CN106345273A - Microorganism formaldehyde scavenging agent containing chitosan and preparation method thereof - Google Patents

Microorganism formaldehyde scavenging agent containing chitosan and preparation method thereof Download PDF

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Publication number
CN106345273A
CN106345273A CN201610710347.4A CN201610710347A CN106345273A CN 106345273 A CN106345273 A CN 106345273A CN 201610710347 A CN201610710347 A CN 201610710347A CN 106345273 A CN106345273 A CN 106345273A
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China
Prior art keywords
microorganism
formaldehyde
parts
preparation
scavenger
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CN201610710347.4A
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Chinese (zh)
Inventor
曲嫣红
宋永骏
卞德振
牛谢宝
辛娜
张可欣
马全政
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Dagong Qingdao New Energy Material Technology Research Institute Co Ltd
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Dagong Qingdao New Energy Material Technology Research Institute Co Ltd
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Priority to CN201610710347.4A priority Critical patent/CN106345273A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Molecular Biology (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention belongs to the technical field of indoor air purification, and specifically relates to a microorganism formaldehyde scavenging agent containing chitosan and a preparation method thereof. The microorganism formaldehyde scavenging agent containing the chitosan is prepared from the following components in parts by weight: 5 to 7 parts of bifidobacterium, 5 to 7 parts of lactobacillus acidophilus, 60 to 80 parts of molasses, 20 to 30 parts of saccharose, 30 to 40 parts of chitosan, 2 to 4 parts of polysorbate and 2000 to 3000 parts of ultrapure water. The microorganism formaldehyde scavenging agent disclosed by the invention utilizes chitosan and lactobacillus as main raw materials to treat formaldehyde, and has many advantages of long acting (the chitosan is capable of promoting reproduction of the lactobacillus), green, fresh air, no pollution and the like.

Description

A kind of microorganism formaldehyde scavenger containing shitosan and preparation method thereof
Technical field
The invention belongs to Techniques for Indoor Air Purification field is and in particular to a kind of microorganism formaldehyde removing containing shitosan Agent and preparation method thereof.
Background technology
With the increasingly raising of China's economic level, people are constantly lifted to the aesthetic of living environment, become more Filling interior decoration again, this has occurred as soon as some new problems simultaneously, such as, interior decoration and the pollution that brings.Items are ground Study carefully and show, the major pollutants of interior decoration are formaldehyde, and the main source of formaldehyde is indoor hardware fitting and furniture, indoor formaldehyde The health of pollution effect people, has caused the highest attention of people, and formaldehyde is mainly reflected in harm eye, exhales to the harm of human body The aspects such as desorption system, nervous system and immune system, cause great threat to health.Therefore, develop a kind of fitting For the indoor Related product except formaldehyde, become extremely to be necessary, the exploitation of such product has wide market.For interior How to remove formaldehyde, market occurs in that various products, opens a plurality of approach except formaldehyde, give people with multiple choosings Select.However, the improvement sweep-out method of some main flows all has some drawbacks.
1. activated carbon removes formaldehyde
The absorbability of activated carbon is limited, actual except formaldehyde during, need every four or five months change one Secondary activated carbon, such as changes not in time and is likely to result in the secondary volatilization of formaldehyde.
More 2. utilize the scavenger of oxidation reaction
There is stronger side effect, the methanol obtaining after oxidation and formic acid equally have a small amount of toxicity, simultaneously high concentration Oxidation scavengers itself also can produce certain injury to human body.
3. utilize green plantss
Formaldehyde amount that photosynthesis of plant can absorb is few, and photosynthesis are unable to whole day and carry out, therefore for 24 hours simultaneously The formaldehyde persistent period can be led to longer, do not accomplish the effect got instant result.
4. air cleaner
Because air purifier is also using some adsorbing materials, such as change not in time, formaldehyde equally can volatilize again, leads Cause secondary pollution.
Content of the invention
For solving the above-mentioned problems in the prior art, the present invention provides a kind of microorganism formaldehyde containing shitosan clear Except agent and preparation method thereof.
A kind of microorganism formaldehyde scavenger containing shitosan, each component including by following weight portion: bacillus bifiduss 5-7 Part, bacillus acidophilus' 5-7 part, molasses 60-80 part, sucrose 20-30 part, shitosan 30-40 part, tween 2-4 part, ultra-pure water 2000-3000 part.
A kind of preparation method of described microorganism formaldehyde scavenger containing shitosan, comprises the following steps:
(1) scavenger stock solution: bacillus bifiduss, bacillus acidophilus are inoculated in the ultra-pure water nutritional solution containing molasses, sucrose In, sealed thermostat ferments, and the product liquid after having fermented is centrifuged, and takes supernatant to add chitosan solution, is sufficiently mixed Obtain scavenger stock solution;
(2) scavenger working solution: 300-600 times adds tween by the dilution of described scavenger stock solution.
Fermentation temperature is 28-35 DEG C, and ph is 6.5-7.0, and fermentation time is 7-8 days.
Described centrifugation rate is 6000-8000r/min.
The concentration of described chitosan solution is 0.3g/ml-0.35g/ml.
Shitosan is the n- deacetylation product of chitin, is the unique alkaline polysaccharide of nature, contains in chitosan molecule There are substantial amounts of free amine group, hydroxyl, there is good biocompatibility and wider application.Itself there is powerful reactivity Amino can carry out chemical reaction with many harmful gass, therefore can mend and catch and the harmful gass such as decomposing formaldehyde, and by its turn Chemical conversion water and " oxime ", do not result in secondary pollution, reach the final purpose removing formaldehyde.
Lactic microorganism, can produce the organic acid such as lactic acid, acetic acid, propanoic acid in growth course, can be to air In formaldehyde decomposed, simultaneously suppression environment in harmful bacteria growth.Additionally, lactic acid bacteria fermentation product can give food one Plant flexible acidic smell, band gives the sensation of pleasure.
It is primary raw material that the present invention utilizes shitosan and lactic acid bacteria, carries out formaldehyde treated, has that long-acting (shitosan can promote Enter breeding again of lactic acid bacteria), green, fresh air, multiple advantages such as pollution-free.
Specific embodiment
Example 1
This scavenger is made by following weight: bacillus bifiduss 7g, bacillus acidophilus 6g, molasses 80g, sucrose 30g, Ultra-pure water 2500ml
Bacillus bifiduss, bacillus acidophilus are inoculated in and are fermented containing in molasses, the ultra-pure water nutritional solution of sucrose, and sealing is permanent Temperature fermentation, 30 DEG C of temperature, ph 6.5, ferments 7 days.Product liquid after having fermented is centrifuged, 6000r/min, is taken supernatant Liquid adds 100ml0.3g/ml chitosan solution, is sufficiently mixed, and gained liquid mixture is scavenger stock solution.Scavenger is former The tween that liquid dilutes 300 times of addition 2ml is scavenger working solution.
Example 2
This scavenger is made by following weight: bacillus bifiduss 5g, bacillus acidophilus 6g, molasses 70g, sucrose 25g, Ultra-pure water 2000ml
Bacillus bifiduss, bacillus acidophilus are inoculated in and are fermented containing in molasses, the ultra-pure water nutritional solution of sucrose, and sealing is permanent Temperature fermentation, 30 DEG C of temperature, ph 6.5, ferments 8 days.Product liquid after having fermented is centrifuged, 6000r/min, is taken supernatant Liquid adds 100ml0.35g/ml chitosan solution, is sufficiently mixed, and gained liquid mixture is scavenger stock solution.By scavenger The tween that stock solution dilutes 400 times of addition 3ml is scavenger working solution.
Burst size of methanal detection is carried out to newly-built office, result processes the room of 24,48,72 hours through spraying remover The clearance rate of formaldehyde in air is respectively 81.24%, 91.24%, 96.77%, processes 72 hours Indoor Air Formaldehyde concentration and reaches To national respective standard;The clearance rate through processing 24,48,72 hours formaldehyde through spraying remover for the wooden boards is respectively 83.91%th, 90.57%, 92.56%.After processing 24 hours, wooden boards burst size of methanal is up to state standards, and air obtains To purification.

Claims (5)

1. a kind of microorganism formaldehyde scavenger containing shitosan is it is characterised in that include each component by following weight portion: double Discrimination bacillus 5-7 part, bacillus acidophilus' 5-7 part, molasses 60-80 part, sucrose 20-30 part, shitosan 30-40 part, tween 2-4 part, Ultra-pure water 2000-3000 part.
2. as claimed in claim 1 a kind of preparation method of the microorganism formaldehyde scavenger containing shitosan it is characterised in that bag Include following steps:
(1) scavenger stock solution: bacillus bifiduss, bacillus acidophilus are inoculated in containing in molasses, the ultra-pure water nutritional solution of sucrose, close Envelope ferment at constant temperature, the product liquid after having fermented is centrifuged, and takes supernatant to add chitosan solution, is sufficiently mixed and must remove Agent stock solution;
(2) scavenger working solution: 300-600 times adds tween by the dilution of described scavenger stock solution.
3. the preparation method of a kind of microorganism formaldehyde scavenger containing shitosan according to claim 2, its feature exists In fermentation temperature is 28-35 DEG C, and ph is 6.5-7.0, and fermentation time is 7-8 days.
4. the preparation method of a kind of microorganism formaldehyde scavenger containing shitosan according to Claims 2 or 3, its feature It is, described centrifugation rate is 6000-8000r/min.
5. the preparation method of a kind of microorganism formaldehyde scavenger containing shitosan according to Claims 2 or 3, its feature It is, the concentration of described chitosan solution is 0.3g/ml-0.35g/ml.
CN201610710347.4A 2016-08-23 2016-08-23 Microorganism formaldehyde scavenging agent containing chitosan and preparation method thereof Pending CN106345273A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142231A (en) * 2017-05-31 2017-09-08 大工(青岛)新能源材料技术研究院有限公司 A kind of probiotics for dispelling in-car formaldehyde and aromatic hydrocarbon and preparation method thereof
CN109010884A (en) * 2018-09-07 2018-12-18 浙江九田环保科技有限公司 Excitated type deodorant and preparation method thereof
CN109794159A (en) * 2017-11-17 2019-05-24 上海青木环保工程有限公司 A kind of preparation method of the formaldehyde scavenger using biological decomposition
CN111909866A (en) * 2020-07-21 2020-11-10 昆山理清生物科技有限公司 Ferment for VOC gas decomposition and preparation method and application thereof

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CN101653618A (en) * 2008-08-23 2010-02-24 王诚德 Formaldehyde remover and its preparation method
CN101711885A (en) * 2009-12-02 2010-05-26 北京普仁生态技术有限公司 Method for preparing high-concentration biological deodorant
CN101791421A (en) * 2010-01-19 2010-08-04 毕献奎 Microorganism cleaning bactericide capable of removing multiple poisonous and harmful substances
CN101954167A (en) * 2010-08-24 2011-01-26 杭州茂龙环保科技有限公司 Composite long-acting formaldehyde remover and preparation method thereof
CN102485275A (en) * 2011-06-22 2012-06-06 聂莹琨 Cleanser for decorated indoor air
CN102961955A (en) * 2012-11-26 2013-03-13 山东泰德新能源有限公司 Formaldehyde scavenger and preparation method thereof
CN103656956A (en) * 2013-12-12 2014-03-26 陈金娥 Green and environment-friendly formaldehyde scavenging agent
CN103924009A (en) * 2014-03-29 2014-07-16 中华人民共和国衡水出入境检验检疫局 Formaldehyde scavenger, as well as preparation method and applications thereof
CN105126559A (en) * 2015-07-13 2015-12-09 甘肃德福生物科技有限公司 Concentrated high-strength indoor formaldehyde purifying method

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101653618A (en) * 2008-08-23 2010-02-24 王诚德 Formaldehyde remover and its preparation method
CN101629157A (en) * 2009-08-06 2010-01-20 江苏省江大绿康生物工程技术研究有限公司 Compound microecologics for purifying water quality
CN101711885A (en) * 2009-12-02 2010-05-26 北京普仁生态技术有限公司 Method for preparing high-concentration biological deodorant
CN101791421A (en) * 2010-01-19 2010-08-04 毕献奎 Microorganism cleaning bactericide capable of removing multiple poisonous and harmful substances
CN101954167A (en) * 2010-08-24 2011-01-26 杭州茂龙环保科技有限公司 Composite long-acting formaldehyde remover and preparation method thereof
CN102485275A (en) * 2011-06-22 2012-06-06 聂莹琨 Cleanser for decorated indoor air
CN102961955A (en) * 2012-11-26 2013-03-13 山东泰德新能源有限公司 Formaldehyde scavenger and preparation method thereof
CN103656956A (en) * 2013-12-12 2014-03-26 陈金娥 Green and environment-friendly formaldehyde scavenging agent
CN103924009A (en) * 2014-03-29 2014-07-16 中华人民共和国衡水出入境检验检疫局 Formaldehyde scavenger, as well as preparation method and applications thereof
CN105126559A (en) * 2015-07-13 2015-12-09 甘肃德福生物科技有限公司 Concentrated high-strength indoor formaldehyde purifying method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142231A (en) * 2017-05-31 2017-09-08 大工(青岛)新能源材料技术研究院有限公司 A kind of probiotics for dispelling in-car formaldehyde and aromatic hydrocarbon and preparation method thereof
CN109794159A (en) * 2017-11-17 2019-05-24 上海青木环保工程有限公司 A kind of preparation method of the formaldehyde scavenger using biological decomposition
CN109010884A (en) * 2018-09-07 2018-12-18 浙江九田环保科技有限公司 Excitated type deodorant and preparation method thereof
CN111909866A (en) * 2020-07-21 2020-11-10 昆山理清生物科技有限公司 Ferment for VOC gas decomposition and preparation method and application thereof
CN111909866B (en) * 2020-07-21 2022-07-29 昆山理清生物科技有限公司 Ferment for VOC gas decomposition and preparation method and application thereof

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