CN106342855A - Pesticide-fertilizer composition, preparation and application thereof - Google Patents
Pesticide-fertilizer composition, preparation and application thereof Download PDFInfo
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- CN106342855A CN106342855A CN201610723588.2A CN201610723588A CN106342855A CN 106342855 A CN106342855 A CN 106342855A CN 201610723588 A CN201610723588 A CN 201610723588A CN 106342855 A CN106342855 A CN 106342855A
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- component
- medicine fertilizer
- fertilizer composition
- described component
- amino acid
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide-fertilizer composition which is characterized by comprising a component A and a component B, wherein the component A refers to one or more in iodine, iodate or hypoiodite; the component B refers to one or more in thidiazuron, forchlorfenuron, 6-benayl aminopurine, phethalanilic acid and derivatives thereof; and a mass ratio of the component A to the component B is 1:(0.1-800). The composition has obvious effects of resisting crop diseases and increasing the yield.
Description
Technical field
The present invention relates to agricultural technology field is and in particular to a kind of medicine fertilizer composition, preparation and its application.
Background technology
Increase with the proportion of crop planting time limit, cropping pattern is more fixing, leads to have accumulated substantial amounts of harmful organism in soil,
There is more and more heavier, year after year cultivating of soil in disease, cause soil physical properties substantially to change, and hardened in a large number, fertilizer in soil
Power and cultivated power decline, and lead to crop yield, quality significantly to decline.Disease and soil fertility decline is made to have become impact agriculture
The key factor of crop production.
In agricultural production, can be by applying the fat existing disease-resistant crops volume increase of medicine.Medicine is fertile to kill suppression crops as having
Pest and disease damage or plant growth one of are adjusted or more than one function, and nutrition or simultaneously have can be provided to carry for crops
Multi-Functional Fertilizers for nutrition and raising fertilizer and medicine fertilizer utilization rate.For realizing increasing crop yield, plant growth regulating can be applied
Agent.Plant growth regulator is a class ectogenic non-nutritive chemical substance, generally can conduct in plant body to working
Position, just can promote or suppress some steps during plant vital activity with relatively low concentration, change the character of plant, make
To the wish growth promoter meeting human needs.
When plant growth regulator is applied to crops, often it is accompanied by bacterial disease, fungal disease, virosiss
Generation.Objectively need to be used together with antibacterial, antiviral agent or successively use, but the sterilization of the azole of life-time service
Agent, such as propiconazole, Difenoconazole, bis(4-fluorophenyl)methyl(1H-1,2,4-triazol-1-ylmethyl)silane are also easy to produce resistance when using, and the gibberellin in plant body can be made to synthesize simultaneously
It is suppressed, makes treatment site, such as Fructus Vitis viniferae, Fructus Litchi, the fruit ear of Arillus Longan too shorten, be unfavorable for keeping the commodity of fruit.And
Bactericidal copper agent is easy to poisoning.On the market effect substantially and Small side effects prevent and treat virosiss medicament more scarce
Weary.
Content of the invention
In view of this, the invention provides a kind of medicine fertilizer composition, described compositionss include component a, component b；Described group
Point a is one or more of iodine, iodate or hypoiodite, described component b is Thidiazuron, forchlorfenuron, 6-benzyl aminopurine,
One or more of benzene peptide amino acid and its derivant；Described component a and described component b mass ratio are 1:(0.1～800).
Preferably, described component a and described component b mass ratio are 1:(0.1～80).
Preferably, described component a and described component b mass ratio are 1:(0.5～40).
Preferably, described component a is iodate and/or hypoiodite.
Preferably, described iodate is potassium iodate, sodium iodate.
Preferably, described iodate is potassium iodate.
Preferably, described hypoiodite is Hypoiodous acid (HIO) potassium, Hypoiodous acid (HIO) sodium.
Preferably, described hypoiodite is Hypoiodous acid (HIO) potassium.
Preferably, described component b is Thidiazuron, forchlorfenuron, 6-benzyl aminopurine, benzene peptide amino acid, benzene peptide amino acid salt, benzene peptide
One or more of amino acid ester.
Preferably, described component b is Thidiazuron, forchlorfenuron, 6-benzyl aminopurine, benzene peptide amino acid, benzene peptide amino acid salt, benzene peptide
One or more of amino acid.
Preferably, described benzene peptide amino acid salt is benzene peptide amino acid potassium, benzene peptide amino acid sodium.
Preferably, described benzene peptamine acid esters is benzene peptide amino acid methyl ester, benzene peptamine acetoacetic ester, benzene peptamine propyl propionate, benzene peptamine
Isopropyl propionate, benzene peptamine acid butyl ester.
Preferably, described component b is benzene peptide amino acid.
Present invention also offers application in disease-resistant crops evil and/or volume increase for the described medicine fertilizer composition.
Preferably, described crops are one or more of Fructus Vitis viniferae, Fructus Litchi, Fructus Jujubae, Semen arachidis hypogaeae or Citrus.
Preferably, described disease is anthrachose of grape, downy mildew, rust, virosiss and charcoal myiasis.
Present invention also offers a kind of medicine fertilizer composition preparation, described preparation includes above-mentioned medicine fertilizer composition and Pesticide Science
Upper acceptable auxiliary agent.
Preferably, it is calculated in mass percent, described composition pesticide content in described preparation is 0.3%～62%.
Described in the pharmaceutical composition that the present invention provides, component a has very strong permeability and oxidisability, can readily penetrate through
Cell wall, moreover it is possible to the active gene of oxidation pathogenic microorganism oleo stock albumen, can also be converted into described Hypoiodous acid (HIO) in plant body
Salt plays a role, and be combined with the amino of protein molecule rear make its protein denaturation precipitation, cause microorganism dead.Described
Hypoiodite has very strong Oxidation, is wide spectrum, efficient, quick-acting antibacterial, can effectively kill most antibacterial numerous
Grow the pathogenic microorganisms such as body, spore, virus, funguses, protozoon, phage.Described iodate sprays in plant surface, enters plant
In vivo, there is stronger Oxidation, pathogen can be killed, reduzate iodine and hypoiodite can also continue to performance and kill cause of disease
Microorganism.
Described in the pharmaceutical composition that the present invention provides, component b has the effect improving crop yield.
Wherein, described Thidiazuron is a kind of cytokinin plant growth regulator, belongs to phenyl urea derivatives, has
Very strong biological activity, can promote cell divide Soviet Union nucleotide in plant to think accumulation and the synthesis of the basic element of cell division, promote further
Enter growth and the regeneration of tissue, the photosynthesis of plant can be significantly increased, promote plant growing, raising is beared fruit, improve yield.
Described forchlorfenuron is a kind of phenylurea class plant growth regulator with cytokine activity, also known as forchlorfenuron,
CPPU, urea therbligs, forchlorfenuron, kt-30,4pu-30, cppu etc., have acceleration cell mitogen, promote cell to increase
And differentiation, prevent fruit drop etc. from acting on.
Described 6-benzyl aminopurine is the basic element of cell division of first man work synthesis, as plant growth regulators,
There is suppression leaves of plants inner chlorophyll, nucleic acid, the decomposition of protein, protect green anti-old, by aminoacid, auxin, inorganic salt etc. to
The efficiency for the treatment of site allocation and transportation；Plant undifferentiated histo-differentiation being promoted, promoting cell to increase weight gaining, thus promoting seed to send out
Bud, the growth of induced dormancy bud, suppression or promotion stem, the elongation growth of leaf, promotion fruit growth, induction tuber character etc..Extensively
It is used in agricultural, fruit tree and garden crop each stage from germinateing to harvesting.
Described benzene peptide amino acid and its derivant are a kind of plant growth regulator with room temperature activity, are sprayed by blade face
Apply, can rapidly permeate in plant body, promote nutrient substance to be transported to the growing point of alabastrum；Strengthen the vigor of plant cell, promote
Enter chlorophyllous synthesis, beneficial to pollination, fertilization, there is the effect that induction alabastrum becomes flower and result；Prevent physiology and preharvest drop,
The natural maturity phase can shift to an earlier date 5～7 days, has obvious guarantor to spend, fruit retention acts on.
The medicine fertilizer composition that the present invention provides adopts component a and component b to compound, and component b may additionally facilitate crops to component a
Absorption, to disease-resistant crops, there is synergistic function.Described component a can affect the absorption of Plant To Nutrient element and turn
Fortune, promotion plant growing, and the Biomass of crop can be improved, it is remarkably improved plant leaf chlorophyll content, improve peroxidating
Hydrogen enzyme (cat), peroxide enzyme (pod), the activity of superoxide dismutase (sod), reduce malonaldehyde (mda) peroxide simultaneously
Change content, increase vc and total soluble sugar content, reduce nitrate and total acid content, compound with component b, tradition can be overcome to kill
The resistance that microbial inoculum is caused when being compounded with component b, the bad weakness of prevention effect, compositionss have in terms of improving the yield of crops
There is synergistic function.
Compared with prior art, the method have the advantages that a kind of medicine fertilizer composition disclosed by the invention and its
Application, preparation, described compositionss include one or more of described component a iodine, iodate or hypoiodite, and described are selected from
One or more of Thidiazuron, forchlorfenuron, 6-benzyl aminopurine, benzene peptide amino acid and its derivant plant growth regulator component
b.Described component a, can prevent and treat the resistant strain that life-time service conventional sterilants cause, obvious to disease-resistant crops evil effect；
Described component a and component b pass through component proportion, notable volume increase, and have synergistic function.
Specific embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment pair
The present invention is described in further detail.
Embodiment 1
Preparation method: iodine, forchlorfenuron add wetting agent fatty alcohol-polyoxyethylene ether to stir after being dissolved in ethylene glycol.
Embodiment 2
Preparation method: ethanol will be added under alkyl phenol formaldehyde resin polyoxyethylene ether sulfate, benzene peptide amino acid stirring condition
Afterwards, with a small amount of water, potassium iodide is dissolved in addition system after water, adds water and supply 100%, stir.
Embodiment 3
Preparation method: second will be added under alkyl phenol formaldehyde resin polyoxyethylene ether sulfate, benzene peptamine ethyl ester stirring condition
After alcohol, with a small amount of water, potassium iodide is dissolved in addition system after water, adds water and supply 100%, stir.
Embodiment 4
Preparation method: will in 50% water add sodium hydroxide, add 6- benzyl aminoadenine after stirring and dissolving, under stirring according to
Secondary addition benzene peptide amino acid, fatty alcohol-polyoxyethylene ether phosphate, Hypoiodous acid (HIO) potassium, add water and supply 100%, stir.
Embodiment 5
Preparation method: by potassium iodate, Hypoiodous acid (HIO) sodium, Thidiazuron, alkylnaphthalene sulfonate, k12, white carbon, kieselguhr mixing all
Even, comminution by gas stream.
Embodiment 6
Preparation method: admix after iodine equivalent ethanol is disperseed and stir after sopa270, with white carbon absorption, add
Benzene peptide amino acid, Hypoiodous acid (HIO) potassium, soluble starch mix homogeneously in mixing tank for coating colors, damp-prrof packing.
Embodiment 7
1st, experimental subject: Fructus Vitis viniferae
2nd, experimental technique: with reference to " farm-chemical indoor determination test rule ny/t 2061.2-2011 " plant growth regulating
Agent part 2: promote, suppression plant strain growth is tested.Fruit expanding period carries out one or many spraying treatment to grape fruit ear.
3rd, data statistic analysis: be analyzed using dps6.55 (duncan) statistical software.Calculated according to test data
Go out per mu yield c1 (kg), with respect to per mu yield increase rate t1 (%) of blank；Calculate averagely disease-resistant finger
Number (anthrachose of grape) c2, with respect to average Disease resistance index (anthrachose of grape) increase rate t2 (%) of blank.
4th, evaluation methodology: obtain per mu yield increase rate e1 (%) after theoretical using with, actual survey using colby formula
Fixed mixed after the theory index e1 (%) that draws with colby formula of deliberated index t1 (%) compared with；Obtain theoretical mixed
Average Disease resistance index (anthrachose of grape) increase rate e2 (%) afterwards, practical measurement mixed after deliberated index t2 (%) and colby
The theory index e2 (%) that formula draws compares；Actual value is more than the effect for Synergistic of theoretical value 12%, actual value
More than theoretical value difference between 0%-12% for be added effect, actual value be less than theoretical value is antagonism.
Colby formula: e=x+y-xy/100；X, y are the actual gaining rate of alone each component gained respectively.
5th, measurement result: be shown in Table 1.
The single medicine of table 1 or compositionss are applied to the result of the test of Fructus Vitis viniferae
Result shows, component a described in compositionss that the present invention provides is compounded with described component b, the upgrowth situation to Fructus Vitis viniferae
Improve significantly, can effectively prevent and treat raising vintage, and there is synergistic function；Effectively grapevine anthracnose can be prevented and treated,
And there is synergistic function.
Embodiment 8
1st, experimental subject: Fructus Vitis viniferae
2nd, experimental technique: in grape fruit expanding stage, using plant growth regulator composition of the present invention to grape fruit ear
Carry out one or many spraying treatment, measure Fructus Vitis viniferae as the indices in table 2 below, record anthrachose of grape Disease resistance index, final
Yield and amount of increase in production.
Table 2 is disease-resistant to grapevine anthracnose, effect of increasing production
Result shows, component a described in compositionss that the present invention provides is compounded with described component b, the upgrowth situation to Fructus Vitis viniferae
Improve significantly, can effectively prevent and treat grapevine anthracnose, increase vintage；The present invention provide compositionss, described component a with
Described component b compounds, and prevention effect is better than effect when conventional sterilants are compounded with described component b.Compared to Difenoconazole
Multiple with Thidiazuron, Difenoconazole and forchlorfenuron, Difenoconazole and 6- benzyl aminoadenine, Difenoconazole and benzene peptide amino acid
Join, disease-resistant and effect of increasing production is more preferably.
Embodiment 9
1st, experimental subject: Fructus Litchi, Fructus Jujubae, Semen arachidis hypogaeae and Citrus
2nd, test method: in fruit expanding period, using the fruit to various crops for the plant growth regulator composition of the present invention
Fringe carries out one or many spraying treatment, measures such as the indices in table 3 below of various crops and records Disease resistance index, final
Yield and amount of increase in production.
To Fructus Litchi, Fructus Jujubae, Semen arachidis hypogaeae and Citrus are disease-resistant, effect of increasing production for table 3 list medicine of the present invention and compositionss
Result shows, component a described in compositionss that the present invention provides is compounded with described component b, to Fructus Litchi, Fructus Jujubae, Semen arachidis hypogaeae
Improve significantly with the upgrowth situation of Citrus, disease-resistant, obvious effect of increasing production, and all show potentiation.
The above is only the preferred embodiment of the present invention it is noted that above-mentioned preferred implementation be not construed as right
The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch also to should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of medicine fertilizer composition is it is characterised in that described compositionss include component a, component b；Described component a is iodine, iodic acid
One or more of salt or hypoiodite, described component b be Thidiazuron, forchlorfenuron, 6-benzyl aminopurine, benzene peptide amino acid and its
One or more of derivant；Described component a and described component b mass ratio are 1:(0.1～800).
2. medicine fertilizer composition according to claim 1 is it is characterised in that described component a and described component b mass ratio are 1:
(0.1～80).
3. medicine fertilizer composition according to claim 2 is it is characterised in that described component a and described component b mass ratio are 1:
(0.5～40).
4. medicine fertilizer composition according to claim 1 is it is characterised in that described component a is iodate and/or Hypoiodous acid (HIO)
Salt.
5. medicine fertilizer composition according to claim 1 is it is characterised in that described component b is Thidiazuron, forchlorfenuron, 6- benzyl
One or more of amidopurin, benzene peptide amino acid, benzene peptide amino acid salt, benzene peptamine acid esters.
6. medicine fertilizer composition according to claim 1 is it is characterised in that described component b is Thidiazuron, forchlorfenuron, 6- benzyl
One or more of amidopurin, benzene peptide amino acid.
7. application in disease-resistant crops evil and/or volume increase for the medicine fertilizer composition described in 1～6 any one as requested.
8. according to claim 7 medicine fertilizer composition it is characterised in that described crops be Fructus Vitis viniferae, Fructus Litchi, Fructus Jujubae, Semen arachidis hypogaeae
One or more of or Citrus.
9. a kind of medicine fertilizer composition preparation it is characterised in that described preparation described in any one of Claims 1 to 5 medicine fertilizer group
Acceptable auxiliary agent composition on compound and Pesticide Science.
10. according to claim 9 preparation it is characterised in that being calculated in mass percent, described composition pesticide is in described system
In agent, content is 0.3%～62%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610723588.2A CN106342855A (en) | 2016-08-25 | 2016-08-25 | Pesticide-fertilizer composition, preparation and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610723588.2A CN106342855A (en) | 2016-08-25 | 2016-08-25 | Pesticide-fertilizer composition, preparation and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107691462A (en) * | 2017-11-10 | 2018-02-16 | 陕西上格之路生物科学有限公司 | A kind of defoliant containing Thidiazuron and benzene peptide amino acid |
| CN110352774A (en) * | 2019-08-16 | 2019-10-22 | 冼志强 | A kind of promoting blossom of longan tree in irregular season method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1180683A (en) * | 1997-10-24 | 1998-05-06 | 常玉 | High-concentrated organic liquid compound fertilizer and producing method thereof |
| CN102919247A (en) * | 2012-10-31 | 2013-02-13 | 四川国光农化股份有限公司 | Plant growth adjustment composition containing 6-benayl aminopurine |
| CN103262840A (en) * | 2013-06-05 | 2013-08-28 | 四川国光农化股份有限公司 | 6-benayl aminopurine soluble granule and preparation method thereof |
| CN104488924A (en) * | 2015-01-19 | 2015-04-08 | 陕西上格之路生物科学有限公司 | Compound composition used for increasing crop fertilization rate |
-
2016
- 2016-08-25 CN CN201610723588.2A patent/CN106342855A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1180683A (en) * | 1997-10-24 | 1998-05-06 | 常玉 | High-concentrated organic liquid compound fertilizer and producing method thereof |
| CN102919247A (en) * | 2012-10-31 | 2013-02-13 | 四川国光农化股份有限公司 | Plant growth adjustment composition containing 6-benayl aminopurine |
| CN103262840A (en) * | 2013-06-05 | 2013-08-28 | 四川国光农化股份有限公司 | 6-benayl aminopurine soluble granule and preparation method thereof |
| CN104488924A (en) * | 2015-01-19 | 2015-04-08 | 陕西上格之路生物科学有限公司 | Compound composition used for increasing crop fertilization rate |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107691462A (en) * | 2017-11-10 | 2018-02-16 | 陕西上格之路生物科学有限公司 | A kind of defoliant containing Thidiazuron and benzene peptide amino acid |
| CN110352774A (en) * | 2019-08-16 | 2019-10-22 | 冼志强 | A kind of promoting blossom of longan tree in irregular season method |
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