CN106283401A - A kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously - Google Patents

A kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously Download PDF

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Publication number
CN106283401A
CN106283401A CN201610689187.XA CN201610689187A CN106283401A CN 106283401 A CN106283401 A CN 106283401A CN 201610689187 A CN201610689187 A CN 201610689187A CN 106283401 A CN106283401 A CN 106283401A
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China
Prior art keywords
woven fabrics
nano
oxygen ion
negative oxygen
titanium oxide
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Pending
Application number
CN201610689187.XA
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Chinese (zh)
Inventor
汪彦羽
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MAANSHAN LAKESIDE NONWOVEN TECHNOLOGY Co Ltd
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MAANSHAN LAKESIDE NONWOVEN TECHNOLOGY Co Ltd
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Priority to CN201610689187.XA priority Critical patent/CN106283401A/en
Publication of CN106283401A publication Critical patent/CN106283401A/en
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/18Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously, it is characterised in that be made up of the raw material of following weight portion: nano titanium oxide 13, nano-tourmaline powder 48, white carbon black 12, polylactic acid 5 10, polyethylene glycol 200 12, activated carbon 35, Mint Essence 48, alginate fibre 12, isotactic polypropylene 50 70, kieselguhr 36, dodecyl sodium sulfate 12, Carboxymethyl cellulose sodium is appropriate, and water is appropriate;The present invention adds nano-tourmaline powder in non-woven fabrics, can reach the effect of continuous releasing negative oxygen ion, when being applied to automotive trim, interior space can be made refrigerant comfortable, spirit and QI cleaning, and Mint Essence of arranging in pairs or groups, effect of refreshing oneself is notable;By adding nano titanium oxide, impart material can light-catalysed function, thus the cleaning of material can be kept.

Description

A kind of have catalysis, can the non-woven fabrics of releasing negative oxygen ion and preparation thereof continuously Method
Technical field
The present invention relates to a kind of non-woven fabrics and preparation method thereof, be specifically related to one and there is catalysis, can discharge continuously Non-woven fabrics of negative oxygen ion and preparation method thereof.
Background technology
Non-woven fabrics is a kind of non-weaving cloth, and it is to directly utilize high polymer section, chopped fiber or long filament fiber is passed through gas Stream or machinery become net, are then passed through spun lacing, acupuncture, or hot rolling and reinforce, and eventually pass the cloth without braiding that Final finishing is formed.Tool Having softness, the ventilative and tencel goods of planar structure, advantage is not produce Soft flocks, tough, durable, silkiness is soft, also It is the one of reinforcing material, and the sensation of also cotton, have been widely used for automotive field.But stay in confined space for a long time In, people can think that dizzy brain rises, when come forest seashore, waterfall etc. local when, we can feel spirit and QI cleaning, and this is just It it is the effect of negative aeroion.Negative aeroion is also negative oxygen ion, refer to obtain excess electron and electronegative oxygen from Son.
Jiang Yinggang, in " containing the preparation of bamboo charcoal powder liner cloth and Study on adsorption properties ", utilizes bamboo charcoal powder and non-weaving cloth, logical Cross coating, the method such as pad, make multiple containing bamboo charcoal powder nonwoven interlining.But, when it is applied to automotive trim, there is also And be not provided that negative oxygen ion, refrigerant fragrance of refreshing oneself etc. can not be discharged be conducive to traffic safety and driving comfortable space is provided Weak point.
Summary of the invention
Comprehensive above consideration, the present invention provides a kind of non-woven fabrics and formula thereof, it is therefore intended that solve when non-woven fabrics is applied When automotive trim, it is impossible to releasing negative oxygen ion continuously, it is provided that the preferably defect of interior space.
For achieving the above object, technical scheme is as follows:
A kind of have catalysis, can the non-woven fabrics of releasing negative oxygen ion continuously, it is characterised in that by the raw material of following weight portion Make:
Nano titanium oxide 1-3, nano-tourmaline powder 4-8, white carbon black 1-2, polylactic acid 5-10, polyethylene glycol 200 1-2, activated carbon 3-5, Mint Essence 4-8, alginate fibre 1-2, isotactic polypropylene 50-70, kieselguhr 3-6, dodecyl sodium sulfate 1-2, hydroxyl first Base sodium cellulosate is appropriate, and water is appropriate;
Described a kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously, it is characterised in that It is made up of following steps:
A., at 150-200 DEG C, nano-tourmaline powder, nano titanium oxide are joined in polylactic acid, adds Polyethylene Glycol 200, stir, make nano-tourmaline powder, nano titanium oxide evenly spread in polylactic acid, and make polylactic acid be wrapped in receive Rice tourmaline powder, nano titanium oxide surface, form microsphere, filter and dry;
B. activated carbon, alginate fibre are added in water and be uniformly dispersed, be then added to Mint Essence, continue dispersion, point Proceed to stand under vacuumized conditions 3-5h after dissipating uniformly, obtain being loaded with the work of Mint Essence by centrifugal, dry, milled processed Property powdered carbon and the mixture of alginate fibre;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and melt, then Non-woven fabrics is prepared after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr is added to the water, is stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into methylol fine Dimension element sodium, white carbon black, adjust modest viscosity, prepare serosity;Step c gained non-woven fabrics is totally submerged in serosity, and puts into ultrasonic Ultrasonic 5-10min in wave oscillator, takes out, the method using " two leachings two are rolled ", and i.e. fully submergence uses padder mangle, further Secondary submergence, then with after padder mangle, puts into baker, bakees 2-5min, take out.
Described a kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously, its feature Being, curer stoving temperature described in step b is 70-110 DEG C.
The invention has the beneficial effects as follows: in non-woven fabrics, add nano-tourmaline powder, can reach to discharge continuously negative oxygen from The effect of son, when being applied to automotive trim, can make interior space refrigerant comfortable, spirit and QI cleaning, Mint Essence of arranging in pairs or groups, effect of refreshing oneself Fruit is notable, reduces and contained the harm of fatigue driving;Utilize polylactic acid to wrap up nano-tourmaline powder, not only prevent nanometer Tourmaline powder broken and coming off, and the appearance promoting tourmaline powder and polypropylene substrate closes and dispersion, polylactic acid tool simultaneously There are excellent breathability, oxygen permeability, and antibacterial and anti-mildew characteristic, improve the fungus resistance of non-woven fabrics, extend service life;With Activated carbon loads Mint Essence, adds loading and the air contact area of Mint Essence, reaches more lasting release Effect, has been simultaneously introduced the characterization of adsorption of activated carbon, increases the function of non-woven fabrics clean air;With kieselguhr serosity to non-woven fabrics Carry out coating, can effectively remove harmful substance and house pet body odor, the rubbish institutes such as the free formaldehyde in air, benzene, ammonia, VOC The abnormal flavour produced, solves in-vehicle air pollution, hence it is evident that improve environment inside car comprehensively;By adding nano titanium oxide, impart Material can light-catalysed function, thus the cleaning of material can be kept.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.
Embodiment
A kind of have catalysis, can the non-woven fabrics of releasing negative oxygen ion continuously, it is characterised in that by following weight portion Raw material is made:
Nano titanium oxide 3, nano-tourmaline powder 8, white carbon black 2, polylactic acid 10, polyethylene glycol 200 2, activated carbon 5, Mint Essence 8, alginate fibre 2, isotactic polypropylene 70, kieselguhr 6, dodecyl sodium sulfate 2, Carboxymethyl cellulose sodium is appropriate, and water is appropriate;
Described a kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously, it is characterised in that It is made up of following steps:
A., at 150-200 DEG C, nano-tourmaline powder, nano titanium oxide are joined in polylactic acid, adds Polyethylene Glycol 200, stir, make nano-tourmaline powder, nano titanium oxide evenly spread in polylactic acid, and make polylactic acid be wrapped in receive Rice tourmaline powder, nano titanium oxide surface, form microsphere, filter and dry;
B. activated carbon, alginate fibre are added in water and be uniformly dispersed, be then added to Mint Essence, continue dispersion, point Proceed to stand under vacuumized conditions 3-5h after dissipating uniformly, obtain being loaded with the work of Mint Essence by centrifugal, dry, milled processed Property powdered carbon and the mixture of alginate fibre;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and melt, then Non-woven fabrics is prepared after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr is added to the water, is stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into methylol fine Dimension element sodium, white carbon black, adjust modest viscosity, prepare serosity;Step c gained non-woven fabrics is totally submerged in serosity, and puts into ultrasonic Ultrasonic 5-10min in wave oscillator, takes out, the method using " two leachings two are rolled ", and i.e. fully submergence uses padder mangle, further Secondary submergence, then with after padder mangle, puts into baker, bakees 2-5min, take out.
Described a kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously, its feature Being, curer stoving temperature described in step b is 70-110 DEG C.
The technical parameter of the present invention is:
Formaldehyde absorbing rate >=11.09% of Unit Weight non-woven fabrics, benzene adsorption rate >=14.83%, TVOC adsorption rate >=13.42%.

Claims (3)

1. one kind have catalysis, can the non-woven fabrics of releasing negative oxygen ion continuously, it is characterised in that former by following weight portion Material is made:
Nano titanium oxide 1-3, nano-tourmaline powder 4-8, white carbon black 1-2, polylactic acid 5-10, polyethylene glycol 200 1-2, activated carbon 3-5, Mint Essence 4-8, alginate fibre 1-2, isotactic polypropylene 50-70, kieselguhr 3-6, dodecyl sodium sulfate 1-2, hydroxyl first Base sodium cellulosate is appropriate, and water is appropriate.
The most according to claim 1 a kind of have catalysis, can the non-woven fabrics of releasing negative oxygen ion and preparation thereof continuously Method, it is characterised in that be made up of following steps:
A., at 150-200 DEG C, nano-tourmaline powder, nano titanium oxide are joined in polylactic acid, adds Polyethylene Glycol 200, stir, make nano-tourmaline powder, nano titanium oxide evenly spread in polylactic acid, and make polylactic acid be wrapped in receive Rice tourmaline powder, nano titanium oxide surface, form microsphere, filter and dry;
B. activated carbon, alginate fibre are added in water and be uniformly dispersed, be then added to Mint Essence, continue dispersion, point Proceed to stand under vacuumized conditions 3-5h after dissipating uniformly, obtain being loaded with the work of Mint Essence by centrifugal, dry, milled processed Property powdered carbon and the mixture of alginate fibre;
C. isotactic polypropylene, step a thus obtained microsphere, step b gained mixture are added to screw extruder and melt, then Non-woven fabrics is prepared after spinning, drawing-off, one-tenth net, hot rolling;
D. kieselguhr is added to the water, is stirring evenly and then adding into dodecyl sodium sulfate, be stirring evenly and then adding into methylol fine Dimension element sodium, white carbon black, adjust modest viscosity, prepare serosity;Step c gained non-woven fabrics is totally submerged in serosity, and puts into ultrasonic Ultrasonic 5-10min in wave oscillator, takes out, the method using " two leachings two are rolled ", and i.e. fully submergence uses padder mangle, further Secondary submergence, then with after padder mangle, puts into baker, bakees 2-5min, take out.
The most according to claim 2 a kind of have catalysis, can the non-woven fabrics of releasing negative oxygen ion and preparation thereof continuously Method, it is characterised in that curer stoving temperature described in step b is 70-110 DEG C.
CN201610689187.XA 2016-08-19 2016-08-19 A kind of have catalysis, can the non-woven fabrics and preparation method thereof of releasing negative oxygen ion continuously Pending CN106283401A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108796819A (en) * 2018-05-31 2018-11-13 合肥洁诺无纺布制品有限公司 A kind of non-woven fabrics and preparation method thereof of high-hydroscopicity energy
CN109045956A (en) * 2018-08-07 2018-12-21 赵文辉 A kind of vaccary deodorizing disinfectant and preparation method thereof
CN109367492A (en) * 2018-10-17 2019-02-22 中国第汽车股份有限公司 A kind of automobile cabin of releasing negative oxygen ion
WO2021042717A1 (en) * 2019-09-02 2021-03-11 中科纺织研究院(青岛)有限公司 Algae-modified pp spunbonded non-woven fabric
CN114673000A (en) * 2022-03-31 2022-06-28 中国第一汽车股份有限公司 Three-proofing negative oxygen ion finishing agent for automotive interior, preparation method and application

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JPS4856965A (en) * 1971-11-26 1973-08-10
CN1267570A (en) * 1999-03-17 2000-09-27 集泰科技股份有限公司 Photocatalyst carrier
CN1394675A (en) * 2002-07-12 2003-02-05 清华大学 Preparation method of titanium dioxide film photocatalyst loaded on surface of flexible base material
CN101041277A (en) * 2006-07-27 2007-09-26 宁波山泉建材有限公司 Three layered composite film for purifying and preventing the air and the preparing method and the application
CN103696127A (en) * 2013-11-25 2014-04-02 芜湖跃飞新型吸音材料股份有限公司 Montmorillonite/isotactic polypropylene/polylactic acid composite sound absorbing cotton and preparation method thereof
CN105506857A (en) * 2016-01-26 2016-04-20 芜湖环瑞汽车内饰件有限公司 Acoustic wool with high impact resistance and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4856965A (en) * 1971-11-26 1973-08-10
CN1267570A (en) * 1999-03-17 2000-09-27 集泰科技股份有限公司 Photocatalyst carrier
CN1394675A (en) * 2002-07-12 2003-02-05 清华大学 Preparation method of titanium dioxide film photocatalyst loaded on surface of flexible base material
CN101041277A (en) * 2006-07-27 2007-09-26 宁波山泉建材有限公司 Three layered composite film for purifying and preventing the air and the preparing method and the application
CN103696127A (en) * 2013-11-25 2014-04-02 芜湖跃飞新型吸音材料股份有限公司 Montmorillonite/isotactic polypropylene/polylactic acid composite sound absorbing cotton and preparation method thereof
CN105506857A (en) * 2016-01-26 2016-04-20 芜湖环瑞汽车内饰件有限公司 Acoustic wool with high impact resistance and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108796819A (en) * 2018-05-31 2018-11-13 合肥洁诺无纺布制品有限公司 A kind of non-woven fabrics and preparation method thereof of high-hydroscopicity energy
CN109045956A (en) * 2018-08-07 2018-12-21 赵文辉 A kind of vaccary deodorizing disinfectant and preparation method thereof
CN109367492A (en) * 2018-10-17 2019-02-22 中国第汽车股份有限公司 A kind of automobile cabin of releasing negative oxygen ion
WO2021042717A1 (en) * 2019-09-02 2021-03-11 中科纺织研究院(青岛)有限公司 Algae-modified pp spunbonded non-woven fabric
CN114673000A (en) * 2022-03-31 2022-06-28 中国第一汽车股份有限公司 Three-proofing negative oxygen ion finishing agent for automotive interior, preparation method and application
CN114673000B (en) * 2022-03-31 2024-04-16 中国第一汽车股份有限公司 Three-proofing negative oxygen ion finishing agent for automotive interiors, preparation method and application

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