Water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating and preparation method thereof
Technical field
The present invention relates to insulating mold coating for building field, particularly a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, it is the rare insulating mold coating that can satisfy the durable and interior wall limits of harmful substances requirement of exterior wall simultaneously.
Background technology
Mostly thermal insulation coatings in the market is that with perlite, vermiculite, asbestos, polystyrene foamed, polyurathamc etc. be lagging material, and effect is not very desirable.Its common weak point is that physical strength is little, the coating failure elongation is little, waterproof effect with wear no resistance, and need thick being coated with (general 2-5cm) just can play function of heat insulation preferably, waste time and energy, decorative effect is poor, material cost is high.
Summary of the invention
The object of the present invention is to provide a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating and preparation method thereof, not only good water-proof effect, A level are not fired for it, resistance to cleavage is good, and cost is low, wear-resisting, only need scumbling to get final product.
Technical scheme of the present invention is made up of following two portions:
(1) scheme one: a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating is characterized in that: it comprises the slurry that is mainly mixed together according to following weight proportion by following material:
Perlite 30-40 part,
Desulfurized powder 5-10 part,
Concentration cellulose solution 10-20 part between 1%-3%,
The emulsion 10-15 part that contains alkene class functional monomer,
Sanitas 1-2 part,
Concentration Z 150PH liquid 10-20 part between 8%-15%,
Water 20-30 part.
In the technique scheme of the present invention, the said emulsion that contains alkene class functional monomer can be made up of in ACRYLIC EMULSION, epoxy emulsion, fluorine carbon emulsion, the polyaminoester emulsion one or more, but is not limited to the above-mentioned emulsion of giving an example.
In addition; In order further to reduce cost; The described water-proofing anticracking fp of technique scheme of the present invention inside and outside wall thermal insulation thermal insulating coating also can comprise mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes, said slurry and auxiliary material are according to 3-5 part: the weight proportion of 2-1 part mixes.
(2) scheme two: a kind of preparation method who is used for preparation scheme one described water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, and it is characterized in that: it comprises following steps:
1. earlier 10-20 weight part and concentration are mixed at a slow speed at emulsion and the 20-30 weight parts water that the Z 150PH liquid between the 8%-15%, 10-20 weight part and concentration cellulose solution, the 10-15 weight part between 1%-3% contains alkene class functional monomer;
2. then in the mixture that 1. step obtains, add 5-10 weight part desulfurized powder, mix fast;
3. in the mixture that 2. step obtains, add 30-40 weight part perlite then, mix, obtain slurry;
And step 1. and/or step 2. and/or step adding in material or the mixing process or mixing and add sanitas after stirring 3., and the adding total amount of said sanitas is the 1-2 weight part.
In addition; In order further to reduce cost; The described preparation method of technique scheme of the present invention also can comprise following steps: the slurry that 4. 3. step is obtained with mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes mixes stirring, and the weight proportion of slurry and auxiliary material is 3-5 part: 2-1 part.
Compared to prior art, the present invention has the following advantages:
(1) adopt the emulsion that contains alkene class functional monomer as one of composition of coating with self-crosslinking structure; Adopt perlite as main resistance hot particle; And the waste desulfurized powder of the employing of innovation steel-making is made tackiness agent; The coating for preparing not only do not fire by good water-proof effect, A level, resistance to cleavage is good, and cost is low, wear-resisting, only needs scumbling to get final product.
(2) raw material that is used for preparing coating do not contain water-absorbents such as asbestos wool, sepiolite by force, the material of not environmental protection, make coating products use all safer environmental protection from producing to, satisfy the environmental protection and the waterproof requirement of indoor use.
(3) because novelty ground introduction itself is the desulfurized powder of iron-making and steel-making waste, the alternative fiber mineral play cohesive action, not only reduce the coating cost, and bounding force is stronger, help to improve resistance to cleavage.
Embodiment
Below in conjunction with embodiment and embodiment to further explain of the present invention:
One, embodiment one
A kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, it comprises the slurry that is mainly mixed together according to following weight proportion by following material:
Perlite 30-40 part,
Desulfurized powder 5-10 part,
Concentration cellulose solution 10-20 part between 1%-3%,
The emulsion 10-15 part that contains alkene class functional monomer,
Sanitas 1-2 part,
Concentration Z 150PH liquid 10-20 part between 8%-15%,
Water 20-30 part.
The said emulsion that contains alkene class functional monomer can be made up of in ACRYLIC EMULSION, epoxy emulsion, fluorine carbon emulsion, the polyaminoester emulsion one or more, but is not limited to the above-mentioned emulsion of giving an example.
The preparation method of above-mentioned coating is following: earlier 10-20 weight part and concentration are mixed at a slow speed at emulsion and the 20-30 weight parts water that the Z 150PH liquid between the 8%-15%, 10-20 weight part and concentration cellulose solution, the 10-15 weight part between 1%-3% contains alkene class functional monomer; Then in the mixture that 1. step obtains, add 5-10 weight part desulfurized powder, mix fast; In the mixture that 2. step obtains, add 30-40 weight part perlite then, mix, obtain slurry.
Described perlite another name pearlife or glass bead.
Described concentration is in advance under 80 ℃ of-100 ℃ of temperature condition at the Z 150PH liquid between the 8%-15%; Z 150PH is dissolved in the water obtains; Described percentage is weight percentage, the Z 150PH liquid after the dissolving should first cool to room temperature after, stir with other mixing of materials again.
The cellulose solution of described concentration between 1%-3% is in advance Mierocrystalline cellulose to be obtained with water dissolution, and described percentage is weight percentage.
Two, embodiment two
A kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating; It is except comprising embodiment one described slurry; It also comprises mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes, said slurry and auxiliary material are according to 3-5 part: the weight proportion of 2-1 part mixes.Said silicate cement preferably adopts white portland cement, with further raising fire resistance.
The preparation method of above-mentioned coating is following: the preparation method by embodiment one said coating obtains slurry earlier; Again with slurry with mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes mixes stirring, and the weight proportion of slurry and auxiliary material is 3-5 part: 2-1 part.
Said auxiliary material mixes with slurry after being pre-mixed by proportioning again.
Three, method of use:
During construction, the coating that embodiment one or embodiment two are made directly spreads upon on the body of wall, can disposable solution construction material and the bonding problem of basic unit.That formed thermal insulation layer has is fire-retardant preferably, cracking resistance, percolation-proof effect.
Four, embodiment:
Example 1-example 3Proportioning as shown in the table
? |
Example 1 |
Example 2 |
Example 3 |
Perlite |
30 parts |
35 parts |
40 parts |
Desulfurized powder |
5 parts |
8 |
10 |
Cellulose solution |
Concentration is 3%, 10 part |
Concentration is 2%, 15 part |
Concentration is 1%, 20 part |
ACRYLIC EMULSION |
10 parts |
12 parts |
15 parts |
Sanitas |
1 part |
1.5 part |
2 parts |
Z 150PH liquid |
Concentration is 15%, 10 part |
Concentration is 10%, 15 part |
Concentration is 8%, 20 part |
Water |
20 parts |
25 parts |
30 parts |
Example 4-example 6Proportioning as shown in the table
? |
Example 4 |
Example 5 |
Example 6 |
Perlite |
30 parts |
35 parts |
40 parts |
Desulfurized powder |
5 parts |
8 |
10 |
Cellulose solution |
Concentration is 3%, 10 part |
Concentration is 2%, 15 part |
Concentration is 1%, 20 part |
Epoxy emulsion |
10 parts |
12 parts |
15 parts |
Sanitas |
1 part |
1.5 part |
2 parts |
Z 150PH liquid |
Concentration is 15%, 10 part |
Concentration is 10%, 15 part |
Concentration is 8%, 20 part |
Water |
20 parts |
25 parts |
30 parts |
Example 7-example 9Proportioning as shown in the table
? |
Example 7 |
Example 8 |
Example 9 |
Perlite |
30 parts |
35 parts |
40 parts |
Desulfurized powder |
5 parts |
8 |
10 |
Cellulose solution |
Concentration is 3%, 10 part |
Concentration is 2%, 15 part |
Concentration is 1%, 20 part |
Fluorine carbon emulsion |
10 parts |
12 parts |
15 parts |
Sanitas |
1 part |
1.5 part |
2 parts |
Z 150PH liquid |
Concentration is 15%, 10 part |
Concentration is 10%, 15 part |
Concentration is 8%, 20 part |
Water |
20 parts |
25 parts |
30 parts |
Example 10-example 12Proportioning as shown in the table
? |
Example 10 |
Example 11 |
Example 12 |
Perlite |
30 parts |
35 parts |
40 parts |
Desulfurized powder |
5 parts |
8 |
10 |
Cellulose solution |
Concentration is 3%, 10 part |
Concentration is 2%, 15 part |
Concentration is 1%, 20 part |
Polyaminoester emulsion |
10 parts |
12 parts |
15 parts |
Sanitas |
1 part |
1.5 part |
2 parts |
Z 150PH liquid |
Concentration is 15%, 10 part |
Concentration is 10%, 15 part |
Concentration is 8%, 20 part |
Water |
20 parts |
25 parts |
30 parts |
Example 13-example 24
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 3:2 respectively, and said auxiliary material is made up of silicate cement; Obtain the coating of routine 13-example 24.
Example 24-example 36
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 4:1.5 respectively, and said auxiliary material is pre-mixed by the weight proportion of 30:70 by silicate cement and wollastonite powder and forms; Obtain the coating of routine 24-example 36.
Example 37-example 48
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 5:1 respectively, and said auxiliary material is pre-mixed by the weight proportion of 50:50 by silicate cement and wollastonite powder and forms; Obtain the coating of routine 37-example 48.
Four, experimental result:
Adopt coating (single component) construction of routine 1-example 12 preparations, and detect, it is as shown in the table to obtain each item index:
Project |
Index |
Application property |
Blade coating is accessible |
Slurry density, kg/
|
600-1000 |
Water regain (10min) g |
≤3 |
Dry density, kg/
|
200~500 |
Volumetric shrinkage, % |
≤20.0 |
Dynamic splitting resistance (basic crack), mm |
≤0.3 |
Cohesive strength, Kpa (standard state) |
≥50 |
The combustionproperty grade |
The A level is not fired |
Thermal conductivity, W/ (mk) |
≤0.05 |
Adopt coating (two-pack) construction of routine 13-example 48 preparations, and detect, it is as shown in the table to obtain each item index:
Project |
Index |
Application property |
Blade coating is accessible |
Slurry density, kg/
|
800~1300 |
Water regain (10min) g |
≤2 |
Dry density, kg/
|
500~700 |
Volumetric shrinkage, % |
≤30.0 |
Dynamic splitting resistance (basic crack), mm |
≤0.2 |
Cohesive strength, Kpa (standard state) |
≥200 |
The combustionproperty grade |
The A level is not fired |
Thermal conductivity, W/ (mk) |
≤0.06 |