CN106280860A - A kind of coating for automobile collection box and preparation method thereof - Google Patents

A kind of coating for automobile collection box and preparation method thereof Download PDF

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Publication number
CN106280860A
CN106280860A CN201610665467.7A CN201610665467A CN106280860A CN 106280860 A CN106280860 A CN 106280860A CN 201610665467 A CN201610665467 A CN 201610665467A CN 106280860 A CN106280860 A CN 106280860A
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CN
China
Prior art keywords
parts
coating
collection box
automobile
automobile collection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610665467.7A
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Chinese (zh)
Inventor
韩梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing Lotus Chemical Co Ltd
Original Assignee
Anqing Lotus Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anqing Lotus Chemical Co Ltd filed Critical Anqing Lotus Chemical Co Ltd
Priority to CN201610665467.7A priority Critical patent/CN106280860A/en
Publication of CN106280860A publication Critical patent/CN106280860A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C09D161/14Modified phenol-aldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of coating for automobile collection box, be made up of following raw materials according: phenol-formaldehyde resin modified, pure-acrylic emulsion, acrylic resin, vinyl, isocyanates, dispersant, catalyst, thickening agent, silicon dioxide, Pulvis Talci, propylene glycol monomethyl ether, dimethylbenzene, deionized water, organic silica gel;Its preparation method in turn includes the following steps: (1) is by uniform for corresponding raw material stirring;(2) mixed solution is prepared;(3) coating mixed liquor is prepared;(4) coating mixed liquor is ground, filter to obtain finished product.Using the coating surface that obtains of the present invention smooth, fine and smooth, smooth, gloss retention is good, and hot strength and elongation at break are superior to common coating such that it is able to meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement;Preparation method of the present invention is simple, and cost is relatively low, is suitable to industrialized mass production.

Description

A kind of coating for automobile collection box and preparation method thereof
Technical field
The present invention relates to coating industry field, particularly relate to a kind of coating for automobile collection box and preparation method thereof.
Background technology
Along with the development of social life level, nowadays increasing people have the private car of oneself, Automobile Products Motor Maintenance articles for use have the most just become the essential part of vehicle maintenance in other words, as three macroplates in market after automobile One of, Automobile Products market is also one of industry the most with fastest developing speed, that prospect is best.Blowout along with Domestic Automotive Industry Formula develops, and Automobile Products industry development speed is at a tremendous pace, and according to statistics, 2011, China's Automobile Products series products gross output value was just 430,000,000,000 yuans are reached, family more than ten thousand more than more than 10 of Automobile Products industry distributing business of current China.Along with Chinese Government Gradually pay attention to Automobile Products industry, actively push forward the industrialization of Automobile Products, encourage the technological innovation of Automobile Products industry, government Also in relevant laws and regulations and the standard of gradual perfection Automobile Products industry, for the competition ring that the development offer of Automobile Products enterprise is orderly Border.Simultaneously Automobile Products enterprise also should constantly autonomous innovation, introduce and cultivate professional, catching the good of Automobile Products industry Opportunity to develop.
Containing box in Automobile Products is mainly placed in automobile trunk, is used for depositing article.At present, people are for vapour Article in the interior material of car and automobile are increasingly paid attention to, to the requirement of the aspects such as the coating property of Automobile Products, environmental protection more Come the highest, but can't be met, in the face of the huge market demand and the ever-increasing application of Automobile Products coating Prospect, need to develop technically, on cost, more show the coating of powerful competitive advantage in performance so that it is to automobile Articles for use have well protection and decoration.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of painting for automobile collection box Material and preparation method thereof, this coating products excellent performance, there is good wearability, and meet environmental requirement.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of coating for automobile collection box, it is characterised in that be prepared by the raw materials in: modified phenolic resin Fat 15~35 parts, pure-acrylic emulsion 5~20 parts, acrylic resin 5~20 parts, vinyl 2~10 parts, isocyanates 1~5 parts, Dispersant 0.2~1 part, catalyst 1~5 parts, thickening agent 0.2~1.5 parts, silica 1~5 parts, Pulvis Talci 1~5 parts, the third two Alcohol methyl ether 0.2~1 part, dimethylbenzene 0.3~2 parts, deionized water 20~50 parts, organic silica gel 2~10 parts;
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, acrylic resin, vinyl, isocyanates and deionized water are put into In reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again silicon dioxide, Pulvis Talci, propylene glycol monomethyl ether and dimethylbenzene are joined in reaction vessel, be stirred continuously straight To mix homogeneously, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to organic silica gel, and stir Mix dissolving 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into dispersant, catalyst and increasing Thick dose, it is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Preferably, described dispersant is sodium tripolyphosphate.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
The present invention is had advantageous effect in that compared with prior art:
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-wear performance of compositions, use this The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, from And disclosure satisfy that automobile collection box uses requirement to the anticorrosion of casing application, weather-proof etc.;Present invention achieves resource and the energy Making full use of, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, Easily stored, the feature such as easy to use, be suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of coating for automobile collection box, it is characterised in that be prepared by the raw materials in: modified phenolic resin 15 parts of fat, pure-acrylic emulsion 5 parts, acrylic resin 5 parts, vinyl 2 parts, isocyanates 1 part, dispersant 0.2 part, catalyst 1 Part, thickening agent 0.2 part, silica 1 part, Pulvis Talci 1 part, propylene glycol monomethyl ether 0.2 part, dimethylbenzene 0.3 part, deionized water 20 Part, organic silica gel 2 parts;
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, acrylic resin, vinyl, isocyanates and deionized water are put into In reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15 minutes;
(2) again silicon dioxide, Pulvis Talci, propylene glycol monomethyl ether and dimethylbenzene are joined in reaction vessel, be stirred continuously straight To mix homogeneously, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1 hour, be finally slowly added to organic silica gel, and stir molten Solve 0.5 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into dispersant, catalyst and increasing Thick dose, it is kept stirring for 20 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4 times, filter to obtain finished product.
Preferably, described dispersant is sodium tripolyphosphate.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
Embodiment 2:
A kind of coating for automobile collection box, it is characterised in that be prepared by the raw materials in: modified phenolic resin 35 parts of fat, pure-acrylic emulsion 20 parts, acrylic resin 20 parts, vinyl 10 parts, isocyanates 5 parts, dispersant 1 part, catalyst 5 Part, thickening agent 1.5 parts, silicon dioxide 5 parts, Pulvis Talci 5 parts, propylene glycol monomethyl ether 1 part, dimethylbenzene 2 parts, deionized water 50 parts, have 10 parts of machine silica gel;
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, acrylic resin, vinyl, isocyanates and deionized water are put into In reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 30 minutes;
(2) again silicon dioxide, Pulvis Talci, propylene glycol monomethyl ether and dimethylbenzene are joined in reaction vessel, be stirred continuously straight To mix homogeneously, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1.5 hours, be finally slowly added to organic silica gel, and stir Dissolve 1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into dispersant, catalyst and increasing Thick dose, it is kept stirring for 50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 6 times, filter to obtain finished product.
In the above embodiment of the present invention:
Described dispersant is sodium tripolyphosphate;
Described catalyst is sodium sulfonate;
Described thickening agent is carboxymethyl cellulose.
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-wear performance of compositions, use this The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, from And disclosure satisfy that automobile collection box uses requirement to the anticorrosion of casing application, weather-proof etc.;Present invention achieves resource and the energy Making full use of, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, Easily stored, the feature such as easy to use, be suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (4)

1. the coating for automobile collection box, it is characterised in that be prepared by the raw materials in: phenol-formaldehyde resin modified 15~35 parts, pure-acrylic emulsion 5~20 parts, acrylic resin 5~20 parts, vinyl 2~10 parts, isocyanates 1~5 part, point Powder 0.2~1 part, catalyst 1~5 parts, thickening agent 0.2~1.5 parts, silica 1~5 parts, Pulvis Talci 1~5 parts, propylene glycol Methyl ether 0.2~1 part, dimethylbenzene 0.3~2 parts, deionized water 20~50 parts, organic silica gel 2~10 parts;
Its preparation method in turn includes the following steps:
(1) phenol-formaldehyde resin modified, pure-acrylic emulsion, acrylic resin, vinyl, isocyanates and deionized water are put into reaction In container, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again silicon dioxide, Pulvis Talci, propylene glycol monomethyl ether and dimethylbenzene being joined in reaction vessel, being stirred continuously until mixing Close uniformly, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to organic silica gel, and stir molten Solve 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into dispersant, catalyst and thickening agent, It is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Coating for automobile collection box the most according to claim 1, it is characterised in that described dispersant is tripolyphosphate Sodium.
Coating for automobile collection box the most according to claim 1, it is characterised in that described catalyst is sodium sulfonate.
Coating for automobile collection box the most according to claim 1, it is characterised in that described thickening agent is that carboxymethyl is fine Dimension element.
CN201610665467.7A 2016-08-13 2016-08-13 A kind of coating for automobile collection box and preparation method thereof Pending CN106280860A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610665467.7A CN106280860A (en) 2016-08-13 2016-08-13 A kind of coating for automobile collection box and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610665467.7A CN106280860A (en) 2016-08-13 2016-08-13 A kind of coating for automobile collection box and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106280860A true CN106280860A (en) 2017-01-04

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104046174A (en) * 2014-05-30 2014-09-17 青岛辰青信息技术有限公司 Waterproof paint
CN104371458A (en) * 2014-12-05 2015-02-25 曹兴 Waterproof paint for outer wall
CN105713428A (en) * 2016-03-24 2016-06-29 安徽鹏峰新型建材科技有限公司 Wear-resistant, flame-retardant and antirust paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104046174A (en) * 2014-05-30 2014-09-17 青岛辰青信息技术有限公司 Waterproof paint
CN104371458A (en) * 2014-12-05 2015-02-25 曹兴 Waterproof paint for outer wall
CN105713428A (en) * 2016-03-24 2016-06-29 安徽鹏峰新型建材科技有限公司 Wear-resistant, flame-retardant and antirust paint

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Application publication date: 20170104