain rises, and when coming the place such as forest seashore, waterfall, we can feel spirit and QI cleaning, and this is just
It is the effect of negative aeroion.Negative aeroion is also negative oxygen ion, refer to obtain excess electron and negatively charged oxygen from
Son.
Jiang Yinggang, in " preparation of liner cloth containing bamboo charcoal powder and Study on adsorption properties ", using bamboo charcoal powder and non-weaving cloth, leads to
The method such as cross coating, pad, making multiple nonwoven interlinings containing bamboo charcoal powder.However, when it is applied to automotive trim, also existing
And be not provided that negative oxygen ion, refrigerant fragrance etc. of refreshing oneself can not be discharged be conducive to traffic safety and driving comfortable space is provided
Weak point.
Content of the invention
Consideration more than synthesis, the present invention provides a kind of non-woven fabrics and its formula it is therefore intended that solving when non-woven fabrics application
It is impossible to continuous releasing negative oxygen ion when automotive trim, provide the defect of more preferable interior space.
For achieving the above object, technical scheme is as follows:
A kind of antibacterial, can continuous releasing negative oxygen ion non-woven fabrics it is characterised in that being made up of the raw material of following weight portion:
Carboxymethyl chitosan zinc 1-2, nano-tourmaline powder 4-8, jelly powder 1-2, polylactic acid 5-10, polyethylene glycol 200 1-2, live
Property charcoal 3-5, Kaolin 1-2, Mint Essence 4-8, isotactic polypropylene 50-70, kieselguhr 3-6, dodecyl sodium sulfate 1-2, hydroxyl
Appropriate sodium carboxymethylcellulose pyce, appropriate amount of water;
Described a kind of antibacterial, can continuously non-woven fabrics of releasing negative oxygen ion and preparation method thereof it is characterised in that by following
Step is made:
A., at 150-200 DEG C, nano-tourmaline powder is added in polylactic acid, adds polyethylene glycol 200, stir,
So that tourmaline powder is evenly spread in polylactic acid, and make polylactic acid be wrapped in nano-tourmaline powder surface, form microsphere, filter simultaneously
Dry;
B. activated carbon and jelly powder are added in water and are uniformly dispersed, be then added to Mint Essence, continue dispersion, point
Proceed to standing 3-5h under vacuumized conditions after dissipating uniformly, by centrifugation, be dried, milled processed obtains the work that is loaded with Mint Essence
Property powdered carbon and gelatin powder mixture;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and are melted, then
Non-woven fabrics are obtained after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr, Kaolin are added to the water, are stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into
Carboxymethyl cellulose sodium and carboxymethyl chitosan zinc, adjust modest viscosity, prepared serosity;Step c gained non-woven fabrics are soaked completely
Not in serosity, and put into ultrasonic 5-10min in ultrasonic oscillator, take out, using the method for " two leachings two are rolled ", fully soak
Not yet, use padder mangle, again submergence, after then using padder mangle, put into baker, bakee 2-5min, take out.
Described a kind of antibacterial, can continuously non-woven fabrics of releasing negative oxygen ion and preparation method thereof it is characterised in that step
Described in rapid b, curer stoving temperature is 70-110 DEG C.
The invention has the beneficial effects as follows: add nano-tourmaline powder in non-woven fabrics, can reach continuous discharge negative oxygen from
The effect of son, when being applied to automotive trim, can make interior space refrigerant comfortable, spirit and QI cleaning, Mint Essence of arranging in pairs or groups, effect of refreshing oneself
Fruit is notable, reduces and contained the harm of fatigue driving;Wrap up nano-tourmaline powder using polylactic acid, not only prevent nanometer
Tourmaline powder broken and coming off, and promote tourmaline powder and close and dispersion with the appearance of polypropylene substrate, polylactic acid tool simultaneously
There are excellent breathability, oxygen permeability, and antibacterial and anti-mildew characteristic, improve the fungus resistance of non-woven fabrics, extend service life;With
Activated carbon, to load Mint Essence, increased loading and the air contact area of Mint Essence, reaches more lasting release
Effect, has been simultaneously introduced the characterization of adsorption of activated carbon, increases the function of non-woven fabrics clean air;With kieselguhr serosity to non-woven fabrics
Carry out coating, can effectively remove harmful substance and house pet body odor, the rubbish institutes such as the free formaldehyde of in the air, benzene, ammonia, voc
The abnormal flavour producing, comprehensively solve in-vehicle air pollution is hence it is evident that improve environment inside car;The carboxymethyl chitosan zinc that cooperation is added is permissible
Effectively suppression bacteria breed.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.
Embodiment
A kind of antibacterial, can continuous releasing negative oxygen ion non-woven fabrics it is characterised in that raw material system by following weight portion
Become:
Carboxymethyl chitosan zinc 2, nano-tourmaline powder 8, jelly powder 2, polylactic acid 10, polyethylene glycol 200 2, activated carbon 5, kaolinite
Soil 2, Mint Essence 8, isotactic polypropylene 70, kieselguhr 6, dodecyl sodium sulfate 2, appropriate Carboxymethyl cellulose sodium, appropriate amount of water;
Described a kind of antibacterial, can continuously non-woven fabrics of releasing negative oxygen ion and preparation method thereof it is characterised in that by following
Step is made:
A., at 150-200 DEG C, nano-tourmaline powder is added in polylactic acid, adds polyethylene glycol 200, stir,
So that tourmaline powder is evenly spread in polylactic acid, and make polylactic acid be wrapped in nano-tourmaline powder surface, form microsphere, filter simultaneously
Dry;
B. activated carbon and jelly powder are added in water and are uniformly dispersed, be then added to Mint Essence, continue dispersion, point
Proceed to standing 3-5h under vacuumized conditions after dissipating uniformly, by centrifugation, be dried, milled processed obtains the work that is loaded with Mint Essence
Property powdered carbon and gelatin powder mixture;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and are melted, then
Non-woven fabrics are obtained after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr, Kaolin are added to the water, are stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into
Carboxymethyl cellulose sodium and carboxymethyl chitosan zinc, adjust modest viscosity, prepared serosity;Step c gained non-woven fabrics are soaked completely
Not in serosity, and put into ultrasonic 5-10min in ultrasonic oscillator, take out, using the method for " two leachings two are rolled ", fully soak
Not yet, use padder mangle, again submergence, after then using padder mangle, put into baker, bakee 2-5min, take out.
Described a kind of antibacterial, can continuously non-woven fabrics of releasing negative oxygen ion and preparation method thereof it is characterised in that step
Described in rapid b, curer stoving temperature is 70-110 DEG C.
The technical parameter of the present invention is:
Formaldehyde absorbing rate >=11.09% of Unit Weight non-woven fabrics, benzene adsorption rate >=14.83%, tvoc adsorption rate >=13.42%.
Claims (3)
1. a kind of antibacterial, can continuous releasing negative oxygen ion non-woven fabrics it is characterised in that raw material system by following weight portion
Become:
Carboxymethyl chitosan zinc 1-2, nano-tourmaline powder 4-8, jelly powder 1-2, polylactic acid 5-10, polyethylene glycol 200 1-2, live
Property charcoal 3-5, Kaolin 1-2, Mint Essence 4-8, isotactic polypropylene 50-70, kieselguhr 3-6, dodecyl sodium sulfate 1-2, hydroxyl
Appropriate sodium carboxymethylcellulose pyce, appropriate amount of water.
2. according to claim 1 a kind of antibacterial, can continuous non-woven fabrics of releasing negative oxygen ion and preparation method thereof, its
It is characterised by, be made up of following steps:
A., at 150-200 DEG C, nano-tourmaline powder is added in polylactic acid, adds polyethylene glycol 200, stir,
So that tourmaline powder is evenly spread in polylactic acid, and make polylactic acid be wrapped in nano-tourmaline powder surface, form microsphere, filter simultaneously
Dry;
B. activated carbon and jelly powder are added in water and are uniformly dispersed, be then added to Mint Essence, continue dispersion, point
Proceed to standing 3-5h under vacuumized conditions after dissipating uniformly, by centrifugation, be dried, milled processed obtains the work that is loaded with Mint Essence
Property powdered carbon and gelatin powder mixture;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and are melted, then
Non-woven fabrics are obtained after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr, Kaolin are added to the water, are stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into
Carboxymethyl cellulose sodium and carboxymethyl chitosan zinc, adjust modest viscosity, prepared serosity;Step c gained non-woven fabrics are soaked completely
Not in serosity, and put into ultrasonic 5-10min in ultrasonic oscillator, take out, using the method for " two leachings two are rolled ", fully soak
Not yet, use padder mangle, again submergence, after then using padder mangle, put into baker, bakee 2-5min, take out.
3. according to claim 2 a kind of antibacterial, can continuous non-woven fabrics of releasing negative oxygen ion and preparation method thereof, its
It is characterised by, curer stoving temperature described in step b is 70-110 DEG C.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112111806A (en) * | 2020-08-21 | 2020-12-22 | 上海题桥纺织染纱有限公司 | Medical fiber and preparation method and application thereof |
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CN105506857A (en) * | 2016-01-26 | 2016-04-20 | 芜湖环瑞汽车内饰件有限公司 | Acoustic wool with high impact resistance and preparation method thereof |
CN105862258A (en) * | 2016-04-22 | 2016-08-17 | 滁州市莎朗新材料科技有限公司 | Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof |
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KR100520715B1 (en) * | 2005-02-05 | 2005-10-11 | 김종권 | Method for manufacturing of functional nonwoven fabric |
CN103696127A (en) * | 2013-11-25 | 2014-04-02 | 芜湖跃飞新型吸音材料股份有限公司 | Montmorillonite/isotactic polypropylene/polylactic acid composite sound absorbing cotton and preparation method thereof |
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CN112111806A (en) * | 2020-08-21 | 2020-12-22 | 上海题桥纺织染纱有限公司 | Medical fiber and preparation method and application thereof |
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Application publication date: 20170125 |