CN106317233B - 一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 - Google Patents
一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 Download PDFInfo
- Publication number
- CN106317233B CN106317233B CN201510359482.4A CN201510359482A CN106317233B CN 106317233 B CN106317233 B CN 106317233B CN 201510359482 A CN201510359482 A CN 201510359482A CN 106317233 B CN106317233 B CN 106317233B
- Authority
- CN
- China
- Prior art keywords
- succinic acid
- acid anhydride
- octenyl succinic
- guar
- anhydride modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- KCYQMQGPYWZZNJ-BQYQJAHWSA-N hydron;2-[(e)-oct-1-enyl]butanedioate Chemical compound CCCCCC\C=C\C(C(O)=O)CC(O)=O KCYQMQGPYWZZNJ-BQYQJAHWSA-N 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 32
- 244000007835 Cyamopsis tetragonoloba Species 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- 229920002907 Guar gum Polymers 0.000 claims abstract description 30
- 239000000665 guar gum Substances 0.000 claims abstract description 30
- 229960002154 guar gum Drugs 0.000 claims abstract description 30
- 235000010417 guar gum Nutrition 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 24
- 238000010792 warming Methods 0.000 claims description 16
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 13
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 235000002639 sodium chloride Nutrition 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 9
- 238000006467 substitution reaction Methods 0.000 abstract description 7
- 235000013305 food Nutrition 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 229910001948 sodium oxide Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000012086 standard solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- TWNIBLMWSKIRAT-RWOPYEJCSA-N (1r,2s,3s,4s,5r)-6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol Chemical compound O1[C@@]2([H])OC[C@]1([H])[C@@H](O)[C@H](O)[C@@H]2O TWNIBLMWSKIRAT-RWOPYEJCSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- GUOCOOQWZHQBJI-UHFFFAOYSA-N 4-oct-7-enoxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCCCCCCC=C GUOCOOQWZHQBJI-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920002527 Glycogen Polymers 0.000 description 1
- GZCGUPFRVQAUEE-KVTDHHQDSA-N aldehydo-D-mannose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)C=O GZCGUPFRVQAUEE-KVTDHHQDSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001720 carbohydrates Chemical group 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229940096919 glycogen Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical class [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 对比例 | |
取代度 | 2.42 | 2.31 | 2.22 | 2.28 | 2.15 |
断裂成/km | 耐折度/次 | 耐破指数/kPa·m2·g-1 | 撕裂指数/mN·m2·g-1 | |
实施例1 | 3.22 | 24 | 1.98 | 4.73 |
实施例2 | 3.18 | 20 | 1.92 | 4.65 |
实施例3 | 3.14 | 20 | 2.12 | 7.31 |
实施例4 | 3.08 | 26 | 1.99 | 4.44 |
对比例 | 2.93 | 19 | 1.91 | 4.31 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510359482.4A CN106317233B (zh) | 2015-06-25 | 2015-06-25 | 一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510359482.4A CN106317233B (zh) | 2015-06-25 | 2015-06-25 | 一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106317233A CN106317233A (zh) | 2017-01-11 |
CN106317233B true CN106317233B (zh) | 2018-11-13 |
Family
ID=57729369
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510359482.4A Active CN106317233B (zh) | 2015-06-25 | 2015-06-25 | 一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106317233B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112107504A (zh) * | 2020-09-24 | 2020-12-22 | 成都维德医疗器械有限责任公司 | 一种改性ⅰ型胶原蛋白凝胶的制备方法 |
CN114409819B (zh) * | 2022-01-25 | 2023-06-30 | 西安奥德石油工程技术有限责任公司 | 植物胶改性材料及基于其的渗吸增强作用的压裂转向剂、制备方法和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102180986A (zh) * | 2011-03-30 | 2011-09-14 | 陕西科技大学 | 一种烯基琥珀酸酐改性胍胶压裂液稠化剂及其制备方法 |
CN102702368A (zh) * | 2012-05-08 | 2012-10-03 | 华南理工大学 | 一种流动性淀粉及其干法制备方法 |
-
2015
- 2015-06-25 CN CN201510359482.4A patent/CN106317233B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102180986A (zh) * | 2011-03-30 | 2011-09-14 | 陕西科技大学 | 一种烯基琥珀酸酐改性胍胶压裂液稠化剂及其制备方法 |
CN102702368A (zh) * | 2012-05-08 | 2012-10-03 | 华南理工大学 | 一种流动性淀粉及其干法制备方法 |
Non-Patent Citations (2)
Title |
---|
低表面张力ASA改性瓜尔胶表面施胶剂的制备及其应用;杨晓武 等;《纸和造纸》;20120930;第31卷(第9期);第1.2、2.1.1、2.1.3节 * |
烯基琥珀酸酐改性瓜尔胶的合成及其;薛贝 等;《油田化学》;20121225;第29卷(第4期);第1.3、2.2.1、2.2.2节 * |
Also Published As
Publication number | Publication date |
---|---|
CN106317233A (zh) | 2017-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Zhang | Cellulosic associative thickeners | |
Xiao et al. | Preparation and characterization of octenyl succinic anhydride modified agarose derivative | |
EP3816194A1 (en) | Preparation method of modified starch ether for improving anti-sliding property of ceramic tile adhesive | |
Liu et al. | Effects of soluble dietary fiber on the crystallinity, pasting, rheological, and morphological properties of corn resistant starch | |
WO2002100902A1 (en) | Galactomannan compositions and methods for making and using same | |
DE1177129B (de) | Verfahren zur Herstellung von Quellstaerkemischaethern und bzw. oder -estern | |
CN104277138B (zh) | 一步醚化制备羧甲基羟烷基瓜尔胶粉的方法 | |
US4758282A (en) | Process for dry cationization of galactomannans | |
CN106317233B (zh) | 一种干法辛烯基琥珀酸酐改性瓜尔胶的制备方法及该方法制得的产物 | |
CN105693868A (zh) | 制备烷基纤维素的方法 | |
JP2012046747A (ja) | ヒドロキシルラジカルの連続的発生を利用した炭水化物の修飾 | |
CA2938747C (en) | A stabilized sizing formulation | |
Petzold et al. | Synthesis and characterization of methyl xylan | |
Chun et al. | Effect of high hydrostatic pressure treatment on conventional hydroxypropylation of maize starch | |
CN104829739B (zh) | 低粘度阳离子瓜尔胶粉的制备方法 | |
EP3102736B1 (en) | A stabilized sizing formulation | |
CN104558205B (zh) | 一种低粘度羧甲基纤维素钠的制备方法 | |
Kittipongpatana et al. | Effects of amylose content on the physicochemical properties of sodium carboxymethyl rice starches | |
CN105315379B (zh) | 一种防油淀粉及其生产工艺和应用 | |
CN107955595A (zh) | 一种用于驱油聚合物的除氧剂及其制备方法 | |
CN105294942B (zh) | 一种阳离子接枝淀粉及其生产工艺和应用 | |
WO2016094467A1 (en) | Cellulose based hydrogels and process for making the same from hemicaustic byproduct | |
CN104558202A (zh) | 一种甲基纤维素的绿色制备方法 | |
Fashi et al. | Solid state cationization reaction of microporous starch with betaine hydrochloride under repeated heating/cooling cycles: Design of a green approach for corn starch modification | |
CN110582517B (zh) | 使羟丙基化产品中丙氯仲醇降低的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190919 Address after: Room 322, Building 32, 680 Guiping Road, Xuhui District, Shanghai Patentee after: SHANGHAI CHANGFA NEW MATERIAL Co.,Ltd. Address before: 200233 Shanghai, Tianlin Road, No. 388, building 701, room 1, Patentee before: SHANGHAI DONGSHENG NEW MATERIALS Co.,Ltd. |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of dry octenylsuccinic anhydride modified guar gum and the product prepared by the method Effective date of registration: 20230216 Granted publication date: 20181113 Pledgee: Bank of Hangzhou Limited by Share Ltd. Shanghai branch Pledgor: SHANGHAI CHANGFA NEW MATERIAL Co.,Ltd. Registration number: Y2023310000032 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20181113 Pledgee: Bank of Hangzhou Limited by Share Ltd. Shanghai branch Pledgor: SHANGHAI CHANGFA NEW MATERIAL Co.,Ltd. Registration number: Y2023310000032 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method for dry method octenylsuccinic anhydride modified guar gum and the product obtained by the method Granted publication date: 20181113 Pledgee: Bank of Hangzhou Limited by Share Ltd. Shanghai branch Pledgor: SHANGHAI CHANGFA NEW MATERIAL Co.,Ltd. Registration number: Y2024310000164 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |