CN106350273A - 一种可消除钙离子沉淀的洗涤剂 - Google Patents

一种可消除钙离子沉淀的洗涤剂 Download PDF

Info

Publication number
CN106350273A
CN106350273A CN201610723236.7A CN201610723236A CN106350273A CN 106350273 A CN106350273 A CN 106350273A CN 201610723236 A CN201610723236 A CN 201610723236A CN 106350273 A CN106350273 A CN 106350273A
Authority
CN
China
Prior art keywords
sodium
detergent
chemical constitution
calcium ions
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610723236.7A
Other languages
English (en)
Inventor
郑东峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Tianxi Of Biological Science And Technology Co Ltd
Original Assignee
Hubei Tianxi Of Biological Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Tianxi Of Biological Science And Technology Co Ltd filed Critical Hubei Tianxi Of Biological Science And Technology Co Ltd
Priority to CN201610723236.7A priority Critical patent/CN106350273A/zh
Publication of CN106350273A publication Critical patent/CN106350273A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3788—Graft polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

本发明公开了一种采用生物提取物消除钙离子沉淀的洗涤剂，在洗涤过程中可清除沉积在纤维上的钙离子，从而使衣物重新变得鲜艳，具有返新增艳的显著效果，延长服装的使用寿命。通过生物提取螯合降解因子STB、螯合剂的螯合作用将水中、衣物表面以及污垢中的钙镁离子溶解消除，并结合生物提取螯合降解因子STB、高分子抗污渍再沉积剂的悬浮分散作用、抗再沉积作用，避免再次沉积于织物表面；本发明组合物与表面活性剂相结合，通过渗透、降解并在液体搅拌流的作用下清除纤维表面的钙离子沉淀，从而达到超洁净的洗涤效果及柔顺效果；本发明可消除钙镁离子的沉淀对织物的影响，提高了织物洗涤剂的洗涤效果，解决了衣物经多次洗涤后发黄、褪色以及织物变硬的问题，大大延长了服装的使用寿命。

Description

一种可消除钙离子沉淀的洗涤剂
技术领域
本发明属于干洗剂技术领域，具体涉及一种采用生物提取物消除钙离子沉淀的洗涤剂。
背景技术
使用洗涤剂进行织物洗涤时，大部分是水洗的方式，即以水为溶剂介质进行洗涤，去除污垢。洗涤最理想的水质是软水，自然界软水极少，通常使用的自来水也是硬水。普通水中，含有大量的钙、镁、铁等金属离子。自来水大约是100mg/L左右，地下水一般是250mg/L～800mg/L之间(不同地区差异很大)。从洗涤角度来看，钙镁之类的杂质对洗涤的危害性最大，在洗涤时必须像清除污垢一样清除这些杂质。
硬水会对洗涤会造成不良的后果。硬水中的钙、镁离子在织物上沉积，使白色织物产生发灰现象，影响白度和手感，使颜色织物的色彩变暗，失去鲜艳感，而且手感粗糙；还有的白色棉洁白度逐渐降低，面料的纤维变硬发脆。
针对水洗中出现的这些状况，可以采取增加洗涤剂量、加大洗涤力度、延长洗涤时间等措施，但是织物的洗涤效果仍然不好。钙镁离子在织物上沉积，与纤维的粘附是相当牢固的，要把织物上粘附的钙、镁离子洗除，使发灰的白色织物变白，在目前的情况来讲，是相当困难的。要使白色织物在硬水条件下洗涤不产生或少产生发灰现象，最好的办法是洗涤过程中采取预防措施(使用软化水)。但在实际操作中成分很高，不可行。
传统织物洗涤剂在水洗的过程中，织物纤维接触到水中大量的钙镁离子。由于钙离子的沉淀作用，使得洗涤剂中较多洗涤表面活性剂失去洗涤作用；且钙离子与纤维表面、以及纤维表面的污渍结合后较难清除，从而给洗涤带来困难，同时残留在织物纤维上的钙离子会引起织物纤维变硬。
传统洗涤剂只能去除尚未钙化的污垢，而对已经钙化的混合污垢无能为力。为了避免衣物变硬，需再次使用柔顺剂，增加洗涤成本，加大用水量。同时织物经多次洗涤后，由于钙镁离子的沉淀，会使衣物表面的光反射形成散射，造成衣物发黄变旧。
发明内容
本发明公开了一种采用生物提取物消除钙离子沉淀的洗涤剂，在洗涤过程中可清除沉积在纤维上的钙离子，从而使衣物重新变得鲜艳，具有返新增艳的显著效果，延长服装的使用寿命。本发明采用如下技术方案：
一种可消除钙离子沉淀的洗涤剂，其特征在于，按质量份数计所述的洗涤剂由以下组分组成：
优选地，所述洗涤剂中各组分含量为：
进一步地，所述的阴离子表面活性剂为：直链烷基苯磺酸或其钠盐、脂肪醇聚氧乙烯醚硫酸钠、仲烷基磺酸钠、烷基硫酸钠、α-烯基磺酸钠、脂肪酸甲酯磺酸钠、脂肪酸盐中的一种或几种；
其中，直链烷基苯磺酸或其钠盐具有化学结构：
CnH2n+1-C6H5-SO3M，其中M为H或Na，CnH2n+1为n＝10-16的直链烷基；
其中，脂肪醇聚氧乙烯醚硫酸钠具有化学结构：
CnH2n+1O-(CH2CH2O)2-3-SO3Na，其中CnH2n+1为n＝10-16的直链烷基；
其中，仲烷基磺酸钠具有化学结构：
R1-CH(R2)-SO3Na，其中R1+R2＝C10-16烷基；
其中，烷基硫酸钠具有化学结构：
CnH2n+1OSO3Na，其中CnH2n+1为n＝10-16的直链烷基；
其中，α-烯基磺酸钠具有化学结构：
RCH＝CH(CH2)nSO3Na及RCHOH(CH2)n-SO3Na，其中R＝C10-16直链烷基；
其中，脂肪酸甲酯磺酸钠具有化学结构：
RCH(SO3Na)COCH3，其中R＝C10-16烷基；
其中，脂肪酸盐具有化学结构：
CnH2n+1-COONa(或-K+，-NH4 +盐)，其中n＝9-15。
进一步地，所述的非离子表面活性剂为：脂肪醇聚氧乙烯醚、烷基葡萄糖苷、椰油酸二乙醇酰胺、烷基二甲基氧化胺、月桂酰胺丙基氧化胺、失水山梨醇单月桂酸酯聚氧乙烯醚(20)中的一种或几种；
其中，脂肪醇聚氧乙烯醚具有化学结构：
CnH2n+1O(CH2CH2O)7-10H，其中n＝C10-16。
其中，烷基葡萄糖苷具有化学结构:
其中R＝C10-16直链烷基，n＝1-3；
其中，椰油酸二乙醇酰胺具有化学结构：
R-CON(CH2CH2O)2，R＝C9-15直链烷基；
其中，烷基二甲基氧化胺具有化学结构：
R-N(CH3)2O，R＝C10-16直链烷基；
其中，月桂酰胺丙基氧化胺具有化学结构：
C11H23CO-NH(CH2)3-N(CH3)2O
其中，失水山梨醇单月桂酸酯聚氧乙烯醚(20)具有化学结构：
C11H25COOC6H11O4(CH2CH2O)20H。
进一步地，所述的生物提取螯合降解因子STB为海藻酸钠、淀粉—聚丙烯酰胺接枝共聚物中的一种或两种。
进一步地，所述的螯合剂选自柠檬酸钠、葡萄糖酸钠、甲基甘氨酸二乙酸钠、羟基亚乙基二膦酸(HEDP)、乙二胺而琥珀酸(或其三钠盐)、三聚磷酸钠、焦磷酸钾中的一种。
进一步地，所述的所述高分子抗再沉积剂为聚丙烯酸钠和/或丙烯酸-马来酸共聚物(PMA)，且其分子量在3000至30000之间。
所述的水为软化水、去离子水或蒸馏水。
进一步地，所述的pH值调节剂选自氢氧化钠、氢氧化钾、三乙醇胺、单乙醇胺、异丙醇胺及柠檬酸中的一种或几种，控制和调整衣物预洗剂的pH值在7至11之间。
进一步地，所述的水溶助长剂选自二甲苯磺酸钠、对甲苯磺酸钠、异丙苯磺酸钠中的一种或几种。
进一步地，所述的防腐剂选自1,2-苯并异噻唑啉-3-酮、氯甲基异噻唑啉酮和甲基异噻唑啉酮、三氯羟基二苯醚、三氯均二苯脲、4-氯-3,5-二甲酚、4-氯-间甲苯酚的一种或几种。
进一步地，所述的香精为任何可赋予产品良好香气的物质。
海藻酸钠(Sodium Alginate,SA)又名褐藻酸钠，是从海洋生物褐藻类的海带或马尾藻中提取的一种聚阴离子多糖(海藻酸)的钠盐。海藻酸钠的分子式为[C5H7O4COONa]N，是一种白色或淡黄色粉末，无味，几乎不溶于乙醇、乙醚等有机溶剂。海藻酸钠具有良好的絮凝性和螯合性。由于海藻酸钠与钙离子、铁离子等形成凝胶沉淀，及其较强的吸附性的特点。
淀粉—聚丙烯酰胺接枝共聚物来源于天然植物淀粉，并与聚丙烯酰胺接枝共聚，是一类有良好应用前景的、价廉物美的新型絮凝剂，具有絮凝能力强、分子链稳定性增加、适应范围广等特点。
为了消除织物洗涤过程中钙镁离子的沉淀，本发明采用新材料生物提取螯合降解因子STB(海藻酸钠、淀粉—聚丙烯酰胺接枝共聚物)，并配合特定的螯合剂与高分子抗污渍再沉积剂，从而达到消除钙离子沉淀问题。
通过生物提取螯合降解因子STB、螯合剂的螯合作用将水中、衣物表面以及污垢中的钙镁离子溶解消除，并结合生物提取螯合降解因子STB、高分子抗污渍再沉积剂的悬浮分散作用、抗再沉积作用，避免再次沉积于织物表面。该发明组合物与表面活性剂相结合，通过渗透、降解并在液体搅拌流的作用下清除纤维表面的钙离子沉淀，从而达到超洁净的洗涤效果及柔顺效果，本发明可消除钙镁离子的沉淀对织物的影响，提高了织物洗涤剂的洗涤效果，解决了衣物经多次洗涤后发黄、褪色以及织物变硬的问题，大大延长了服装的使用寿命。结合衣物洗涤水质状况，生物提取螯合降解因子STB确定添加比例应不小于0.2％以上。
具体实施方式
实施例1
实施例2
实施例3
实施例4
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (10)

1.一种可消除钙离子沉淀的洗涤剂，其特征在于，按质量份数计所述的洗涤剂由以下组分组成：
2.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于，所述的阴离子表面活性剂为：直链烷基苯磺酸或其钠盐、脂肪醇聚氧乙烯醚硫酸钠、仲烷基磺酸钠、烷基硫酸钠、α-烯基磺酸钠、脂肪酸甲酯磺酸钠、脂肪酸盐中的一种或几种；
其中，直链烷基苯磺酸或其钠盐具有化学结构：
CnH2n+1-C6H5-SO3M，其中M为H或Na，CnH2n+1为n＝10-16的直链烷基；
其中，脂肪醇聚氧乙烯醚硫酸钠具有化学结构：
CnH2n+1O-(CH2CH2O)2-3-SO3Na，其中CnH2n+1为n＝10-16的直链烷基；
其中，仲烷基磺酸钠具有化学结构：
R1-CH(R2)-SO3Na，其中R1+R2＝C10-16烷基；
其中，烷基硫酸钠具有化学结构：
CnH2n+1OSO3Na，其中CnH2n+1为n＝10-16的直链烷基；
其中，α-烯基磺酸钠具有化学结构：
RCH＝CH(CH2)nSO3Na及RCHOH(CH2)n-SO3Na，其中R＝C10-16直链烷基；
其中，脂肪酸甲酯磺酸钠具有化学结构：
RCH(SO3Na)COCH3，其中R＝C10-16烷基；
其中，脂肪酸盐具有化学结构：
CnH2n+1-COONa(或-K+，-NH4 +盐)，其中n＝9-15。
3.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于，所述的非离子表面活性剂为：脂肪醇聚氧乙烯醚、烷基葡萄糖苷、椰油酸二乙醇酰胺、烷基二甲基氧化胺、月桂酰胺丙基氧化胺、失水山梨醇单月桂酸酯聚氧乙烯醚(20)中的一种或几种；
其中，脂肪醇聚氧乙烯醚具有化学结构：
CnH2n+1O(CH2CH2O)7-10H，其中n＝10-16。
其中，烷基葡萄糖苷具有化学结构:
其中R＝C10-16直链烷基，n＝1-3；
其中，椰油酸二乙醇酰胺具有化学结构：
R-CON(CH2CH2O)2，R＝C9-15直链烷基；
其中，烷基二甲基氧化胺具有化学结构：
R-N(CH3)2O，R＝C10-16直链烷基；
其中，月桂酰胺丙基氧化胺具有化学结构：
C11H23CO-NH(CH2)3-N(CH3)2O
其中，失水山梨醇单月桂酸酯聚氧乙烯醚(20)具有化学结构：
C11H25COOC6H11O4(CH2CH2O)20H。
4.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于所述的生物提取螯合降解因子STB为海藻酸钠、淀粉—聚丙烯酰胺接枝共聚物中的一种或两种。
5.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于所述的螯合剂选自柠檬酸钠、葡萄糖酸钠、甲基甘氨酸二乙酸钠、羟基亚乙基二膦酸(HEDP)、乙二胺而琥珀酸(或其三钠盐)、三聚磷酸钠、焦磷酸钾中的一种。
6.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于所述的所述高分子抗再沉积剂为聚丙烯酸钠和/或丙烯酸-马来酸共聚物(PMA)，且其分子量在3000至30000之间。
7.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于所述的水为软化水、去离子水或蒸馏水。
8.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于，所述的pH值调节剂选自氢氧化钠、氢氧化钾、三乙醇胺、单乙醇胺、异丙醇胺及柠檬酸中的一种或几种，控制和调整衣物预洗剂的pH值在7至11之间。
9.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于，所述的水溶助长剂选自二甲苯磺酸钠、对甲苯磺酸钠、异丙苯磺酸钠中的一种或几种。
10.根据权利要求1所述的可消除钙离子沉淀的洗涤剂，其特征在于，所述的防腐剂选自1,2-苯并异噻唑啉-3-酮、氯甲基异噻唑啉酮和甲基异噻唑啉酮、三氯羟基二苯醚、三氯均二苯脲、4-氯-3,5-二甲酚、4-氯-间甲苯酚的一种或几种。
CN201610723236.7A 2016-08-25 2016-08-25 一种可消除钙离子沉淀的洗涤剂 Pending CN106350273A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610723236.7A CN106350273A (zh) 2016-08-25 2016-08-25 一种可消除钙离子沉淀的洗涤剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610723236.7A CN106350273A (zh) 2016-08-25 2016-08-25 一种可消除钙离子沉淀的洗涤剂

Publications (1)

Publication Number Publication Date
CN106350273A true CN106350273A (zh) 2017-01-25

Family

ID=57854358

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610723236.7A Pending CN106350273A (zh) 2016-08-25 2016-08-25 一种可消除钙离子沉淀的洗涤剂

Country Status (1)

Country Link
CN (1) CN106350273A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189865A (zh) * 2017-05-30 2017-09-22 花舜 一种抑菌型衣物洗涤剂
CN107841393A (zh) * 2017-11-29 2018-03-27 鹿寨卡森洗涤服务有限公司 洗涤组合物
CN108623021A (zh) * 2018-05-23 2018-10-09 宁夏佳士洁水处理有限公司 一种高压锅炉炉水处理剂及其应用
US10800996B2 (en) 2019-02-11 2020-10-13 American Sterilizer Company High foaming liquid alkaline cleaner concentrate composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100728243B1 (ko) * 2006-07-21 2007-06-13 켐맥스 주식회사 천연 염료 염색된 섬유용 레시틴 함유 섬유 유연제 조성물
WO2015031418A1 (en) * 2013-08-28 2015-03-05 The Procter & Gamble Company Microcapsule-containing detergent or cleaning agent
CN104987960A (zh) * 2015-07-13 2015-10-21 于文 织物纤维护理型生物酶洗衣液及其制备方法
CN105039005A (zh) * 2015-06-15 2015-11-11 湖州厉华妤婕联合纺织有限公司 一种新型织物净洗剂组合物
CN105754745A (zh) * 2016-05-11 2016-07-13 于文 不含有机溶剂的全效衣物预洗剂

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100728243B1 (ko) * 2006-07-21 2007-06-13 켐맥스 주식회사 천연 염료 염색된 섬유용 레시틴 함유 섬유 유연제 조성물
WO2015031418A1 (en) * 2013-08-28 2015-03-05 The Procter & Gamble Company Microcapsule-containing detergent or cleaning agent
CN105039005A (zh) * 2015-06-15 2015-11-11 湖州厉华妤婕联合纺织有限公司 一种新型织物净洗剂组合物
CN104987960A (zh) * 2015-07-13 2015-10-21 于文 织物纤维护理型生物酶洗衣液及其制备方法
CN105754745A (zh) * 2016-05-11 2016-07-13 于文 不含有机溶剂的全效衣物预洗剂

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
秦益民 主编: "《海藻酸》", 30 June 2008, 中国轻工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107189865A (zh) * 2017-05-30 2017-09-22 花舜 一种抑菌型衣物洗涤剂
CN107841393A (zh) * 2017-11-29 2018-03-27 鹿寨卡森洗涤服务有限公司 洗涤组合物
CN108623021A (zh) * 2018-05-23 2018-10-09 宁夏佳士洁水处理有限公司 一种高压锅炉炉水处理剂及其应用
US10800996B2 (en) 2019-02-11 2020-10-13 American Sterilizer Company High foaming liquid alkaline cleaner concentrate composition

Similar Documents

Publication Publication Date Title
CN106350273A (zh) 一种可消除钙离子沉淀的洗涤剂
CN106661514B (zh) 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物
CN106574214B (zh) 包含氨基硅氧烷聚合物纳米乳液的织物处理组合物
US8546314B2 (en) Surface treatment compositions including polyquaternium-22 and sheilding salts
US8075637B2 (en) Modified lignin biopolymer useful in cleaning compositions
KR101952567B1 (ko) 제형, 식기세척용 세제로서의 또는 이를 제조하기 위한 이의 용도, 및 이의 제조
JP2008519148A (ja) 酸性洗濯洗剤組成物
JP2011508817A (ja) 許容可能な色を有する洗剤
CN104053762A (zh) 酸性衣物洗涤剂组合物
CN106795461A (zh) 包含富集aes的表面活性剂体系中的阳离子聚合物的清洁组合物
KR20140088568A (ko) 제형, 이의 제조 및 식기세척용 세제로서의 또는 이를 제조하기 위한 이의 용도
CN109370799B (zh) 一种抗菌洗衣液及其用途
CN102392374A (zh) 一种用于牛仔服装酶洗的防返沾色剂
JP2003535986A (ja) リンス剤、仕上げ剤、洗剤及び洗浄剤のための添加剤としてのカチオン変性された粒子形の疎水性ポリマーの使用
CN103695187A (zh) 提高洗涤剂组合物在高硬度水质环境下去污能力的方法及洗涤剂组合物
JPH11501701A (ja) 湿式加工した布地のストーンウォッシュした外観を形成する方法
CN105647678B (zh) 提升洗涤组合物对蛋白污垢去除能力的方法及洗涤剂组合物
CN106281749B (zh) 一种洗涤剂组合物
CN110964605B (zh) 一种柔软型液体洗涤剂组合物
EP1019477A1 (en) Laundry additive compositions including dispersible polyolefin and method for using same
CN111534388A (zh) 一种低泡易漂的除菌洗衣液及其制备方法
CN106350248A (zh) 一种环保洗衣液
CN101809138B (zh) 包含螯合剂和分散剂的织物处理组合物的相关改进
CN109135960B (zh) 一种聚合物在洗涤剂中作为蛋白酶稳定剂的用途及洗涤剂组合物
CN102224291A (zh) 处理织物的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170125

WD01 Invention patent application deemed withdrawn after publication