CN1090232A - Composite glazed tile with glass fiber reinforced plastics - Google Patents
Composite glazed tile with glass fiber reinforced plastics Download PDFInfo
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- CN1090232A CN1090232A CN 93118610 CN93118610A CN1090232A CN 1090232 A CN1090232 A CN 1090232A CN 93118610 CN93118610 CN 93118610 CN 93118610 A CN93118610 A CN 93118610A CN 1090232 A CN1090232 A CN 1090232A
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- compound watt
- watt
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Abstract
A kind of composite glazed tile with glass fiber reinforced plastics, magnesium oxychloride cement by modification is mud, is that skeleton is formed the B of basic unit with the glass fibre, is mud by talcum powder and 191 lacquer type organic coatings, with the glass fibre pin check cloth is that skeleton constitutes top layer A, synthetic A, B layer through moulding, solidify, the demoulding, maintenance, clear limit is made compound watt.This compound watt of surface-brightening, water absorption rate is extremely low, and it is good to have water resistance, the rupture strength height, fire protection flame retarding, freeze proof, advantages such as acid-alkali-corrosive-resisting are specially adapted to rainy southern area, are a kind of good magnesia watt and substitute products of glazed tiles.
Description
The present invention relates to the tile in the construction material, particularly the fiberglass glazed tiles.
With Sorel cement (magnesia, magnesium chloride) is base-material, is that magnesia watt of subject matter of aggregate is to return halogen with the glass fabric, and water resistance is poor, and water absorption rate is 20%, and rough surface is not attractive in appearance.Be modified magnesium watt, CN88101237A " stained glass watt production method " patent application provides a kind of colour glazed tile, and its water absorption rate is 9%, scribbles sealer on its surface, and its water absorbent surface rate is 1.5%, and impermeability was increased to 720 hours by 12 hours.This colour glazed tile is suitable for for the northern area of arid, but feels still that for rainy south the surface is smooth inadequately, and water resistance is still not good enough, and causes the rupture strength deficiency through moisture, and service life is short.
The objective of the invention is to overcome the problem that prior art exists, develop a kind of any surface finish, water resistance is good, rupture strength height, the construction material of long service life.
Purpose of the present invention adopts following technical scheme to reach:
Compound watt of the present invention is composited by top layer A and basic unit's B two parts.Being skeleton with the fiberglass gridding cloth in the B of basic unit, is base-material with the magnesium oxychloride, is aided with silica flour and various modifier; Top layer A is a skeleton with the glass fibre pin check cloth, is base-material with the talcum powder, is aided with lacquer type organic coating, through synthetic i.e. corresponding infiltration chemical combination on A, B bed boundary, solidifies compound watt that the back constitutes.Remove the glass fabric skeleton, constitute composition of raw materials of the present invention compound watt (weight %, down with) and be:
Magnesia 25～50%
Magnesium chloride 15～25%
Silica flour 10～20%
Talcum powder 10～20%
191 lacquer type organic coatings 2～5%
Waterproofing agent 0.3～1%
Curing agent 0.01～0.5%
Promoter 0.01～0.5%
Wherein 191 lacquer type organic coatings are by 37% styrene, 28% cis-butenedioic anhydride, and 25% phthalic anhydride, 10% propane diols is formed.
Wherein curing agent is by two tincture esters 48%, and hydrogen peroxide 52% is formed.
Wherein promoter is by cobalt naphthenate 8%, and styrene 92% is formed.
Wherein waterproofing agent is by ferrous sulfate 48%, oxalic acid 48%, and surplus impurity is formed.
The technological process of composite glazed tile with glass fiber reinforced plastics of the present invention is:
1, weighing:
The raw material of each component is pressed the prescription weighing.
2, batching:
Lacquer type organic coating and talcum powder are combined together the material into top layer A; Magnesium oxychloride, silica flour, curing agent, promoter, waterproofing agent are combined together the material into bottom B.
3, stir:
A, B layered material mix respectively, are stirred into material-mud A, B.
4, tiling mud:
A, B layer material-mud are paved respectively.
5, shop cloth:
At A layer material-mud upper berth glass fibre pin check cloth, constitute surface layer A, constitute the B of basic unit at B layer material-mud upper berth fiberglass gridding cloth.
6, synthetic:
Add together the composite plate that pressurization synthesizes one A, B are stacked.
7, moulding:
The synthetic two-layer composite plate of A, B is put into a watt mould extrusion forming, and solidified 48～60 hours.
8, the demoulding:
From watt mould, take out and be compound watt.
9, maintenance:
Under 20 ℃ of left and right sides room temperatures, natural maintenance 40 days.
10, clear limit:
Remove unnecessary burr.
11, check:
By standard test.
12, warehouse-in:
The product warehouse-in that is up to the standards.
Compound watt of the present invention is detected through Jiangxi Province construction material scientific research and design institute, the proof impermeability is brought up to 1000 hours by 25 hours of glass steel tile, water absorption rate is reduced to 5% by 9% of documents, and the superficial layer light is attractive in appearance, and the top layer water absorption rate is reduced to zero by 15% of documents.Promptly do not absorb water completely.Laterally rupture strength is brought up to 5～6KN by 2～3KN of glazed tiles, and vertically rupture strength is brought up to 2～3KN by 0.5～1.5KN.This compound watt advantage that also has common magnesium oxychloride watt is promptly fire-retardant, advantages such as acid-alkali-corrosive-resisting.
Further specify the present invention below in conjunction with embodiment:
Take by weighing 6 kilograms in magnesia, 3 kilograms of halogen sheets (magnesium chloride) are made the aqueous solution (Be ° 20), 1.5 kilograms of silica flours, waterproofing agent 45 grams, curing agent 5 grams, promoter 5 grams, through batching, mix, stir the material-mud of making the B of basic unit, repave one of the fiberglass gridding cloth of 0.3 millimeters thick after paving, constitute the B of basic unit, take by weighing 1.5 kilograms of talcum powder, 7 0.5 kilograms of 191 resins are through batching, mix, stir into mud, pave material-mud, spread one of 0.2 millimeters thick glass fibre pin check cloth more thereon and constitute superficial layer A.The pressurization of A and B two superimposed is synthesized the composite plate of one, composite plate is put into a watt mould extrusion forming, solidified 55 hours, the demoulding is taken out compound watt, at room temperature natural maintenance 40 days, and reaming is pressed standard test, warehouse-in.This product is 1800 * 720 * 5 millimeters specification tiles.Send Jiangxi Province construction material scientific research and design institute to detect, drawing its horizontal drag is 5.18KN, and vertically drag is 2.78KN.Water absorption rate is 5%, and the superficial layer water absorption rate is 0%, and impermeability test reaches 1000 hours, and freezing and thawing test reaches 50 times.Every index all reaches the requirement of the object of the invention.
Claims (8)
1, a kind of composite glazed tile with glass fiber reinforced plastics, be to be skeleton with the glass fibre, the fiberglass that with the magnesium oxychloride is major ingredient is basic unit, the invention is characterized in and in the B of basic unit, be aided with silica flour and waterproofing agent, curing agent, promoter, with the glass fibre pin check cloth is skeleton, with the talcum powder is base-material, is aided with lacquer type organic coating and constitutes top layer A, through compound watt of the synthetic two-layer formation of A, B.
2, compound watt according to claim 1, it is characterized in that the prescription (weight %) of removing each raw material outside the glass fabric is:
Magnesia 25～50%
Magnesium chloride 15～25%
Silica flour 10～20%
Talcum powder 10～20%
191 lacquer type organic coatings 2～5%
Waterproofing agent 0.3～1%
Curing agent 0.01～0.5%
Promoter 0.01～0.5%
3, compound watt according to claim 1 and 2, it is characterized in that described 191 lacquer type organic coatings by 37% styrene, 28% cis-butenedioic anhydride, 25% phthalic anhydride, 10% propane diols is formed.
4, compound watt according to claim 1 and 2, it is characterized in that described waterproofing agent by 48% ferrous sulfate, 48% oxalic acid and surplus impurity are formed.
5, compound watt according to claim 1 and 2, it is characterized in that described curing agent is made up of 48% 2 tincture ester and 52% hydrogen peroxide.
6, compound watt according to claim 1 and 2, it is characterized in that described promoter is made up of 8% cobalt naphthenate and 92% styrene.
7, a kind of technological process of compound watt making claim 1 is: weighing, divide two-layer batching, and stir, tiling mud, at A layer shop glass fibre pin check cloth, B layer shop fiberglass gridding cloth, synthetic A, B are two-layer to be one, go into mold forming, solidified the demoulding 48～60 hours, maintenance 40 days, clear limit, check, 12 procedures such as warehouse-in.
8, according to claim 1 or 2 or 7 compound watt and technology be: take by weighing 6 kilograms in magnesia, 3 kilograms in magnesium chloride, 1.5 kilograms of silica flours, waterproofing agent 45 grams, curing agent 5 grams, promoter 5 grams are through batching, be mixed and made into mud, spread 0.3 millimeters thick glass cloth and constitute the B of basic unit, take by weighing 1.5 kilograms of talcum powder, 0.5 kilogram of 191 lacquer type organic coating are through batching, mix, stir into mud, spread 0.2 millimeters thick glass pin check cloth and constitute top layer A, synthetic A, B goes into mold forming, solidified 55 hours, the demoulding is taken out compound watt, maintenance 40 days, clear limit, check, warehouse-in, make 1800 * 720 * 5 millimeters compound watt of a slices.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93118610 CN1090232A (en) | 1993-10-09 | 1993-10-09 | Composite glazed tile with glass fiber reinforced plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93118610 CN1090232A (en) | 1993-10-09 | 1993-10-09 | Composite glazed tile with glass fiber reinforced plastics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1090232A true CN1090232A (en) | 1994-08-03 |
Family
ID=4992551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93118610 Pending CN1090232A (en) | 1993-10-09 | 1993-10-09 | Composite glazed tile with glass fiber reinforced plastics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1090232A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445936A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | High-quality colored glaze formula |
| CN104445940A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | Production process of high-clarity colored glaze |
| CN106316339A (en) * | 2016-08-24 | 2017-01-11 | 永仁承信钢结构制作中心 | Glazed tile and preparing method thereof |
-
1993
- 1993-10-09 CN CN 93118610 patent/CN1090232A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104445936A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | High-quality colored glaze formula |
| CN104445940A (en) * | 2014-10-31 | 2015-03-25 | 太仓市科教新城琉璃艺术策划中心 | Production process of high-clarity colored glaze |
| CN106316339A (en) * | 2016-08-24 | 2017-01-11 | 永仁承信钢结构制作中心 | Glazed tile and preparing method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |