CN105862258A - Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof - Google Patents
Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof Download PDFInfo
- Publication number
- CN105862258A CN105862258A CN201610253433.7A CN201610253433A CN105862258A CN 105862258 A CN105862258 A CN 105862258A CN 201610253433 A CN201610253433 A CN 201610253433A CN 105862258 A CN105862258 A CN 105862258A
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- China
- Prior art keywords
- base paper
- wallpaper base
- add
- woven fabric
- hour
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper. Nano silica is organically modified and then composited into tourmaline powder, the mixture is subjected to activation modification and then added to a raw material, the average fineness of fibers can be improved, a fiber web structure is sparse, the average pore diameter is increased, the gas permeability is improved, meanwhile, glass fibers, chlorinated paraffin and the like are added, and the corrosion resistance of the base paper is improved. The manufactured non-woven fabric wallpaper base paper is excellent in anti-static and anti-ultraviolet performance, has the good gas permeability, moisture resistance and anti-mold performance, and is good in stability, impact-resistant, free from deformation and good in coverage.
Description
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper and preparation method thereof.
Background technology
Wallpaper, is with paper, non-weaving cloth or woven cloths as base material, adds decorative coveringn, be widely used in the decoration of some metopes or wall.Although wallpaper is not requisite to the decoration function of building, but it has been to build room style, atmosphere and the important means of color.Especially with the non-weaving cloth (non-woven fabrics) wallpaper as base material, from properties of product or environmental requirement, no matter enjoy the favor of people.
Non-weaving cloth wallpaper is to prepare with the mixture of natural fiber Yu synthetic fibers, and they are long fibered paper also person, can clean, can breathe.Which eliminate gas lock, can prevent mouldy, it is also possible to for kitchen and toilet.Such wallpaper is to be looked at and eco-friendly product by user parent on current market, has good stability of the dimension, the mounting advantage such as pull convenient, anti-tear.Although a little higher than common wallpaper of such wallpaper price, but the main body of consumption in future is after 80s, after 90s, the consumer that their consumption view is different from the past, more focuses on quality, health, the speedup of China's economic is also fully able to provide support, the most medium-to-high grade non-weaving cloth wallpaper more market potential.And the enhancing of the health care consciousness along with people, novel environment friendly health type wallpaper more receives favor, the most in recent years, along with the exploration of researcher, finds that tourmaline has the generation function such as anion, radiation infrared, antibacterial, deodorizing.Thus develop a kind of add tourmaline can the non-weaving cloth wallpaper of anion releasing extremely urgent！
The anion master batch of different proportion is blended by " preparation of polypropylene anion melt-blowing nonwoven and performance study " literary composition with polypropylene chip, it is prepared for polypropylene anion melt-blowing nonwoven, and have studied the impact on non-weaving cloth performance of the anion master batch content.Result shows: along with the increase of anion master batch content, the thickness of melt-blowing nonwoven, surface density and antistatic property change are little, gas permeability and mechanical properties decrease, and uvioresistant performance improves.
By reducing gas permeability and mechanical property after adding anion master batch in literary composition, the non-weaving cloth prepared is used as wallpaper base paper and there is the defects such as easy laying dust incrustation, poor air permeability, the most mouldy, chance water is the wettest, soundproof effect is poor, function singleness, therefore, the present invention improves existing production technology and formula, add nano silicon in addition modified to improve gas permeability, and other effective additives of compatibility prepare the anion melt-blowing nonwoven wallpaper base paper of diverse in function.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper, is prepared by the raw materials in: isotactic polypropylene 61-63, tourmaline 14-15, nano silicon 0.4-0.5, glass fibre 5-7, stannous chloride 0.2-0.4, chlorinated paraffin 4-6, elm bark plant gum powder 6-8, mountain common jujube bark 16-18, theaflavin 1-2, acetic anhydride 5-6, lauryl glucosyl 6-7.
The preparation method of described a kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper, comprises the following steps:
(1) under nitrogen protection lauryl glucosyl heating is boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the chlorinated paraffin adding tourmaline and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) elm bark plant gum powder, mountain common jujube bark are stirred and evenly mixed, add water and break into slurry, add sodium hydrate aqueous solution boiling 5-8 hour that appropriate mass concentration is 1-2%, keep temperature to add acetic anhydride, stannous chloride, theaflavin grind 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(3) isotactic polypropylene is heated to molten condition, adds step (1), step (2) material and other residual components and stir and evenly mix, by nozzle spinneret, discharging.
The invention have the advantage that the present invention is compound in tourmaline powder after organically-modified for nano silicon, add to after activation modification in raw material, fiber average fineness can be improved, fibre net structure is sparse, average pore size increases, gas permeability becomes big, add glass fibre, chlorinated paraffin etc. simultaneously and improve the corrosion resistance of base paper, the non-weaving cloth wallpaper base paper utilizing the present invention to prepare is antistatic, anti-ultraviolet property is excellent, there is good permeability, moisture resistance and fungicidal properties, and good stability, impact resistance, indeformable, and spreadability is good.
Detailed description of the invention
A kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper, is prepared by the raw materials in: isotactic polypropylene 61, tourmaline 14, nano silicon 0.4, glass fibre 5, stannous chloride 0.2, chlorinated paraffin 4, elm bark plant gum powder 6, mountain common jujube bark 16, theaflavin 1, acetic anhydride 5, lauryl glucosyl 6.
The preparation method of described a kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper, comprises the following steps:
(1) under nitrogen protection lauryl glucosyl heating is boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the chlorinated paraffin adding tourmaline and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) elm bark plant gum powder, mountain common jujube bark are stirred and evenly mixed, add water and break into slurry, add sodium hydrate aqueous solution boiling 5-8 hour that appropriate mass concentration is 1-2%, keep temperature to add acetic anhydride, stannous chloride, theaflavin grind 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(3) isotactic polypropylene is heated to molten condition, adds step (1), step (2) material and other residual components and stir and evenly mix, by nozzle spinneret, discharging.
The non-weaving cloth wallpaper base paper utilizing the present invention to prepare has a following technical indicator:
Air penetrability/(mm s-1): 1916；
Ultimate strength/N:33.6；
Elongation at break/%:23.6.
Claims (2)
1. an anticorrosive anion melt-blowing nonwoven wallpaper base paper, it is characterized in that, be prepared by the raw materials in: isotactic polypropylene 61-63, tourmaline 14-15, nano silicon 0.4-0.5, glass fibre 5-7, stannous chloride 0.2-0.4, chlorinated paraffin 4-6, elm bark plant gum powder 6-8, mountain common jujube bark 16-18, theaflavin 1-2, acetic anhydride 5-6, lauryl glucosyl 6-7.
The preparation method of a kind of anticorrosive anion melt-blowing nonwoven wallpaper base paper the most according to claim 1, it is characterised in that comprise the following steps:
(1) under nitrogen protection lauryl glucosyl heating is boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the chlorinated paraffin adding tourmaline and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) elm bark plant gum powder, mountain common jujube bark are stirred and evenly mixed, add water and break into slurry, add sodium hydrate aqueous solution boiling 5-8 hour that appropriate mass concentration is 1-2%, keep temperature to add acetic anhydride, stannous chloride, theaflavin grind 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(3) isotactic polypropylene is heated to molten condition, adds step (1), step (2) material and other residual components and stir and evenly mix, by nozzle spinneret, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610253433.7A CN105862258A (en) | 2016-04-22 | 2016-04-22 | Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610253433.7A CN105862258A (en) | 2016-04-22 | 2016-04-22 | Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105862258A true CN105862258A (en) | 2016-08-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610253433.7A Pending CN105862258A (en) | 2016-04-22 | 2016-04-22 | Corrosion-resistant anion melt-blown non-woven fabric wallpaper base paper and manufacturing method thereof |
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| CN (1) | CN105862258A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350942A (en) * | 2016-08-19 | 2017-01-25 | 马鞍山湖滨无纺布科技有限公司 | Bacteriostatic nonwovens capable of continuously releasing negative oxygen ions and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| JP2010222726A (en) * | 2009-03-23 | 2010-10-07 | Emu Emu Eemu:Kk | Negative ion generating material and method for producing the same |
| CN103696130A (en) * | 2013-11-25 | 2014-04-02 | 芜湖跃飞新型吸音材料股份有限公司 | Environment-friendly non-woven fabric noise-absorbing cotton and preparation method thereof |
| CN103757820A (en) * | 2013-11-27 | 2014-04-30 | 芜湖跃飞新型吸音材料股份有限公司 | Far infrared negative ion functional non-woven fabric and preparation method thereof |
| KR20150055538A (en) * | 2013-11-13 | 2015-05-21 | 한상숙 | Production technology of printing coating on quantum energy and far-infrared functional nonwoven house fused with inorganic agent |
| CN105155030A (en) * | 2015-08-25 | 2015-12-16 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of releasing negative ions and preparation method thereof |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
-
2016
- 2016-04-22 CN CN201610253433.7A patent/CN105862258A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| JP2010222726A (en) * | 2009-03-23 | 2010-10-07 | Emu Emu Eemu:Kk | Negative ion generating material and method for producing the same |
| KR20150055538A (en) * | 2013-11-13 | 2015-05-21 | 한상숙 | Production technology of printing coating on quantum energy and far-infrared functional nonwoven house fused with inorganic agent |
| CN103696130A (en) * | 2013-11-25 | 2014-04-02 | 芜湖跃飞新型吸音材料股份有限公司 | Environment-friendly non-woven fabric noise-absorbing cotton and preparation method thereof |
| CN103757820A (en) * | 2013-11-27 | 2014-04-30 | 芜湖跃飞新型吸音材料股份有限公司 | Far infrared negative ion functional non-woven fabric and preparation method thereof |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105155030A (en) * | 2015-08-25 | 2015-12-16 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of releasing negative ions and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106350942A (en) * | 2016-08-19 | 2017-01-25 | 马鞍山湖滨无纺布科技有限公司 | Bacteriostatic nonwovens capable of continuously releasing negative oxygen ions and preparation method thereof |
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Application publication date: 20160817 |