CN106283790A - 多功能环保型墙纸 - Google Patents

多功能环保型墙纸 Download PDF

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CN106283790A
CN106283790A CN201610767207.0A CN201610767207A CN106283790A CN 106283790 A CN106283790 A CN 106283790A CN 201610767207 A CN201610767207 A CN 201610767207A CN 106283790 A CN106283790 A CN 106283790A
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庞瑜
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Advertising Co Ltd Nanning East Era
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Abstract

本发明公开了一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份材料制成：旧衣服20‑30份、废木料10‑20份、黄麻10‑20份、纳米氧化锌2‑5份、聚二甲基硅氧烷1‑2份、硫化钠2‑8份、氢氧化钠10‑25份、玉米淀粉5‑10份、丙烯酸丁酯2‑5份、钛酸酯偶联剂1‑2份、阳离子聚丙烯酰胺1‑3份、椰油酰基甘氨酸钠1‑2份、偶氮二异丁腈1‑2份、去离子水60‑100份、乙酸乙酯20‑30份，本发明多功能环保型墙纸采用旧衣服、废木料和黄麻作为纤维基料，有效利于资源，避免资源浪费，达到环保效果，具有防霉、抗菌、防辐射、防潮、抗老化等多种功能。

Description

多功能环保型墙纸
技术领域
本发明涉及一种多功能环保型墙纸，属于墙纸技术领域。
背景技术
墙纸，也称为壁纸，它是一种应用相当广泛的室内装饰材料。因为墙纸具有色彩多样、图案丰富、豪华气派、安全环保、施工方便、价格适宜等多种其它室内装饰材料所无法比拟的特点，故在欧美、东南亚、日本等发达国家和地区得到相当程度的普及。壁纸分为很多类，如涂布壁纸、覆膜壁纸、压花壁纸等。通常用漂白化学木浆生产原纸，再经不同工序的加工处理，如涂布、印刷、压纹或表面覆塑，最后经裁切、包装后出厂。因为具有一定的强度、美观的外表和良好的抗水性能，广泛用于住宅、办公室、宾馆的室内装修等。墙纸的原料一般是木头、竹子等，由于应用广泛，墙纸的使用量越来越多，原料紧缺，导致树木、竹林遭到过度的滥伐，资源过度利用。
发明内容
本发明的一个目的是解决上述问题，并提供一种多功能环保型墙纸，本发明多功能环保型墙纸采用旧衣服、废木料和黄麻作为纤维基料，有效利于资源，避免资源浪费，达到环保效果。
本发明提供的技术方案为：
一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份材料制成：旧衣服20-30份、废木料10-20份、黄麻10-20份、纳米氧化锌2-5份、聚二甲基硅氧烷1-2份、硫化钠2-8份、氢氧化钠10-25份、玉米淀粉5-10份、丙烯酸丁酯2-5份、钛酸酯偶联剂1-2份、阳离子聚丙烯酰胺1-3份、椰油酰基甘氨酸钠1-2份、偶氮二异丁腈1-2份、去离子水60-100份、乙酸乙酯20-30份。
优选的是，所述多功能环保型墙纸由以下重量份材料制成：旧衣服25份、废木料15份、黄麻12份、纳米氧化锌3份、聚二甲基硅氧烷2份、硫化钠4份、氢氧化钠20份、玉米淀粉7份、丙烯酸丁酯3份、钛酸酯偶联剂1份、阳离子聚丙烯酰胺2份、椰油酰基甘氨酸钠1份、偶氮二异丁腈2份、去离子水80份、乙酸乙酯25份。
优选的是，所述活性氧化锌粒径≤50纳米。
优选的是，所述玉米淀粉与丙烯酸丁酯的重量比为2∶1。
一种所述的多功能环保型墙纸的制备方法，包括以下步骤：
步骤一、将旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将黄麻去除心只留黄麻皮，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入去离子水、硫化钠、氢氧化钠置于超声波机器中制浆1-2小时，制浆温度为100-150℃，制得纤维浆；
步骤二、将纳米氧化锌、去离子水与乙酸乙酯混合加热至80℃加入氢氧化钠后马上加入钛酸酯偶联剂，采用搅拌机不断搅拌1-2小时，搅拌速度为100-200rmp，得到表面改性纳米氧化锌；
步骤三、将玉米淀粉加入去离子水、椰油酰基甘氨酸钠，搅拌0.5小时后加入乙酸乙酯，温度加热至80-90℃加入丙烯酸丁酯、阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50-60℃加入偶氮二异丁腈，搅拌3-4小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，温度为80-90℃搅拌2-4小时，涂布干燥印花得到所述多功能环保型墙纸。
优选的是，步骤一中，纳米高压脉冲粉碎机的工作电压为30-40kv，脉冲波数为20-30；超声波工作的频率为50-100赫兹。
优选的是，步骤四中，反应釜的真空度为0.8-0.9Mpa。
本发明的有益效果如下：
本发明的多功能环保型墙纸中纳米氧化锌通过钛酸酯偶联剂改性后能均匀分布，自身不易发生团聚现象，旧衣服、废木料和黄麻制成纤维浆表面形成一层涂层，起到抗菌防霉作用，本发明中玉米淀粉与丙烯酸丁酯、阳离子聚丙烯酰胺共聚反应得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物，这些共聚物能与纤维浆形成致密的网状结构，显著提高了墙纸的防潮性，也改善了墙纸的抗老化性能，延长墙纸的使用寿命；同时本发明多功能环保型墙纸采用旧衣服、废木料和黄麻作为纤维基料，有效利于资源，避免资源浪费，达到环保效果，并且旧衣服、废木料和黄麻中的纤维相互结合抗拉强度高，本发明具有防霉、抗菌、防辐射、防潮、抗老化、抗拉强度高等多种功能。
具体实施方式
下面结合具体实施例对本发明做进一步的详细说明，以令本领域技术人员参照说明书文字能够据以实施。
本发明中所提到的百分数含量均为质量百分数含量，有特殊说明除外。
实施例1：
一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份(kg)材料制成：旧衣服20份、废木料10份、黄麻10份、纳米氧化锌2份、聚二甲基硅氧烷1份、硫化钠2份、氢氧化钠10份、玉米淀粉5份、丙烯酸丁酯2份、钛酸酯偶联剂1份、阳离子聚丙烯酰胺1份、椰油酰基甘氨酸钠1份、偶氮二异丁腈1份、去离子水60份、乙酸乙酯20份。
上述的多功能环保型墙纸的制备方法，包括以下步骤：
步骤一、将20kg旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将10kg黄麻去除心只留黄麻皮，0.5kg氢氧化钠与9.5kg水混合得到5％的氢氧化钠溶液，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与10kg废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入30.5kg去离子水、2kg硫化钠、7.5kg氢氧化钠置于超声波机器中制浆1-2小时，制浆温度为100-150℃，制得纤维浆；
步骤二、将2kg纳米氧化锌、10kg去离子水与10kg乙酸乙酯混合加热至80℃加入2kg氢氧化钠后马上加入1kg钛酸酯偶联剂，采用搅拌机不断搅拌1小时，搅拌速度为100rmp，得到表面改性纳米氧化锌；
步骤三、将5kg玉米淀粉加入10kg去离子水、1kg椰油酰基甘氨酸钠，搅拌0.5小时后加入10kg乙酸乙酯，温度加热至80-90℃加入2kg丙烯酸丁酯、1kg阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50-60℃加入1kg偶氮二异丁腈，搅拌3-4小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，温度为80-90℃搅拌2-4小时，涂布干燥印花得到所述多功能环保型墙纸。
实施例2
一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份(kg)材料制成：旧衣服30份、废木料20份、黄麻20份、纳米氧化锌5份、聚二甲基硅氧烷2份、硫化钠8份、氢氧化钠25份、玉米淀粉10份、丙烯酸丁酯5份、钛酸酯偶联剂2份、阳离子聚丙烯酰胺3份、椰油酰基甘氨酸钠2份、偶氮二异丁腈2份、去离子水80份、乙酸乙酯30份；所述活性氧化锌粒径≤50纳米。
上述的多功能环保型墙纸的制备方法，包括以下步骤：
步骤一、将30kg旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将20kg黄麻去除心只留黄麻皮，0.5kg氢氧化钠与9.5kg去离子水混合得到5％的氢氧化钠溶液，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与20kg废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入40.5kg去离子水、8kg硫化钠、20.5kg氢氧化钠置于超声波机器中制浆2小时，制浆温度为150℃，制得纤维浆；纳米高压脉冲粉碎机的工作电压为30kv，脉冲波数为20；超声波工作的频率为50赫兹；
步骤二、将5kg纳米氧化锌、15kg去离子水与15kg乙酸乙酯混合加热至80℃加入4kg氢氧化钠后马上加入2kg钛酸酯偶联剂，采用搅拌机不断搅拌2小时，搅拌速度为200rmp，得到表面改性纳米氧化锌；
步骤三、将10kg玉米淀粉加入15kg去离子水、2kg椰油酰基甘氨酸钠，搅拌0.5小时后加入15kg乙酸乙酯，温度加热至80℃加入5kg丙烯酸丁酯、3kg阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50℃加入2kg偶氮二异丁腈，搅拌3小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，反应釜的真空度为0.8Mpa，温度为80℃搅拌2小时，涂布干燥印花得到所述多功能环保型墙纸。
实施例3
一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份(kg)材料制成：旧衣服25份、废木料15份、黄麻12份、纳米氧化锌3份、聚二甲基硅氧烷2份、硫化钠4份、氢氧化钠20份、玉米淀粉7份、丙烯酸丁酯3份、钛酸酯偶联剂1份、阳离子聚丙烯酰胺2份、椰油酰基甘氨酸钠1份、偶氮二异丁腈2份、去离子水80份、乙酸乙酯25份；所述活性氧化锌粒径≤50纳米。
上述的多功能环保型墙纸的制备方法，包括以下步骤：
步骤一、将旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将黄麻去除心只留黄麻皮，0.5kg氢氧化钠与9.5kg去离子水混合得到5％的氢氧化钠溶液，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入去离子水、硫化钠、氢氧化钠置于超声波机器中制浆1-2小时，制浆温度为100-150℃，制得纤维浆；纳米高压脉冲粉碎机的工作电压为30-40kv，脉冲波数为20-30；超声波工作的频率为50-100赫兹；
步骤二、将纳米氧化锌、去离子水、椰油酰基甘氨酸钠与乙酸乙酯混合加热至80℃加入氢氧化钠后马上加入钛酸酯偶联剂，采用搅拌机不断搅拌1-2小时，搅拌速度为100-200rmp，得到表面改性纳米氧化锌；
步骤三、将玉米淀粉加入去离子水、椰油酰基甘氨酸钠，搅拌0.5小时后加入乙酸乙酯，温度加热至80-90℃加入丙烯酸丁酯、阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50-60℃加入偶氮二异丁腈，搅拌3-4小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，反应釜的真空度为0.8-0.9Mpa，温度为80-90℃搅拌2-4小时，涂布干燥印花得到所述多功能环保型墙纸。
实施例4
一种多功能环保型墙纸，所述多功能环保型墙纸由以下重量份(kg)材料制成：旧衣服25份、废木料15份、黄麻12份、纳米氧化锌3份、聚二甲基硅氧烷2份、硫化钠4份、氢氧化钠20份、玉米淀粉7份、丙烯酸丁酯3.5份、钛酸酯偶联剂1份、阳离子聚丙烯酰胺2份、椰油酰基甘氨酸钠1份、偶氮二异丁腈2份、去离子水100份、乙酸乙酯25份；所述活性氧化锌粒径≤50纳米。
上述的多功能环保型墙纸的制备方法，包括以下步骤：
步骤一、将旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将黄麻去除心只留黄麻皮，0.5kg氢氧化钠与9.5kg水混合得到5％的氢氧化钠溶液，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入去离子水、硫化钠、氢氧化钠置于超声波机器中制浆1-2小时，制浆温度为100-150℃，制得纤维浆；纳米高压脉冲粉碎机的工作电压为30-40kv，脉冲波数为20-30；超声波工作的频率为50-100赫兹；
步骤二、将纳米氧化锌、去离子水、椰油酰基甘氨酸钠与乙酸乙酯混合加热至80℃加入氢氧化钠后马上加入钛酸酯偶联剂，采用搅拌机不断搅拌1-2小时，搅拌速度为100-200rmp，得到表面改性纳米氧化锌；
步骤三、将玉米淀粉加入去离子水、椰油酰基甘氨酸钠，搅拌0.5小时后加入乙酸乙酯，温度加热至80-90℃加入丙烯酸丁酯、阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50-60℃加入偶氮二异丁腈，搅拌3-4小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，反应釜的真空度为0.8-0.9Mpa，温度为80-90℃搅拌2-4小时，涂布干燥印花得到所述多功能环保型墙纸。
尽管本发明的实施方案已公开如上，但其并不仅仅限于说明书和实施方式中所列运用，它完全可以被适用于各种适合本发明的领域，对于熟悉本领域的人员而言，可容易地实现另外的修改，因此在不背离权利要求及等同范围所限定的一般概念下，本发明并不限于特定的细节和这里示出与描述的实施例。

Claims (7)

1.一种多功能环保型墙纸，其特征在于，所述多功能环保型墙纸由以下重量份材料制成：旧衣服20-30份、废木料10-20份、黄麻10-20份、纳米氧化锌2-5份、聚二甲基硅氧烷1-2份、硫化钠2-8份、氢氧化钠10-25份、玉米淀粉5-10份、丙烯酸丁酯2-5份、钛酸酯偶联剂1-2份、阳离子聚丙烯酰胺1-3份、椰油酰基甘氨酸钠1-2份、偶氮二异丁腈1-2份、去离子水60-100份、乙酸乙酯20-30份。
2.如权利要求1所述的多功能环保型墙纸，其特征在于，所述多功能环保型墙纸由以下重量份材料制成：旧衣服25份、废木料15份、黄麻12份、纳米氧化锌3份、聚二甲基硅氧烷2份、硫化钠4份、氢氧化钠20份、玉米淀粉7份、丙烯酸丁酯3份、钛酸酯偶联剂1份、阳离子聚丙烯酰胺2份、椰油酰基甘氨酸钠1份、偶氮二异丁腈2份、去离子水80份、乙酸乙酯25份。
3.如权利要求1所述的多功能环保型墙纸，其特征在于，所述活性氧化锌粒径≤50纳米。
4.如权利要求1所述的多功能环保型墙纸，其特征在于，所述玉米淀粉与丙烯酸丁酯的重量比为2∶1。
5.如权利要求1-4中任一所述的多功能环保型墙纸的制备方法，其特征在于，包括以下步骤：
步骤一、将旧衣服上的塑料及金属物品去除后，采用碎布机将旧衣服粉碎，将黄麻去除心只留黄麻皮，然后采用5％的氢氧化钠溶液浸泡2-3天后，将经过浸泡的黄麻皮进行揉搓0.5-1小时，干燥至水分含量低于10％，采用碎布机将干燥后的黄麻皮粉碎，最后将经过粉碎的旧衣服、黄麻皮与废木料混合采用纳米高压脉冲粉碎机粉碎，粉碎至颗粒粒径小于10微米，加入去离子水、硫化钠、氢氧化钠置于超声波机器中制浆1-2小时，制浆温度为100-150℃，制得纤维浆；
步骤二、将纳米氧化锌、去离子水与乙酸乙酯混合加热至80℃加入氢氧化钠后马上加入钛酸酯偶联剂，采用搅拌机不断搅拌1-2小时，搅拌速度为100-200rmp，得到表面改性纳米氧化锌；
步骤三、将玉米淀粉加入去离子水、椰油酰基甘氨酸钠，搅拌0.5小时后加入乙酸乙酯，温度加热至80-90℃加入丙烯酸丁酯、阳离子聚丙烯酰胺，搅拌0.5小时后温度降到50-60℃加入偶氮二异丁腈，搅拌3-4小时，得到玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物；
步骤四、将步骤一的纤维浆、步骤二的表面改性纳米氧化锌、玉米淀粉-丙烯酸丁酯共聚物和玉米淀粉-聚丙烯酰胺共聚物与聚二甲基硅氧烷混合放入反应釜，温度为80-90℃搅拌2-4小时，涂布干燥印花得到所述多功能环保型墙纸。
6.如权利要求5所述的多功能环保型墙纸的制备方法，其特征在于，步骤一中，纳米高压脉冲粉碎机的工作电压为30-40kv，脉冲波数为20-30；超声波工作的频率为50-100赫兹。
7.如权利要求5所述的多功能环保型墙纸的制备方法，其特征在于，步骤四中，反应釜的真空度为0.8-0.9Mpa。
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Application publication date: 20170104