CN106280945A - A kind of anti-dust coating for fender and preparation method thereof - Google Patents

A kind of anti-dust coating for fender and preparation method thereof Download PDF

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Publication number
CN106280945A
CN106280945A CN201610665017.8A CN201610665017A CN106280945A CN 106280945 A CN106280945 A CN 106280945A CN 201610665017 A CN201610665017 A CN 201610665017A CN 106280945 A CN106280945 A CN 106280945A
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CN
China
Prior art keywords
parts
coating
fender
resin
dust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610665017.8A
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Chinese (zh)
Inventor
韩梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing Lotus Chemical Co Ltd
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Anqing Lotus Chemical Co Ltd
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Publication date
Application filed by Anqing Lotus Chemical Co Ltd filed Critical Anqing Lotus Chemical Co Ltd
Priority to CN201610665017.8A priority Critical patent/CN106280945A/en
Publication of CN106280945A publication Critical patent/CN106280945A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-dust coating for fender, be made up of following raw materials according: polyurethane resin, pure-acrylic emulsion, silicone modified polyester resin, vinyl, sodium carbonate, levelling agent, catalyst, synergist, mica powder, titanium dioxide, hexone, dimethyl carbonate, deionized water, modified rosin resin;Its preparation method in turn includes the following steps: (1) is by uniform for corresponding raw material stirring;(2) mixed solution is prepared;(3) coating mixed liquor is prepared;(4) coating mixed liquor is ground, filter to obtain finished product.Excellent product performance of the present invention, has good anti-dust performance, and its coating surface is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, can meet fender and the anticorrosion of casing application, weather-proof etc. is used requirement;Preparation method of the present invention is simple, and cost is relatively low, is suitable to industrialized mass production.

Description

A kind of anti-dust coating for fender and preparation method thereof
Technical field
The present invention relates to coating industry field, particularly relate to a kind of anti-dust coating for fender and preparation thereof Method.
Background technology
Along with the development of social life level, nowadays increasing people have the private car of oneself, Automobile Products Motor Maintenance articles for use have the most just become the essential part of vehicle maintenance in other words, as three macroplates in market after automobile One of, Automobile Products market is also one of industry the most with fastest developing speed, that prospect is best.Blowout along with Domestic Automotive Industry Formula develops, and Automobile Products industry development speed is at a tremendous pace, and according to statistics, 2011, China's Automobile Products series products gross output value was just 430,000,000,000 yuans are reached, family more than ten thousand more than more than 10 of Automobile Products industry distributing business of current China.Along with Chinese Government Gradually pay attention to Automobile Products industry, actively push forward the industrialization of Automobile Products, encourage the technological innovation of Automobile Products industry, government Also in relevant laws and regulations and the standard of gradual perfection Automobile Products industry, for the competition ring that the development offer of Automobile Products enterprise is orderly Border.Simultaneously Automobile Products enterprise also should constantly autonomous innovation, introduce and cultivate professional, catching the good of Automobile Products industry Opportunity to develop.
Mud guard in Automobile Products is mainly used in when vehicle travels spattering on stop silt, is often installed on the wheel of automobile Rear portion.At present, the article that people use for automobile are increasingly paid attention to, to aspects such as the coating property of Automobile Products, environmental protection Require more and more higher, but can't be met, in the face of the huge market demand and the constantly growth of Automobile Products coating Application prospect, need to develop technically, on cost, more show the coating of powerful competitive advantage in performance so that it is Automobile Products are had well protection and decoration.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of preventing for fender Viscous ash coating and preparation method thereof, this coating products excellent performance, there is good anti-dust performance, and meet environmental requirement.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of anti-dust coating for fender, it is characterised in that be prepared by the raw materials in: poly-ammonia Ester resin 15~35 parts, pure-acrylic emulsion 5~20 parts, silicone modified polyester resin 5~20 parts, vinyl 2~10 parts, carbonic acid Sodium 1~5 parts, levelling agent 0.2~1 part, catalyst 1~5 parts, synergist 0.2~1.5 parts, mica powder 1~5 parts, titanium dioxide 1 ~5 parts, hexone 0.2~1 part, dimethyl carbonate 0.3~2 parts, deionized water 20~50 parts, modified rosin resin 2~10 parts;
Its preparation method in turn includes the following steps:
(1) by polyurethane resin, pure-acrylic emulsion, silicone modified polyester resin, vinyl, sodium carbonate and deionized water Putting in reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again mica powder, titanium dioxide, hexone and dimethyl carbonate are joined in reaction vessel, no Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to Colophonium by disconnected stirring Modified resin, and stirring and dissolving 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Effect agent, is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described synergist is that the tetrabutyl is fluorinated phosphine.
The present invention is had advantageous effect in that compared with prior art:
The present invention mostly is plastic material in view of fender, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-dust performance of compositions, use this The coating surface that invention obtains is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, Fender can be met the anticorrosion of casing application, weather-proof etc. is used requirement;Present invention achieves the abundant of resource and the energy Utilizing, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to Store, the feature such as easy to use, be suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of anti-dust coating for fender, it is characterised in that be prepared by the raw materials in: poly-ammonia Ester resin 15 parts, pure-acrylic emulsion 5 parts, silicone modified polyester resin 5 parts, vinyl 2 parts, sodium carbonate 1 part, levelling agent 0.2 Part, catalyst 1 part, synergist 0.2 part, mica powder 1 part, titanium dioxide 1 part, hexone 0.2 part, dimethyl carbonate 0.3 part, deionized water 20 parts, modified rosin resin 2 parts;
Its preparation method in turn includes the following steps:
(1) by polyurethane resin, pure-acrylic emulsion, silicone modified polyester resin, vinyl, sodium carbonate and deionized water Putting in reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15 minutes;
(2) again mica powder, titanium dioxide, hexone and dimethyl carbonate are joined in reaction vessel, no Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1 hour, be finally slowly added to Abietyl modified tree by disconnected stirring Fat, and stirring and dissolving 0.5 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Effect agent, is kept stirring for 20 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4 times, filter to obtain finished product.
Preferably, described levelling agent is polyester modification siloxanes.
Preferably, described catalyst is sulfonic acid zinc.
Preferably, described synergist is that the tetrabutyl is fluorinated phosphine.
Embodiment 2:
A kind of anti-dust coating for fender, it is characterised in that be prepared by the raw materials in: poly-ammonia Ester resin 35 parts, pure-acrylic emulsion 20 parts, silicone modified polyester resin 20 parts, vinyl 10 parts, sodium carbonate 5 parts, levelling agent 1 Part, catalyst 5 parts, synergist 1.5 parts, mica powder 5 parts, titanium dioxide 5 parts, hexone 1 part, dimethyl carbonate 2 Part, deionized water 50 parts, modified rosin resin 10 parts;
Its preparation method in turn includes the following steps:
(1) by polyurethane resin, pure-acrylic emulsion, silicone modified polyester resin, vinyl, sodium carbonate and deionized water Putting in reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 30 minutes;
(2) again mica powder, titanium dioxide, hexone and dimethyl carbonate are joined in reaction vessel, no Temperature, until mix homogeneously, is risen to 70~75 DEG C and carries out being heated at reflux 1.5 hours, be finally slowly added to Abietyl modified by disconnected stirring Resin, and stirring and dissolving 1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and increasing Effect agent, is kept stirring for 50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 6 times, filter to obtain finished product.
In the above embodiment of the present invention:
Described levelling agent is polyester modification siloxanes;
Described catalyst is sulfonic acid zinc;
Described synergist is that the tetrabutyl is fluorinated phosphine.
The present invention mostly is plastic material in view of fender, and its lower hardness, the feature of surface not scratch resistance, by adopting With combination property preferably high-molecular organic material and carry out optimum organization, improve the anti-dust performance of compositions, use this The coating surface that invention obtains is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, Fender can be met the anticorrosion of casing application, weather-proof etc. is used requirement;Present invention achieves the abundant of resource and the energy Utilizing, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to Store, the feature such as easy to use, be suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained In scope of the presently claimed invention.

Claims (4)

1. the anti-dust coating for fender, it is characterised in that be prepared by the raw materials in: polyurethane Resin 15~35 parts, pure-acrylic emulsion 5~20 parts, silicone modified polyester resin 5~20 parts, vinyl 2~10 parts, sodium carbonate 1~5 part, levelling agent 0.2~1 part, catalyst 1~5 parts, synergist 0.2~1.5 parts, mica powder 1~5 parts, titanium dioxide 1~5 Part, hexone 0.2~1 part, dimethyl carbonate 0.3~2 parts, deionized water 20~50 parts, modified rosin resin 2~ 10 parts;
Its preparation method in turn includes the following steps:
(1) polyurethane resin, pure-acrylic emulsion, silicone modified polyester resin, vinyl, sodium carbonate and deionized water are put into In reaction vessel, controlling temperature is 50~60 DEG C, stirs and makes mixture dispersed in 15~30 minutes;
(2) again mica powder, titanium dioxide, hexone and dimethyl carbonate are joined in reaction vessel, constantly stir Mix until mix homogeneously, temperature is risen to 70~75 DEG C and carries out being heated at reflux 1~1.5 hour, be finally slowly added to Abietyl modified Resin, and stirring and dissolving 0.5~1 hour, obtain mixed solution;
(3) mixed solution that step (2) prepares is cooled to 20~30 DEG C, then is separately added into levelling agent, catalyst and synergist, It is kept stirring for 20~50 minutes, obtains coating mixed liquor;
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4~6 times, filter to obtain finished product.
Anti-dust coating for fender the most according to claim 1, it is characterised in that described levelling agent is poly- Ester modified siloxanes.
Anti-dust coating for fender the most according to claim 1, it is characterised in that described catalyst is sulphur Acid zinc.
Anti-dust coating for fender the most according to claim 1, it is characterised in that described synergist is four Butyl fluorination phosphine.
CN201610665017.8A 2016-08-13 2016-08-13 A kind of anti-dust coating for fender and preparation method thereof Pending CN106280945A (en)

Priority Applications (1)

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CN201610665017.8A CN106280945A (en) 2016-08-13 2016-08-13 A kind of anti-dust coating for fender and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610665017.8A CN106280945A (en) 2016-08-13 2016-08-13 A kind of anti-dust coating for fender and preparation method thereof

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535999A (en) * 2018-11-14 2019-03-29 天津市五棵松涂料有限公司 A kind of anti-dust coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789348A (en) * 2004-12-16 2006-06-21 Sk株式会社 Coating composition for weatherstrips of automobile vehicles
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN102702952A (en) * 2012-06-14 2012-10-03 天长市银狐漆业有限公司 Aqueous coating for automobile weather strip

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1789348A (en) * 2004-12-16 2006-06-21 Sk株式会社 Coating composition for weatherstrips of automobile vehicles
CN102585681A (en) * 2012-02-08 2012-07-18 上海三恩化工有限公司 Coating for automobile sealing strip and preparation method thereof
CN102702952A (en) * 2012-06-14 2012-10-03 天长市银狐漆业有限公司 Aqueous coating for automobile weather strip

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109535999A (en) * 2018-11-14 2019-03-29 天津市五棵松涂料有限公司 A kind of anti-dust coating

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Application publication date: 20170104