CN104532382B - Negative-ion fiber - Google Patents
Negative-ion fiber Download PDFInfo
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- CN104532382B CN104532382B CN201510021239.1A CN201510021239A CN104532382B CN 104532382 B CN104532382 B CN 104532382B CN 201510021239 A CN201510021239 A CN 201510021239A CN 104532382 B CN104532382 B CN 104532382B
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- terbium
- negative
- anionic additive
- fiber
- ion fiber
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Abstract
The invention discloses a kind of negative-ion fiber, this negative-ion fiber is made up of 0.2 1.2wt% anionic additive and 98.8 99.8wt% polypropylene fibres, and described anionic additive comprises hokutolite.After the present invention adds anionic additive in polypropylene fibre fiber, anion solubility has a net increase of substantially.The air ion solubility that the negative-ion fiber of the present invention produces is high, and effect is lasting.
Description
Technical field
The present invention relates to a kind of fiber, particularly relate to a kind of negative-ion fiber.
Background technology
Fiber refers to the material being made up of continuous or discrete filament.In animal and plant body, fiber is in dimension
It is that organizational aspects plays an important role.Fiber applications is extensive, can be made into fine rule, the end of a thread and the rope made of hemp, papermaking
Or fibrous layer when knitting felt, can also be made into；The most also it is commonly used to manufacture unclassified stores, and is total to unclassified stores
With forming composite.
Anion, to the health of people, long-lived and ecological significant impact, has been that domestic and international medical circle expert is led to
Cross clinical practice to be verified.Contemporary science has opened bioelectric secret, and each cell of organism is just
It is a micro cell, inside and outside cell membrane, has the potential difference of 50-90mv, if " cell battery " can not get
Sufficiently electric charge supplements, and the electric process of body is difficult to continue to, thus has influence on the normal of body and live
Dynamic, produce aging and senilism.
Anion can not only facilitate human body synthesis and vitamin storage, strengthening and the physiological activity of human activin,
Therefore it is otherwise known as " air vitamin ", it is believed that it is as the vitamin of food, to human body and other
Biological vital movement has highly important impact, and after thunderstorm, the anion of air increases, people
Feel happy.And at air-conditioned room, because in air, anion processes through a series of air conditioning purges
Disappear with almost all after very long ventilation shaft, people's extended stationary periods wherein can feel uncomfortable in chest, dizzy,
Weak, work efficiency and health status decline, and are referred to as " air conditioner comprehensive disease ".In medical circle, negative
Ion is identified it is to have kill pathogenic bacteria and purify the effective means of air.Its mechanism essentially consists in anion
After being combined with antibacterial, make antibacterial produce change or the transfer of energy of structure, cause bacterial death, finally
Fall is sunken to ground.Medical research shows, in air, electronegative microgranule makes oxygen content in blood increase, favorably
In the conveying of blood oxygen, absorb and utilize, there is promotion human metabolism, improving human body immunity, increasing
Strong man's body flesh energy, the effect of regulation human body function balance.According to textual criticism, anion to 7 systems of human body,
Nearly more than 30 kinds of diseases have suppression, alleviate and auxiliary therapeutic action, especially to the health-care effect of human body more
Substantially.
In prior art, there is not a kind of fiber, it is possible to effectively anion releasing.
Summary of the invention
For the deficiencies in the prior art, it is fine that the technical problem to be solved is to provide a kind of anion
Dimension.
A kind of negative-ion fiber, fine by 0.2-1.2wt% anionic additive and 98.8-99.8wt% polypropylene
Dimension composition, described anionic additive comprises hokutolite.
Preferably,
Described anionic additive, is made up of following materials by weight percentage: terbium oxide 3-5%, and four is different
Propyl group two (dioctyl phosphito acyloxy) titanate esters 0.5-1.5%, surplus is hokutolite.
Described anionic additive, is made up of following materials by weight percentage: terbium oxide 3-5%, phosphoric acid
Zirconium 1-2%, tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters 0.5-1.5%, surplus is hokutolite.
Preferably, described terbium oxide is terbium sesquioxide and/or terbium peroxide.
Optimally, described terbium oxide is the mixture of terbium sesquioxide and terbium peroxide, three oxidations two
The mass ratio of terbium and terbium peroxide is 2:1-1:2.
Tetra isopropyl two (dioctyl phosphito acyloxy) titanate esters, CAS:65460-52-8, English
Name: Tetraisopropyl di (dioctylphosphate) titanate.
Described negative-ion fiber can use industry universal method to be prepared, such as by terbium oxide,
The mixing of zirconium phosphate, tetra isopropyl two (dioctyl phosphito acyloxy) each raw material such as titanate esters and hokutolite is stirred
Mix uniformly, add in grinding equipment and carry out superfine grinding, until particle diameter distribution is 50～80nm, mistake
Sieve, is dried, can be prepared by described anionic additive；Again that described anionic additive is fine with polypropylene
Dimension fiber pelletizing uses conventional melt spinning method, can be prepared by the negative-ion fiber of the present invention.
After the present invention adds anionic additive in polypropylene fibre fiber, anion solubility has a net increase of substantially.
The air ion solubility that the negative-ion fiber of the present invention produces is high, and effect is lasting.
Detailed description of the invention
By table 1 corresponding data, by terbium oxide, zirconium phosphate, tetra isopropyl two (dioctyl phosphito acyl-oxygen
Base) each raw material mixing and stirring such as titanate esters and hokutolite, add in grinding equipment and carry out superfine grinding,
Until particle diameter distribution is 50～80nm, sieve, be dried, can be prepared by described anionic additive.
Again described anionic additive is used conventional melt spinning side with polypropylene fibre fiber pelletizing
Method, can be prepared by the negative-ion fiber of the present invention.Anionic additive and polypropylene fibre fiber pelletizing
Mass ratio is 1:99.
Table 1: anionic additive formula table unit: kilogram
Test case:
The negative-ion fiber of the present invention is prepared as the plain weave fabric of density 140g/.Use again
" detection of GBT 30128-2013 textile anion generating capacity and evaluation " measures anion-generating capacity,
It is shown in Table 2.
Table 2: anion-generating capacity test tables of data
| Anion solubility (individual/cm3) | |
| Embodiment 1 | 1055 |
| Embodiment 2 | 935 |
| Embodiment 3 | 960 |
| Embodiment 4 | 1185 |
| Embodiment 5 | 995 |
| Embodiment 6 | 1015 |
| Comparative example 1 | 975 |
Visible, the negative-ion fiber of the present invention, it is possible to effectively anion releasing, it is possible to purify air.
Comparing embodiment 1 and embodiment 2-3, comparing embodiment 4 and embodiment 5-6, use three oxidations two
The terbium oxide that terbium and terbium peroxide compound produces anion effect than the single terbium oxide of employing and substantially wants
Good, the two Synergistic.
Comparing embodiment 1 and embodiment 4, embodiment 2 and embodiment 5, embodiment 3 and embodiment 6,
Anion effect is produced without zirconium phosphate it was unexpectedly observed that contain in the negative-ion fiber formula of terbium oxide
It is better than the effect that with the addition of zirconium phosphate on the contrary.
Above-described embodiment, it is thus understood that be merely to illustrate the present invention rather than limit the protection model of the present invention
Enclose.After having read the content that the present invention records, the present invention can be made various by those skilled in the art
Changing or amendment, these equivalence changes and modification fall into the scope of the claims in the present invention equally.
Claims (2)
1. a negative-ion fiber, it is characterised in that by 0.2-1.2wt% anionic additive
Forming with 98.8-99.8wt% polypropylene fibre, described anionic additive, by following weight
Percentage ratio raw material is made: terbium oxide 3 5%, tetra isopropyl two (dioctyl phosphito acyloxy)
Titanate esters 0.5 1.5%, surplus is hokutolite；Described terbium oxide is terbium sesquioxide and seven oxygen
The mass ratio changing the mixture of four terbiums, terbium sesquioxide and terbium peroxide is 2:1 1:2.
2. a negative-ion fiber, it is characterised in that by 0.2-1.2wt% anionic additive
Forming with 98.8-99.8wt% polypropylene fibre, described anionic additive, by following weight
Percentage ratio raw material is made: terbium oxide 3 5%, zirconium phosphate 1 2%, tetra isopropyl two (dioctyl
Phosphorous acid acyloxy) titanate esters 0.5 1.5%, surplus is hokutolite；Described terbium oxide is three oxygen
The mass ratio changing the mixture of two terbiums and terbium peroxide, terbium sesquioxide and terbium peroxide is
2:1‐1:2。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021239.1A CN104532382B (en) | 2015-01-15 | 2015-01-15 | Negative-ion fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510021239.1A CN104532382B (en) | 2015-01-15 | 2015-01-15 | Negative-ion fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104532382A CN104532382A (en) | 2015-04-22 |
| CN104532382B true CN104532382B (en) | 2016-08-17 |
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| CN201510021239.1A Active CN104532382B (en) | 2015-01-15 | 2015-01-15 | Negative-ion fiber |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463602A (en) * | 2016-01-12 | 2016-04-06 | 山东盈如生物科技有限公司 | Preparation method for hokutolite anion additive and hokutolite anion fiber |
| CN110802687B (en) * | 2019-11-12 | 2022-03-29 | 中科宜居(青岛)物联科技有限公司 | Preparation method of composite cereal fragrant board containing negative ions |
| CN111691229B (en) * | 2020-06-19 | 2021-10-26 | 齐鲁工业大学 | Negative ion electrostatic dust removal paper base paper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1818161A (en) * | 2006-03-07 | 2006-08-16 | 天津工业大学 | Health-care fibre and production thereof |
| CN1827868A (en) * | 2005-03-02 | 2006-09-06 | 张洪泽 | Negative ion fiber and preparation method thereof |
| CN101109114A (en) * | 2007-08-15 | 2008-01-23 | 辽宁银珠化纺集团有限公司 | Negative ion polyamide fibre and manufacturing method therefor |
| CN102704022A (en) * | 2012-01-12 | 2012-10-03 | 上海韬鸿化工科技有限公司 | Health anion fiber |
| CN103933590A (en) * | 2013-01-17 | 2014-07-23 | 陕西百业腾达实业有限责任公司 | Fluctuant anion mineral powder and manufacturing method thereof |
-
2015
- 2015-01-15 CN CN201510021239.1A patent/CN104532382B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1827868A (en) * | 2005-03-02 | 2006-09-06 | 张洪泽 | Negative ion fiber and preparation method thereof |
| CN1818161A (en) * | 2006-03-07 | 2006-08-16 | 天津工业大学 | Health-care fibre and production thereof |
| CN101109114A (en) * | 2007-08-15 | 2008-01-23 | 辽宁银珠化纺集团有限公司 | Negative ion polyamide fibre and manufacturing method therefor |
| CN102704022A (en) * | 2012-01-12 | 2012-10-03 | 上海韬鸿化工科技有限公司 | Health anion fiber |
| CN103933590A (en) * | 2013-01-17 | 2014-07-23 | 陕西百业腾达实业有限责任公司 | Fluctuant anion mineral powder and manufacturing method thereof |
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| CN104532382A (en) | 2015-04-22 |
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Effective date of registration: 20181017 Address after: 317100 No. 29, industrial road, hareun street, three county, Zhejiang Patentee after: Zhejiang Hai ah auto supplies Co., Ltd. Address before: 315100 room 1, 1 18 Xingye two, Ningbo bonded area, Zhejiang, China Patentee before: NINGBO FREE TRADE ZONE TAOHONG CHEMICAL TECHNOLOGY CO., LTD. |
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Address after: 317100 No. 29 Industrial Avenue, Hairun Street, Sanmen County, Taizhou City, Zhejiang Province Patentee after: Haiah Technology Co., Ltd Address before: 317100 No. 29, industrial road, hareun street, three county, Zhejiang Patentee before: Higher Auto Accessories Co.,Ltd. |
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Address after: 317100 No. 29 Industrial Avenue, Hairun Street, Sanmen County, Taizhou City, Zhejiang Province Patentee after: Haiah Technology Co.,Ltd. Address before: 317100 No. 29 Industrial Avenue, Hairun Street, Sanmen County, Taizhou City, Zhejiang Province Patentee before: Haiah Technology Co.,Ltd. |
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