CN106350308A - Salt compound for cleaning metal and ceramics and method for cleaning metal and ceramics - Google Patents
Salt compound for cleaning metal and ceramics and method for cleaning metal and ceramics Download PDFInfo
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- CN106350308A CN106350308A CN201610721773.8A CN201610721773A CN106350308A CN 106350308 A CN106350308 A CN 106350308A CN 201610721773 A CN201610721773 A CN 201610721773A CN 106350308 A CN106350308 A CN 106350308A
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- Prior art keywords
- metal
- porcelain
- cleaning
- parts
- salt composite
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 102
- 239000002184 metal Substances 0.000 title claims abstract description 102
- 238000004140 cleaning Methods 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000919 ceramic Substances 0.000 title abstract 12
- -1 Salt compound Chemical class 0.000 title abstract 7
- 150000003839 salts Chemical class 0.000 claims abstract description 34
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001509 sodium citrate Substances 0.000 claims abstract description 6
- 229910052573 porcelain Inorganic materials 0.000 claims description 101
- 239000002131 composite material Substances 0.000 claims description 26
- 102000003886 Glycoproteins Human genes 0.000 claims description 11
- 108090000288 Glycoproteins Proteins 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000007853 buffer solution Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910001868 water Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000004515 gallic acid Nutrition 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 6
- 239000004814 polyurethane Substances 0.000 claims description 6
- 235000011083 sodium citrates Nutrition 0.000 claims description 5
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 3
- 238000002137 ultrasound extraction Methods 0.000 claims description 3
- 229920002752 Konjac Polymers 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 235000010485 konjac Nutrition 0.000 claims description 2
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid group Chemical class S(N)(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000006481 Colocasia esculenta Nutrition 0.000 claims 1
- 240000004270 Colocasia esculenta var. antiquorum Species 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 235000015096 spirit Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 7
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005336 cracking Methods 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 235000015165 citric acid Nutrition 0.000 description 6
- 238000010186 staining Methods 0.000 description 6
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 5
- IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 description 5
- 229960002510 mandelic acid Drugs 0.000 description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 208000010392 Bone Fractures Diseases 0.000 description 3
- 206010017076 Fracture Diseases 0.000 description 3
- 241000255964 Pieridae Species 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 238000005457 optimization Methods 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- AOJJSUZBOXZQNB-VTZDEGQISA-N 4'-epidoxorubicin Chemical group O([C@H]1C[C@@](O)(CC=2C(O)=C3C(=O)C=4C=CC=C(C=4C(=O)C3=C(O)C=21)OC)C(=O)CO)[C@H]1C[C@H](N)[C@@H](O)[C@H](C)O1 AOJJSUZBOXZQNB-VTZDEGQISA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 208000031481 Pathologic Constriction Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 210000001215 vagina Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention provides a salt compound for cleaning metal and ceramics and a method for cleaning metal and ceramics. The salt compound comprises the following components in parts by weight: 50-70 parts of crude salt, 15-35 parts of sulfamic acid, 5-10 parts of sodium citrate and 1-8 parts of citric acid. According to the method, the salt compound for cleaning metal and ceramics is adopted for cleaning metal and ceramics. When the salt compound is used for cleaning metal and ceramics, the spots and rust on the surfaces of metal and ceramics can be thoroughly removed; the metal and ceramics are prevented from being corroded; the metal is prevented from cracking and breaking and the ceramic surface is prevented from being corroded; the metal and ceramics after being cleaned with the salt compound provided by the invention can be effectively prevented from being spotted and rusted; the salt compound has protection effect for metal and ceramics.
Description
Technical field
The invention belongs to cleaning agent technical field is and in particular to a kind of salt composite for cleaning metal and porcelain and right
The method that metal and porcelain are cleaned.
Background technology
Metal is because easily react with the oxygen of in the air, and then the phenomenon got rusty easily, and causes metal surface
Have rusty stains, had a strong impact on using texture and attractive in appearance.There is much trickle aperture, these apertures are in the use of porcelain in porcelain
During easily absorb color and the composition taking up material in porcelain, and then easily cause to be formed in porcelain and much cannot clean
The spot removed, and the glaze on porcelain surface also can be affected by extraneous humidity, temperature and illumination ultraviolet in use,
And then so that the glaze on porcelain surface is decoloured or come off, and then porcelain is made to be easier in itself to be exposed in external environment.
Based on this, prior art develops cleaning agent and is used for cleaning metal and porcelain, but the acid that existing abluent adopts
The class cleaning multipair metal of composition and porcelain have deep-etching effect, can and metal react generation hydrogen, and the hydrogen producing is expanded
It is scattered in the lattice voids of metal, makes metal that crackle easily to occur, and also can react with compositions such as the Calcium Carbonate in porcelain,
Make in porcelain, to produce more tiny micropores, lead to the total quality of porcelain to be deteriorated, be easily broken, these tiny micropores are also more
Easily absorb coloring matter, make the porcelain after cleaning be easier absorption spot in later stage use.Additionally, existing cleaning agent is only
In order to obtain instant cleaning effect, there are no the article after protection cleaning and no longer get rusty easily or be infected with the function of spot.Comprehensive
Above as can be seen that the cleaning product of existing metal and porcelain has certain weak point.
Content of the invention
For deficiencies of the prior art, the technical problem to be solved in the present invention is: for existing abluent
Easily corrosion metal and porcelain, makes metal crackle easily, and porcelain produces more tiny micropores and leads to porcelain total quality to become
Differ from, and the article not having after protection cleaning no longer get rusty easily or are infected with the technical problem of spot, and provide one kind right
Metal and porcelain cause to corrode, and after long-acting can keeping cleaning article no longer get rusty or be infected with spot for clean metal with
The salt composite of porcelain and the method that metal and porcelain are cleaned.
In order to solve above-mentioned technical problem, the present invention adopt the following technical scheme that a kind of for cleaning metal and porcelain
Salt composite, including the component of following weight portion: 50 ~ 70 parts of crude salts, 15 ~ 35 parts of sulfamic acids, 5 ~ 10 parts of sodium citrates and 1 ~ 8
Part citric acid.During using salt composite of the present invention, it is possible to use the frosted of crude salt and adsorption are to metal and porcelain surface
Spot is purged and adsorbs, and crude salt also has dissipation effect to the antibacterial of metal, porcelain surface, after cleaning is effectively ensured
Product surface flora sum reduces, and is not in have pathogenic bacterium, and more crucially present invention is particularly directed to prior art is clear
Acid used in clean dose is easily reacted with metal generation hydrogen, and then leads to metal easily to generate crackle, or acid appearance therein
Easily react with the composition such as Calcium Carbonate in porcelain, so that porcelain mesopore is increased, the technical problem of degradation, especially through research
Find, carry out compounding as acid clean composition using sulfamic acid and citric acid, acid can ensured to metal, porcelain surface
Spot while carry out effective cleaning, metal will not be caused to corrode and so that metal surface is cracked, also will not be with porcelain
In the composition such as Calcium Carbonate react, the cavity in porcelain will not be made to become many, also will not corrode the enamel on porcelain surface, clear
Clean rigid injury is not caused to porcelain and metal simultaneously, effectively extend the useful life of porcelain and metal.
Further, 2 ~ 5 parts of mandelic acid and 3 ~ 8 parts of gallic acids are also included.By mandelic acid, gallic acid, sulfamic acid
With the collaborative compatibility effect of citric acid, depth can also be carried out to the coloured stains of the oxidation rust staining of metal surface and porcelain surface
Degree cleaning, makes the metal surface after cleaning smooth, the porcelain after cleaning does not have local mottle, cleaning effect is more preferably.
Further, 4 ~ 9 parts of aqueous polyurethanes are also included.The present invention can be used to fill up metal by compounding aqueous polyurethane
The crackle having existed with porcelain surface, makes the metal after repairing and porcelain smooth surface non-notch, effectively prevent because existing
Crackle and lead to metal and the generation of porcelain phenomenon of rupture, and add aqueous polyurethane can also completely cut off to a certain extent air and
Metal porcelain, reduces the harmful effect that external environment causes to metal, porcelain.
As optimization, also include 2 ~ 7 parts of Rhizoma amorphophalli glycoproteins；Described Rhizoma amorphophalli glycoprotein adopts following method to be obtained:
1) Rhizoma amorphophalli cleaned, remove the peel, pulverized after 8 ~ 12h being dried at 60 ~ 80 DEG C, obtain Rhizoma amorphophalli powder；
2) by Rhizoma amorphophalli powder described in step 1) and na2hpo4-nah2po4Buffer solution is with the mass volume ratio of 1 g:200 ~ 400 ml
Mixing, after 50 ~ 70 DEG C of extraction 2 ~ 4 h, takes lixiviating solution to filter, collects clear liquid；
3) by step 2) described clear liquid and the ethanol collected mixes according to the volume ratio of 1:2 ~ 4 and at room temperature after standing 5 ~ 8h,
Collect precipitation；
4) clean precipitation with water at least twice, being deposited at 60 ~ 80 DEG C after cleaning is dried 6 ~ 8 h, obtains described konjak sugar
Albumen.
The present invention also only has instant cleaning effect particular for cleaning agent in prior art, and can not long-acting guarantee porcelain
No longer get rusty or be infected with the technical problem of spot with metal, by research find by compounding Rhizoma amorphophalli glycoprotein can in porcelain and
Metallic surface forms layer protecting film, can open metal and porcelain with external environment isolation, and then avoid air and water
Vapour directly and metal reaction and form rust staining, it also avoid the porcelain disorganization that external environment impacts to porcelain and causes
With the problem turning yellow；And the Rhizoma amorphophalli glycoprotein adding also has certain bacteriostasis, metal and the life of porcelain surface can be avoided
Long mycete and moss.
As another optimization, step 2) in using ph6.0 ~ 7.2 na2hpo4-nah2po4Buffer solution.Using such ph
The buffer solution of scope can avoid the problem making glycoprotein activity lose efficacy because ph is improper, and then prepared sugar is effectively ensured
Albumen can form protecting film in article surface.
Optimize as another, step 2) in by Rhizoma amorphophalli powder described in step 1) and na2hpo4-nah2po4Buffer solution is with 1 g:
The mass volume ratio mix homogeneously of 200 ~ 400 ml, ultrasonic extraction 2 ~ 4 h at 50 ~ 70 DEG C, wherein, described ultrasonic power is
300~450 w.Extracted using ultrasound wave, extraction efficiency can be made higher, extract more Rhizoma amorphophalli glycoproteins, make production
Cost reduces.
A kind of method that metal and porcelain are carried out, using the described salt composite pair for cleaning metal and porcelain
Metal and porcelain are carried out.Using salt composite of the present invention, metal and porcelain are carried out, metal, porcelain can be removed with deep layer
The spot on device surface and rust staining, and will not metal and porcelain be caused to corrode, it is to avoid crack fracture and porcelain table in metal
The occurrence of face is corroded, long-acting guarantee can also be difficult contaminant using the metal after salt composite of the present invention cleaning and porcelain
Provide and get rusty, to metal and porcelain, there is protection effect.
As optimization, by the described salt composite being used for cleaning metal and porcelain and water according to 1g:10 ~ 50 ml quality
Volume ratio is hybridly prepared into cleaning solution, using described cleaning solution, metal and porcelain is carried out.Present aspect salt composite is joined
After becoming aqueous solution, then pay metal and porcelain is carried out, the elimination effect of complex can be made more preferably, cleaning effect is more excellent.
Compared to existing technology, can be removed with deep layer during salt composite of the present invention the invention has the following beneficial effects: adopting
Metal, the spot on porcelain surface and rust staining, and more crucially adopt the formula of salt composite of the present invention can ensure acid
While carrying out effective cleaning to the spot on metal, porcelain surface, metal will not be caused corrode and make metal surface to produce to split
Stricture of vagina, also will not be reacted with compositions such as the Calcium Carbonate in porcelain, the cavity in porcelain will not be made to become many, also will not corrode porcelain
The enamel on surface, does not cause rigid injury to porcelain and metal in cleaning simultaneously, effectively extends the use of porcelain and metal
Time limit.Additionally, Component Source is extensive in inventive formulation, price is more cheap, is accepted employing by vast producer, has good
Good market application foreground.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.The implementation case with the technology of the present invention is being
Under the premise of implemented, now provide detailed embodiment and specific operating process be creative the present invention to be described, but
Protection scope of the present invention is not limited to below example.
Embodiment 1
A kind of salt composite for cleaning metal and porcelain, including the component of following weight portion: 50 parts of crude salts, 15 parts of amino sulphurs
Acid, 5 parts of sodium citrates, 1 part of citric acid, 2 parts of mandelic acid and 3 parts of gallic acids.
Using the present embodiment salt composite, metal and porcelain are carried out, the metal surface after result display cleaning is no dirty
Stain, there is obvious metallic luster, cleaning does not make metal surface crackle, the porcelain after cleaning returns to this by yellow
Color, and clean and do not make porcelain decolouring, the phenomenon that comes off of enamel occur, while ensureing good cleaning effect, it is to avoid right
Metal and porcelain damage.
Embodiment 2
A kind of salt composite for cleaning metal and porcelain, including the component of following weight portion: 60 parts of crude salts, 25 parts of amino sulphurs
Acid, 8 parts of sodium citrates, 5 parts of citric acids, 4 parts of mandelic acid, 5 parts of gallic acids and 7 parts of aqueous polyurethanes.
Using the present embodiment salt composite, metal and porcelain are carried out, the metal surface after result display cleaning is no dirty
Stain and rust staining, there is obvious metallic luster, cleaning does not make metal surface crackle, also there is metal surface to original
Crackle is filled up, make metallic surface smooth, it is to avoid the metal fracture risk that the Metal Crack of former presence is brought；Cleaning
Porcelain afterwards returns to true qualities and the not coloured mottle in local precipitation presence by yellow, and cleaning does not make porcelain decolouring, glaze
The phenomenon that matter comes off, and the hole that original surface exists to porcelain carried out repairing it is ensured that porcelain surface smooth complete,
While ensureing good cleaning effect, it is to avoid metal and porcelain damaged.
Embodiment 3
A kind of salt composite for cleaning metal and porcelain, including the component of following weight portion: 70 parts of crude salts, 35 parts of amino sulphurs
Acid, 10 parts of sodium citrates, 8 parts of citric acids, 5 parts of mandelic acid, 8 parts of gallic acids, 9 parts of aqueous polyurethanes and 2 parts of Rhizoma amorphophalli glycoproteins；
Described Rhizoma amorphophalli glycoprotein adopts following method to be obtained:
1) Rhizoma amorphophalli cleaned, remove the peel, pulverized after 8h being dried at 60 DEG C, obtain Rhizoma amorphophalli powder；
2) by the na of Rhizoma amorphophalli powder described in step 1) and ph7.02hpo4-nah2po4Buffer solution is with the quality volume of 1 g:200 ml
Ratio mixing, after 50 DEG C of ultrasonic extraction 2 h, takes lixiviating solution to filter, collects clear liquid；Wherein, described ultrasonic power is 300 w；
3) by step 2) described clear liquid and the ethanol collected mixes according to the volume ratio of 1:2 and at room temperature after standing 5h, collects
Precipitation；
4) clean precipitation with water at least twice, being deposited at 60 DEG C after cleaning is dried 8 h, obtains described Rhizoma amorphophalli glycoprotein.
Using the present embodiment salt composite, metal and porcelain are carried out, the metal surface after result display cleaning is no dirty
Stain and rust staining, there is obvious metallic luster, cleaning does not make metal surface crackle, also there is metal surface to original
Crackle is filled up, make metallic surface smooth, it is to avoid the metal fracture risk that the Metal Crack of former presence is brought；Cleaning
Porcelain afterwards returns to true qualities and the not coloured mottle in local precipitation presence by yellow, and cleaning does not make porcelain decolouring, glaze
The phenomenon that matter comes off, and the hole that original surface exists to porcelain carried out repairing it is ensured that porcelain surface smooth complete,
While ensureing good cleaning effect, it is to avoid metal and porcelain damaged.Can also be in gold using the present embodiment cleaning
Belong to and layer protective layer is brought on the surface of porcelain, directly contact with metal and porcelain in order to completely cut off external environment, can long-acting protect
Card metal and porcelain are no longer contaminated and be infected with spot or react with oxygen and cause to get rusty.
Finally illustrate, above example only in order to technical scheme to be described and unrestricted, although with reference to relatively
Good embodiment has been described in detail to the present invention, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent, the objective without deviating from technical solution of the present invention and scope, and it all should be covered at this
In the middle of the right of invention.
Claims (8)
1. a kind of salt composite for cleaning metal and porcelain is it is characterised in that include the component of following weight portion: 50 ~ 70
Part crude salt, 15 ~ 35 parts of sulfamic acids, 5 ~ 10 parts of sodium citrates and 1 ~ 8 part of citric acid.
2. be used for according to claim 1 cleaning the salt composite of metal and porcelain it is characterised in that also include 2 ~ 5 parts flat
Fructus Persicae acid and 3 ~ 8 parts of gallic acids.
3. it is used for according to claim 1 cleaning the salt composite of metal and porcelain it is characterised in that also including 4 ~ 9 parts of water
Property polyurethane.
4. it is used for according to claim 1 cleaning the salt composite of metal and porcelain it is characterised in that also including 2 ~ 7 parts of evil spirits
Taro glycoprotein；Described Rhizoma amorphophalli glycoprotein adopts following method to be obtained:
1) Rhizoma amorphophalli cleaned, remove the peel, after 8 ~ 12h being dried at 60 ~ 80 DEG C, carry out pulverizing and obtain Rhizoma amorphophalli powder；
2) by Rhizoma amorphophalli powder described in step 1) and na2hpo4-nah2po4Buffer solution is mixed with the mass volume ratio of 1 g:200 ~ 400 ml
Close uniformly, after 50 ~ 70 DEG C of extraction 2 ~ 4 h, take lixiviating solution to filter, collect clear liquid；
3) by step 2) described clear liquid and the ethanol collected mixes according to the volume ratio of 1:2 ~ 4 and at room temperature after standing 5 ~ 8h,
Collect precipitation；
4) clean precipitation with water at least twice, being deposited at 60 ~ 80 DEG C after cleaning is dried 6 ~ 8 h, obtains described konjak sugar
Albumen.
5. be used for cleaning the salt composite of metal and porcelain it is characterised in that step 2 according to claim 4) in adopt
The na of ph6.0 ~ 7.22hpo4-nah2po4Buffer solution.
6. be used for cleaning the salt composite of metal and porcelain it is characterised in that step 2 according to claim 4) in by step
1) described Rhizoma amorphophalli powder and na2hpo4-nah2po4Buffer solution with the mass volume ratio mix homogeneously of 1 g:200 ~ 400 ml, in 50
Ultrasonic extraction 2 ~ 4 h at ~ 70 DEG C, wherein, described ultrasonic power is 300 ~ 450 w.
7. a kind of method that metal and porcelain are carried out it is characterised in that using claim 1 ~ 6 arbitrary described for clear
The salt composite of clean metal and porcelain is carried out to metal and porcelain.
8. the method according to claim 7 metal and porcelain being carried out is it is characterised in that be used for cleaning gold by described
Belong to and the salt composite of porcelain is hybridly prepared into cleaning solution with water according to the mass volume ratio of 1g:10 ~ 50 ml, using described clear
Clean liquid is carried out to metal and porcelain.
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