CN102704022A - Health anion fiber - Google Patents

Health anion fiber Download PDF

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Publication number
CN102704022A
CN102704022A CN2012100092771A CN201210009277A CN102704022A CN 102704022 A CN102704022 A CN 102704022A CN 2012100092771 A CN2012100092771 A CN 2012100092771A CN 201210009277 A CN201210009277 A CN 201210009277A CN 102704022 A CN102704022 A CN 102704022A
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parts
fiber
anion
kilograms
anionic additive
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CN2012100092771A
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CN102704022B (en
Inventor
宋国新
黄毅
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Nantong Dreamla Home Textile Co., Ltd.
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Shanghai Taohong Chemical Technology Co Ltd
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Abstract

The invention discloses a health anion fiber. The health anion fiber comprises 0.2-5wt% of anion additive and 95-99.8wt% of fiber-forming polymer. The anion additive and the fiber-forming polymer are subjected to melt spinning to obtain the health anion fiber. The anion additive comprises, by weight, 10-15 parts of carol fossil, 10-15 parts of tourmaline, 30-35 parts of opal, 15-20 parts of serpentine, 5-10 parts of medical stone, 10-15 parts of elbaite, 2-4 parts of hokutolite, 2-4 parts of YiWang stone, 3-6 parts of shell, 2-4 parts of aluminum oxide, 2-4 parts of zirconium oxide, and 2-4 parts of zirconium phosphate. No special requirement on selection of the fiber-forming polymer of the health anion fiber is needed, and accordingly the health anion fiber is widely applicable. The health anion fiber generates air ions with high solubility and is persistently effective.

Description

The anion healthy fiber
Technical field
The present invention relates to a kind of functional fiber, relate in particular to a kind of anion healthy fiber.
Background technology
Anion is verified through clinical practice by domestic and international medical circle expert people's health, longevity and ecological significant impact.Contemporary science has been opened bioelectric secret; Each cell of organism is exactly a micro cell; The potential difference that 50-90mv is arranged inside and outside the cell membrane is replenished if " cell battery " can not get sufficient charge, and the electric process of body just is difficult to continue to keep; Thereby have influence on the normal activity of body, produce aging and early ageing.
Pollute few place in forest, beach, waterfall, countryside etc.; Contain a large amount of anion air; Its concentration is seriously polluted urban hundred times, and here people can feel with fresh air, breathe happy, relaxation and happiness, relaxed and joyful, the effect that numerous anion air that Here it is produce.Therefore anion air is referred to as " long-lived plain " or " air vitamin " by people.
Anionic additive is the principle that human use's nature produces anion, and artificial synthetic perhaps a kind of complex mineral of proportioning generally all is that tourmaline powder adds lanthanide series or rare earth element.
The effect of anionic additive mainly is presented as: the negative aeroion generation function that (1) is permanent: the mechanism of gas molecule ionization in the air, and main outer boundary ionizer is to the result of gas effect, and ionizer has ultraviolet ray, radioactive ray, photoelectric effect etc.Composition in the anionic additive has pyroelectricity and piezoelectricity; Therefore (even small variation) can cause the electrical potential difference between the composition crystal under the situation that has temperature and pressure to change; This static is up to 1,000,000 electron-volts; Thereby make air generation ionization, the electron attachment of being hit is in contiguous water and oxygen molecule and make it be converted into negative aeroion, i.e. negative oxygen ion.(2) stronger far-infrared transmitting function: the composition in the anionic additive is to be aluminium, sodium, the iron of characteristic, the silicate material of lithium circulus with the boracic; Isomorph is grown; Because of its pyroelectricity and piezoelectricity; Make its polarity ion in equilbrium position vibration and cause that dipole moment changes the electromagnetic radiation that produces far infrared band, if add (for example fiber) in the product to by a certain percentage, makes its free ion through self, impurity ion and ionic substance; Impurity and two, three phonon sympathetic responses produce radiation; Affecting ionic bond polarity vibration organic and the inorganic molecule interlinkage, formed stronger radiation broadband, is more than 90% according to the test anionic additive to far emissivity.The far infrared performance of anionic additive to the health care of human body and other effect mainly contain the following aspects 1. far infrared can quicken the hydrone motion; Make light water become active water; Thereby penetrability, extension, dissolving power, the metabolism power of water are strengthened, and produce the water conservation film.2. far infrared can play the expansion capillary for the circulatory system, strengthens blood circulation, enhances metabolism, and strengthens the effect of lymph circulation.3. far infrared can make cell activation for cell tissue, makes old dead cell drainage or gives power of regeneration, can strengthen cellular energy, effects such as the function of enhancing cell and vigor.(3) good antibiotic and sterilizing function: the negative oxygen ion that produces in the anionic additive has higher activity, and very strong redox is arranged, and can destroy the activity of cell membrane or the cellular plasm organized enzyme of bacterium, thereby reaches the purpose of antibiotic and sterilizing.
The purposes of anionic additive is presented as: (1) purificationization air: the anion in the anionic additive moves in air and presents " Z " font.And carry negative electrical charge to give bacterium, dust, smoke particles and water droplet etc., this particulate of electric charge and this combines and gathers balling-up and sink, thereby reaches the purpose that purifies air.(2) eliminate foreign flavor indoors and various pernicious gas: leftovers leftovers acid smell in irritative gas such as the benzene that the art work that in the interior decoration process, uses evaporates, formaldehyde, ketone, ammonia and the daily life; Cigarette etc. are to this harmful peculiar smell of people; With the wall cloth, curtain that contain anionic additive etc. or contain the coating of anionic additive, the negative aeroion of its release can both be eliminated effectively.(3) health-care function: wallpaper, the carpet used through fabric such as clothes, sheet and the indoor decoration of negative-ion fiber processing; Or contain coating of anionic additive etc.; All have health care and environmental protection dual-use function, for example process fabric in the automobile, can eliminate peculiar smell in the automobile with negative-ion fiber; Purify air, regulate neural excitement of driver and holddown, improve the cerebral cortex function and keep the good state of mind.(4) water treatment: be used for water dispenser with anionic additive adding filtering material and cross filter core; Can kill bacterium in the water, increase oxygen in water, process the bathroom towel or be used for the bathroom water treatment with negative-ion fiber; Can quicken the hydrone motion, make light water become active water.Increase energy, remove the human body dirt easily, allaying tiredness.Treated water is used for the training in indoor year of high-grade green plants, can improve the survival rate of plant, and shorten the maturity period, is sprayed onto the blade face of flowers, can make the freshness date of flowers prolong 5-10 doubly.Other purposes of anionic additive: have the effect that purifies air, eliminates human-body fatigue, promotes health.In addition, these series of products also have antibacterial, degermation, and have tangible deodorization functions.This product can be used for fiber, when weaving clothing and be worn in the person with this, can excite anion to human body continuously, makes human body keep energetic; On the other hand again can be constantly be that human body is eliminated rubbish in the various bodies of being discharged in the body, simultaneously, having this function dress ornament can be because of the many reason of washing, and reduces its effect.In addition, this product also can be used in indoor coating, the paint, also can be placed directly in the room and use as extraordinary air cleaner, deodorant.
Yet in the existing functional fiber that contains anionic additive, though be added with a certain amount of anionic additive, the air ion solubility that its product produces is not high yet, and effect is not lasting.
Summary of the invention
To the above-mentioned deficiency that exists in the prior art, technical problem to be solved by this invention provides a kind of anion healthy fiber, and the air ion solubility that anion healthy fiber of the present invention produces is high, and effect is lasting.
For solving the problems of the technologies described above, the present invention realizes through following technical scheme:
A kind of anion healthy fiber is made up of 0.2~5wt% anionic additive and 95~99.8wt% fibre-forming polymer, with said anionic additive and said fibre-forming polymer melt spinning, processes the anion healthy fiber,
Wherein, said anionic additive, form by following components in mass portion:
10~15 parts of astroies;
10~15 parts in tourmaline;
30~50 parts on opal;
15~20 parts in serpentine;
5~10 parts of medical stones;
10~15 parts in strange ice stone;
2~4 parts of hokutolites;
2~4 parts of doctor Wang Shis;
3~6 parts in shell;
2~4 parts of alundum (Als;
2~4 parts of zirconias;
2~4 parts of basic zirconium phosphates.
With said astroies, tourmaline, opal, serpentine, medical stone, very ice stone, hokutolite, doctor Wang Shi, shell, alundum (Al, zirconia and basic zirconium phosphate and mix; Add in the grinding equipment and carry out ultra-fine grinding; Until particle diameter distribution at 50~80nm; Sieve, drying can make said anionic additive.
Said anionic additive and said fibre-forming polymer are adopted conventional melt spinning method, promptly can be made into anion healthy fiber of the present invention.
Described in the present invention fibre-forming polymer is meant the synthesising macromolecule copolymer that can process fiber.With coal, oil, natural gas etc. is that the various low molecule organic matters that raw material is produced through a series of chemical actions are called monomer, is synthesized into fibre-forming polymer through manual work again, also can be processed into fibre-forming polymer to some inorganic matter raw material.Generally, fibre-forming polymer not only should have the ability that forms fiber, also must in suitable solvent, dissolve fully, forms the concentrated solution of thickness; Or fusion is converted into viscous state and does not decompose under heating up, so that carry out solvent spinning or melt spinning.Can select terylene, acrylic fibers, polyethylene, polypropylene fibre, polyvinyl, polyvinyl chloride fibre, polyamide fibre, spandex etc. for use.
Need not carry out roasting in the preparation process of anionic additive of the present invention, so technology is simple, easily control to each raw materials such as tourmaline.Anion healthy fiber of the present invention does not have specific (special) requirements to the selection of fibre-forming polymer; So wide adaptability; What is more important the present invention adds anionic additive in fibre-forming polymer after; Anion solubility has a net increase of obviously, and the air ion solubility that anion healthy fiber of the present invention produces is high, and effect is lasting.
The specific embodiment
Embodiment 1:
Take by weighing: 10 kilograms of astroies; 15 kilograms in tourmaline; 30 kilograms on opal; 20 kilograms in serpentine; 5 kilograms of medical stones; 15 kilograms in strange ice stone; 2 kilograms of hokutolites; 4 kilograms of doctor Wang Shis; 3 kilograms in shell; 4 kilograms of alundum (Als; 2 kilograms of zirconias; 4 kilograms of basic zirconium phosphates.
With said astroies, tourmaline, opal, serpentine, medical stone, very ice stone, hokutolite, doctor Wang Shi, shell, alundum (Al, zirconia and basic zirconium phosphate and mix; Add in the grinding equipment and carry out ultra-fine grinding; Until particle diameter distribution at 50~80nm; Sieve, drying can make said anionic additive.
Embodiment 2:
Take by weighing 15 kilograms of astroies; 10 kilograms in tourmaline; 50 kilograms on opal; 15 kilograms in serpentine; 10 kilograms of medical stones; 10 kilograms in strange ice stone; 4 kilograms of hokutolites; 2 kilograms of doctor Wang Shis; 6 kilograms in shell; 2 kilograms of alundum (Als; 4 kilograms of zirconias; 2 kilograms of basic zirconium phosphates.
Adopt embodiment 1 said method, can make said anionic additive.
Embodiment 3:
Take by weighing: 12.5 kilograms of astroies; 12.5 kilograms in tourmaline; 40 kilograms on opal; 17.5 kilograms in serpentine; 7.5 kilograms of medical stones; 12.5 kilograms in strange ice stone; 3 kilograms of hokutolites; 3 kilograms of doctor Wang Shis; 4.5 kilograms in shell; 3 kilograms of alundum (Als; 3 kilograms of zirconias; 3 kilograms of basic zirconium phosphates.
Adopt embodiment 1 said method, can make said anionic additive.
Embodiment 4:
The anionic additive that in 99 kilograms nylon fibre pelletizing, adds 1 kilogram embodiment 3 preparations after mixing, is processed pelletizing with the fusion double screw extruder is mixing; Melt spinning is processed the chinlon filament that contains anionic additive then, anion healthy fiber promptly of the present invention.
The gained chinlon filament after the knitting processing of conventional method, can be made into negative ion knitting measuring fiber article.Through friction testing, negative ion concentration is 260/cm when static by wooden unit 33260/cm when increasing to wooden unit and rubbing fast 3, improved 12.5 times.This knitted fabric has also shown tangible anti-microbial property: Staphylococcus aureus and colibacillary bacteriostasis rate have all surpassed 50%.This knitted cloth is placed family expenses humidifier gas outlet place, start humidifier after, can indoor cigarette stink be removed rapidly.
Compare test is carried out friction testing to pure chinlon filament, and negative ion concentration is 260/cm when static by wooden unit 3605/cm when increasing to wooden unit and rubbing fast 3
Embodiment 5:
The anionic additive that in 99.8 kilograms polyster fibre pelletizing, adds 0.2 kilogram embodiment 1 preparation after mixing, is processed pelletizing with the fusion double screw extruder is mixing; Melt spinning is processed the polyester filament that contains anionic additive then, anion healthy fiber promptly of the present invention.
The gained chinlon filament after the knitting processing of conventional method, can be made into negative ion knitting measuring fiber article.Through friction testing, negative ion concentration is 250/cm when static by wooden unit 33060/cm when increasing to wooden unit and rubbing fast 3
Compare test is carried out friction testing to pure polyester filament, and negative ion concentration is 250/cm when static by wooden unit 3580/cm when increasing to wooden unit and rubbing fast 3
Embodiment 6:
The anionic additive that in 95 kilograms polypropylene fibre pelletizing, adds 5 kilograms embodiment 3 preparations after mixing, is processed pelletizing with the fusion double screw extruder is mixing; Melt spinning is processed the polypropylene filament yarn that contains anionic additive then, anion healthy fiber promptly of the present invention.
The gained chinlon filament after the knitting processing of conventional method, can be made into negative ion knitting measuring fiber article.Through friction testing, negative ion concentration is 220/cm when static by wooden unit 34380/cm when increasing to wooden unit and rubbing fast 3
Compare test is carried out friction testing to pure polyester filament, and negative ion concentration is 220/cm when static by wooden unit 3495/cm when increasing to wooden unit and rubbing fast 3
Wherein, the detection method of friction described in the embodiment 4-6 is:, rub the variation of negative ion concentration in the air of testing friction front and back fast with fabric of the present invention or common used for textiles water-wet with certain pressure at textile surface with the smooth wooden unit of diameter 8cm.
Undoubtedly, the present invention can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those conspicuous to those skilled in the art conversion or substitute and remodeling.

Claims (2)

1. an anion healthy fiber is characterized in that, is made up of 0.2~5wt% anionic additive and 95~99.8wt% fibre-forming polymer, with said anionic additive and said fibre-forming polymer melt spinning, processes the anion healthy fiber.
2. an anion healthy fiber is characterized in that, is made up of 0.2~5wt% anionic additive and 95~99.8wt% fibre-forming polymer, with said anionic additive and said fibre-forming polymer melt spinning, processes the anion healthy fiber,
Wherein, said anionic additive, form by following components in mass portion:
10~15 parts of astroies;
10~15 parts in tourmaline;
30~50 parts on opal;
15~20 parts in serpentine;
5~10 parts of medical stones;
10~15 parts in strange ice stone;
2~4 parts of hokutolites;
2~4 parts of doctor Wang Shis;
3~6 parts in shell;
2~4 parts of alundum (Als;
2~4 parts of zirconias;
2~4 parts of basic zirconium phosphates.
CN201210009277.1A 2012-01-12 2012-01-12 Health anion fiber Active CN102704022B (en)

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Application Number Priority Date Filing Date Title
CN201210009277.1A CN102704022B (en) 2012-01-12 2012-01-12 Health anion fiber

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Application Number Priority Date Filing Date Title
CN201210009277.1A CN102704022B (en) 2012-01-12 2012-01-12 Health anion fiber

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CN102704022A true CN102704022A (en) 2012-10-03
CN102704022B CN102704022B (en) 2014-05-07

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104480565A (en) * 2015-01-15 2015-04-01 宁波保税区韬鸿化工科技有限公司 Anion healthy polyester fiber
CN104499078A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Anion healthy polyamide fiber
CN104532382A (en) * 2015-01-15 2015-04-22 宁波保税区韬鸿化工科技有限公司 Anion fiber
CN104651971A (en) * 2015-02-11 2015-05-27 泉州海天材料科技股份有限公司 Knitted fabric capable of releasing negative oxygen ions and production method of knitted fabric
CN105463602A (en) * 2016-01-12 2016-04-06 山东盈如生物科技有限公司 Preparation method for hokutolite anion additive and hokutolite anion fiber
CN106376110A (en) * 2016-10-21 2017-02-01 青岛首创嘉业工贸有限公司 Active electric blanket and preparation method thereof
CN106435796A (en) * 2016-10-21 2017-02-22 青岛首创嘉业工贸有限公司 Active protective tool and preparation method thereof
CN106498704A (en) * 2016-10-21 2017-03-15 青岛首创嘉业工贸有限公司 A kind of active dress ornament and preparation method thereof
CN106519305A (en) * 2016-10-21 2017-03-22 青岛首创嘉业工贸有限公司 Active shoes and insoles and manufacturing method thereof
CN107385534A (en) * 2017-08-16 2017-11-24 河北卓达建材研究院有限公司 A kind of anion environmental protection health fiber and preparation method thereof
CN108193305A (en) * 2018-01-23 2018-06-22 华盛爽朗纺织品(北京)有限公司 A kind of preparation method of Polyamide Yarns

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1360093A (en) * 2000-12-21 2002-07-24 上海惠尔婷高级内衣有限公司 Health-care anionic fibre and its preparing process
CN1766184A (en) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 Functionalized polypropylene fibre and its preparation method
US20080258347A1 (en) * 2007-04-20 2008-10-23 The Hong Kong Polytechnic University Method of enhancing moisture management and providing negative ion properties to fabric materials
CN201330291Y (en) * 2008-12-31 2009-10-21 李胜春 Nanometer anion powder PTT hollow fiber

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1360093A (en) * 2000-12-21 2002-07-24 上海惠尔婷高级内衣有限公司 Health-care anionic fibre and its preparing process
CN1766184A (en) * 2004-10-27 2006-05-03 上海依福瑞实业有限公司 Functionalized polypropylene fibre and its preparation method
US20080258347A1 (en) * 2007-04-20 2008-10-23 The Hong Kong Polytechnic University Method of enhancing moisture management and providing negative ion properties to fabric materials
CN201330291Y (en) * 2008-12-31 2009-10-21 李胜春 Nanometer anion powder PTT hollow fiber

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104532382B (en) * 2015-01-15 2016-08-17 宁波保税区韬鸿化工科技有限公司 Negative-ion fiber
CN104499078A (en) * 2015-01-15 2015-04-08 宁波保税区韬鸿化工科技有限公司 Anion healthy polyamide fiber
CN104532382A (en) * 2015-01-15 2015-04-22 宁波保税区韬鸿化工科技有限公司 Anion fiber
CN104480565A (en) * 2015-01-15 2015-04-01 宁波保税区韬鸿化工科技有限公司 Anion healthy polyester fiber
CN104499078B (en) * 2015-01-15 2016-08-24 宁波保税区韬鸿化工科技有限公司 Anion healthy nylon fibre
CN104651971A (en) * 2015-02-11 2015-05-27 泉州海天材料科技股份有限公司 Knitted fabric capable of releasing negative oxygen ions and production method of knitted fabric
CN105463602A (en) * 2016-01-12 2016-04-06 山东盈如生物科技有限公司 Preparation method for hokutolite anion additive and hokutolite anion fiber
CN106376110A (en) * 2016-10-21 2017-02-01 青岛首创嘉业工贸有限公司 Active electric blanket and preparation method thereof
CN106435796A (en) * 2016-10-21 2017-02-22 青岛首创嘉业工贸有限公司 Active protective tool and preparation method thereof
CN106498704A (en) * 2016-10-21 2017-03-15 青岛首创嘉业工贸有限公司 A kind of active dress ornament and preparation method thereof
CN106519305A (en) * 2016-10-21 2017-03-22 青岛首创嘉业工贸有限公司 Active shoes and insoles and manufacturing method thereof
CN107385534A (en) * 2017-08-16 2017-11-24 河北卓达建材研究院有限公司 A kind of anion environmental protection health fiber and preparation method thereof
CN108193305A (en) * 2018-01-23 2018-06-22 华盛爽朗纺织品(北京)有限公司 A kind of preparation method of Polyamide Yarns

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