CN105926155A - Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof - Google Patents
Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof Download PDFInfo
- Publication number
- CN105926155A CN105926155A CN201610253449.8A CN201610253449A CN105926155A CN 105926155 A CN105926155 A CN 105926155A CN 201610253449 A CN201610253449 A CN 201610253449A CN 105926155 A CN105926155 A CN 105926155A
- Authority
- CN
- China
- Prior art keywords
- base paper
- flame retardant
- wallpaper base
- hour
- nonwoven wallpaper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses a flame retardant anion meltblown nonwoven wallpaper base paper. Nano-silica is organically modified and is combined in tourmaline powders, after activation and modification, the tourmaline powders are added into a raw material, so as to improve finer average fineness, make a web structure sparse, increase average pore size, and increase permeability. Modified defatted soybean meal is used as an adhesive, and the modified defatted soybean meal has a cohesive action among fibers and is used as plant fibers to improve elongation at break and stretch resistance of the nonwoven, and the modified defatted soybean meal acts with cellulose pulp, to form a compact three-dimensional network structure. The structure has relatively good water insulation performance. The nonwoven wallpaper base paper is excellent in antistatic performance and anti-ultraviolet performance. The nonwoven wallpaper base paper is high in strength and good in flame retardant property, and is not easily affected with damp, and functional finishing in need can be performed.
Description
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper and preparation method thereof.
Background technology
Wallpaper, is with paper, non-weaving cloth or woven cloths as base material, adds decorative coveringn, be widely used in the decoration of some metopes or wall.Although wallpaper is not requisite to the decoration function of building, but it has been to build room style, atmosphere and the important means of color.Especially with the non-weaving cloth (non-woven fabrics) wallpaper as base material, from properties of product or environmental requirement, no matter enjoy the favor of people.
Non-weaving cloth wallpaper is to prepare with the mixture of natural fiber Yu synthetic fibers, and they are long fibered paper also person, can clean, can breathe.Which eliminate gas lock, can prevent mouldy, it is also possible to for kitchen and toilet.Such wallpaper is to be looked at and eco-friendly product by user parent on current market, has good stability of the dimension, the mounting advantage such as pull convenient, anti-tear.Although a little higher than common wallpaper of such wallpaper price, but the main body of consumption in future is after 80s, after 90s, the consumer that their consumption view is different from the past, more focuses on quality, health, the speedup of China's economic is also fully able to provide support, the most medium-to-high grade non-weaving cloth wallpaper more market potential.And the enhancing of the health care consciousness along with people, novel environment friendly health type wallpaper more receives favor, the most in recent years, along with the exploration of research worker, finds that tourmaline has the generation function such as anion, radiation infrared, antibacterial, deodorization.Thus develop a kind of add tourmaline can the non-weaving cloth wallpaper of anion releasing extremely urgent！
The anion master batch of different proportion is blended by " preparation of polypropylene anion melt-blowing nonwoven and performance study " literary composition with polypropylene chip, it is prepared for polypropylene anion melt-blowing nonwoven, and have studied the impact on non-weaving cloth performance of the anion master batch content.Result shows: along with the increase of anion master batch content, the thickness of melt-blowing nonwoven, surface density and antistatic property change are little, breathability and mechanical properties decrease, and uvioresistant performance improves.
By reducing breathability and mechanical property after adding anion master batch in literary composition, the non-weaving cloth prepared is used as wallpaper base paper and there is the defects such as easy laying dust dirty, poor air permeability, the most mouldy, chance water is the wettest, soundproof effect is poor, function singleness, therefore, the present invention improves existing production technology and formula, add nano silicon in addition modified to improve breathability, and other effective additives of compatibility prepare the anion melt-blowing nonwoven wallpaper base paper of diverse in function.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper, is prepared by the raw materials in: isotactic polypropylene 45-47, tourmaline powder 15-17, nano silicon 0.4-0.6, butyl oleate 5-7, ethylenediaminetetraacetic acid dianhydride 3-5, sepiolite powder 4-6, de-fatted soybean dregs 5-7, Caulis Sacchari sinensis fiber 14-16, Semen Vitis viniferae 4-6, Aloe superfine powder 7-9, polylactic acid 3-5.
The manufacture method of described a kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper, comprises the following steps:
(1) under nitrogen protection by butyl oleate heated and boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the polylactic acid adding tourmaline powder and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) by ground for de-fatted soybean dregs 100 eye mesh screens; spray concentration is the hydrochloric acid solution stirring and evenly mixing of 1-2mol/L; continuous magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control; washing is to neutral vacuum drying; add ethylenediaminetetraacetic acid dianhydride ultrasonic grinding 1-3 hour at 55-75 DEG C, obtain acylation modification de-fatted soybean dregs；
(3) by Semen Vitis viniferae, Caulis Sacchari sinensis fiber and Aloe superfine powder stirring and evenly mixing, add water pulping, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, keeps temperature to add step (2) material and grinds 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(4) isotactic polypropylene is heated to molten condition, adds step (1), step (3) material and other residual components stirring and evenly mixing, by nozzle spray webbing, discharging.
The invention have the advantage that the present invention is compound in tourmaline powder after organically-modified for nano silicon, add in raw material, can improve fiber average fineness after activation modification, fibre net structure is sparse, and average pore size increases, and breathability becomes big；Simultaneously using modified de-fatted soybean dregs as bonding agent, not only play interfibrous cementation but also elongation at break and the stretch-proof performance of non-weaving cloth can be improved as Plant fiber, again it is reacted with cellulose slurry, form fine and close tridimensional network, there is stronger water isolating, utilize non-weaving cloth wallpaper base paper antistatic that the present invention prepares, anti-ultraviolet property excellent, there is intensity high flame resistance good, and be difficult to make moist and can carry out finishing functions in need.
Detailed description of the invention
A kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper, is prepared by the raw materials in: isotactic polypropylene 45, tourmaline powder 15, nano silicon 0.4, butyl oleate 5, ethylenediaminetetraacetic acid dianhydride 3, sepiolite powder 4, de-fatted soybean dregs 5, Caulis Sacchari sinensis fiber 14, Semen Vitis viniferae 4, Aloe superfine powder 7, polylactic acid 3.
The manufacture method of described a kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper, comprises the following steps:
(1) under nitrogen protection by butyl oleate heated and boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the polylactic acid adding tourmaline powder and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) by ground for de-fatted soybean dregs 100 eye mesh screens; spray concentration is the hydrochloric acid solution stirring and evenly mixing of 1-2mol/L; continuous magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control; washing is to neutral vacuum drying; add ethylenediaminetetraacetic acid dianhydride ultrasonic grinding 1-3 hour at 55-75 DEG C, obtain acylation modification de-fatted soybean dregs；
(3) by Semen Vitis viniferae, Caulis Sacchari sinensis fiber and Aloe superfine powder stirring and evenly mixing, add water pulping, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, keeps temperature to add step (2) material and grinds 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(4) isotactic polypropylene is heated to molten condition, adds step (1), step (3) material and other residual components stirring and evenly mixing, by nozzle spray webbing, discharging.
The non-weaving cloth wallpaper base paper utilizing the present invention to prepare has a following technical specification:
Air penetrability/(mm s-1): 1911；
Ultimate strength/N:33.1；
Elongation at break/%:23.1.
Claims (2)
1. a flame retardant type anion melt-blowing nonwoven wallpaper base paper, it is characterized in that, be prepared by the raw materials in: isotactic polypropylene 45-47, tourmaline powder 15-17, nano silicon 0.4-0.6, butyl oleate 5-7, ethylenediaminetetraacetic acid dianhydride 3-5, sepiolite powder 4-6, de-fatted soybean dregs 5-7, Caulis Sacchari sinensis fiber 14-16, Semen Vitis viniferae 4-6, Aloe superfine powder 7-9, polylactic acid 3-5.
The manufacture method of a kind of flame retardant type anion melt-blowing nonwoven wallpaper base paper the most according to claim 1, it is characterised in that comprise the following steps:
(1) under nitrogen protection by butyl oleate heated and boiled; add nano silicon and keep temperature magnetic agitation 1-2 hour; filter, washing is dried; the polylactic acid adding tourmaline powder and molten condition grinds 30-40 minute; at subzero 15-20 DEG C, freezing 3-5 hour, grinds to obtain modified verdelite powder；
(2) by ground for de-fatted soybean dregs 100 eye mesh screens; spray concentration is the hydrochloric acid solution stirring and evenly mixing of 1-2mol/L; continuous magnetic agitation 2-3 hour in 60-80 DEG C of water bath with thermostatic control; washing is to neutral vacuum drying; add ethylenediaminetetraacetic acid dianhydride ultrasonic grinding 1-3 hour at 55-75 DEG C, obtain acylation modification de-fatted soybean dregs；
(3) by Semen Vitis viniferae, Caulis Sacchari sinensis fiber and Aloe superfine powder stirring and evenly mixing, add water pulping, adds sodium hydrate aqueous solution steaming and decocting 5-8 hour that appropriate mass concentration is 1-2%, keeps temperature to add step (2) material and grinds 30-40 minute, flowing water rinsed clean is used in cooling, dries；
(4) isotactic polypropylene is heated to molten condition, adds step (1), step (3) material and other residual components stirring and evenly mixing, by nozzle spray webbing, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610253449.8A CN105926155A (en) | 2016-04-22 | 2016-04-22 | Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610253449.8A CN105926155A (en) | 2016-04-22 | 2016-04-22 | Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105926155A true CN105926155A (en) | 2016-09-07 |
Family
ID=56839763
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610253449.8A Pending CN105926155A (en) | 2016-04-22 | 2016-04-22 | Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105926155A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| JP2010222726A (en) * | 2009-03-23 | 2010-10-07 | Emu Emu Eemu:Kk | Negative ion generating material and method for producing the same |
| CN103696130A (en) * | 2013-11-25 | 2014-04-02 | 芜湖跃飞新型吸音材料股份有限公司 | Environment-friendly non-woven fabric noise-absorbing cotton and preparation method thereof |
| CN103757820A (en) * | 2013-11-27 | 2014-04-30 | 芜湖跃飞新型吸音材料股份有限公司 | Far infrared negative ion functional non-woven fabric and preparation method thereof |
| KR20150055538A (en) * | 2013-11-13 | 2015-05-21 | 한상숙 | Production technology of printing coating on quantum energy and far-infrared functional nonwoven house fused with inorganic agent |
| CN105155030A (en) * | 2015-08-25 | 2015-12-16 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of releasing negative ions and preparation method thereof |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
-
2016
- 2016-04-22 CN CN201610253449.8A patent/CN105926155A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101029433A (en) * | 2007-03-06 | 2007-09-05 | 天津工业大学 | Production and producer for functional modified microgranular melt-jetting non-woven cloth |
| JP2010222726A (en) * | 2009-03-23 | 2010-10-07 | Emu Emu Eemu:Kk | Negative ion generating material and method for producing the same |
| KR20150055538A (en) * | 2013-11-13 | 2015-05-21 | 한상숙 | Production technology of printing coating on quantum energy and far-infrared functional nonwoven house fused with inorganic agent |
| CN103696130A (en) * | 2013-11-25 | 2014-04-02 | 芜湖跃飞新型吸音材料股份有限公司 | Environment-friendly non-woven fabric noise-absorbing cotton and preparation method thereof |
| CN103757820A (en) * | 2013-11-27 | 2014-04-30 | 芜湖跃飞新型吸音材料股份有限公司 | Far infrared negative ion functional non-woven fabric and preparation method thereof |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105155030A (en) * | 2015-08-25 | 2015-12-16 | 安徽省中日农业环保科技有限公司 | Woven fabric capable of releasing negative ions and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄世德等: "《粘接和粘接技术手册》", 28 February 1990, 四川科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102162174B (en) | Silver/carbon deodorizing antibacterial non-woven fabric and preparation method thereof | |
| WO2020024517A1 (en) | Method for preparing moisture-retentive, breathable, and antibacterial spunlace non-woven fabric for polyurethane synthetic leather | |
| CN103485072A (en) | Novel blending deodorant antibacterial non-woven fabrics | |
| CN107201697B (en) | A kind of luffa wallpaper and preparation method thereof | |
| CN106757773A (en) | A kind of antibacterial, fire-retardant, antistatic non-weaving cloth and its method for weaving | |
| CN1899814B (en) | Multicomponent and multiple boundary layer composite heat insulation material and its producing method | |
| CN108796831B (en) | Antistatic antibacterial acrylic non-woven fabric and preparation method thereof | |
| CN101307632B (en) | Multifunctional nonwoven material for architecture | |
| CN204193668U (en) | One can non-thermal shaped folding filter core composite filter | |
| CN108143543B (en) | Multilayer combined biodegradable core and preparation method thereof | |
| CN210420402U (en) | Functional composite spunlace non-woven fabric | |
| CN104120617B (en) | Non-woven fabric wet process net forming technology | |
| CN105821715A (en) | Mosquito-repellent wear-resistant negative ion melt spraying non-woven fabric wallpaper base layer and manufacture method thereof | |
| CN104997203A (en) | Method for manufacturing composite non-woven fabric collar interlining | |
| CN106012289A (en) | Method for preparing nonwoven fabric from bamboo fibers | |
| CN106319993A (en) | Preparation method of superfine fiber polyurethane synthetic leather for clothing leather | |
| CN105862518A (en) | Permanently antibacterial negative-ion melt-blown non-woven fabric wallpaper base paper and making method thereof | |
| CN105926155A (en) | Flame retardant anion meltblown nonwoven wallpaper base paper and manufacturing method thereof | |
| CN105922662B (en) | A kind of fire resistance fibre non-woven fabrics | |
| CN105821583A (en) | Lavender flavor type sleeping-aiding negative ion melt-blown non-woven fabric wall paper base paper and manufacturing method thereof | |
| CN108149382A (en) | A kind of fire retardant elastic non-woven fabrics and preparation method thereof | |
| CN105541246B (en) | A kind of boccaro wall clothing, thermal insulation decorative material | |
| CN105821716A (en) | Negative ion melt spraying non-woven fabric wallpaper base layer with high thermal insulation property and tensile strength and manufacture method thereof | |
| CN217922498U (en) | Clean lint with long-acting deodorization function | |
| CN105862519A (en) | Negative-ion melt-blown non-woven fabric wallpaper base paper capable of purifying indoor air and making method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160907 |
|
| RJ01 | Rejection of invention patent application after publication |