CN106316339A - Glazed tile and preparing method thereof - Google Patents

Glazed tile and preparing method thereof Download PDF

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Publication number
CN106316339A
CN106316339A CN201610714147.6A CN201610714147A CN106316339A CN 106316339 A CN106316339 A CN 106316339A CN 201610714147 A CN201610714147 A CN 201610714147A CN 106316339 A CN106316339 A CN 106316339A
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China
Prior art keywords
parts
light
burned
compound
gained
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CN201610714147.6A
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Chinese (zh)
Inventor
杨吉权
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Yongren Chengxin Steel Structure Manufacture Center
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Yongren Chengxin Steel Structure Manufacture Center
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Priority to CN201610714147.6A priority Critical patent/CN106316339A/en
Publication of CN106316339A publication Critical patent/CN106316339A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B23/00—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects
    • B28B23/02—Arrangements specially adapted for the production of shaped articles with elements wholly or partly embedded in the moulding material; Production of reinforced objects wherein the elements are reinforcing members
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • B28B3/10—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form each charge of material being compressed against previously formed body
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61—Coating or impregnation
    • C04B41/65—Coating or impregnation with inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34—Non-shrinking or non-cracking materials
    • C04B2111/343—Crack resistant materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40—Porous or lightweight materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52—Sound-insulating materials

Abstract

The invention discloses a glazed tile and a preparing method thereof. The glazed tile is prepared from, by weigth, 60-70 parts of magnesium oxide, 20-30 parts of magnesium chloride, 24-30 parts of quartz powder, 8-10 parts of talcum powder, 1.5-2. 6 parts of magnesite admixture , 1-1 5 parts of PVA,1-2 parts of PET, 1 8-2. 8 parts of PVC, and 1-1.5 parts of PAE wet strength agent. The glazed tile is pressed by three processes. The obtained glazed tile has light weight, strong compressive strength, excellent falling resistance, strong bearing strength, better anti-seismic property, fire and damp resistance, corrosion prevention, insulation flame retardant, good heat and sound insulation effect, easy cutting, strong decoration and ageing resistance. The service life is above 30 years.

Description

A kind of glazed tiles and preparation method thereof
Technical field
The present invention relates to a kind of glazed tiles and preparation method thereof, belong to construction material preparing technical field.
Background technology
Glazed tiles are conventional roof building materials, and the roofing using glazed tiles to lay has elegant in appearance, corrosion resistance The advantages such as good, good waterproof performance.Traditional glazed tiles produce the method being to use slip casting compressing and mineral dust compacting are formed 's.Owing to being all the breeze of compacting inside tradition glazed tiles, therefore its fragility is relatively big, and structural strength is poor, in transport or laying During the most do not note making glazed tiles damaged, and if the glazed roof laid is hit by hard object, also Glazed tiles can be made to crush.Not only affect the structural integrity of building roof and attractive in appearance, and broken glazed tiles also can be to people within doors Member and article bring security threat.
Summary of the invention
For solving the deficiencies in the prior art, it is an object of the invention to provide a kind of intensity high, corrosion resistance, good waterproof performance Glazed tiles and preparation method thereof.
The present invention is realized by following technical proposal: a kind of glazed tiles, including the raw material of following masses part:
Magnesium oxide 60～70 parts, magnesium chloride 20～30 parts, silica flour 24～30 parts, Pulvis Talci 8～10 parts, magnesite modification agent 1.5 ～2.6 parts, PVA 1～1.5 parts, PET 1～2 parts, PVC 1.8～2.8 parts, PAE wet strength agent 1～1.5 parts.
Another object of the present invention also resides in the preparation method providing a kind of glazed tiles, through following each step:
(1) by the material preparation of following mass parts:
Magnesium oxide 60～70 parts, magnesium chloride 20～30 parts, silica flour 24～30 parts, Pulvis Talci 8～10 parts, magnesite modification agent 1.5 ～2.6 parts, PVA 1～1.5 parts, PET 1～2 parts, PVC 1.8～2.8 parts, PAE wet strength agent 1～1.5 parts；
(2) by after the component mix homogeneously in step (1), by compound at 60～70 DEG C, light-burned 10～20 minutes, obtain light Burn compound；
(3) by the light-burned compound of step (2) gained under normal temperature condition, it is covered with bottom injection in the mould of glass fabric, note The light-burned compound thickness entered is 1/2nd of die depth, sends on forming machine, suppress under the pressure of 3500 MPas 1～ 2 minutes；
(4) the light-burned compound upper berth suppressed in step (3) enters second layer glass fabric, reinjects step (2) gained light-burned Compound, the light-burned compound thickness of injection is 2/3rds of die depth, sends on forming machine, at the pressure of 3500 MPas Lower compacting 1～2 minutes；
(5) the light-burned compound upper berth suppressed in step (4) enters third layer glass fabric, reinjects step (2) gained light-burned Compound is full to mould, the more light-burned mix surface paving skin glass fiber cloth at full mould, sends on forming machine, 3,500,000,000 Suppress 1～2 minute under the pressure of handkerchief；
(6) after the mixed material heating that step (5) is suppressed being warming up to 40～45 DEG C, break away from moulds, obtain blank；
(7) step (6) gained blank surface being smeared conventional glaze fabric, glazed layer thickness is 2～5mm, after natural drying, obtains coloured glaze Glass watt.
Advantage that the present invention possesses and effect: in the raw material of the present invention, magnesium oxide energy glazed tiles surface forms porcelain shape activity Material, moreover it is possible to after magnesium chloride chemical reaction, produces temperature rise effect, makes material form strong magnesium oxide hard, wear-resisting, elastic Cement；Silica flour can improve product hardness, and Pulvis Talci makes product surface smooth, attractive in appearance, magnificent, magnesite modification agent energy acid-fast alkali-proof Agent, makes product corrosion resistance strengthen, and can effectively strengthen environmental-protecting performance, fire protecting performance, moistureproof resistance to frost, and PVA resina increases The cohesive of its material strong and density performance, PET strengthens the hardness of product, activity degree, makes product smooth, uvioresistant；PVC makes Product is waterproof, rain-tight;PAE makes product appearance zero defect, and internal indefectible, product soundproof effect significantly improves；Use glass Cloth can make product not ftracture, non-friable, drop resistant ability is superpower, strengthen caking ability, strengthen load-bearing dynamics, strengthens anti-seismic performance.
Gained glazed tiles of the present invention have the following characteristics that
1, green material, lightweight, comprcssive strength is high, indeformable；
2, fire-proof and damp-proof, anticorrosion, heat-insulating and fire-proof, heat-insulating sound-insulating is effective；
3, the easy cutting of product, machinability is good；
4, ornamental strong, easily it is connected with multiple building materials:
5, simple installation, quick, easily grasps；
6, color is various, colour-fast, ageing-resistant, more than 30 years service life.
7, be difficult to split, non-friable, drop resistant ability is good, load-bearing dynamics is strong, anti-seismic performance good.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
(1) by the material preparation of following mass parts:
Magnesium oxide 65 parts, 25 parts of magnesium chloride, silica flour 28 parts, Pulvis Talci 9 parts, magnesite modification agent 2 parts, PVA1.2 part, PET 1.5 Part, PVC 2.2 parts, PAE wet strength agent 1.3 parts；
(2) by after the component mix homogeneously in step (1), by compound at 65 DEG C, light-burned 15 minutes, light-burned mixing is obtained Material；
(3) by the light-burned compound of step (2) gained under normal temperature condition, it is covered with bottom injection in the mould of glass fabric, note The light-burned compound thickness entered is 1/2nd of die depth, sends on forming machine, suppress under the pressure of 3500 MPas 1～ 2 minutes；
(4) the light-burned compound upper berth suppressed in step (3) enters second layer glass fabric, reinjects step (2) gained light-burned Compound, the light-burned compound thickness of injection is 2/3rds of die depth, sends on forming machine, at the pressure of 3500 MPas Lower compacting 1～2 minutes；
(5) the light-burned compound upper berth suppressed in step (4) enters third layer glass fabric, reinjects step (2) gained light-burned Compound is full to mould, the more light-burned mix surface paving skin glass fiber cloth at full mould, sends on forming machine, 3,500,000,000 Suppress 1～2 minute under the pressure of handkerchief；
(6) after the mixed material heating that step (5) is suppressed being warming up to 42 DEG C, break away from moulds, obtain blank；
(7) step (6) gained blank surface being smeared conventional glaze fabric, glazed layer thickness is 3mm, after natural drying, obtains coloured glaze Watt.
Gained glazed tiles are lightweight, comprcssive strength is high, and drop resistant ability is good, load-bearing dynamics is strong, anti-seismic performance good, and fire prevention is anti- Tide, anticorrosion, heat-insulating and fire-proof, heat-insulating sound-insulating is effective, easy cutting, ornamental strong, ageing-resistant, more than 30 years service life.
Embodiment 2
(1) by the material preparation of following mass parts:
Magnesium oxide 60 parts, 20 parts of magnesium chloride, silica flour 24 parts, Pulvis Talci 8 parts, magnesite modification agent 1.5 parts, PVA 1 part, PET 1 Part, PVC 1.8 parts, PAE wet strength agent 1 part；
(2) by after the component mix homogeneously in step (1), by compound at 60 DEG C, light-burned 20 minutes, light-burned mixing is obtained Material；
(3) by the light-burned compound of step (2) gained under normal temperature condition, it is covered with bottom injection in the mould of glass fabric, note The light-burned compound thickness entered is 1/2nd of die depth, sends on forming machine, suppress under the pressure of 3500 MPas 1～ 2 minutes；
(4) the light-burned compound upper berth suppressed in step (3) enters second layer glass fabric, reinjects step (2) gained light-burned Compound, the light-burned compound thickness of injection is 2/3rds of die depth, sends on forming machine, at the pressure of 3500 MPas Lower compacting 1～2 minutes；
(5) the light-burned compound upper berth suppressed in step (4) enters third layer glass fabric, reinjects step (2) gained light-burned Compound is full to mould, the more light-burned mix surface paving skin glass fiber cloth at full mould, sends on forming machine, 3,500,000,000 Suppress 1～2 minute under the pressure of handkerchief；
(6) after the mixed material heating that step (5) is suppressed being warming up to 40 DEG C, break away from moulds, obtain blank；
(7) step (6) gained blank surface being smeared conventional glaze fabric, glazed layer thickness is 2mm, after natural drying, obtains coloured glaze Watt.
Gained glazed tiles are lightweight, comprcssive strength is high, and drop resistant ability is good, load-bearing dynamics is strong, anti-seismic performance good, and fire prevention is anti- Tide, anticorrosion, heat-insulating and fire-proof, heat-insulating sound-insulating is effective, easy cutting, ornamental strong, ageing-resistant, more than 30 years service life.
Embodiment 3
(1) by the material preparation of following mass parts:
Magnesium oxide 70 parts, 30 parts of magnesium chloride, silica flour 30 parts, Pulvis Talci 10 parts, magnesite modification agent 2.6 parts, PVA 1.5 parts, PET 2 parts, PVC 2.8 parts, PAE wet strength agent 1.5 parts；
(2) by after the component mix homogeneously in step (1), by compound at 70 DEG C, light-burned 10 minutes, light-burned mixing is obtained Material；
(3) by the light-burned compound of step (2) gained under normal temperature condition, it is covered with bottom injection in the mould of glass fabric, note The light-burned compound thickness entered is 1/2nd of die depth, sends on forming machine, suppress under the pressure of 3500 MPas 1～ 2 minutes；
(4) the light-burned compound upper berth suppressed in step (3) enters second layer glass fabric, reinjects step (2) gained light-burned Compound, the light-burned compound thickness of injection is 2/3rds of die depth, sends on forming machine, at the pressure of 3500 MPas Lower compacting 1～2 minutes；
(5) the light-burned compound upper berth suppressed in step (4) enters third layer glass fabric, reinjects step (2) gained light-burned Compound is full to mould, the more light-burned mix surface paving skin glass fiber cloth at full mould, sends on forming machine, 3,500,000,000 Suppress 1～2 minute under the pressure of handkerchief；
(6) after the mixed material heating that step (5) is suppressed being warming up to 45 DEG C, break away from moulds, obtain blank；
(7) step (6) gained blank surface being smeared conventional glaze fabric, glazed layer thickness is 5mm, after natural drying, obtains coloured glaze Watt.
Gained glazed tiles are lightweight, comprcssive strength is high, and drop resistant ability is good, load-bearing dynamics is strong, anti-seismic performance good, and fire prevention is anti- Tide, anticorrosion, heat-insulating and fire-proof, heat-insulating sound-insulating is effective, easy cutting, ornamental strong, ageing-resistant, more than 30 years service life.

Claims (2)

1. glazed tiles, it is characterised in that include the raw material of following masses part:
Magnesium oxide 60～70 parts, magnesium chloride 20～30 parts, silica flour 24～30 parts, Pulvis Talci 8～10 parts, magnesite modification agent 1.5 ～2.6 parts, PVA 1～1.5 parts, PET 1～2 parts, PVC 1.8～2.8 parts, PAE wet strength agent 1～1.5 parts.
2. the preparation method of glazed tiles, it is characterised in that through following each step:
(1) by the material preparation of following mass parts:
Magnesium oxide 60～70 parts, magnesium chloride 20～30 parts, silica flour 24～30 parts, Pulvis Talci 8～10 parts, magnesite modification agent 1.5 ～2.6 parts, PVA 1～1.5 parts, PET 1～2 parts, PVC 1.8～2.8 parts, PAE wet strength agent 1～1.5 parts；
(2) by after the component mix homogeneously in step (1), by compound at 60～70 DEG C, light-burned 10～20 minutes, obtain light Burn compound；
(3) by the light-burned compound of step (2) gained under normal temperature condition, it is covered with bottom injection in the mould of glass fabric, note The light-burned compound thickness entered is 1/2nd of die depth, sends on forming machine, suppress under the pressure of 3500 MPas 1～ 2 minutes；
(4) the light-burned compound upper berth suppressed in step (3) enters second layer glass fabric, reinjects step (2) gained light-burned Compound, the light-burned compound thickness of injection is 2/3rds of die depth, sends on forming machine, at the pressure of 3500 MPas Lower compacting 1～2 minutes；
(5) the light-burned compound upper berth suppressed in step (4) enters third layer glass fabric, reinjects step (2) gained light-burned Compound is full to mould, the more light-burned mix surface paving skin glass fiber cloth at full mould, sends on forming machine, 3,500,000,000 Suppress 1～2 minute under the pressure of handkerchief；
(6) after the mixed material heating that step (5) is suppressed being warming up to 40～45 DEG C, break away from moulds, obtain blank；
(7) step (6) gained blank surface being smeared conventional glaze fabric, glazed layer thickness is 2～5mm, after natural drying, obtains coloured glaze Glass watt.
CN201610714147.6A 2016-08-24 2016-08-24 Glazed tile and preparing method thereof Pending CN106316339A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610714147.6A CN106316339A (en) 2016-08-24 2016-08-24 Glazed tile and preparing method thereof

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Application Number Priority Date Filing Date Title
CN201610714147.6A CN106316339A (en) 2016-08-24 2016-08-24 Glazed tile and preparing method thereof

Publications (1)

Publication Number Publication Date
CN106316339A true CN106316339A (en) 2017-01-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601871A (en) * 2017-09-27 2018-01-19 太仓经济开发区坚毅工艺美术品工作室 The preparation method of resistant to damage crystal colored glaze

Citations (6)

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Publication number Priority date Publication date Assignee Title
CN1075113A (en) * 1992-09-29 1993-08-11 朝阳市双塔建筑材料厂 Light weight glazed tile production technique and product
CN1078449A (en) * 1993-02-26 1993-11-17 朝阳市双塔建筑材料厂 Utilize flyash to make light weight glazed tile production technique and product
CN1090232A (en) * 1993-10-09 1994-08-03 峡江县铁工厂 Composite glazed tile with glass fiber reinforced plastics
CN1099333A (en) * 1993-09-29 1995-03-01 唐长锡 Method for making high-strength light glass corrugated tile
CN1117949A (en) * 1994-10-24 1996-03-06 周培文 Method for production of colour porcelain imitation glass tile
WO2001085642A1 (en) * 2000-05-10 2001-11-15 Armonite S.P.A. Process for making extrusions for producing multi-property tiles and obtained tiles

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075113A (en) * 1992-09-29 1993-08-11 朝阳市双塔建筑材料厂 Light weight glazed tile production technique and product
CN1078449A (en) * 1993-02-26 1993-11-17 朝阳市双塔建筑材料厂 Utilize flyash to make light weight glazed tile production technique and product
CN1099333A (en) * 1993-09-29 1995-03-01 唐长锡 Method for making high-strength light glass corrugated tile
CN1090232A (en) * 1993-10-09 1994-08-03 峡江县铁工厂 Composite glazed tile with glass fiber reinforced plastics
CN1117949A (en) * 1994-10-24 1996-03-06 周培文 Method for production of colour porcelain imitation glass tile
WO2001085642A1 (en) * 2000-05-10 2001-11-15 Armonite S.P.A. Process for making extrusions for producing multi-property tiles and obtained tiles

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* Cited by examiner, † Cited by third party
Title
李书田: "《现代建筑新材料与施工》", 31 January 2006 *
李向烈主编: "《中国建材专利大全》", 30 September 1999 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107601871A (en) * 2017-09-27 2018-01-19 太仓经济开发区坚毅工艺美术品工作室 The preparation method of resistant to damage crystal colored glaze

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Application publication date: 20170111