CN106189599A - A kind of anti-dust coating for automobile collection box and preparation method thereof - Google Patents

A kind of anti-dust coating for automobile collection box and preparation method thereof Download PDF

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Publication number
CN106189599A
CN106189599A CN201610665424.9A CN201610665424A CN106189599A CN 106189599 A CN106189599 A CN 106189599A CN 201610665424 A CN201610665424 A CN 201610665424A CN 106189599 A CN106189599 A CN 106189599A
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CN
China
Prior art keywords
parts
coating
collection box
resin
automobile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610665424.9A
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Chinese (zh)
Inventor
韩梅
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Anqing Lotus Chemical Co Ltd
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Anqing Lotus Chemical Co Ltd
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Priority to CN201610665424.9A priority Critical patent/CN106189599A/en
Publication of CN106189599A publication Critical patent/CN106189599A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of anti-dust coating for automobile collection box, be made up of following raw materials according: Hydroxylated acrylic resin, styrene-acrylic emulsion, silicone modified polyester resin, vinyl, dichloroethanes, levelling agent, catalyst, thickening agent, aluminum paste, silicon dioxide, hexone, isophorone, deionized water, terpene resin;Its preparation method in turn includes the following steps: (1) is by uniform for corresponding raw material stirring;(2) mixed solution is prepared;(3) coating mixed liquor is prepared;(4) coating mixed liquor is ground, filter to obtain finished product.Excellent product performance of the present invention, has good anti-dust performance, and its coating surface is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, can meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement;Preparation method of the present invention is simple, and cost is relatively low, is suitable to industrialized mass production.

Description

A kind of anti-dust coating for automobile collection box and preparation method thereof
Technical field
The present invention relates to coating industry field, particularly relate to a kind of anti-dust coating for automobile collection box and preparation thereof Method.
Background technology
Along with the development of social life level, nowadays increasing people have the private car of oneself, Automobile Products Motor Maintenance articles for use have the most just become the essential part of vehicle maintenance in other words, as three macroplates in market after automobile One of, Automobile Products market is also one of industry the most with fastest developing speed, that prospect is best.Blowout along with Domestic Automotive Industry Formula develops, and Automobile Products industry development speed is at a tremendous pace, and according to statistics, 2011, China's Automobile Products series products gross output value was just 430,000,000,000 yuans are reached, family more than ten thousand more than more than 10 of Automobile Products industry distributing business of current China.Along with Chinese Government Gradually pay attention to Automobile Products industry, actively push forward the industrialization of Automobile Products, encourage the technological innovation of Automobile Products industry, government Also in relevant laws and regulations and the standard of gradual perfection Automobile Products industry, for the competition ring that the development offer of Automobile Products enterprise is orderly Border.Simultaneously Automobile Products enterprise also should constantly autonomous innovation, introduce and cultivate professional, catching the good of Automobile Products industry Opportunity to develop.
Containing box in Automobile Products is mainly placed in automobile trunk, is used for depositing article.At present, people are for vapour Article in the interior material of car and automobile are increasingly paid attention to, to the requirement of the aspects such as the coating property of Automobile Products, environmental protection more Come the highest, but can't be met, in the face of the huge market demand and the ever-increasing application of Automobile Products coating Prospect, need to develop technically, on cost, more show the coating of powerful competitive advantage in performance so that it is to automobile Articles for use have well protection and decoration.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of preventing for automobile collection box Viscous ash coating and preparation method thereof, this coating products excellent performance, there is good anti-dust performance, and meet environmental requirement.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of anti-dust coating for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl Acrylic resin 15~35 parts, styrene-acrylic emulsion 5~20 parts, silicone modified polyester resin 5~20 parts, vinyl 2~10 parts, Dichloroethanes 1~5 parts, levelling agent 0.2~1 part, catalyst 1~5 parts, thickening agent 0.2~1.5 parts, aluminum paste 1~5 parts, dioxy SiClx 1~5 parts, hexone 0.2~1 part, isophorone 0.3~2 parts, deionized water 20~50 parts, terpene resin 2 ~10 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, styrene-acrylic emulsion, silicone modified polyester resin, vinyl, dichloroethanes with go Ionized water is put in reaction vessel, and controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again aluminum paste, silicon dioxide, hexone and isophorone are joined in reaction vessel, constantly Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to terpenes tree by stirring Fat, and stirring and dissolving 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Thick dose, it is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described thickening agent is sodium polyacrylate.
The present invention is had advantageous effect in that compared with prior art:
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-dust performance of compositions, use this The coating surface that invention obtains is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, Automobile collection box can be met the anticorrosion of casing application, weather-proof etc. is used requirement;Present invention achieves the abundant of resource and the energy Utilizing, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to Store, the feature such as easy to use, be suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of anti-dust coating for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl Acrylic resin 15 parts, styrene-acrylic emulsion 5 parts, silicone modified polyester resin 5 parts, vinyl 2 parts, dichloroethanes 1 part, levelling Agent 0.2 part, catalyst 1 part, thickening agent 0.2 part, aluminum paste 1 part, silica 1 part, hexone 0.2 part, different Buddhist That ketone 0.3 part, deionized water 20 parts, terpene resin 2 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, styrene-acrylic emulsion, silicone modified polyester resin, vinyl, dichloroethanes with go Ionized water is put in reaction vessel, and controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15 minutes;
(2) again aluminum paste, silicon dioxide, hexone and isophorone are joined in reaction vessel, constantly Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1 hour, be finally slowly added to terpene resin by stirring, and Stirring and dissolving 0.5 hour, obtains mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Thick dose, it is kept stirring for 20 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4 times, filter to obtain finished product.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described thickening agent is sodium polyacrylate.
Embodiment 2:
A kind of anti-dust coating for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl Acrylic resin 35 parts, styrene-acrylic emulsion 20 parts, silicone modified polyester resin 20 parts, vinyl 10 parts, dichloroethanes 5 parts, Levelling agent 1 part, catalyst 5 parts, thickening agent 1.5 parts, aluminum paste 5 parts, silicon dioxide 5 parts, hexone 1 part, different Buddhist That ketone 2 parts, deionized water 50 parts, terpene resin 10 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, styrene-acrylic emulsion, silicone modified polyester resin, vinyl, dichloroethanes with go Ionized water is put in reaction vessel, and controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 30 minutes;
(2) again aluminum paste, silicon dioxide, hexone and isophorone are joined in reaction vessel, constantly Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1.5 hours, be finally slowly added to terpene resin by stirring, And stirring and dissolving 1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Thick dose, it is kept stirring for 50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 6 times, filter to obtain finished product.
In the above embodiment of the present invention:
Described levelling agent is polyester modification siloxanes;
Described catalyst is sulfonic acid zinc;
Described thickening agent is sodium polyacrylate.
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-dust performance of compositions, use this The coating surface that invention obtains is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, Automobile collection box can be met the anticorrosion of casing application, weather-proof etc. is used requirement;Present invention achieves the abundant of resource and the energy Utilizing, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to Store, the feature such as easy to use, be suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (4)

1. the anti-dust coating for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl third Olefin(e) acid resin 15~35 parts, styrene-acrylic emulsion 5~20 parts, silicone modified polyester resin 5~20 parts, vinyl 2~10 parts, two Ethyl chloride 1~5 parts, levelling agent 0.2~1 part, catalyst 1~5 parts, thickening agent 0.2~1.5 parts, aluminum paste 1~5 parts, titanium dioxide Silicon 1~5 parts, hexone 0.2~1 part, isophorone 0.3~2 parts, deionized water 20~50 parts, terpene resin 2~ 10 parts;
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, styrene-acrylic emulsion, silicone modified polyester resin, vinyl, dichloroethanes and deionization Water is put in reaction vessel, and controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again aluminum paste, silicon dioxide, hexone and isophorone are joined in reaction vessel, be stirred continuously Until mix homogeneously, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to terpene resin, and Stirring and dissolving 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and thickening agent, It is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Anti-dust coating for automobile collection box the most according to claim 1, it is characterised in that described levelling agent is poly- Ester modified siloxanes.
Anti-dust coating for automobile collection box the most according to claim 1, it is characterised in that described catalyst is sulphur Acid zinc.
Anti-dust coating for automobile collection box the most according to claim 1, it is characterised in that described thickening agent is poly- Sodium acrylate.
CN201610665424.9A 2016-08-13 2016-08-13 A kind of anti-dust coating for automobile collection box and preparation method thereof Pending CN106189599A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610665424.9A CN106189599A (en) 2016-08-13 2016-08-13 A kind of anti-dust coating for automobile collection box and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610665424.9A CN106189599A (en) 2016-08-13 2016-08-13 A kind of anti-dust coating for automobile collection box and preparation method thereof

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Publication Number Publication Date
CN106189599A true CN106189599A (en) 2016-12-07

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Application Number Title Priority Date Filing Date
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101514272A (en) * 2009-03-27 2009-08-26 武汉斯达日用化工有限公司 Wood floor clean-care agent
CN102277086A (en) * 2011-09-07 2011-12-14 合肥华清金属表面处理有限责任公司 Environment-friendly chrome-free fingerprint-resistant treating agent for stainless steel
CN104327630A (en) * 2014-10-14 2015-02-04 马鞍山市恒毅机械制造有限公司 Glass coating with anti-radiation function, and its preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101514272A (en) * 2009-03-27 2009-08-26 武汉斯达日用化工有限公司 Wood floor clean-care agent
CN102277086A (en) * 2011-09-07 2011-12-14 合肥华清金属表面处理有限责任公司 Environment-friendly chrome-free fingerprint-resistant treating agent for stainless steel
CN104327630A (en) * 2014-10-14 2015-02-04 马鞍山市恒毅机械制造有限公司 Glass coating with anti-radiation function, and its preparation method

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Application publication date: 20161207

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