CN106278652A - A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels and preparation method - Google Patents

A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels and preparation method Download PDF

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Publication number
CN106278652A
CN106278652A CN201610723639.1A CN201610723639A CN106278652A CN 106278652 A CN106278652 A CN 106278652A CN 201610723639 A CN201610723639 A CN 201610723639A CN 106278652 A CN106278652 A CN 106278652A
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Prior art keywords
garlicin
carbon aerogels
fertilizer
standby
degerming
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CN201610723639.1A
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Inventor
何基武
李勇
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HEXIAN CHANGJIU AGRICULTURE Co Ltd
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HEXIAN CHANGJIU AGRICULTURE Co Ltd
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Priority to CN201610723639.1A priority Critical patent/CN106278652A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to fruit fertilizer field, specifically a kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels is disclosed, it is characterized in that, including following parts by weight of component: calcium lignosulfonate, cellulose acetate, ammonium polyacrylate, DMF, garlicin, Folium toonae sinensis extract, glycine betaine, paulownia sawdust, bamboo charcoal particle, purple sweet potato, biogas fermentation slag, corn fermentation slag, activity yeast rich in selenium powder, sodium hexameta phosphate, Bamboo vinegar solution, sodium humate, trace element salt, humic acid breeze etc..The present invention uses paulownia sawdust etc. to prepare Fruit Cucumber organic fertilizer for major ingredient after activity yeast rich in selenium powder fermentation, rich in fluorescence probe, it is easy in Fruit Cucumber growing process absorb, the stable garlicin carbon aerogels being simultaneously introduced, by adsorption and enrichment nutrient substance, while promoting Efficient Cultivation, extra-nutrition that can be permanently effective also by the garlicin loaded, realize the most degerming, collectively promote the Efficient Cultivation of Fructus Cucumidis sativi.

Description

A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels and preparation Method
Technical field
The invention belongs to fruit fertilizer field, be specifically related to a kind of degerming height of Fruit Cucumber adding garlicin carbon aerogels Effect fertilizer and preparation method.
Background technology
Nanotechnology has potentiality to be exploited and application prospect at agriculture field, and it is widely used in disinfection, promotion The aspects such as photosynthesis, growth regulation hormone.Carbon aerogels is a kind of novel light nanoporous amorphous carbon cellulosic material, its hole Gap rate is up to 80-98%, and pore-size is less than 50nm, and size 3-20mn of network colloidal solid, specific surface area can reach 600- 1000m2/ g, variable density scope is then 0.05-0.80g/cm3, because of structure and the performance characteristic of its uniqueness, agriculture can be used for Industry fertilizer field, is used for developing concentrated fertilizer, but adds the existing report of the fertilizer of functional nano carbon aerogels, product at present Kind and nutrition know little about it especially, how the effect by nano-sized carbon aeroge realizes wide in variety, the fertilizer of comprehensive nutrition Significant for cultivation of plants.
Summary of the invention
The present invention is directed to add the growth requirement of the fertilizer of functional nano carbon aerogels, propose one and add garlicin carbon The degerming concentrated fertilizer of Fruit Cucumber of aeroge and preparation method.
The technical solution used in the present invention is as follows:
A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels, it is characterised in that include following weight portion group Point: calcium lignosulfonate 12-14, cellulose acetate 10-12, ammonium polyacrylate 3.5-3.9, DMF 2.6- 2.8, garlicin 2.7-2.8, Folium toonae sinensis extract 1.6-1.8, Flos Lonicerae extract 1.7-1.9, thiourea 2.4-2.6, glycine betaine 3.6-3.8, paulownia sawdust 18-20, bamboo charcoal particle 10-12, purple sweet potato 20-22, Testa oryzae 22-24, hoof-and-horn meal 14-16, plant ash 10-12, biogas fermentation slag 20-22, corn fermentation slag 22-24, water solublity lanoline 10-12, activity yeast rich in selenium powder 2.9- 3.1, sodium hexameta phosphate 1-1.1, Bamboo vinegar solution 1.2-1.3, dicyandiamide 0.8-0.9, vinyl silanes 0.2-0.3, sodium humate 1.2-1.3, trace element salt 0.8-0.9, PHA 2-3, humic acid breeze 29-30, silane coupler 2.5-2.7, Appropriate water.
A kind of Fruit Cucumber degerming concentrated fertilizer preparation method adding garlicin carbon aerogels, it is characterised in that include Following steps:
(1) water of methyl thiourea, glycine betaine and gross weight 2-3 times is mixed, after 60 DEG C stir, add Bulbus Allii afterwards After element, Folium toonae sinensis extract, Flos Lonicerae extract stir, put into nanometer generator and process 15-20min, use spray Mist dry technology is dried, and obtains nanometer embedding garlicin material, nanometer embeds garlicin material afterwards and uses the shape of air-cooled freezing Formula, at the freezing 0.4-0.6h of low temperature 2.2-2.6 DEG C, obtains low temperature garlicin material standby;
(2) by calcium lignosulfonate, cellulose acetate, ammonium polyacrylate, DMF and gross weight 1.5-1.7 Water mixing again, 178-180 DEG C of heated and stirred 9.4-9.6h, reacts fully, stops heating afterwards, and by means of indifferent gas Body N2Low temperature garlicin material is quickly uniformly added into by stream, calcines 0.2-0.24h afterwards and be dried under 200 DEG C of inert gas environments Obtain stable garlicin carbon aerogels standby;
(3) by sodium hexameta phosphate, Bamboo vinegar solution, dicyandiamide, vinyl silanes, sodium humate, trace element salt and gross weight The water mixing of 2.4-2.6 times, at 60 DEG C of stirring 23-25min, to being completely dissolved, uniformly to obtain nutritional solution standby;
(4) by paulownia sawdust, bamboo charcoal particle, purple sweet potato, Testa oryzae, hoof-and-horn meal, plant ash, biogas fermentation slag, corn fermentation slag, water Dissolubility lanoline mixes, and puts in pulverizer and pulverizes, and crosses 80 mesh sieves, obtains ground product, by ground product, activity yeast rich in selenium powder And water mix and blend, adjusting moisture is the 41-45% of gross weight, at room temperature aerobic fermentation 38-40d, high temperature 85 DEG C baking Dry that fermentation material is standby;Stable garlicin carbon aerogels, fermentation material, nutritional solution, PHA and appropriate water are mixed Conjunction stirs, and adjusting moisture is the 16-18% of gross weight, uses screw extrusion comminutor to be manufactured into the fertilizer of particle diameter 3-4mm Material granule is standby;
(5) by the water mixing and ball milling pulping of humic acid breeze and gross weight 2.1-2.3 times, and heat at 110-120 DEG C and stir Mix 0.8-1h, whipping process adds silane coupler, mixes into paste, be prepared as coating liquid standby;
(6) fertiliser granulates being placed into top to be equipped with on the drying fluidized-bed of high-pressure sprayer nozzle, coating liquid passes through high-pressure fog Shower nozzle is sprayed on granulated fertilizer uniformly, and be dried by the quick 30s of high temperature of 120 DEG C hot blast, secondary spraying peplos, middle temperature 80 DEG C hot blast 1min is dried, three spraying peplos, 30-32 DEG C of hot blast 60-100min of low temperature are dried for a long time, completes peplos and is dried i.e. ?.
Beneficial effects of the present invention is embodied in:
The present invention uses paulownia sawdust, bamboo charcoal particle, purple sweet potato, Testa oryzae, hoof-and-horn meal, plant ash, biogas fermentation slag, corn fermentation Slag, water solublity lanoline prepare Fruit Cucumber organic fertilizer for major ingredient after activity yeast rich in selenium powder fermentation, little rich in Organic substance Molecule, it is simple to absorb in Fruit Cucumber growing process, the stable garlicin carbon aerogels being simultaneously introduced, by inhaling Attached enrichment nutrient substance, promotes while Efficient Cultivation, extra-nutrition that can be permanently effective also by the garlicin loaded, real The most degerming, collectively promote the Efficient Cultivation of Fructus Cucumidis sativi.The stable garlicin carbon aerogels used uses in pyroreaction Add embedding, wind frozen matter, then prepare through high temperature drying, Stability Analysis of Structures, load effective, can effectively protect garlicin Activity and there is time, action effect, it is achieved long-acting degerming, relatively physics homogenizing absorption load, have higher LOADING RATES and Preferably slow release effect, higher utilization rate, can enrich Fruit Cucumber nutrition and promote the green cultivation of Fruit Cucumber.
Detailed description of the invention
Embodiment
A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels described in the present embodiment, its feature exists In, including following parts by weight of component: calcium lignosulfonate 13, cellulose acetate 11, ammonium polyacrylate 3.7, N, N. dimethyl methyl Amide 2.7, garlicin 2.75, Folium toonae sinensis extract 1.7, Flos Lonicerae extract 1.8, thiourea 2.5, glycine betaine 3.7, paulownia sawdust 19, bamboo charcoal particle 11, purple sweet potato 21, Testa oryzae 23, hoof-and-horn meal 15, plant ash 11, biogas fermentation slag 21, corn fermentation slag 23, water Dissolubility lanoline 11, activity yeast rich in selenium powder 3, sodium hexameta phosphate 1.05, Bamboo vinegar solution 1.25, dicyandiamide 0.85, vinyl silanes 0.25, sodium humate 1.25, trace element salt 0.85, PHA 2.5, humic acid breeze 29.5, silane coupler 2.6, appropriate water.
A kind of Fruit Cucumber degerming concentrated fertilizer preparation method adding garlicin carbon aerogels described in the present embodiment, its It is characterised by, comprises the following steps:
(1) water of methyl thiourea, glycine betaine and gross weight 2.5 times is mixed, after 60 DEG C stir, add Bulbus Allii afterwards After element, Folium toonae sinensis extract, Flos Lonicerae extract stir, put into nanometer generator and process 17.5min, use spraying Dry technology is dried, and obtains nanometer embedding garlicin material, nanometer embeds garlicin material afterwards and uses the form of air-cooled freezing At 2.4 DEG C of freezing 0.5h of low temperature, obtain low temperature garlicin material standby;
(2) by calcium lignosulfonate, cellulose acetate, ammonium polyacrylate, N, N. dimethylformamide and gross weight 1.6 times Water mixes, and 178.180 DEG C of heated and stirred 9.5h, reacts fully, and stops heating afterwards, and by means of noble gas N2Stream is fast Low temperature garlicin material is uniformly added into by speed, calcines 0.22h afterwards and be dried to obtain stable Bulbus Allii under 200 DEG C of inert gas environments Element carbon aerogels is standby;
(3) by sodium hexameta phosphate, Bamboo vinegar solution, dicyandiamide, vinyl silanes, sodium humate, trace element salt and gross weight 2.5 Times water mixing, at 60 DEG C of stirring 24min, to being completely dissolved, uniformly to obtain nutritional solution standby;
(4) by paulownia sawdust, bamboo charcoal particle, purple sweet potato, Testa oryzae, hoof-and-horn meal, plant ash, biogas fermentation slag, corn fermentation slag, water Dissolubility lanoline mixes, and puts in pulverizer and pulverizes, and crosses 80 mesh sieves, obtains ground product, by ground product, activity yeast rich in selenium powder And water mix and blend, adjusting moisture is the 43% of gross weight, at room temperature aerobic fermentation 39d, and high temperature 85 DEG C dries to send out Ferment material is standby;By stable garlicin carbon aerogels, fermentation material, nutritional solution, PHA and appropriate water mix and blend Uniformly, adjusting moisture is the 16.18% of gross weight, uses screw extrusion comminutor to be manufactured into the fertiliser granulates of particle diameter 3-4mm Standby;
(5) by the water mixing and ball milling pulping of humic acid breeze and gross weight 2.2 times, and heated and stirred 0.9h at 115 DEG C, stir Add silane coupler during mixing, mix into paste, be prepared as coating liquid standby;
(6) fertiliser granulates being placed into top to be equipped with on the drying fluidized-bed of high-pressure sprayer nozzle, coating liquid passes through high-pressure fog Shower nozzle is sprayed on granulated fertilizer uniformly, and be dried by the quick 30s of high temperature of 120 DEG C hot blast, secondary spraying peplos, middle temperature 80 DEG C hot blast 1min is dried, three spraying peplos, 31 DEG C of hot blast 80min of low temperature are dried for a long time, completes peplos and is drying to obtain.
Take two pieces of identical Fruit Cucumber planting sites of size respectively as experimental group and matched group, experimental group every mu water Really green cucumber ground uniformly applies fertilizer 60Kg of the present invention, and matched group does not processes, and other cultivation condition keeps consistent, and fruit is yellow In melon Growth and anthesis outcome procedure, finding that experimental group Fruit Cucumber Seedling is grown up strong and sturdy, fast growth, disease Seedling is few, treats fruit After harvesting, finding that experimental group Fruit Cucumber fruit is big compared with matched group Fruit Cucumber fruit head, disease Fruit Cucumber fruit is less, Per mu yield is heavily added up, finds that experimental group every mu Fruit Cucumber yield is 1.784 times of matched group every mu Fruit Cucumber yield; Meanwhile, inviting 200 tasters to taste experimental group and matched group Fruit Cucumber fruit respectively, 185 tasters think experimental group Fruit Cucumber mouthfeel is better than matched group Fruit Cucumber mouthfeel, and 15 tasters think similar.

Claims (2)

1. the degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels, it is characterised in that include following weight portion Component: calcium lignosulfonate 12-14, cellulose acetate 10-12, ammonium polyacrylate 3.5-3.9, DMF 2.6- 2.8, garlicin 2.7-2.8, Folium toonae sinensis extract 1.6-1.8, Flos Lonicerae extract 1.7-1.9, thiourea 2.4-2.6, glycine betaine 3.6-3.8, paulownia sawdust 18-20, bamboo charcoal particle 10-12, purple sweet potato 20-22, Testa oryzae 22-24, hoof-and-horn meal 14-16, plant ash 10-12, biogas fermentation slag 20-22, corn fermentation slag 22-24, water solublity lanoline 10-12, activity yeast rich in selenium powder 2.9- 3.1, sodium hexameta phosphate 1-1.1, Bamboo vinegar solution 1.2-1.3, dicyandiamide 0.8-0.9, vinyl silanes 0.2-0.3, sodium humate 1.2-1.3, trace element salt 0.8-0.9, PHA 2-3, humic acid breeze 29-30, silane coupler 2.5-2.7, Appropriate water.
A kind of Fruit Cucumber degerming concentrated fertilizer preparation method adding garlicin carbon aerogels the most as claimed in claim 1, It is characterized in that, comprise the following steps:
(1) water of methyl thiourea, glycine betaine and gross weight 2-3 times is mixed, after 60 DEG C stir, add Bulbus Allii afterwards After element, Folium toonae sinensis extract, Flos Lonicerae extract stir, put into nanometer generator and process 15-20min, use spray Mist dry technology is dried, and obtains nanometer embedding garlicin material, nanometer embeds garlicin material afterwards and uses the shape of air-cooled freezing Formula, at the freezing 0.4-0.6h of low temperature 2.2-2.6 DEG C, obtains low temperature garlicin material standby;
(2) by calcium lignosulfonate, cellulose acetate, ammonium polyacrylate, DMF and gross weight 1.5-1.7 Water mixing again, 178-180 DEG C of heated and stirred 9.4-9.6h, reacts fully, stops heating afterwards, and by means of indifferent gas Body N2Low temperature garlicin material is quickly uniformly added into by stream, calcines 0.2-0.24h afterwards and be dried under 200 DEG C of inert gas environments Obtain stable garlicin carbon aerogels standby;
(3) by sodium hexameta phosphate, Bamboo vinegar solution, dicyandiamide, vinyl silanes, sodium humate, trace element salt and gross weight The water mixing of 2.4-2.6 times, at 60 DEG C of stirring 23-25min, to being completely dissolved, uniformly to obtain nutritional solution standby;
(4) by paulownia sawdust, bamboo charcoal particle, purple sweet potato, Testa oryzae, hoof-and-horn meal, plant ash, biogas fermentation slag, corn fermentation slag, water Dissolubility lanoline mixes, and puts in pulverizer and pulverizes, and crosses 80 mesh sieves, obtains ground product, by ground product, activity yeast rich in selenium powder And water mix and blend, adjusting moisture is the 41-45% of gross weight, at room temperature aerobic fermentation 38-40d, high temperature 85 DEG C baking Dry that fermentation material is standby;Stable garlicin carbon aerogels, fermentation material, nutritional solution, PHA and appropriate water are mixed Conjunction stirs, and adjusting moisture is the 16-18% of gross weight, uses screw extrusion comminutor to be manufactured into the fertilizer of particle diameter 3-4mm Material granule is standby;
(5) by the water mixing and ball milling pulping of humic acid breeze and gross weight 2.1-2.3 times, and heat at 110-120 DEG C and stir Mix 0.8-1h, whipping process adds silane coupler, mixes into paste, be prepared as coating liquid standby;
(6) fertiliser granulates being placed into top to be equipped with on the drying fluidized-bed of high-pressure sprayer nozzle, coating liquid passes through high-pressure fog Shower nozzle is sprayed on granulated fertilizer uniformly, and be dried by the quick 30s of high temperature of 120 DEG C hot blast, secondary spraying peplos, middle temperature 80 DEG C hot blast 1min is dried, three spraying peplos, 30-32 DEG C of hot blast 60-100min of low temperature are dried for a long time, completes peplos and is dried i.e. ?.
CN201610723639.1A 2016-08-26 2016-08-26 A kind of degerming concentrated fertilizer of Fruit Cucumber adding garlicin carbon aerogels and preparation method Pending CN106278652A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109776166A (en) * 2017-11-14 2019-05-21 丹阳市陵口镇漕塘土地股份专业合作社 A kind of Radix Ophiopogonis is compound fertilizer dedicated
CN112673908A (en) * 2020-12-29 2021-04-20 广西雾野农业科技有限公司 Atomization interplanting device and application thereof

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Publication number Priority date Publication date Assignee Title
CN101580437A (en) * 2009-06-24 2009-11-18 中国农业科学院农业资源与农业区划研究所 Long-acting zinc fertilizer and preparation method thereof
CN102503695A (en) * 2011-11-09 2012-06-20 赵万群 Microorganism bacterial fertilizer and preparation method thereof
CN105294293A (en) * 2015-11-24 2016-02-03 合肥永盛养殖有限公司 Micro-nano dual channel regulation efficient fertilizer supplemented with micron nutrition hydrogel for cherry tomato and preparation method thereof
CN105503387A (en) * 2015-12-18 2016-04-20 合肥市新禾米业有限公司 High-efficiency fertilizer used for succulent flowers and having automatic water adjusting function and preparing method thereof
CN105503410A (en) * 2015-12-29 2016-04-20 芜湖润蓝生物科技有限公司 Efficient beet fertilizer where small-molecular glycyrrhetinic acid is added to moisten lugs to arrest coughs and preparation method of efficient beet fertilizer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101580437A (en) * 2009-06-24 2009-11-18 中国农业科学院农业资源与农业区划研究所 Long-acting zinc fertilizer and preparation method thereof
CN102503695A (en) * 2011-11-09 2012-06-20 赵万群 Microorganism bacterial fertilizer and preparation method thereof
CN105294293A (en) * 2015-11-24 2016-02-03 合肥永盛养殖有限公司 Micro-nano dual channel regulation efficient fertilizer supplemented with micron nutrition hydrogel for cherry tomato and preparation method thereof
CN105503387A (en) * 2015-12-18 2016-04-20 合肥市新禾米业有限公司 High-efficiency fertilizer used for succulent flowers and having automatic water adjusting function and preparing method thereof
CN105503410A (en) * 2015-12-29 2016-04-20 芜湖润蓝生物科技有限公司 Efficient beet fertilizer where small-molecular glycyrrhetinic acid is added to moisten lugs to arrest coughs and preparation method of efficient beet fertilizer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109776166A (en) * 2017-11-14 2019-05-21 丹阳市陵口镇漕塘土地股份专业合作社 A kind of Radix Ophiopogonis is compound fertilizer dedicated
CN112673908A (en) * 2020-12-29 2021-04-20 广西雾野农业科技有限公司 Atomization interplanting device and application thereof
CN112673908B (en) * 2020-12-29 2023-10-31 广西雾野农业科技有限公司 Atomizing interplanting device and application thereof

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Application publication date: 20170104