CN102704022B - Health anion fiber - Google Patents
Health anion fiber Download PDFInfo
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- CN102704022B CN102704022B CN201210009277.1A CN201210009277A CN102704022B CN 102704022 B CN102704022 B CN 102704022B CN 201210009277 A CN201210009277 A CN 201210009277A CN 102704022 B CN102704022 B CN 102704022B
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Abstract
The invention discloses a health anion fiber. The health anion fiber comprises 0.2-5wt% of anion additive and 95-99.8wt% of fiber-forming polymer. The anion additive and the fiber-forming polymer are subjected to melt spinning to obtain the health anion fiber. The anion additive comprises, by weight, 10-15 parts of carol fossil, 10-15 parts of tourmaline, 30-35 parts of opal, 15-20 parts of serpentine, 5-10 parts of medical stone, 10-15 parts of elbaite, 2-4 parts of hokutolite, 2-4 parts of YiWang stone, 3-6 parts of shell, 2-4 parts of aluminum oxide, 2-4 parts of zirconium oxide, and 2-4 parts of zirconium phosphate. No special requirement on selection of the fiber-forming polymer of the health anion fiber is needed, and accordingly the health anion fiber is widely applicable. The health anion fiber generates air ions with high solubility and is persistently effective.
Description
Technical field
The present invention relates to a kind of functional fiber, relate in particular to a kind of anion healthy fiber.
Background technology
Anion, to people's health, longevity and ecological significant impact, is verified by clinical practice by domestic and international medical circle expert.Contemporary science has been opened bioelectric secret; each cell of organism is exactly a micro cell; the potential difference that has 50-90mv inside and outside cell membrane; if can not get sufficient electric charge, " cell battery " supplement; the electric process of body is just difficult to continue to maintain; thereby have influence on the normal activity of body, produce aging and early ageing.
Pollute few place in forest, beach, waterfall, countryside etc., contain a large amount of anion air, its concentration is seriously polluted urban hundred times, and here people can feel with fresh air, breathe happy, relaxation and happiness, relaxed and joyful, the effect that numerous anion air that Here it is produce.Therefore anion air is referred to as " long-lived element " or " air vitamin " by people.
Anionic additive, is the principle that human use's nature produces anion, and manually a kind of complex mineral of synthetic or proportioning, is all generally that tourmaline powder adds lanthanide series or rare earth element.
The effect major embodiment of anionic additive is: the negative aeroion generating function that (1) is permanent: the mechanism of gas molecule ionization in air, and the result of main outer boundary ionizer to gas effect, ionizer has ultraviolet ray, radioactive ray, photoelectric effect etc.Composition in anionic additive has pyroelectricity and piezoelectricity, therefore in the situation that having temperature and pressure to change, (even small variation) can cause the electrical potential difference between composition crystal, this static is up to 1,000,000 electron-volts, thereby air is ionized, the electron attachment of being hit is in contiguous water and oxygen molecule and make it be converted into negative aeroion, i.e. negative oxygen ion.(2) stronger far-infrared transmitting function: the composition in anionic additive is to take the aluminium that boracic is feature, sodium, iron, the silicate material of lithium circulus, isomorph is grown, because of its pyroelectricity and piezoelectricity, make its polarity ion cause that in equilbrium position vibration dipole moment changes the electromagnetic radiation that produces far infrared band, for example, if add to by a certain percentage by (fiber) in product, make it by the free ion of self, impurity ion and ionic substance, impurity and two, three phonon sympathetic responses produce radiation, affect ionic bond polarity vibration organic and inorganic molecule interlinkage, formed stronger radiation broadband, according to test anionic additive, to far emissivity, be more than 90%.The far infrared performance of anionic additive to the health care of human body and other effect mainly contain the following aspects 1. far infrared can accelerate hydrone motion; make light water become active water; thereby make penetrability, extension, dissolving power, the metabolism power of water strengthen, and produce water conservation film.2. far infrared, for the circulatory system, can play expansion capillary, strengthens blood circulation, enhances metabolism, and strengthens the effect of Lymphatic Circulation.3. far infrared, for cell tissue, can make cell activation, makes old dead cell excretion or gives power of regeneration, can strengthen cellular energy, the effects such as the function of enhancing cell and vigor.(3) good antibiotic and sterilizing function: the negative oxygen ion producing in anionic additive has higher activity, has very strong redox, can destroy the activity of cell membrane or the cellular plasm organized enzyme of bacterium, thereby reaches the object of antibiotic and sterilizing.
The purposes of anionic additive is presented as: (1) purificationization air: the anion in anionic additive is mobile " Z " font that presents in air.And carry negative electrical charge to bacterium, dust, smoke particles and water droplet etc., this particulate of electric charge and this combines and is polymerized to ball and sinks, thereby reaches the object purifying air.(2) eliminate foreign flavor indoors and various pernicious gas: leftovers leftovers acid smell in the irritative gas such as the benzene that the art work using evaporates, formaldehyde, ketone, ammonia and daily life in interior decoration process, cigarette etc. are to this harmful peculiar smell of people, with containing the wall cloth of anionic additive, curtain etc. or containing the coating of anionic additive, the negative aeroion of its release can be eliminated effectively.(3) health-care function: wallpaper, the carpet used as clothes, sheet and indoor decoration through the fabric of negative-ion fiber processing, or containing the coating of anionic additive etc., all there is health care and environmental protection dual-use function, for example with negative-ion fiber, make fabric in automobile, can eliminate peculiar smell in automobile, purify air, regulate the neural excitement of driver and holddown, improve cerebral cortex function and keep the good state of mind.(4) water treatment: add filtering material to cross filter core for water dispenser with anionic additive, can kill bacterium in water, increase oxygen in water, with negative-ion fiber, make bathroom towel or for bathroom water treatment, can accelerate hydrone motion, make light water become active water.Increase energy, easily remove human body dirt, eliminate tired.Treated water, for the training in indoor year of high-grade green plants, can improve the survival rate of plant, and shorten the maturity period, is sprayed onto the blade face of flowers, can make the freshness date of flowers extend 5-10 doubly.Other purposes of anionic additive: there is the effect that purifies air, eliminates human-body fatigue, promotes health.In addition, these series of products also have antibacterial, degermation, and have obvious deodorization functions.This product can be used for fiber, when weaving clothing and be worn in the person with this, can to human body, excite anion continuously, makes human body keep energetic; On the other hand again can be constantly be that human body is eliminated rubbish in the various bodies of discharging in body, meanwhile, having this function dress ornament can be because of the many reason of washing, and reduces its effect.In addition, this product also can be used for, in indoor coating, paint, also can being placed directly in room and using as extraordinary air cleaner, deodorant.
Yet existing containing in the functional fiber of anionic additive, although be added with a certain amount of anionic additive, the air ion solubility that its product produces is not high yet, effect is not lasting.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of anion healthy fiber, and the air ion solubility that anion healthy fiber of the present invention produces is high, and effect is lasting.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
An anion healthy fiber, is comprised of 0.2～5wt% anionic additive and 95～99.8wt% fibre-forming polymer, by described anionic additive and described fibre-forming polymer melt spinning, makes anion healthy fiber,
Wherein, described anionic additive, is comprised of following components in mass portion:
10～15 parts of astroies;
10～15 parts, tourmaline;
30～50 parts, opal;
15～20 parts, serpentine;
5～10 parts of medical stones;
10～15 parts, strange ice stone;
2～4 parts of hokutolites;
2～4 parts of doctor Wang Shis;
3～6 parts, shell;
2～4 parts of alundum (Al2O3)s;
2～4 parts of zirconias;
2～4 parts of basic zirconium phosphates.
Described astroies, tourmaline, opal, serpentine, medical stone, strange ice stone, hokutolite, doctor Wang Shi, shell, alundum (Al2O3), zirconia and basic zirconium phosphate are mixed, add and in grinding equipment, carry out ultra-fine grinding, until particle diameter distribution is at 50～80nm, sieve, dry, can make described anionic additive.
Described anionic additive and described fibre-forming polymer are adopted to conventional melt spinning method, can be made into anion healthy fiber of the present invention.
Described fibre-forming polymer, refers to the synthesising macromolecule copolymer that can make fiber in the present invention.The various low molecule organic matters that coal, oil, natural gas etc. are that raw material is produced through a series of chemical actions of take are called monomer, then through being manually synthesized into fibre-forming polymer, also some inorganic matter Raw material processing can be become to fibre-forming polymer.Generally, fibre-forming polymer not only should have the ability that forms fiber, also must in suitable solvent, dissolve completely, forms the concentrated solution of thickness; Or melting is converted into viscous state and does not decompose under heating up, to carry out solution spinning or melt spinning.Can select terylene, acrylic fibers, polyethylene, polypropylene fibre, polyvinyl, polyvinyl chloride fibre, polyamide fibre, spandex etc.
In the preparation process of anionic additive of the present invention, do not need each raw materials such as tourmaline to carry out roasting, so technique is simple, easily controls.Anion healthy fiber of the present invention there is no specific (special) requirements to the selection of fibre-forming polymer, so wide adaptability, what is more important the present invention adds after anionic additive in fibre-forming polymer, anion solubility has a net increase of obviously, the air ion solubility that anion healthy fiber of the present invention produces is high, and effect is lasting.
The specific embodiment
Embodiment 1:
Take: 10 kilograms of astroies; 15 kilograms, tourmaline; 30 kilograms, opal; 20 kilograms, serpentine; 5 kilograms of medical stones; 15 kilograms, strange ice stone; 2 kilograms of hokutolites; 4 kilograms of doctor Wang Shis; 3 kilograms, shell; 4 kilograms of alundum (Al2O3)s; 2 kilograms of zirconias; 4 kilograms of basic zirconium phosphates.
Described astroies, tourmaline, opal, serpentine, medical stone, strange ice stone, hokutolite, doctor Wang Shi, shell, alundum (Al2O3), zirconia and basic zirconium phosphate are mixed, add and in grinding equipment, carry out ultra-fine grinding, until particle diameter distribution is at 50～80nm, sieve, dry, can make described anionic additive.
Embodiment 2:
Take 15 kilograms of astroies; 10 kilograms, tourmaline; 50 kilograms, opal; 15 kilograms, serpentine; 10 kilograms of medical stones; 10 kilograms, strange ice stone; 4 kilograms of hokutolites; 2 kilograms of doctor Wang Shis; 6 kilograms, shell; 2 kilograms of alundum (Al2O3)s; 4 kilograms of zirconias; 2 kilograms of basic zirconium phosphates.
Method described in employing embodiment 1, can make described anionic additive.
Embodiment 3:
Take: 12.5 kilograms of astroies; 12.5 kilograms, tourmaline; 40 kilograms, opal; 17.5 kilograms, serpentine; 7.5 kilograms of medical stones; 12.5 kilograms, strange ice stone; 3 kilograms of hokutolites; 3 kilograms of doctor Wang Shis; 4.5 kilograms, shell; 3 kilograms of alundum (Al2O3)s; 3 kilograms of zirconias; 3 kilograms of basic zirconium phosphates.
Method described in employing embodiment 1, can make described anionic additive.
Embodiment 4:
The anionic additive that adds embodiment 3 preparation of 1 kilogram in the nylon fibre pelletizing of 99 kilograms, after mixing, makes pelletizing with melting double screw extruder is mixing; Then melt spinning, makes the chinlon filament that contains anionic additive, i.e. anion healthy fiber of the present invention.
Gained chinlon filament, after the knitting processing of conventional method, be can be made into negative ion knitting measuring fiber product.Through friction testing, 260/cm when negative ion concentration is static by wooden unit
33260/cm when increasing to wooden unit and rubbing fast
3, improved 12.5 times.This knitted fabric has also shown obvious anti-microbial property: Staphylococcus aureus and colibacillary bacteriostasis rate have all surpassed 50%.This knitted cloth is placed in to place, household humidifier gas outlet, starts after humidifier, indoor cigarette stink can be removed rapidly.
Compare test, carries out friction testing to pure chinlon filament, 260/cm when negative ion concentration is static by wooden unit
3605/cm when increasing to wooden unit and rubbing fast
3.
Embodiment 5:
The anionic additive that adds embodiment 1 preparation of 0.2 kilogram in the polyster fibre pelletizing of 99.8 kilograms, after mixing, makes pelletizing with melting double screw extruder is mixing; Then melt spinning, makes the polyester filament that contains anionic additive, i.e. anion healthy fiber of the present invention.
Gained chinlon filament, after the knitting processing of conventional method, be can be made into negative ion knitting measuring fiber product.Through friction testing, 250/cm when negative ion concentration is static by wooden unit
33060/cm when increasing to wooden unit and rubbing fast
3.
Compare test, carries out friction testing to pure polyester filament, 250/cm when negative ion concentration is static by wooden unit
3580/cm when increasing to wooden unit and rubbing fast
3.
Embodiment 6:
The anionic additive that adds embodiment 3 preparation of 5 kilograms in the polypropylene fibre pelletizing of 95 kilograms, after mixing, makes pelletizing with melting double screw extruder is mixing; Then melt spinning, makes the polypropylene filament yarn that contains anionic additive, i.e. anion healthy fiber of the present invention.
Gained chinlon filament, after the knitting processing of conventional method, be can be made into negative ion knitting measuring fiber product.Through friction testing, 220/cm when negative ion concentration is static by wooden unit
34380/cm when increasing to wooden unit and rubbing fast
3.
Compare test, carries out friction testing to pure polyester filament, 220/cm when negative ion concentration is static by wooden unit
3495/cm when increasing to wooden unit and rubbing fast
3.
Wherein, the detection method that rubs described in embodiment 4-6 is: by fabric of the present invention or common used for textiles water-wet, with the smooth wooden unit of diameter 8cm, at textile surface, with certain pressure, rub fast, and the variation of negative ion concentration in air before and after testing friction.
Certainly, the present invention, can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those apparent conversion or alternative and remodeling to those skilled in the art.
Claims (1)
1. an anion healthy fiber, is characterized in that, 0.2～5wt% anionic additive and 95～99.8wt% fibre-forming polymer, consists of, and by described anionic additive and described fibre-forming polymer melt spinning, makes anion healthy fiber,
Wherein, described anionic additive, adopts following method to be prepared from:
Take: 12.5 kilograms of astroies; 12.5 kilograms, tourmaline; 40 kilograms, opal; 17.5 kilograms, serpentine; 7.5 kilograms of medical stones; 12.5 kilograms, strange ice stone; 3 kilograms of hokutolites; 3 kilograms of doctor Wang Shis; 4.5 kilograms, shell; 3 kilograms of alundum (Al2O3)s; 3 kilograms of zirconias; 3 kilograms of basic zirconium phosphates;
Described astroies, tourmaline, opal, serpentine, medical stone, strange ice stone, hokutolite, doctor Wang Shi, shell, alundum (Al2O3), zirconia and basic zirconium phosphate are mixed, add and in grinding equipment, carry out ultra-fine grinding, until particle diameter distribution, at 50～80nm, is sieved, be dried.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210009277.1A CN102704022B (en) | 2012-01-12 | 2012-01-12 | Health anion fiber |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210009277.1A CN102704022B (en) | 2012-01-12 | 2012-01-12 | Health anion fiber |
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| CN102704022A CN102704022A (en) | 2012-10-03 |
| CN102704022B true CN102704022B (en) | 2014-05-07 |
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| CN201210009277.1A Active CN102704022B (en) | 2012-01-12 | 2012-01-12 | Health anion fiber |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480565B (en) * | 2015-01-15 | 2016-06-15 | 宁波保税区韬鸿化工科技有限公司 | Anion healthy polyster fibre |
| CN104532382B (en) * | 2015-01-15 | 2016-08-17 | 宁波保税区韬鸿化工科技有限公司 | Negative-ion fiber |
| CN104499078B (en) * | 2015-01-15 | 2016-08-24 | 宁波保税区韬鸿化工科技有限公司 | Anion healthy nylon fibre |
| CN104651971A (en) * | 2015-02-11 | 2015-05-27 | 泉州海天材料科技股份有限公司 | Knitted fabric capable of releasing negative oxygen ions and production method of knitted fabric |
| CN105463602A (en) * | 2016-01-12 | 2016-04-06 | 山东盈如生物科技有限公司 | Preparation method for hokutolite anion additive and hokutolite anion fiber |
| CN106376110A (en) * | 2016-10-21 | 2017-02-01 | 青岛首创嘉业工贸有限公司 | Active electric blanket and preparation method thereof |
| CN106519305A (en) * | 2016-10-21 | 2017-03-22 | 青岛首创嘉业工贸有限公司 | Active shoes and insoles and manufacturing method thereof |
| CN106435796A (en) * | 2016-10-21 | 2017-02-22 | 青岛首创嘉业工贸有限公司 | Active protective tool and preparation method thereof |
| CN106498704A (en) * | 2016-10-21 | 2017-03-15 | 青岛首创嘉业工贸有限公司 | A kind of active dress ornament and preparation method thereof |
| CN107385534A (en) * | 2017-08-16 | 2017-11-24 | 河北卓达建材研究院有限公司 | A kind of anion environmental protection health fiber and preparation method thereof |
| CN108193305A (en) * | 2018-01-23 | 2018-06-22 | 华盛爽朗纺织品（北京）有限公司 | A kind of preparation method of Polyamide Yarns |
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| CN1360093A (en) * | 2000-12-21 | 2002-07-24 | 上海惠尔婷高级内衣有限公司 | Health-care anionic fibre and its preparing process |
| CN1766184A (en) * | 2004-10-27 | 2006-05-03 | 上海依福瑞实业有限公司 | Functionalized polypropylene fibre and its preparation method |
| CN201330291Y (en) * | 2008-12-31 | 2009-10-21 | 李胜春 | Nanometer anion powder PTT hollow fiber |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7879404B2 (en) * | 2007-04-20 | 2011-02-01 | The Hong Kong Polytechnic University | Method of enhancing moisture management and providing negative ion properties to fabric materials |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360093A (en) * | 2000-12-21 | 2002-07-24 | 上海惠尔婷高级内衣有限公司 | Health-care anionic fibre and its preparing process |
| CN1766184A (en) * | 2004-10-27 | 2006-05-03 | 上海依福瑞实业有限公司 | Functionalized polypropylene fibre and its preparation method |
| CN201330291Y (en) * | 2008-12-31 | 2009-10-21 | 李胜春 | Nanometer anion powder PTT hollow fiber |
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| CN102704022A (en) | 2012-10-03 |
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Owner name: NANTONG DREAMLA HOMETEXTILE CO., LTD. Free format text: FORMER OWNER: SHANGHAI TAOHONG CHEMICAL TECHNOLOGY CO., LTD. Effective date: 20140512 |
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Effective date of registration: 20140512 Address after: 226371 Xingren Industrial Park, Nantong, Jiangsu, China, Tongzhou District Patentee after: Nantong Dreamla Home Textile Co., Ltd. Address before: 200137 room 1F79, building, No. 528, Yang Gao Bei Road, Shanghai, Pudong New Area Patentee before: Shanghai Taohong Chemical Technology Co., Ltd. |
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Inventor after: Jiu Guojian Inventor after: Gu Ping Inventor after: Mao Xuefen Inventor before: Song Guoxin Inventor before: Huang Yi |
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Free format text: CORRECT: INVENTOR; FROM: SONG GUOXIN HUANG YI TO: MIAO GUOJIAN GU PING MAO XUEFEN |