CN106280659A - A kind of freeze proof anti-cracking putty of external wall - Google Patents
A kind of freeze proof anti-cracking putty of external wall Download PDFInfo
- Publication number
- CN106280659A CN106280659A CN201610841581.0A CN201610841581A CN106280659A CN 106280659 A CN106280659 A CN 106280659A CN 201610841581 A CN201610841581 A CN 201610841581A CN 106280659 A CN106280659 A CN 106280659A
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- China
- Prior art keywords
- freeze proof
- stirring
- deionized water
- putty
- external wall
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
Abstract
The invention discloses a kind of freeze proof anti-cracking putty of external wall, be made up of following raw material: cement, hollow glass micropearl, tetraethyl orthosilicate, dehydrated alcohol, 1mol/L hydrochloric acid, template F127, polyoxyethylene nonylphenol ether 10, sodium bicarbonate, Ludox, Ammonium persulfate., lightweight sand, Pulvis Talci, ground calcium carbonate, building emulsion, ferrous oxide, triethyl group base phosphoric acid, oxidized asphalt, carboxymethyl cellulose, cocoyl alanine sodium, silane coupler kh550, deionized water are appropriate;The present invention provide a kind of waterproof, anticracking, adhesive force big, the freeze proof powder of lacquer putty for use on of high intensity exterior wall, preparation method is simple, and low cost is worthy to be popularized.
Description
Technical field
The present invention relates to building putties technical field, particularly relate to a kind of freeze proof anti-cracking putty of external wall.
Background technology
Along with industrial expansion and the raising of living standards of the people, the demand of the energy is continuously increased by people, and the energy lacks
Mouth continues to increase.Building industry is one of China's fastest-rising industry of current energy resource consumption, and at present, China's town and country existing building is total
Area about 40,000,000,000 square metres, these buildings in use, its heating, air-conditioning, ventilate, energy that the aspect such as illumination consumes
Having accounted for about the 30% of whole nation total energy consumption, along with the fast development of real estate in recent years, this ratio is also riseing year by year, according to
Achievement by advanced countries, the ratio that building energy consumption is shared in Chinese society's terminal total energy consumption, about 35% will be stepped up, because of
This, it is necessary to pay attention to Energy Conservation Project in Construction, the consumption of the energy is greatly reduced, alleviate China's energy supply and demand contradiction, reduce environment
Pollute and greenhouse effect, to keep the sustainable development of national economy.
In " haydites of book structure and the preparation of heat preservation putty and correlated performance research " literary composition, author uses natural resources shale to make
For wall thermal insulating heat-barrier material, article points out that slate flour physicochemical property is stable, and heat conductivity is relatively low, is suitable as being incubated merit
Can filler, and the present invention uses slate flour and glass bead to be functional stuffing, cement and rubber powder composition base material, and in addition fine
Dimension manufactures experimently shale insulated putty, and uses orthogonal design to obtain the optimal proportion of each component, test result indicate that, glass bead
And the heat conductivity of heat preservation putty is had a significant impact by shale, the consumption of glass bead is fixing to the shrinkage factor one of heat preservation putty
Ringing, finally obtaining optimal parameter is: slate flour: glass bead: cement and other auxiliary agents are according to mass ratio 50:22:15:4
Mixing, the heat preservation putty heat conductivity of preparation is up to 0.087W/(m K), although the heat preservation putty obtained in this invention has good
Good effect of heat insulation, but do not reach the most far away energy-saving and cost-reducing in practice, and it is greasy to external wall to can not meet people
The use demand that sub-material is the highest, and the filler such as glass microballoon is applied directly in putty material, bad dispersibility, it is impossible to have
The performance having given play to self of effect, it is impossible to give the new performance of material, so the surface-functionalized of hollow glass micropearl is to carry
The key of high hollow glass bead composite performance.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of freeze proof anti-cracking putty of external wall.
The present invention is achieved by the following technical solutions:
A kind of freeze proof anti-cracking putty of external wall, is made up of the raw material of following weight portion: cement 24-32, hollow glass are micro-
Pearl 18-25, tetraethyl orthosilicate 3.5-5, dehydrated alcohol 40-48,1mol/L hydrochloric acid 0.35-0.5, template F1271.6-2.5,
Emulsifier op-10 0.7-1, sodium bicarbonate 0.4-0.6, Ludox 12-15, Ammonium persulfate. 0.3-0.5, lightweight sand 4-6, Pulvis Talci
7-9, ground calcium carbonate 11-14, building emulsion 7-10, ferrous oxide 4-6, triethyl group base phosphoric acid 3-4, oxidized asphalt 5-7, carboxylic
Methylcellulose 1-2, cocoyl alanine sodium 0.8-1.4, silane coupler kh5500.06-0.1, deionized water are appropriate.
Described a kind of freeze proof anti-cracking putty of external wall, is made up of following concrete steps:
(1) hollow glass micropearl is impregnated in the sodium hydroxide solution that mass concentration is 3-5g/L of 80 DEG C and carries out oil processing
20-30min, taking-up deionized water is rinsed post-drying well, then it is at room temperature placed in 1-2g/L Fluohydric acid. corrosion
20min, takes out and is placed in ultrasonic cleaner cleaning, then it is standby to obtain microballon through vacuum filtration;
(2) hydrochloric acid of tetraethyl orthosilicate, the dehydrated alcohol of 1/2, deionized water and 1mol/L is stirred at 65 DEG C 1-2h to mix
Close uniformly, obtain silicon dioxide gel, template F127 is extremely dissolved by remaining absolute ethyl alcohol and stirring simultaneously, add self
The silane coupler of weight 0.5-1%, is added to product prepared by step (1) wherein after stirring and ultrasonic disperse is uniform,
Being added in above-mentioned silicon dioxide gel by this mixed liquor, be stirred at room temperature 1-2h, stirring end is placed in 60 DEG C of baking ovens
Evaporate into dry, be subsequently placed in Muffle furnace and calcine 3-4h in 550-600 DEG C, naturally cool to room temperature;
(3) adding emulsifier op-10, sodium bicarbonate, deionized water and Ludox in four-hole boiling flask, water bath with thermostatic control is heated to instead
Answering temperature is 80 DEG C, the Ammonium persulfate. of addition 3/5 and the butyl acrylate of 1/10 and cinnamic mixture, and at the uniform velocity stirring is to breast
There is blue light, dropping residue mix monomer, it is ensured that dripping off in 3h, be subsequently adding remaining Ammonium persulfate., temperature reaction is extremely in liquid
85 DEG C, be cooled to after isothermal reaction 1-1.5h at 40 DEG C regulate pH value to 7-8, standby after natural cooling;
(4) oxidized asphalt is heated to 155-165 DEG C, carboxymethyl cellulose has been stirred well to in appropriate dehydrated alcohol
CL, adds cocoyl alanine sodium and stirs into pastel, be more jointly added to oxidized asphalt in colloid mill grind all
Even, add glass fibre and silane coupler kh550 stirs standby after naturally cooling to room temperature;
(5) just remaining leftover materials is added to grinding machine for grinding, adds step (2), step (3) and step after grinding uniformly
(4) product prepared, after stirring and get final product.
The invention have the advantage that the present invention uses hollow glass micropearl as main filler, it has excellent resistance to compression
Intensity is high, fusing point high, resistivity is high, thermal conductivity coefficient and the feature such as Thermal Contraction Coefficient is little, and the most obvious loss of weight and sound insulation
Heat insulation effect, but the surface-functionalized key being to improve its composite property of hollow glass micropearl, so with Fluohydric acid. pair
Its surface corrosion, improves surface area, and recycling chemical method generates order mesoporous silicon dioxide gel and is coated on its surface, enters
One step improves its lightweight, fire prevention, the performance such as heat insulation, improves adhesion in the base simultaneously, the powder of lacquer putty for use on water suction of cement based
It is easily generated cracking, and most binding agent all has hydrophilic, use emulsion polymerization for solving this problem present invention
Having synthesized Ludox/phenylpropyl alcohol compounded latex, its caking property is high, good waterproof performance, and resistance to water is high, it is possible to effectively avoid putty to open
Splitting, cement based putty becomes the root in crackle, crack due to the generation of internal stress cure shrinkage when, for preventing crackle
Producing, the present invention utilizes oxidized asphalt to prepare the asphalt emulsion that frost resistance is effective, and is coated on fiberglass surfacing, makes
The advantages such as it is good dispersion in powder of lacquer putty for use on, and intensity is high, corrosion resistance is good, it is possible to the effective putty that improves the most easily produces
The advantage of crackle, the present invention provides that a kind of waterproof, anticracking, adhesive force are big, do not have come off, the high intensity exterior wall of cracking phenomena
Freeze proof powder of lacquer putty for use on, preparation method is simple, and low cost is worthy to be popularized.
Detailed description of the invention
A kind of freeze proof anti-cracking putty of external wall, is made up of the raw material of following weight portion (kilogram): cement 24, hollow
Glass microballoon 18, tetraethyl orthosilicate 3.5, dehydrated alcohol 40,1mol/L hydrochloric acid 0.35, template F127 1.6, polyoxyethylene nonylphenol ether-
10 0.7, sodium bicarbonate 0.4, Ludox 12, Ammonium persulfate. 0.3, lightweight sand 4, Pulvis Talci 7, ground calcium carbonate 11, building emulsion
7, ferrous oxide 4, triethyl group base phosphoric acid 3, oxidized asphalt 5, carboxymethyl cellulose 1, cocoyl alanine sodium 0.8, silane
Coupling agent kh5500.06, deionized water are appropriate.
Described a kind of freeze proof anti-cracking putty of external wall, is made up of following concrete steps:
(1) hollow glass micropearl is impregnated in the sodium hydroxide solution that mass concentration is 3g/L of 80 DEG C and carries out oil processing
20min, taking-up deionized water is rinsed post-drying well, then it is at room temperature placed in 1g/L Fluohydric acid. corrosion 20min, takes
Go out to be placed in ultrasonic cleaner cleaning, then it is standby to obtain microballon through vacuum filtration;
(2) hydrochloric acid of tetraethyl orthosilicate, the dehydrated alcohol of 1/2, deionized water and 1mol/L is stirred at 65 DEG C 1h mixing
Uniformly, obtain silicon dioxide gel, template F127 is extremely dissolved by remaining absolute ethyl alcohol and stirring simultaneously, add from heavy sensation of the body
The silane coupler of amount 0.5%, is added to product prepared by step (1) wherein after stirring and ultrasonic disperse is uniform, then will
This mixed liquor is added in above-mentioned silicon dioxide gel, is stirred at room temperature 1h, and stirring end is placed in 60 DEG C of baking ovens and evaporates into
Dry, it is subsequently placed in Muffle furnace and calcines 3h in 550 DEG C, naturally cool to room temperature;
(3) adding emulsifier op-10, sodium bicarbonate, deionized water and Ludox in four-hole boiling flask, water bath with thermostatic control is heated to instead
Answering temperature is 80 DEG C, the Ammonium persulfate. of addition 3/5 and the butyl acrylate of 1/10 and cinnamic mixture, and at the uniform velocity stirring is to breast
There is blue light, dropping residue mix monomer, it is ensured that dripping off in 3h, be subsequently adding remaining Ammonium persulfate., temperature reaction is extremely in liquid
85 DEG C, be cooled to after isothermal reaction 1h at 40 DEG C regulate pH value to 7, standby after natural cooling;
(4) oxidized asphalt is heated to 155 DEG C, carboxymethyl cellulose is the most molten with being stirred well in appropriate dehydrated alcohol
Solve, add cocoyl alanine sodium and stir into pastel, be more jointly added to oxidized asphalt in colloid mill grind uniformly, then
Add glass fibre and silane coupler kh550 stirs standby after naturally cooling to room temperature;
(5) just remaining leftover materials is added to grinding machine for grinding, adds step (2), step (3) and step after grinding uniformly
(4) product prepared, after stirring and get final product.
The heat preservation putty prepared according to embodiment, carries out performance test to it, and result is as follows:
Water absorption (g/min): 0.08;Initial dry cracking resistance (6h): flawless;Resistance to water (96h): without exception;Alkali resistance
(48h): without exception.
Claims (2)
1. the freeze proof anti-cracking putty of external wall, it is characterised in that be made up of the raw material of following weight portion: cement 24-
32, hollow glass micropearl 18-25, tetraethyl orthosilicate 3.5-5, dehydrated alcohol 40-48,1mol/L hydrochloric acid 0.35-0.5, template
Agent F1271.6-2.5, emulsifier op-10 0.7-1, sodium bicarbonate 0.4-0.6, Ludox 12-15, Ammonium persulfate. 0.3-0.5, light
Matter sand 4-6, Pulvis Talci 7-9, ground calcium carbonate 11-14, building emulsion 7-10, ferrous oxide 4-6, triethyl group base phosphoric acid 3-4,
Oxidized asphalt 5-7, carboxymethyl cellulose 1-2, cocoyl alanine sodium 0.8-1.4, silane coupler kh5500.06-0.1,
Deionized water is appropriate.
A kind of freeze proof anti-cracking putty of external wall, it is characterised in that prepared by following concrete steps
Make:
(1) hollow glass micropearl is impregnated in the sodium hydroxide solution that mass concentration is 3-5g/L of 80 DEG C and carries out oil processing
20-30min, taking-up deionized water is rinsed post-drying well, then it is at room temperature placed in 1-2g/L Fluohydric acid. corrosion
20min, takes out and is placed in ultrasonic cleaner cleaning, then it is standby to obtain microballon through vacuum filtration;
(2) hydrochloric acid of tetraethyl orthosilicate, the dehydrated alcohol of 1/2, deionized water and 1mol/L is stirred at 65 DEG C 1-2h to mix
Close uniformly, obtain silicon dioxide gel, template F127 is extremely dissolved by remaining absolute ethyl alcohol and stirring simultaneously, add self
The silane coupler of weight 0.5-1%, is added to product prepared by step (1) wherein after stirring and ultrasonic disperse is uniform,
Being added in above-mentioned silicon dioxide gel by this mixed liquor, be stirred at room temperature 1-2h, stirring end is placed in 60 DEG C of baking ovens
Evaporate into dry, be subsequently placed in Muffle furnace and calcine 3-4h in 550-600 DEG C, naturally cool to room temperature;
(3) adding emulsifier op-10, sodium bicarbonate, deionized water and Ludox in four-hole boiling flask, water bath with thermostatic control is heated to instead
Answering temperature is 80 DEG C, the Ammonium persulfate. of addition 3/5 and the butyl acrylate of 1/10 and cinnamic mixture, and at the uniform velocity stirring is to breast
There is blue light, dropping residue mix monomer, it is ensured that dripping off in 3h, be subsequently adding remaining Ammonium persulfate., temperature reaction is extremely in liquid
85 DEG C, be cooled to after isothermal reaction 1-1.5h at 40 DEG C regulate pH value to 7-8, standby after natural cooling;
(4) oxidized asphalt is heated to 155-165 DEG C, carboxymethyl cellulose has been stirred well to in appropriate dehydrated alcohol
CL, adds cocoyl alanine sodium and stirs into pastel, be more jointly added to oxidized asphalt in colloid mill grind all
Even, add glass fibre and silane coupler kh550 stirs standby after naturally cooling to room temperature;
(5) just remaining leftover materials is added to grinding machine for grinding, adds step (2), step (3) and step after grinding uniformly
(4) product prepared, after stirring and get final product.
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CN201610841581.0A CN106280659A (en) | 2016-09-22 | 2016-09-22 | A kind of freeze proof anti-cracking putty of external wall |
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CN201610841581.0A CN106280659A (en) | 2016-09-22 | 2016-09-22 | A kind of freeze proof anti-cracking putty of external wall |
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CN201610841581.0A Pending CN106280659A (en) | 2016-09-22 | 2016-09-22 | A kind of freeze proof anti-cracking putty of external wall |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109437721A (en) * | 2018-12-20 | 2019-03-08 | 石家庄市筑鑫混凝土有限公司 | A kind of frost-resistant concrete and its processing technology |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104017413A (en) * | 2014-05-05 | 2014-09-03 | 苏州弗克新型建材有限公司 | Thermal insulation putty for internal walls and application method thereof |
-
2016
- 2016-09-22 CN CN201610841581.0A patent/CN106280659A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104017413A (en) * | 2014-05-05 | 2014-09-03 | 苏州弗克新型建材有限公司 | Thermal insulation putty for internal walls and application method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109437721A (en) * | 2018-12-20 | 2019-03-08 | 石家庄市筑鑫混凝土有限公司 | A kind of frost-resistant concrete and its processing technology |
CN109437721B (en) * | 2018-12-20 | 2021-04-30 | 石家庄市筑鑫混凝土有限公司 | Anti-freezing concrete and processing technology thereof |
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Application publication date: 20170104 |
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