CN106221487A - A kind of water-repellent paint for automobile collection box and preparation method thereof - Google Patents
A kind of water-repellent paint for automobile collection box and preparation method thereof Download PDFInfo
- Publication number
- CN106221487A CN106221487A CN201610669096.XA CN201610669096A CN106221487A CN 106221487 A CN106221487 A CN 106221487A CN 201610669096 A CN201610669096 A CN 201610669096A CN 106221487 A CN106221487 A CN 106221487A
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- parts
- collection box
- water
- repellent paint
- automobile
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of water-repellent paint for automobile collection box, be made up of following raw materials according: amino resins, silicone acrylic emulsion, polyester resin, alkyd resin, nano zine oxide, synergist, catalyst, thickening agent, calcium carbonate, lithopone, 2-Butoxyethyl acetate, butyl acetate, deionized water, rosin resin；Its preparation method in turn includes the following steps: (1) is by uniform for corresponding raw material stirring；(2) mixed solution is prepared；(3) coating mixed liquor is prepared；(4) coating mixed liquor is ground, filter to obtain finished product.Excellent product performance of the present invention, has good water resistance, and its coating surface is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, can meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement；Preparation method of the present invention is simple, and cost is relatively low, is suitable to industrialized mass production.
Description
Technical field
The present invention relates to coating industry field, particularly relate to a kind of water-repellent paint for automobile collection box and preparation side thereof
Method.
Background technology
Along with the development of social life level, nowadays increasing people have the private car of oneself, Automobile Products
Motor Maintenance articles for use have the most just become the essential part of vehicle maintenance in other words, as three macroplates in market after automobile
One of, Automobile Products market is also one of industry the most with fastest developing speed, that prospect is best.Blowout along with Domestic Automotive Industry
Formula develops, and Automobile Products industry development speed is at a tremendous pace, and according to statistics, 2011, China's Automobile Products series products gross output value was just
430,000,000,000 yuans are reached, family more than ten thousand more than more than 10 of Automobile Products industry distributing business of current China.Along with Chinese Government
Gradually pay attention to Automobile Products industry, actively push forward the industrialization of Automobile Products, encourage the technological innovation of Automobile Products industry, government
Also in relevant laws and regulations and the standard of gradual perfection Automobile Products industry, for the competition ring that the development offer of Automobile Products enterprise is orderly
Border.Simultaneously Automobile Products enterprise also should constantly autonomous innovation, introduce and cultivate professional, catching the good of Automobile Products industry
Opportunity to develop.
Containing box in Automobile Products is mainly placed in automobile trunk, is used for depositing article.At present, people are for vapour
Article in the interior material of car and automobile are increasingly paid attention to, to the requirement of the aspects such as the coating property of Automobile Products, environmental protection more
Come the highest, but can't be met, in the face of the huge market demand and the ever-increasing application of Automobile Products coating
Prospect, need to develop technically, on cost, more show the coating of powerful competitive advantage in performance so that it is to automobile
Articles for use have well protection and decoration.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of preventing for automobile collection box
Water paint and preparation method thereof, this coating products excellent performance, there is good water resistance, and meet environmental requirement.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of water-repellent paint for automobile collection box, it is characterised in that be prepared by the raw materials in: amino tree
Fat 15～35 parts, silicone acrylic emulsion 5～20 parts, polyester resin 5～20 parts, alkyd resin 2～10 parts, nano zine oxide 1～5 parts,
Synergist 0.2～1 part, catalyst 1～5 parts, thickening agent 0.2～1.5 parts, calcium carbonate 1～5 parts, lithopone 1～5 parts, ethylene glycol
Monobutyl ether acetate 0.2～1 part, butyl acetate 0.3～2 parts, deionized water 20～50 parts, rosin resin 2～10 parts；
Its preparation method in turn includes the following steps:
(1) amino resins, silicone acrylic emulsion, polyester resin, alkyd resin, nano zine oxide and deionized water are put into reaction
In container, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15～30 minutes；
(2) again calcium carbonate, lithopone, 2-Butoxyethyl acetate and butyl acetate are joined in reaction vessel, constantly
Temperature, until mix homogeneously, is risen to 70～75 DEG C and carries out being heated at reflux 1～1.5 hour, be finally slowly added to rosin tree by stirring
Fat, and stirring and dissolving 0.5～1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into synergist, catalyst and increasing
Thick dose, it is kept stirring for 20～50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4～6 times, filter to obtain finished product.
Preferably, described synergist is diethylin sulfur trifluoride.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
The present invention is had advantageous effect in that compared with prior art:
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting
With combination property preferably high-molecular organic material and carry out optimum organization, improve the water resistance of compositions, use this
The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, energy
Meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement；Present invention achieves the abundant profit of resource and the energy
With, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to storage
Deposit, the feature such as easy to use, be suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of water-repellent paint for automobile collection box, it is characterised in that be prepared by the raw materials in: amino tree
15 parts of fat, silicone acrylic emulsion 5 parts, 5 parts of polyester resin, alkyd resin 2 parts, nano zine oxide 1 part, synergist 0.2 part, catalyst 1
Part, thickening agent 0.2 part, calcium carbonate 1 part, 1 part of lithopone, 2-Butoxyethyl acetate 0.2 part, butyl acetate 0.3 part, deionization
20 parts of water, rosin resin 2 parts；
Its preparation method in turn includes the following steps:
(1) amino resins, silicone acrylic emulsion, polyester resin, alkyd resin, nano zine oxide and deionized water are put into reaction
In container, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15 minutes；
(2) again calcium carbonate, lithopone, 2-Butoxyethyl acetate and butyl acetate are joined in reaction vessel, constantly
Temperature, until mix homogeneously, is risen to 70～75 DEG C and carries out being heated at reflux 1 hour, be finally slowly added to rosin resin by stirring, and
Stirring and dissolving 0.5 hour, obtains mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into synergist, catalyst and increasing
Thick dose, it is kept stirring for 20 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4 times, filter to obtain finished product.
Preferably, described synergist is diethylin sulfur trifluoride.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
Embodiment 2:
A kind of water-repellent paint for automobile collection box, it is characterised in that be prepared by the raw materials in: amino tree
35 parts of fat, silicone acrylic emulsion 20 parts, 20 parts of polyester resin, alkyd resin 10 parts, nano zine oxide 5 parts, synergist 1 part, catalyst 5
Part, thickening agent 1.5 parts, calcium carbonate 5 parts, 5 parts of lithopone, 2-Butoxyethyl acetate 1 part, butyl acetate 2 parts, deionized water 50
Part, rosin resin 10 parts；
Its preparation method in turn includes the following steps:
(1) amino resins, silicone acrylic emulsion, polyester resin, alkyd resin, nano zine oxide and deionized water are put into reaction
In container, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 30 minutes；
(2) again calcium carbonate, lithopone, 2-Butoxyethyl acetate and butyl acetate are joined in reaction vessel, constantly
Temperature, until mix homogeneously, is risen to 70～75 DEG C and carries out being heated at reflux 1.5 hours, be finally slowly added to rosin resin by stirring,
And stirring and dissolving 1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into synergist, catalyst and increasing
Thick dose, it is kept stirring for 50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 6 times, filter to obtain finished product.
In the above embodiment of the present invention:
Described synergist is diethylin sulfur trifluoride；
Described catalyst is sodium sulfonate；
Described thickening agent is carboxymethyl cellulose.
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting
With combination property preferably high-molecular organic material and carry out optimum organization, improve the water resistance of compositions, use this
The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, energy
Meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement；Present invention achieves the abundant profit of resource and the energy
With, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to storage
Deposit, the feature such as easy to use, be suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (4)
1. the water-repellent paint for automobile collection box, it is characterised in that be prepared by the raw materials in: amino resins
15～35 parts, silicone acrylic emulsion 5～20 parts, polyester resin 5～20 parts, alkyd resin 2～10 parts, nano zine oxide 1～5 parts, increasing
Effect agent 0.2～1 part, catalyst 1～5 parts, thickening agent 0.2～1.5 parts, calcium carbonate 1～5 parts, lithopone 1～5 parts, ethylene glycol fourth
Ether acetate 0.2～1 part, butyl acetate 0.3～2 parts, deionized water 20～50 parts, rosin resin 2～10 parts；
Its preparation method in turn includes the following steps:
(1) amino resins, silicone acrylic emulsion, polyester resin, alkyd resin, nano zine oxide and deionized water are put into reaction vessel
In, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15～30 minutes；
(2) again calcium carbonate, lithopone, 2-Butoxyethyl acetate and butyl acetate are joined in reaction vessel, be stirred continuously
Until mix homogeneously, temperature is risen to 70～75 DEG C and carries out being heated at reflux 1～1.5 hour, be finally slowly added to rosin resin, and
Stirring and dissolving 0.5～1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into synergist, catalyst and thickening agent,
It is kept stirring for 20～50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4～6 times, filter to obtain finished product.
Water-repellent paint for automobile collection box the most according to claim 1, it is characterised in that described synergist is diethyl
Amido sulfur trifluoride.
Water-repellent paint for automobile collection box the most according to claim 1, it is characterised in that described catalyst is sulfonic acid
Sodium.
Water-repellent paint for automobile collection box the most according to claim 1, it is characterised in that described thickening agent is carboxylic first
Base cellulose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669096.XA CN106221487A (en) | 2016-08-13 | 2016-08-13 | A kind of water-repellent paint for automobile collection box and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669096.XA CN106221487A (en) | 2016-08-13 | 2016-08-13 | A kind of water-repellent paint for automobile collection box and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221487A true CN106221487A (en) | 2016-12-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610669096.XA Pending CN106221487A (en) | 2016-08-13 | 2016-08-13 | A kind of water-repellent paint for automobile collection box and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1254040A (en) * | 1999-12-06 | 2000-05-24 | 金城剑 | Textile fabric surface treatment agent |
| CN1865372A (en) * | 2006-06-09 | 2006-11-22 | 太原理工大学 | Aqueous coating for silicon-steel sheet |
| CN101550311A (en) * | 2009-05-07 | 2009-10-07 | 杭州传化涂料有限公司 | Aqueous finish paint used for coiled material |
| CN103351763A (en) * | 2013-06-20 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Organic silicon acrylic anticorrosive paint |
-
2016
- 2016-08-13 CN CN201610669096.XA patent/CN106221487A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1254040A (en) * | 1999-12-06 | 2000-05-24 | 金城剑 | Textile fabric surface treatment agent |
| CN1865372A (en) * | 2006-06-09 | 2006-11-22 | 太原理工大学 | Aqueous coating for silicon-steel sheet |
| CN101550311A (en) * | 2009-05-07 | 2009-10-07 | 杭州传化涂料有限公司 | Aqueous finish paint used for coiled material |
| CN103351763A (en) * | 2013-06-20 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Organic silicon acrylic anticorrosive paint |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161214 |
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