CN106701349B - A kind of three-in-one automobile evaporator cleaning agent and preparation method thereof - Google Patents

A kind of three-in-one automobile evaporator cleaning agent and preparation method thereof Download PDF

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CN106701349B
CN106701349B CN201611220122.7A CN201611220122A CN106701349B CN 106701349 B CN106701349 B CN 106701349B CN 201611220122 A CN201611220122 A CN 201611220122A CN 106701349 B CN106701349 B CN 106701349B
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parts
agent
weight
cleaning agent
mixture
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CN106701349A (en
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郑俊明
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Dongguan Huachang Electromechanical Technology Co Ltd
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Dongguan Huachang Electromechanical Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
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    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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    • C11D3/33—Amino carboxylic acids
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    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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    • C11D3/361—Phosphonates, phosphinates or phosphonites
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
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    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11D1/721—End blocked ethers

Abstract

The present invention relates to cleaning agent technical fields, it more particularly to three-in-one automobile evaporator cleaning agent and preparation method thereof, is made of the raw material of following weight percents: nonionic surfactant 10-15%, anionic surfactant 10-15%, chelating agent 6-20%, corrosion inhibiter 2-5%, nano material 1-5%, eliminating smell agent 2-10%, deionized water 10-45%, plant extraction liquid 3-6%, mineral oil 0.1-0.3%, peppermint oil 1-5%.The present invention prepares three-in-one automobile evaporator cleaning agent and infiltration emulsification decontamination, blistering cleaning and antibacterial three-in-one automobile evaporator cleaning agent, cleaning agent emulsifying effectiveness of the invention is good, biological degradability is good, taste removal is good, performance is stablized, and storage time is long, and preparation method is simple, it can be mass, it is easy to operate.

Description

A kind of three-in-one automobile evaporator cleaning agent and preparation method thereof
Technical field
The present invention relates to cleaning agent technical fields, and in particular to a kind of three-in-one automobile evaporator cleaning agent and its preparation Method.
Background technique
As car industry quickly increases, parts industry has also obtained development at full speed, and air conditioning for automobiles is used as and mentions A kind of important component of high vehicle ride comfort is approved by vast automobile manufacturing enterprise and consumer.The core of air-conditioning is Evaporator after air conditioning for automobiles long-time use, can gather a large amount of dust inside evaporator, dedicated cleaning agent is needed to carry out Cleaning, current cleaning way are first to be emulsified using detergent to obstinate dirty agent, reuse cleaning agent and have emulsified to it Bubble finally reuses bacteriostatic agent to its antibacterial cleaning treatment, avoids subsequent use from producing a large amount of bacterium, pollute vehicle convenient for rinsing Interior air.
Summary of the invention
The purpose of the present invention is be directed to above-mentioned deficiency in the prior art, provide and infiltration emulsification decontamination, blistering cleaning and Antibacterial three-in-one automobile evaporator cleaning agent, cleaning agent emulsifying effectiveness of the invention is good, and biological degradability is good, taste removal Good, performance is stablized, and storage time is long, and preparation method is simple, can be mass, easy to operate
The purpose of the present invention is achieved through the following technical solutions: a kind of three-in-one automobile evaporator cleaning agent, by following The raw material of weight percent forms:
Nonionic surfactant 10-15%
Anionic surfactant 10-15%
Chelating agent 6-20%
Corrosion inhibiter 2-5%
Nano material 1-5%
Eliminating smell agent 2-10%
Deionized water 10-45%
Plant extraction liquid 3-6%
Mineral oil 0.1-0.3%
Peppermint oil 1-5%.
Preferably, it is made of the raw material of following weight percents:
Nonionic surfactant 1215%
Anionic surfactant 12-15%
Chelating agent 12-20%
Corrosion inhibiter 3-5%
Nano material 2-5%
Eliminating smell agent 5-10%
Deionized water 20-45%
Plant extraction liquid 3-6%
Mineral oil 0.1-0.3%
Peppermint oil 1-5%.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 0.1-1:1:1.5-3.5 with N- lauroyl musculamine acid sodium.Brij 35 Sodium sulphate has excellent decontamination, emulsification and foam performance, and secondary alkyl sulfonate biological degradability is splendid, is green surface-active Agent, resistance to hard water, N- lauroyl musculamine acid sodium has good hair compatibility, extremely mildly, with various surfactant compatibilities pole By force, strong using the anionic surfactant emulsification dirt-removing power obtained after above-mentioned three compounding, while performance is mildly stablized, it is raw Object degradability is good.
Wherein, the nonionic surfactant is by sorbitan monooleate, alkyl glycosides, alkylphenol-polyethenoxy Ether, isomeric alcohol polyethenoxy ether carboxylate are the mixture of 1-5:0.5-3.5:1-3:3 with weight fraction ratio.Using it is above-mentioned it is non-from Sub- surfactant is compounded, and the hydrophilic radical with ehter bond, hydroxyl, amido and carboxyl, good hydrophilic property, stability are formed It is high.
Wherein, the chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetramethylene phosphonic acid, second two The mixture of three kinds or more in the adjacent phenylacetic acid of amine tetraacethyl, ethylenediamine two, sodium potassium tartrate tetrahydrate and ammonium citrate.Horse third Copolymer is a kind of polyelectrolyte of low molecular weight, and horse propylene copolymer has very strong peptizaiton, thermostabilization to carbonate etc. Property it is high, can be used under the mal-conditions such as 300 DEG C of high temperature, there is good compatibility and synergy with other water treatment agents Effect.Hydroxy ethylene diphosphonic acid and ethylenediamine tetramethylene phosphonic acid are organic phosphates chelating agent, hydroxy ethylene diphosphonic acid Stable complex compound can be formed with various metals ions such as iron, copper, zinc, the oxide of metal surface can be dissolved.It is resistance to acid and alkali, resistance to The more other organic phospho acids of oxychloride performance (salt) are good.Six annulus chelates can be formed with underwater gold category ion, especially calcium ion, Thus have preferable scale inhibition effect and have apparent threshold effect, when being used in combination with other water treatment agents, shows ideal Synergistic effect；Ethylenediamine tetramethylene phosphonic acid (EDTMPA) has the ability of very strong chelated metal ions, with copper ion Complexation constant is big, stable chelate can be formed with copper, said two devices compounding is stronger to the binding ability of metal, and boil together effect More preferably.Ethylenediamine tetra-acetic acid and the adjacent phenylacetic acid of ethylenediamine two are amide quasi-chelate compound, are not only had to metal ion extremely strong Capture effect, also there is alkali resistance outstanding and dispersibility, wherein ethylenediamine tetra-acetic acid and Mg2+、Ca2+、Mn2+、Fe2+Deng two Valence metal ion has very strong binding force, and the adjacent phenylacetic acid of ethylenediamine two has chelation and peptizaiton, has complexity Molecular structure, molecule is annular in shape, stable water-soluble compound can be generated with metal ion, and be firmly adsorbed on crystal table Face guarantees the stability of water column stability and chelate, while the adjacent sodium of ethylenediamine two can prevent iron ion to be catalyzed The stench of fatty acid avoids discoloration and peculiar smell.Sodium potassium tartrate tetrahydrate and ammonium citrate are inorganic salts chelating agent, are had a wide range of application Model, resistance to highly basic.Preferably, chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and sodium potassium tartrate tetrahydrate The mixture for being 1-5:0.5-3.5:4-9:1-7 by mass parts ratio.
Wherein, the corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzothiazole with parts by weight as 1-5:1 Mixture.Corrosion inhibiter of the invention has polar group and nonpolar base, has asymmetry, has good suction to metal surface Attached property is adsorbed film type corrosion inhibiter, and when inhibitor molecular is after metal surface is adsorbed, longer nonpolarity base is in Van der Waals force Under the action of close-packed arrays, to form firm adsorbed film.Wherein, dredging base benzothiazole is had very to copper and copper alloy Effective corrosion mitigating effect, and also can effectively slow down the corrosion rate of copper and copper alloy at a lower temperature.
Wherein, the nano material is nano-TiO2、ZnO、Fe2O3、Fe3O4、SiO2, one of nano-bentonite or two The combination of kind.The nano material is nano inorganic material, and stable stream can be formed by the peptizaiton of surfactant Body, and it is with strong adsorption capacity and flocculation ability can adsorb from coal ash metal ion and with detergent It rinses out, while there is good mating reaction with the chelating agent of the application, the surface of chelating agent can be coated on, form nanometer Particle/chelating agent complex, the nanoparticle/chelating agent complex is to Cr2+、Cu2+、Ni2+Ion has good chelating energy Power, Cr2+、Cu2+、Ni2+Ion chelating packet and concentration respectively reach 30mg/L, 60mg/L and 40mg/L.Nano material tool simultaneously Playing the role of photocatalytic degradation surfactant can under illumination condition after forming foam after surfactant emulsifies blistering Defoaming degradation, does not pollute water body, biological degradability is good, environment-protecting and non-poisonous.
Wherein, the eliminating smell agent includes the raw material of following parts by weight: 4-7 parts of zeolites, 1-5 parts of ethyl alcohol, 5-15 parts of inclusions Agent, 2-8 parts of atlapulgites and 10-20 parts of lye.The preparation method of the eliminating smell agent is that zeolite is soaked in concentration is 1.5- In the lye of 3molL-1, drying calcining adds ethyl alcohol, inclusion agents and atlapulgite and is stirred to obtain the final product.The lye is Sodium hydroxide or potassium hydroxide solution, the inclusion agents are that cyclodextrin and nano magnesia are the mixed of 1-5:2-6 in parts by weight Close object.The inclusion agents are the mixture that cyclodextrin and nano magnesia are 1-5:2-6 in parts by weight.Its adsorption mechanism is Harmless odorlessness substance is converted by odorous gas by adsorbing concurrent biochemical reaction, in the electronics level of nano magnesia There are oxygen defect and magnesium defect, the presence of exactly these defects makes to dispel taste with strong chemical adsorption capacity, nano magnesia Also there is high specific surface area, the defect for being exposed to surface is also just more, and gas can come into full contact with nano powder, thus adsorb Ability is also just stronger.Meanwhile nano magnesia can also be by the cell membrane disruption of bacterium.Such Antibacterial Mechanism can overcome silver Series antibacterial agent acts on the insufficient disadvantage that slow, easy to change and titanium dioxide series antibacterial agent needs ultraviolet light to irradiate.Cyclodextrin molecular In wide at the top and narrow at the bottom, both ends open, hollow tubular article, intracavitary portion is in relative hydrophobicity, and all hydroxyls are then outside molecule, because And it is capable of providing a hydrophobic binding site, as the various gas molecules of main body envelope, forms clathrate, and changes By the physics and chemical property of inclusion complex.Its cyclodextrin includes beta-cyclodextrin, dimethyl-β-cyclodextrin, ethoxy-β-ring paste Essence, it is preferable that cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin are 1-2 by ratio of weight and the number of copies: The mixture of 2-5:0.1-1.The adsorption method that this eliminating smell agent is combined using physical absorption and chemisorption, physical absorption absorption It is combined using zeolite and atlapulgite, and zeolite also carries out alkali process, is soaked in zeolite in lye, has dissolved in zeolite Amorphous impurities, improve the crystallinity of zeolite, to improve specific surface area and pore volume, increase physical absorption ability.Change Absorption is learned using cyclodextrin and nano magnesia, there is good binding ability with scent molecule.
Wherein, the plant extraction liquid includes the raw material of following parts by weight: 5-15 parts of gleditsia sinensis, 1-7 portions of beets, 2-9 parts Timbol, 3-8 portions of lemons, 1-4 parts of lotus leaf powders, 0.5-2 portions of aloes.Gleditsia sinensis contains gleditschiasaponin, palmitinic acid, stearic acid, oil Ingredients, the alkaloids contained by it such as acid, sub- sterol, sitosterol, nonacosane there are also health care and kill in addition to washing function Bacterium function, using spaonin powder to scavenger surface without any corrosion, it, better than other any chemicals, is a plant Object surfactant is optimal efficiency natural surface-active cleaning agent.It combines the glycine betaine in beet, in timbol Soap two, the citric acid in lemon, the Nuciferine in lotus leaf powder greatly improves the deoiling ability of stain, naturally at It is point environment-protecting and non-poisonous, do not damage product surface, while lotus leaf powder surface is whether there is or not the wax mastoid process structure of several microns grade, while lotus leaf There is lotus leaf powder alkali, greasy dirt dust can be taken away under the action of water and be decomposed to lotus leaf powder alkali and these structures, reduce residual in powder There are the moisture of product surface.Lotus leaf powder alkali can also will form layer protecting film in product surface, and greasy dirt dust is prevented to be adsorbed in Tableware surface reduces the contaminated probability of tableware.Aloe contain aloe saponaria glucoside, Aloesin, tinctura aloes etc. it is a variety of chemistry at Point, there is bactericidal effect, purify product surface.
A kind of preparation method of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 20-30min are warming up to 80-100 DEG C, inhibition are added Agent, nano material, eliminating smell agent, peppermint oil stir 5-10min, are cooled to 20-30 DEG C, and plant extraction liquid and mineral oil stirring is added To obtain the final product；This method preparation is simple, easy to operate, and the detergent that can be mass, and prepare has good stability, storage Time is long.Wherein, the plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, stir It mixes and is ground to 50-100 mesh, be placed in the ethanol solution that content concn is 60-80% and extract 2-3 times, lotus leaf powder is added and is stirred To obtain the final product.Above-mentioned plant material is extracted using this method, can the chemical component in above-mentioned plant effectively extracted, it is right The recovery rate of chemical bases is high, and retains in plant and protect composition, effective protection product surface.
Beneficial effects of the present invention:
One, a kind of automobile evaporator cleaning agent of the invention is living by a variety of nonionic surfactants and anionic surface Property agent compounded, the emulsifying capacity and cleaning ability of cleaning agent of deducting a percentage, using wetting agent reduce solution surface tension, make to clean The more readily soluble easy cleaning of agent reduces the erosion to automobile metal surface using corrosion inhibiter；Use a variety of cleaning agents for forming and preparing Volatile, biological degradability is good；
Two, the nonionic surfactant compounding that the present invention uses is made, relative to single use nonionic table after compounding Face activating agent performance is more preferable, and clean effect is more preferable, while also having the advantage that 1, surface tension is low, and wetability is good, thus more It is easy in body surface drawout；2, foamability is strong, and the foam formed is stablized, and has stronger detergency ability；3, material Compatibility is good, can carry out good coordinated with other raw materials, give full play to synergistic effect；4, the alkyl glycosides used is to plant Material resource material, thus, it is possible to by quickly, thoroughly degrading；
Three, the anionic surfactant compounding that the present invention uses is made, dodecyl alcohol polyoxyethylene ether sodium sulfate, secondary Sodium alkyl sulfonate and N- lauroyl musculamine acid sodium have good compatibility, and clean effect is more preferable after compounding, easily biological-degradable, Performance is mildly stablized；
Four, the corrosion inhibiter that the present invention uses uses organic inhibitor to compound with vapour phase inhibitor and is made, can be to a variety of gold Metal surface forms chemisorbed layer or insoluble surface protection film；
Five, the adsorption method that eliminating smell agent of the invention is combined using physical absorption and chemisorption, physical absorption absorption It is combined using zeolite and atlapulgite, and zeolite also carries out alkali process, is soaked in zeolite in lye, has dissolved in zeolite Amorphous impurities, improve the crystallinity of zeolite, to improve specific surface area and pore volume, increase physical absorption ability.Change Absorption is learned using cyclodextrin and nano magnesia, there is good binding ability with scent molecule；
Six, the present invention is used cooperatively using nano material and chelating agent, forms nanoparticle/chelating agent complex, is increased To the soil release performance of metal ion；
Seven, the present invention reduces solution surface tension using plant extraction liquid, makes the more readily soluble easy cleaning of cleaning agent；
Eight, preparation method of the invention is simple, can be mass, easy to operate.
Specific embodiment
The invention will be further described with the following Examples.
Embodiment 1
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 10Kg, anionic surfactant 12Kg, chelating agent 6Kg, corrosion inhibiter 2Kg, nano material 1Kg, eliminating smell agent 2Kg, go from Sub- water 12Kg, plant extraction liquid 3Kg, mineral oil 0.15Kg, peppermint oil 2Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 0.8:1:2.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by losing Water sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio The mixture of 1:0.5:1:3；The chelating agent is ethylenediamine tetramethylene phosphonic acid, ethylenediamine tetra-acetic acid, the adjacent phenyl of ethylenediamine two The mixture that acetic acid and ammonium citrate are 1:0.5:4:1 by mass parts ratio.The corrosion inhibiter be 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and It is the mixture of 2:1 that 2-, which dredges base benzothiazole with parts by weight,；The nano material is that nanometer is nano-bentonite；The taste removal Agent includes the raw material of following parts by weight: 4 parts of zeolites, 5 parts of ethyl alcohol, 15 parts of inclusion agents, 8 parts of atlapulgites and 20 parts of lye；Institute Stating inclusion agents is the mixture that cyclodextrin and nano magnesia are 5:2 in parts by weight.The inclusion agents are cyclodextrin and nanometer Magnesia is the mixture of 3:5 in parts by weight.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, ethoxy-β-ring paste Essence is the mixture of 1:5:1 by ratio of weight and the number of copies；The plant extraction liquid includes the raw material of following parts by weight: 12 parts of soaps Angle, 7 portions of beets, 4 parts of timbols, 6 portions of lemons, 4 parts of lotus leaf powders, 2 portions of aloes.
A kind of preparation side of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 20-30min are warming up to 80-100 DEG C, inhibition are added Agent, nano material, eliminating smell agent, peppermint oil stir 5-10min, are cooled to 20-30 DEG C, and plant extraction liquid and mineral oil stirring is added To obtain the final product；Wherein, the plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, stirring It is ground to 50-100 mesh, is placed in the ethanol solution that content concn is 70% and extracts 2-3 times, lotus leaf powder is added and is stirred to obtain the final product.
Embodiment 2
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 12Kg, anionic surfactant 10Kg, chelating agent 10Kg, corrosion inhibiter 5Kg, nano material 3Kg, eliminating smell agent 4Kg, go from Sub- water 45Kg, plant extraction liquid 5Kg, mineral oil 0.3Kg, peppermint oil 4Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 0.1:1:3.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by losing Water sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio The mixture of 1:3.5:1:3；The chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and winestone The mixture that sour potassium sodium is 1:0.5:4:7 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzene And thiazole is the mixture of 1:1 with parts by weight；The nano material is nano-TiO2；The eliminating smell agent includes following parts by weight Several raw material: 7 parts of zeolites, 1 part of ethyl alcohol, 5 parts of inclusion agents, 2 parts of atlapulgites and 20 parts of lye；The inclusion agents are cyclodextrin It is in parts by weight the mixture of 2:5 with nano magnesia.The inclusion agents be cyclodextrin and nano magnesia in parts by weight For the mixture of 2:5.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin are by ratio of weight and the number of copies The mixture of 1:2:0.1；The plant extraction liquid includes the raw material of following parts by weight: 5 parts of gleditsia sinensis, 1 portion of beet, 2 parts without trouble Sub- skin, 3 portions of lemons, 1 part of lotus leaf powder, 0.5 portion of aloe.
A kind of preparation side of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 20min are warming up to 90 DEG C, corrosion inhibiter, nanometer are added Material, eliminating smell agent, peppermint oil stir 10min, are cooled to 20 DEG C, and plant extraction liquid is added and mineral oil stirs to obtain the final product；Wherein, institute State plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, agitation grinding to 80 mesh, It is placed in the ethanol solution that content concn is 70Kg and extracts 2 times, lotus leaf powder is added and is stirred to obtain the final product.
Embodiment 3
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 15Kg, anionic surfactant 15Kg, chelating agent 15Kg, corrosion inhibiter 4Kg, nano material 4Kg, eliminating smell agent 6Kg, go from Sub- water 30Kg, plant extraction liquid 6Kg, mineral oil 0.1Kg, peppermint oil 3Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 1:1:3.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by dehydration Sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio for 5: The mixture of 3.5:3:3；The chelating agent horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and potassium tartrate The mixture that sodium is 5:3.5:9:7 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzo Thiazole is the mixture of 2:1 with parts by weight；The nano material is nano-ZnO；The eliminating smell agent includes following parts by weight Raw material: 5 parts of zeolites, 5 parts of ethyl alcohol, 15 parts of inclusion agents, 8 parts of atlapulgites and 11 parts of lye；The inclusion agents be cyclodextrin and Nano magnesia is the mixture of 5:6 in parts by weight.The inclusion agents are cyclodextrin and nano magnesia is in parts by weight The mixture of 5:6.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin are 1 by ratio of weight and the number of copies: The mixture of 5:1；The plant extraction liquid includes the raw material of following parts by weight: 15 parts of gleditsia sinensis, 7 portions of beets, 9 parts of soapberrys Skin, 8 portions of lemons, 4 parts of lotus leaf powders, 2 portions of aloes.
A kind of preparation side of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 30min are warming up to 80 DEG C, corrosion inhibiter, nanometer are added Material, eliminating smell agent, peppermint oil stir 5min, are cooled to 30 DEG C, and plant extraction liquid is added and mineral oil stirs to obtain the final product；Wherein, institute State plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, agitation grinding to 90 mesh, It is placed in the ethanol solution that content concn is 80Kg and extracts 2 times, lotus leaf powder is added and is stirred to obtain the final product.
Embodiment 4
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 13Kg, it anionic surfactant 14Kg, chelating agent 18Kg, corrosion inhibiter 3Kg, nano material 2Kg, eliminating smell agent 8Kg, goes Ionized water 20Kg, plant extraction liquid 4Kg, mineral oil 0.2Kg, peppermint oil 5Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 05:1:2 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by dehydration mountain Pears alcohol oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are 1-5 with weight fraction ratio: The mixture of 2:2:3；The chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and potassium tartrate The mixture that sodium is 2:3:5:1 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzothiazole It is the mixture of 4:1 with parts by weight；The nano material is that nanometer is Fe2O3 and mixing of the Fe3O4 with parts by weight for 2:1 Object；The eliminating smell agent includes the raw material of following parts by weight: 5 parts of zeolites, 2 parts of ethyl alcohol, 12 parts of inclusion agents, 7 parts of atlapulgites and 12 Part lye；The inclusion agents are the mixture that cyclodextrin and nano magnesia are 3:5 in parts by weight.The inclusion agents are ring paste Essence and nano magnesia are the mixture of 3:2 in parts by weight.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyl second Group-beta-cyclodextrin is the mixture of 2:5:0.5 by ratio of weight and the number of copies；The plant extraction liquid includes the original of following parts by weight Material: 6 parts of gleditsia sinensis, 6 portions of beets, 4 parts of timbols, 3 portions of lemons, 1 part of lotus leaf powder, 1.5 portions of aloes.
A kind of preparation side of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 25min are warming up to 80 DEG C, corrosion inhibiter, nanometer are added Material, eliminating smell agent, peppermint oil stir 5min, are cooled to 27 DEG C, and plant extraction liquid is added and mineral oil stirs to obtain the final product；Wherein, institute State plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, agitation grinding to 80 mesh, It is placed in the ethanol solution that content concn is 65Kg and extracts 3 times, lotus leaf powder is added and is stirred to obtain the final product.
Embodiment 5
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 12Kg, it anionic surfactant 13Kg, chelating agent 20Kg, corrosion inhibiter 4Kg, nano material 2Kg, eliminating smell agent 10Kg, goes Ionized water 10Kg, plant extraction liquid 3Kg, mineral oil 0.1Kg, peppermint oil 1Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 0.8:1:1.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by losing Water sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio The mixture of 2:0.5:3:3；The chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid and ethylenediamine tetramethylene phosphonic acid The mixture for being 3.5:4:1 by mass parts ratio.The corrosion inhibiter be 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzothiazole with Parts by weight are the mixture of 4:1；The nano material is nano TiO 2 and SiO2It is the mixture of 1:1 with parts by weight；Institute State the raw material that eliminating smell agent includes following parts by weight: 5 parts of zeolites, 5 parts of ethyl alcohol, 14 parts of inclusion agents, 7 parts of atlapulgites and 18 parts of alkali Liquid；The inclusion agents are the mixture that cyclodextrin and nano magnesia are 4:5 in parts by weight.The inclusion agents be cyclodextrin and Nano magnesia is the mixture of 3:5 in parts by weight.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, ethoxy-β- Cyclodextrin is the mixture of 1:2:0.8 by ratio of weight and the number of copies；The plant extraction liquid includes the raw material of following parts by weight: 14 parts Gleditsia sinensis, 5 portions of beets, 8 parts of timbols, 7 portions of lemons, 3 parts of lotus leaf powders, 1.5 portions of aloes.
A kind of preparation side of three-in-one automobile evaporator cleaning agent, by the non-ionic surface active of above-mentioned weight percent Agent, anionic surfactant, chelating agent and deionized water mixing, stirring 26min are warming up to 90 DEG C, corrosion inhibiter, nanometer are added Material, eliminating smell agent, peppermint oil stir 6min, are cooled to 27 DEG C, and plant extraction liquid is added and mineral oil stirs to obtain the final product；Wherein, institute State plant extraction liquid the preparation method comprises the following steps: by gleditsia sinensis, beet, timbol, lemon and aloe particle, agitation grinding to 68 mesh, It is placed in the ethanol solution that content concn is 60Kg and extracts 2-3 times, lotus leaf powder is added and is stirred to obtain the final product.
Embodiment 6
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 15Kg, anionic surfactant 15Kg, chelating agent 15Kg, corrosion inhibiter 4Kg, nano material 4Kg, eliminating smell agent 6Kg, go from Sub- water 30Kg, plant extraction liquid 6Kg, mineral oil 0.1Kg, peppermint oil 3Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 0.1:1:3.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by losing Water sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio The mixture of 1:3.5:1:3；The chelating agent is horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and winestone The mixture that sour potassium sodium is 1:0.5:4:7 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzene And thiazole is the mixture of 1:1 with parts by weight；The nano material is nano TiO 2；The eliminating smell agent includes following parts by weight Several raw material: 5 parts of zeolites, 5 parts of ethyl alcohol, 14 parts of inclusion agents, 7 parts of atlapulgites and 18 parts of lye；The inclusion agents are cyclodextrin It is in parts by weight the mixture of 4:5 with nano magnesia.The inclusion agents be cyclodextrin and nano magnesia in parts by weight For the mixture of 3:5.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin are by ratio of weight and the number of copies The mixture of 1:2:0.8；The plant extraction liquid includes the raw material of following parts by weight: 14 parts of gleditsia sinensis, 5 portions of beets, 8 parts without trouble Sub- skin, 7 portions of lemons, 3 parts of lotus leaf powders, 1.5 portions of aloes.
Embodiment 7
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 13Kg, it anionic surfactant 14Kg, chelating agent 18Kg, corrosion inhibiter 3Kg, nano material 2Kg, eliminating smell agent 8Kg, goes Ionized water 20Kg, plant extraction liquid 4Kg, mineral oil 0.2Kg, peppermint oil 5Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 1:1:3.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by dehydration Sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio for 5: The mixture of 3.5:3:3；The chelating agent horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and potassium tartrate The mixture that sodium is 5:3.5:9:7 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzo Thiazole is the mixture of 2:1 with parts by weight；The nano material is nano-ZnO；The eliminating smell agent includes following parts by weight Raw material: 5 parts of zeolites, 2 parts of ethyl alcohol, 12 parts of inclusion agents, 7 parts of atlapulgites and 12 parts of lye；The inclusion agents are cyclodextrin and receive Rice magnesia is the mixture of 3:2 in parts by weight.Cyclodextrin is beta-cyclodextrin, dimethyl-β-cyclodextrin, ethoxy-β-ring Dextrin is the mixture of 2:5:0.5 by ratio of weight and the number of copies；The plant extraction liquid includes the raw material of following parts by weight: 6 parts of soaps Angle, 6 portions of beets, 4 parts of timbols, 3 portions of lemons, 1 part of lotus leaf powder, 1.5 portions of aloes.
Embodiment 8
A kind of three-in-one automobile evaporator cleaning agent, is made of the raw material of following weight percents, and non-ionic surface is living Property agent 12Kg, anionic surfactant 10Kg, chelating agent 10Kg, corrosion inhibiter 5Kg, nano material 3Kg, eliminating smell agent 4Kg, go from Sub- water 45Kg, plant extraction liquid 5Kg, mineral oil 0.3Kg, peppermint oil 4Kg.
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate It with weight fraction ratio is the mixture of 1:2:3.5 with N- lauroyl musculamine acid sodium；The nonionic surfactant is by dehydration Sorbitan oleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, isomeric alcohol polyethenoxy ether carboxylate are with weight fraction ratio for 5: The mixture of 3.5:3:3；The chelating agent horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetra-acetic acid and potassium tartrate The mixture that sodium is 5:3.5:9:6 by mass parts ratio.The corrosion inhibiter is that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2- dredge base benzo Thiazole is the mixture of 1:1 with parts by weight；The nano material be nano TiO 2, ZnO and Fe2O with parts by weight for 1:1:1 Mixture；The eliminating smell agent includes the raw material of following parts by weight: 5 parts of zeolites, 5 parts of ethyl alcohol, 14 parts of inclusion agents, 7 parts of activity Carclazyte and 18 parts of lye；The inclusion agents are the mixture that cyclodextrin and nano magnesia are 4:5 in parts by weight.Cyclodextrin is Beta-cyclodextrin, dimethyl-β-cyclodextrin, hydroxyethyl-β-cyclodextrin are the mixture of 2:5:0.5 by ratio of weight and the number of copies；The plant Object extracting solution includes the raw material of following parts by weight: 8 parts of gleditsia sinensis, 5 portions of beets, 7 parts of timbols, 4 portions of lemons, 1 part of lotus leaf powder, 1.5 portions of aloes.
Performance test
The three-in-one automobile evaporator that above-described embodiment 1-8 is prepared is subjected to following test with cleaning agent, and will be commercially available Cleaning agent test as a comparison:
Erosion test: weighing fin for evaporator to be tested, then that fin for evaporator is soaked in cleaning agent 2 is small When, show that fin for evaporator impregnates the mass change of front and back；
Cleaning agent: being placed in 50 DEG C of interior 8 hours by stability test, sees whether crystallization metachromatism occur；
Biocidal property test: treating test evaporator with cleaning agent and carry out cleaning 10 minutes with fin, test 1 minute, it is 3 small When and the bacterial number after 6 hours；
Erosion test can be seen that the three-in-one automobile evaporator cleaning agent pair of the present embodiment 1-8 from above table Metal protection is weak, and solution property is stablized, and wherein the effect of embodiment 3,5 and 8 is best, and the effect of comparative example 1 is than embodiment 1-8 Effect it is poor, illustrate the present invention using chelating agent, corrosion inhibiter, nonionic surfactant and anionic surfactant compounding after It is good to the protectiveness of metal, prevent the effect of corrosion good；Biocidal property test is it can be seen that this reality from above table There is good fungistatic effect, antibacterial time after applying the cleaning to sheet metal of the three-in-one automobile evaporator cleaning agent of a 1-8 Long, wherein the effect of embodiment 5 is best, and flora number is only 152 CFU/g after 6 hours, much smaller than 200 CFU/g of standard, than 861 CFU/g of comparative example 1 are small, illustrate that the present invention is living using plant extraction liquid, nonionic surfactant and anionic surface Property agent compounding after it is good to the effect after cleaning metal surface.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention Matter and range.

Claims (6)

1. a kind of three-in-one automobile evaporator cleaning agent, it is characterised in that: be made of the raw material of following weight percents:
Nonionic surfactant 10-15%
Anionic surfactant 10-15%
Chelating agent 6-20%
Corrosion inhibiter 2-5%
Nano material 1-5%
Eliminating smell agent 2-10%
Deionized water 10-45%
Plant extraction liquid 3-6%
Mineral oil 0.1-0.3%
Peppermint oil 1-5%；
Wherein, the anionic surfactant is by dodecyl alcohol polyoxyethylene ether sodium sulfate, sodium secondary alkyl sulfonate and N- Lauroyl musculamine acid sodium is the mixture of 0.1-1:1:1.5-3.5 with weight fraction ratio；
Wherein, the nonionic surfactant be by sorbitan monooleate, alkyl glycosides, alkyl phenol polyoxyethylene ether, Isomeric alcohol polyethenoxy ether carboxylate is the mixture of 1-5:0.5-3.5:1-3:3 with weight fraction ratio；Wherein, the chelating agent For horse propylene copolymer, hydroxy ethylene diphosphonic acid, ethylenediamine tetramethylene phosphonic acid, ethylenediamine tetra-acetic acid, the adjacent phenyl of ethylenediamine two The mixture of three kinds or more in acetic acid, sodium potassium tartrate tetrahydrate and ammonium citrate；
Wherein, the eliminating smell agent includes the raw material of following parts by weight: 4-7 parts of zeolites, 1-5 parts of ethyl alcohol, 5-15 parts of inclusion agents, 2- 8 parts of atlapulgites and 10-20 parts of lye.
2. a kind of three-in-one automobile evaporator cleaning agent according to claim 1, it is characterised in that: by following weight hundred Divide the raw material composition of ratio:
Nonionic surfactant 12-15%
Anionic surfactant 12-15%
Chelating agent 12-20%
Corrosion inhibiter 3-5%
Nano material 2-5%
Eliminating smell agent 5-10%
Deionized water 20-45%
Plant extraction liquid 3-6%
Mineral oil 0.1-0.3%
Peppermint oil 1-5%.
3. a kind of three-in-one automobile evaporator cleaning agent according to claim 1, it is characterised in that: the corrosion inhibiter is It is the mixture of 1-5:1 that 1-hydroxy ethylidene-1,1-diphosphonic acid sodium and 2-, which dredge base benzothiazole with parts by weight,.
4. a kind of three-in-one automobile evaporator cleaning agent according to claim 1, it is characterised in that: the nano material For the combination of one or both of nano TiO 2, ZnO, Fe2O3, Fe3O4, SiO2, nano-bentonite.
5. a kind of three-in-one automobile evaporator cleaning agent according to claim 1, it is characterised in that: the plant extract Liquid includes the raw material of following parts by weight: 5-15 parts of gleditsia sinensis, 1-7 portions of beets, 2-9 parts of timbols, 3-8 portions of lemons, 1-4 portions of lotuses Ye Fen, 0.5-2 portions of aloes.
6. a kind of described in any item preparation methods of three-in-one automobile evaporator cleaning agent of claim 1-5, feature exist In: the nonionic surfactant of above-mentioned weight percent, anionic surfactant, chelating agent and deionized water are mixed, stirred It mixes 20-30min and is warming up to 80-100 DEG C, corrosion inhibiter, nano material, eliminating smell agent, peppermint oil is added and stirs 5-10min, is cooled to 20-30 DEG C, plant extraction liquid is added and mineral oil stirs to obtain the final product；Wherein, the plant extraction liquid the preparation method comprises the following steps: by soap Angle, beet, timbol, lemon and aloe particle, agitation grinding to 50-100 mesh are placed in the second that content concn is 60-80% It is extracted 2-3 times in alcoholic solution, lotus leaf powder is added and is stirred to obtain the final product.
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