CN102219450B - Waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating and preparation method thereof - Google Patents

Waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating and preparation method thereof Download PDF

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Publication number
CN102219450B
CN102219450B CN 201110088817 CN201110088817A CN102219450B CN 102219450 B CN102219450 B CN 102219450B CN 201110088817 CN201110088817 CN 201110088817 CN 201110088817 A CN201110088817 A CN 201110088817A CN 102219450 B CN102219450 B CN 102219450B
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parts
weight
insulating coating
emulsion
slurry
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CN102219450A (en
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唐龙珑
李美栋
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Fujian new Mstar Technology Ltd
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FUZHOU CHUANGMEI DECORATION MATERIAL CO LTD
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating. The waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating is characterized by comprising slurry mainly formed by mixing and stirring the following materials in part by weight: 30 to 40 parts of pearlite, 5 to 10 parts of desulfurated powder, 10 to 20 parts of cellulose liquid at the concentration of 1 to 3 percent, 10 to 15 parts of emulsion containing an alkene functional monomer, 1 to 2 parts of preservative, 10 to 20 parts of polyving akohol liquid at the concentration of 8 to 15 percent and 20 to 30 parts of water. The waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating has good waterproof effect, A-level noninflammability, high crack resistance, low cost and wear resistance, and only a thin layer needs to be coated.

Description

Water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating and preparation method thereof
Technical field
The present invention relates to insulating mold coating for building field, particularly a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, it is the rare insulating mold coating that can satisfy the durable and interior wall limits of harmful substances requirement of exterior wall simultaneously.
Background technology
Mostly thermal insulation coatings in the market is that with perlite, vermiculite, asbestos, polystyrene foamed, polyurathamc etc. be lagging material, and effect is not very desirable.Its common weak point is that physical strength is little, the coating failure elongation is little, waterproof effect with wear no resistance, and need thick being coated with (general 2-5cm) just can play function of heat insulation preferably, waste time and energy, decorative effect is poor, material cost is high.
Summary of the invention
The object of the present invention is to provide a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating and preparation method thereof, not only good water-proof effect, A level are not fired for it, resistance to cleavage is good, and cost is low, wear-resisting, only need scumbling to get final product.
Technical scheme of the present invention is made up of following two portions:
(1) scheme one: a kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating is characterized in that: it comprises the slurry that is mainly mixed together according to following weight proportion by following material:
Perlite 30-40 part,
Desulfurized powder 5-10 part,
Concentration cellulose solution 10-20 part between 1%-3%,
The emulsion 10-15 part that contains alkene class functional monomer,
Sanitas 1-2 part,
Concentration Z 150PH liquid 10-20 part between 8%-15%,
Water 20-30 part.
In the technique scheme of the present invention, the said emulsion that contains alkene class functional monomer can be made up of in ACRYLIC EMULSION, epoxy emulsion, fluorine carbon emulsion, the polyaminoester emulsion one or more, but is not limited to the above-mentioned emulsion of giving an example.
In addition; In order further to reduce cost; The described water-proofing anticracking fp of technique scheme of the present invention inside and outside wall thermal insulation thermal insulating coating also can comprise mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes, said slurry and auxiliary material are according to 3-5 part: the weight proportion of 2-1 part mixes.
(2) scheme two: a kind of preparation method who is used for preparation scheme one described water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, and it is characterized in that: it comprises following steps:
1. earlier 10-20 weight part and concentration are mixed at a slow speed at emulsion and the 20-30 weight parts water that the Z 150PH liquid between the 8%-15%, 10-20 weight part and concentration cellulose solution, the 10-15 weight part between 1%-3% contains alkene class functional monomer;
2. then in the mixture that 1. step obtains, add 5-10 weight part desulfurized powder, mix fast;
3. in the mixture that 2. step obtains, add 30-40 weight part perlite then, mix, obtain slurry;
And step 1. and/or step 2. and/or step adding in material or the mixing process or mixing and add sanitas after stirring 3., and the adding total amount of said sanitas is the 1-2 weight part.
In addition; In order further to reduce cost; The described preparation method of technique scheme of the present invention also can comprise following steps: the slurry that 4. 3. step is obtained with mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes mixes stirring, and the weight proportion of slurry and auxiliary material is 3-5 part: 2-1 part.
Compared to prior art, the present invention has the following advantages:
(1) adopt the emulsion that contains alkene class functional monomer as one of composition of coating with self-crosslinking structure; Adopt perlite as main resistance hot particle; And the waste desulfurized powder of the employing of innovation steel-making is made tackiness agent; The coating for preparing not only do not fire by good water-proof effect, A level, resistance to cleavage is good, and cost is low, wear-resisting, only needs scumbling to get final product.
(2) raw material that is used for preparing coating do not contain water-absorbents such as asbestos wool, sepiolite by force, the material of not environmental protection, make coating products use all safer environmental protection from producing to, satisfy the environmental protection and the waterproof requirement of indoor use.
(3) because novelty ground introduction itself is the desulfurized powder of iron-making and steel-making waste, the alternative fiber mineral play cohesive action, not only reduce the coating cost, and bounding force is stronger, help to improve resistance to cleavage.
Embodiment
Below in conjunction with embodiment and embodiment to further explain of the present invention:
One, embodiment one
A kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating, it comprises the slurry that is mainly mixed together according to following weight proportion by following material:
Perlite 30-40 part,
Desulfurized powder 5-10 part,
Concentration cellulose solution 10-20 part between 1%-3%,
The emulsion 10-15 part that contains alkene class functional monomer,
Sanitas 1-2 part,
Concentration Z 150PH liquid 10-20 part between 8%-15%,
Water 20-30 part.
The said emulsion that contains alkene class functional monomer can be made up of in ACRYLIC EMULSION, epoxy emulsion, fluorine carbon emulsion, the polyaminoester emulsion one or more, but is not limited to the above-mentioned emulsion of giving an example.
The preparation method of above-mentioned coating is following: earlier 10-20 weight part and concentration are mixed at a slow speed at emulsion and the 20-30 weight parts water that the Z 150PH liquid between the 8%-15%, 10-20 weight part and concentration cellulose solution, the 10-15 weight part between 1%-3% contains alkene class functional monomer; Then in the mixture that 1. step obtains, add 5-10 weight part desulfurized powder, mix fast; In the mixture that 2. step obtains, add 30-40 weight part perlite then, mix, obtain slurry.
Described perlite another name pearlife or glass bead.
Described concentration is in advance under 80 ℃ of-100 ℃ of temperature condition at the Z 150PH liquid between the 8%-15%; Z 150PH is dissolved in the water obtains; Described percentage is weight percentage, the Z 150PH liquid after the dissolving should first cool to room temperature after, stir with other mixing of materials again.
The cellulose solution of described concentration between 1%-3% is in advance Mierocrystalline cellulose to be obtained with water dissolution, and described percentage is weight percentage.
Two, embodiment two
A kind of water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating; It is except comprising embodiment one described slurry; It also comprises mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes, said slurry and auxiliary material are according to 3-5 part: the weight proportion of 2-1 part mixes.Said silicate cement preferably adopts white portland cement, with further raising fire resistance.
The preparation method of above-mentioned coating is following: the preparation method by embodiment one said coating obtains slurry earlier; Again with slurry with mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes mixes stirring, and the weight proportion of slurry and auxiliary material is 3-5 part: 2-1 part.
Said auxiliary material mixes with slurry after being pre-mixed by proportioning again.
Three, method of use:
During construction, the coating that embodiment one or embodiment two are made directly spreads upon on the body of wall, can disposable solution construction material and the bonding problem of basic unit.That formed thermal insulation layer has is fire-retardant preferably, cracking resistance, percolation-proof effect.
Four, embodiment:
Example 1-example 3Proportioning as shown in the table
? Example 1 Example 2 Example 3
Perlite 30 parts 35 parts 40 parts
Desulfurized powder 5 parts 8 10
Cellulose solution Concentration is 3%, 10 part Concentration is 2%, 15 part Concentration is 1%, 20 part
ACRYLIC EMULSION 10 parts 12 parts 15 parts
Sanitas 1 part 1.5 part 2 parts
Z 150PH liquid Concentration is 15%, 10 part Concentration is 10%, 15 part Concentration is 8%, 20 part
Water 20 parts 25 parts 30 parts
Example 4-example 6Proportioning as shown in the table
? Example 4 Example 5 Example 6
Perlite 30 parts 35 parts 40 parts
Desulfurized powder 5 parts 8 10
Cellulose solution Concentration is 3%, 10 part Concentration is 2%, 15 part Concentration is 1%, 20 part
Epoxy emulsion 10 parts 12 parts 15 parts
Sanitas 1 part 1.5 part 2 parts
Z 150PH liquid Concentration is 15%, 10 part Concentration is 10%, 15 part Concentration is 8%, 20 part
Water 20 parts 25 parts 30 parts
Example 7-example 9Proportioning as shown in the table
? Example 7 Example 8 Example 9
Perlite 30 parts 35 parts 40 parts
Desulfurized powder 5 parts 8 10
Cellulose solution Concentration is 3%, 10 part Concentration is 2%, 15 part Concentration is 1%, 20 part
Fluorine carbon emulsion 10 parts 12 parts 15 parts
Sanitas 1 part 1.5 part 2 parts
Z 150PH liquid Concentration is 15%, 10 part Concentration is 10%, 15 part Concentration is 8%, 20 part
Water 20 parts 25 parts 30 parts
Example 10-example 12Proportioning as shown in the table
? Example 10 Example 11 Example 12
Perlite 30 parts 35 parts 40 parts
Desulfurized powder 5 parts 8 10
Cellulose solution Concentration is 3%, 10 part Concentration is 2%, 15 part Concentration is 1%, 20 part
Polyaminoester emulsion 10 parts 12 parts 15 parts
Sanitas 1 part 1.5 part 2 parts
Z 150PH liquid Concentration is 15%, 10 part Concentration is 10%, 15 part Concentration is 8%, 20 part
Water 20 parts 25 parts 30 parts
Example 13-example 24
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 3:2 respectively, and said auxiliary material is made up of silicate cement; Obtain the coating of routine 13-example 24.
Example 24-example 36
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 4:1.5 respectively, and said auxiliary material is pre-mixed by the weight proportion of 30:70 by silicate cement and wollastonite powder and forms; Obtain the coating of routine 24-example 36.
Example 37-example 48
The slurry of routine 1-example 12 preparations is mixed with the weight proportion of auxiliary material by 5:1 respectively, and said auxiliary material is pre-mixed by the weight proportion of 50:50 by silicate cement and wollastonite powder and forms; Obtain the coating of routine 37-example 48.
Four, experimental result:
Adopt coating (single component) construction of routine 1-example 12 preparations, and detect, it is as shown in the table to obtain each item index:
Project Index
Application property Blade coating is accessible
Slurry density, kg/ 600-1000
Water regain (10min) g ≤3
Dry density, kg/ 200~500
Volumetric shrinkage, % ≤20.0
Dynamic splitting resistance (basic crack), mm ≤0.3
Cohesive strength, Kpa (standard state) ≥50
The combustionproperty grade The A level is not fired
Thermal conductivity, W/ (mk) ≤0.05
Adopt coating (two-pack) construction of routine 13-example 48 preparations, and detect, it is as shown in the table to obtain each item index:
Project Index
Application property Blade coating is accessible
Slurry density, kg/
Figure 111350DEST_PATH_IMAGE001
800~1300
Water regain (10min) g ≤2
Dry density, kg/
Figure 996130DEST_PATH_IMAGE001
500~700
Volumetric shrinkage, % ≤30.0
Dynamic splitting resistance (basic crack), mm ≤0.2
Cohesive strength, Kpa (standard state) ≥200
The combustionproperty grade The A level is not fired
Thermal conductivity, W/ (mk) ≤0.06

Claims (5)

1. water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating is characterized in that: it comprises the slurry that is mainly mixed together according to following weight proportion by following material:
The percentage of said cellulose solution is weight percentage, and the percentage of said Z 150PH liquid is weight percentage.
2. water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating according to claim 1 is characterized in that: the said emulsion that contains alkene class functional monomer is made up of in ACRYLIC EMULSION, epoxy emulsion, fluorine carbon emulsion, the polyaminoester emulsion more than one.
3. water-proofing anticracking fp inside and outside wall thermal insulation thermal insulating coating according to claim 1 and 2; It is characterized in that: it also comprises mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes, said slurry and auxiliary material are according to 3-5 part: the weight proportion of 2-1 part mixes.
4. preparation method who is used to prepare the described water-proofing anticracking fp of claim 1 inside and outside wall thermal insulation thermal insulating coating, it is characterized in that: it comprises following steps:
1. earlier 10-20 weight part and concentration are mixed at a slow speed at emulsion and the 20-30 weight parts water that the Z 150PH liquid between the 8%-15%, 10-20 weight part and concentration cellulose solution, the 10-15 weight part between 1%-3% contains alkene class functional monomer;
2. then in the mixture that 1. step obtains, add 5-10 weight part desulfurized powder, mix fast;
3. in the mixture that 2. step obtains, add 30-40 weight part perlite then, mix, obtain slurry;
And step 1. and/or step 2. and/or step adding in material or the mixing process or mixing and add sanitas after stirring 3., and the adding total amount of said sanitas is the 1-2 weight part.
5. preparation method according to claim 4 is characterized in that: it also comprises following steps:
4. the slurry that 3. step is obtained with mainly by silicate cement and wollastonite powder according to 30-100 part: the auxiliary material that the weight proportion of 0-70 part mixes mixes stirring, and the weight proportion of slurry and auxiliary material is 3-5 part: 2-1 part.
CN 201110088817 2011-04-11 2011-04-11 Waterproof crack-resistant fireproof internal and external wall heat-preserving heat-insulating coating and preparation method thereof Expired - Fee Related CN102219450B (en)

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Families Citing this family (5)

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Publication number Priority date Publication date Assignee Title
CN104629507A (en) * 2015-02-26 2015-05-20 青岛华联装饰工程有限公司 Water proof paint for outer wall and preparation method thereof
CN105062247A (en) * 2015-08-05 2015-11-18 天长市巨龙车船涂料有限公司 Fluorocarbon emulsion resin waterproof coating
CN106277917A (en) * 2016-08-24 2017-01-04 河南省德嘉丽科技开发有限公司 A kind of concrete Anchor Agent
CN106867341A (en) * 2017-03-06 2017-06-20 南平博士达节能科技有限公司 A kind of construction wall insulation water-thinned nanometer paint
CN109111804A (en) * 2018-06-25 2019-01-01 滁州麦斯特新型建材有限公司 A kind of green environment protection external wall paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1493544A (en) * 2002-10-31 2004-05-05 武汉市鹏凌集团有限公司 Wall surface heat insulating meterial
CN1673166A (en) * 2004-03-22 2005-09-28 常州市宇乔建材科技有限公司 Heat insulating mortar powder and its prepn process
CN101434772A (en) * 2007-11-15 2009-05-20 于士井 Construction exterior wall paint with superior heat preserving performance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1493544A (en) * 2002-10-31 2004-05-05 武汉市鹏凌集团有限公司 Wall surface heat insulating meterial
CN1673166A (en) * 2004-03-22 2005-09-28 常州市宇乔建材科技有限公司 Heat insulating mortar powder and its prepn process
CN101434772A (en) * 2007-11-15 2009-05-20 于士井 Construction exterior wall paint with superior heat preserving performance

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Patentee after: Fujian new Mstar Technology Ltd

Address before: BaiHuaZhou road in Cangshan District of Fuzhou City, Fujian province 350000 No. 41 Jinshan Industrial Zone Cangshan Pu Park No. 27

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