CN102786317B - Recycled foam material using granite powder as raw material - Google Patents
Recycled foam material using granite powder as raw material Download PDFInfo
- Publication number
- CN102786317B CN102786317B CN201210286373.0A CN201210286373A CN102786317B CN 102786317 B CN102786317 B CN 102786317B CN 201210286373 A CN201210286373 A CN 201210286373A CN 102786317 B CN102786317 B CN 102786317B
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- Prior art keywords
- powder
- granite
- composition
- percent
- fluxing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000843 powder Substances 0.000 title claims abstract description 65
- 239000010438 granite Substances 0.000 title claims abstract description 39
- 239000002994 raw material Substances 0.000 title claims abstract description 11
- 239000006261 foam material Substances 0.000 title abstract 5
- 239000000463 material Substances 0.000 claims abstract description 54
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 239000011148 porous material Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 238000005187 foaming Methods 0.000 claims description 18
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 239000010433 feldspar Substances 0.000 claims description 8
- 239000010445 mica Substances 0.000 claims description 8
- 229910052618 mica group Inorganic materials 0.000 claims description 8
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 7
- 229910000278 bentonite Inorganic materials 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 7
- 229910052570 clay Inorganic materials 0.000 claims description 7
- 239000011863 silicon-based powder Substances 0.000 claims description 7
- 239000004328 sodium tetraborate Substances 0.000 claims description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- 239000000454 talc Substances 0.000 claims description 7
- 229910052623 talc Inorganic materials 0.000 claims description 7
- 235000012222 talc Nutrition 0.000 claims description 7
- 239000010456 wollastonite Substances 0.000 claims description 7
- 229910052882 wollastonite Inorganic materials 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000008187 granular material Substances 0.000 abstract description 8
- 238000009413 insulation Methods 0.000 abstract description 8
- 239000002699 waste material Substances 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000003825 pressing Methods 0.000 abstract description 4
- 230000002265 prevention Effects 0.000 abstract description 4
- 238000007906 compression Methods 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000004134 energy conservation Methods 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 238000005452 bending Methods 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 230000036314 physical performance Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 231100000614 Poison Toxicity 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 230000002742 anti-folding Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001413 cellular Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- -1 promoter Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052904 quartz Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004642 transportation engineering Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
Abstract
The invention discloses a recycled foam material using granite powder as a raw material. The formula composition of the recycled foam material comprises the following components in percentage by weight: 70-90 percent of granite powder, 6-25 percent of fluxing filler, 1-5 percent of pore forming material and 1-5 percent of polymeric material. A manufacturing method of the recycled foam material sequentially comprises the following steps of: controlling the fineness of the particles of the powder to be over 100 meshes; uniformly stirring and mixing; pressing mixture into a required granular material; stacking and forming the granular material; feeding into a high temperature furnace to heat; and cooling and taking out to obtain a finished product. The recycled foam material has the advantages of fully consuming granite powder waste material, solving the problem of serious environmental pollution existing at a granite processing base for a long time and meeting environmental protection requirements. The product has the advantages of stable physical performance, light weight, thermal insulation, compression resistance, bending resistance, capabilities of being used for building wall or external wall decoration and fulfilling the aims of weight reduction and energy conservation of a building, fire prevention, water prevention and sound isolation performance and capability of being used as a fire-proof material and a wall isolating material.
Description
Technical field
The present invention relates to a kind of generative foaming material that granite powder waste material is raw material that utilizes.
Background technology
Granite be a kind of magma below earth's surface, condense form igneous rock, main component is feldspar and quartz.Because granite is plutonic rock, often can form physically well develop, mineral grain that naked eyes can be distinguished, thereby gain the name.Granite is easy-weathering not, and color is attractive in appearance, more than appearance luster can keep a century, and because its hardness is high, wear-resistant, except being used as senior building decorative engineering, ground, hall, or the material of the first-selection of outdoor engraving.The natural formation of granite need to through upper a century even thousands of before, because the mankind constantly exploit, the reserves of natural granite constantly reduce, and in the process of granite, can produce waste material and the granite powder of many granite, the words that these waste materials and granite powder are not used, will produce severe contamination, welding, restriction expanding economy.The method of traditional digestion granite powder adopts low temperature, mixed sticky technique to make regrown material, and the density of its product is large, reaches 2.5 tons/m
3, conduct heat fast, and in manufacturing process, need to add chemical adhesive.
Also have a kind of application number to be 200710142893.3 to be called the Chinese invention patent application of " utilize granite powder waste material artificial compound board prepared " to disclose a kind of novel artificial composite plank, made by granite waste material.Formula comprises resin, curing agent, promoter, granite powder, gravel particle etc.This artificial composite plank, pattern is many, and length can accomplish enough large, thereby can be applied to various places.But in the formula due to described artificial composite plank, use inflammable or poisonous chemicals, people is known from experience and damaged, and density has been large, heavy weight, transport and installation are all inconvenient, are difficult for again insulation, nor can reuse.Therefore, the structure of this composite plate also needs to be further improved.
Summary of the invention
Technical problem to be solved by this invention is the generative foaming material that granite powder is raw material that utilizes that a kind of insulation, fire prevention, lightweight and environmental protection are provided for above-mentioned prior art present situation.
The present invention solves the problems of the technologies described above adopted technical scheme: this utilizes the generative foaming material that granite powder is raw material, it is characterized in that: the formula of this generative foaming material consists of: granite powder is 70%～90%, the filler of fluxing is 6%～25%, pore creating agent is 1%～5%, polymerization material is 1%～5%, and above-mentioned percentage is mass percent.
As improvement, described in the filler of fluxing may be selected to be the combined composition of any two and feldspar powder in talcum powder, silicon powder, wollastonite material, mica powder, dry powder.
As improvement, the component ratio of described composition can be preferably: A: B: C=5: 1.5: 1.5, wherein A represents feldspar powder, B is the one in talcum powder, silicon powder, wollastonite material, mica powder, dry powder, C is the one in talcum powder, silicon powder, wollastonite material, mica powder, dry powder, and B and C are two kinds of not identical materials.
As improvement, described pore creating agent can be preferably diatomite, titanium dioxide, carborundum, calcium carbonate, any two composition in brium carbonate.
Improve, the component ratio of described composition may be selected to be 1: 1 again.
As improvement, described polymerization material may be selected to be the composition of clay, bentonite, borax.
Improve, the component ratio of described composition can be preferably clay: bentonite: borax=1: 1: 1 again.
Compared with prior art, the invention has the advantages that: generative foaming material of the present invention has following product performance:
(1) all raw materials are inorganic material, without chemical contamination.
(2) high temperature burns till, and more than high temperature resistant 1100 degree, fire-resistant A level.
(3) cellular hole-closing structure, airtight, waterproof, and heat conduction is slow.Waterproof, sound insulation, insulation.
(4) 0.3 ton/m of density range
3～1.2 tons/m
3, pressure-proof and snap-resistent is physical good.
(5) can reuse, dead meal still can burn till after again preparing burden.
According to above-mentioned feature, the advantage of product of the present invention is, can fully digest granite powder waste material, can solve the long-standing severe environmental pollution problem in granite processing base, meet the requirement of environmental protection.This product stable physical property, lightweight, insulation, resistance to compression, anti-folding, can be used for construction wall or decoration of exterior wall, reaches building loss of weight and energy-conservation target.Also have this product also to there is the performance of fire prevention, waterproof, sound insulation, can be used for fire proofing material, body of wall barrier material.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, below the percentage of indication be mass percent;
Embodiment mono-, the formula that utilizes the generative foaming material that granite powder is raw material of the present embodiment consists of granite powder 70%, the filler 22% of fluxing, pore creating agent 3%, polymerization material 5%.The described filler of fluxing is feldspar powder, talcum powder, and silicon powder composition, its ratio is 5: 1.5: 1.5, described pore creating agent is diatomite, carborundum composition, and its ratio is 1: 1, described polymerization material is clay, bentonite, borax composition, its ratio is 1: 1: 1.
According to above-mentioned formula, the preparation method of generative foaming material, comprises the following steps successively:
One, be more than 100 orders through pulverizing, screening by the grain fineness control of granite powder, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, the filler of fluxing, pore creating agent, polymerization material powder are uniformly mixed and make compound, then compound is made to required granular material by mold pressing or roll extrusion;
Three, granulated material is put into the die body of required form, stacked moulding;
Four, then the material of stacking moulding being put into high temperature furnace together with die body slowly heats, until the temperature of high temperature furnace reaches 1100～1400 degree, and be to heat 50～70 minutes in 1100～1400 high temperature furnaces of spending in temperature, be preferably 60 minutes, after having heated, from high temperature furnace, take out, naturally after cooling 11～13 hours, from die body, take out, be generative foaming finished material.
Embodiment bis-, the formula that utilizes the generative foaming material that granite powder is raw material of the present embodiment is: granite powder 76%, the filler 18% of fluxing, pore creating agent 3%, polymerization material 3%.The described filler of fluxing is feldspar powder, wollastonite material, and mica powder composition, its ratio is 5: 1.5: 1.5, described pore creating agent is diatomite, brium carbonate composition, and its ratio is 1: 1, described polymerization material is clay, bentonite, borax composition, its ratio is 1: 1: 1.
According to above-mentioned formula, the preparation method of generative foaming material, comprises the following steps successively:
One, be more than 100 orders through pulverizing, screening by the grain fineness control of granite powder, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, the filler of fluxing, pore creating agent, polymerization material powder are uniformly mixed and make compound, then compound is made to required granular material by mold pressing or roll extrusion;
Three, granulated material is put into the die body of required form, stacked moulding;
Four, then the material of stacking moulding being put into high temperature furnace together with die body slowly heats, until the temperature of high temperature furnace reaches 1100～1400 degree, and be to heat 50～70 minutes in 1100～1400 high temperature furnaces of spending in temperature, be preferably 60 minutes, after having heated, from high temperature furnace, take out, naturally after cooling 11～13 hours, from die body, take out, be generative foaming finished material.
Embodiment tri-, the formula that utilizes the generative foaming material that granite powder is raw material of the present embodiment is: granite powder 75%, the filler 15% of fluxing, pore creating agent 4%, polymerization material 6%.The described filler of fluxing is feldspar powder, mica powder, and dry powder composition, its ratio is followed successively by 5: 1.5: 1.5, described pore creating agent is titanium dioxide, carborundum composition, and its ratio is 1: 1, described polymerization material is clay, bentonite, borax composition, its ratio is 1: 1: 1.
According to above-mentioned formula, the preparation method of generative foaming material, comprises the following steps successively:
One, be more than 100 orders through pulverizing, screening by the grain fineness control of granite powder, the filler of fluxing, pore creating agent, polymerization material powder;
Two, granite powder, the filler of fluxing, pore creating agent, polymerization material powder are uniformly mixed and make compound, then compound is made to required granular material by mold pressing or roll extrusion;
Three, granulated material is put into the die body of required form, stacked moulding;
Four, then the material of stacking moulding being put into high temperature furnace together with die body heats, until the temperature of high temperature furnace reaches 1100～1400 degree, and be to heat 50～70 minutes in 1100～1400 high temperature furnaces of spending in temperature, be preferably 60 minutes, after having heated, from high temperature furnace, take out, naturally after cooling 11～13 hours, from die body, take out, be generative foaming finished material.This generative foaming material can be processed into exterior wall thermal insulation brick or warming plate, also can be used as the wall brick of indoor separation etc.
Claims (1)
1. one kind is utilized the generative foaming material that granite powder is raw material, it is characterized in that: the formula of this generative foaming material consists of: granite powder is 70%～90%, the filler of fluxing is 6%～25%, pore creating agent is 1%～5%, polymerization material is 1%～5%, and above-mentioned percentage is mass percent;
The described filler of fluxing is the combined composition of any two and the feldspar powder in talcum powder, silicon powder, wollastonite material, mica powder, dry powder; The component ratio of fill composition of fluxing is: A: B: C=5: 1.5: 1.5, wherein A represents feldspar powder, B is the one in talcum powder, silicon powder, wollastonite material, mica powder, dry powder, C is the one in talcum powder, silicon powder, wollastonite material, mica powder, dry powder, and B and C are two kinds of not identical materials; Described pore creating agent is diatomite, titanium dioxide, carborundum, calcium carbonate, any two composition in brium carbonate; The component ratio of pore creating agent composition is 1: 1; Described polymerization material is the composition of clay, bentonite, borax; The component of polymerization feed composition is than being clay: bentonite: borax=1: 1: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210286373.0A CN102786317B (en) | 2012-08-13 | 2012-08-13 | Recycled foam material using granite powder as raw material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210286373.0A CN102786317B (en) | 2012-08-13 | 2012-08-13 | Recycled foam material using granite powder as raw material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102786317A CN102786317A (en) | 2012-11-21 |
| CN102786317B true CN102786317B (en) | 2014-09-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210286373.0A Expired - Fee Related CN102786317B (en) | 2012-08-13 | 2012-08-13 | Recycled foam material using granite powder as raw material |
Country Status (1)
| Country | Link |
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| CN (1) | CN102786317B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103073328B (en) * | 2013-01-16 | 2014-11-05 | 宁波振强建材有限公司 | Regenerative foam material taking granite powder as raw material and preparation method of regenerative foam material |
| CN103396085B (en) * | 2013-08-14 | 2014-12-31 | 武汉科技大学 | Low-heat-conductivity light-weight heat-insulating material based on granite waste and preparation method thereof |
| CN103396153B (en) * | 2013-08-14 | 2015-01-14 | 武汉科技大学 | Light-weight heat-insulating material taking granite waste as raw material and preparation method thereof |
| CN105503257B (en) * | 2015-12-28 | 2018-06-05 | 厦门天石再生科技有限公司 | A kind of sintering stone material bee-hole regrown material |
| CN105622158B (en) * | 2015-12-28 | 2018-03-27 | 厦门天石再生科技有限公司 | A kind of three layers of regrown material of crystallite face bee-hole |
| CN106187134A (en) * | 2016-07-13 | 2016-12-07 | 深圳市超超科技发展有限公司 | Based on granite foamed light materials for wall and preparation method thereof |
| CN106187087A (en) * | 2016-07-13 | 2016-12-07 | 深圳市超超科技发展有限公司 | Composite foamed pottery of facing based on granite mine tailing and preparation method thereof |
| CN107698237A (en) * | 2016-12-01 | 2018-02-16 | 张晓辉 | Silicide additive, silicon protect stone series of plates and its processing technology |
| CN109081703A (en) * | 2018-11-06 | 2018-12-25 | 中集绿建环保科技有限公司 | A kind of preparation method of decoration of exterior wall rock beam not easy to fade |
| CN112266230A (en) * | 2020-10-23 | 2021-01-26 | 郑州大学 | High-temperature micro-foamed light heat-insulating material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491920A (en) * | 2002-10-26 | 2004-04-28 | 江苏省陶瓷研究所有限公司 | Light foamed ceramic medium ball and its producing method |
| CN201704910U (en) * | 2010-04-22 | 2011-01-12 | 谢林杰 | Fireproof sound insulation board made from granite waste material |
| CN102101792A (en) * | 2009-12-18 | 2011-06-22 | 黄家洞 | Production process of light foam ceramic bricks |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003246687A (en) * | 2002-02-22 | 2003-09-02 | Ngk Insulators Ltd | Method of manufacturing water absorptive ceramics |
-
2012
- 2012-08-13 CN CN201210286373.0A patent/CN102786317B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1491920A (en) * | 2002-10-26 | 2004-04-28 | 江苏省陶瓷研究所有限公司 | Light foamed ceramic medium ball and its producing method |
| CN102101792A (en) * | 2009-12-18 | 2011-06-22 | 黄家洞 | Production process of light foam ceramic bricks |
| CN201704910U (en) * | 2010-04-22 | 2011-01-12 | 谢林杰 | Fireproof sound insulation board made from granite waste material |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2003-246687A 2003.09.02 |
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| CN102786317A (en) | 2012-11-21 |
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Effective date of registration: 20151023 Address after: Ningbo City, Zhejiang province 315612 unity Tang Ninghai County Qiangjiao Zhenning Bay Circulation Economic Development Zone Patentee after: Ningbo strong vibration technology Co.,Ltd. Address before: Kaohsiung Beilun District 315821 in Zhejiang province Ningbo city new village Zhu 76 Building No. 2 (1) Patentee before: NINGBO ZHENQIANG BUILDING MATERIAL Co.,Ltd. |
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