CN106278526B - A kind of preparation method of microbial organic fertilizer - Google Patents
A kind of preparation method of microbial organic fertilizer Download PDFInfo
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- CN106278526B CN106278526B CN201610560100.9A CN201610560100A CN106278526B CN 106278526 B CN106278526 B CN 106278526B CN 201610560100 A CN201610560100 A CN 201610560100A CN 106278526 B CN106278526 B CN 106278526B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
- C05F5/002—Solid waste from mechanical processing of material, e.g. seed coats, olive pits, almond shells, fruit residue, rice hulls
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Abstract
The invention discloses a kind of preparation method of microbial organic fertilizer, it the steps include: after raw material turf, vinasse, oil cake to be mixed to adjusting moisture and pH value in proportion, high temperature decomposing agent be added, carries out compost fermentation after mixing；Then function microbial inoculum is added in the fertilizer of compost fermentation to stir evenly；Both microbial organic fertilizer is obtained.The invention has the benefit that vinasse contain compared with high organic and nutrient, make full use of vinasse that can economize on resources as fertilizer matrix, reduce waste, solubility humic acid rich in the turf added in matrix, it is a kind of nontoxic, nuisanceless, pollution-free, noresidue matrix, fertilizer efficiency is long, promotes underground root system development, is conducive to plant growth；The present invention is also added into function bacterium, and function strain of the invention can effectively promote the matrix nutrition of organic fertilizer, and can significantly decompose organic fertilizer enables crop to absorb, to promote the healthy growth of crops.
Description
Technical field
The present invention relates to microbial manure fields, more particularly relate to a kind of preparation method of microbial organic fertilizer.
Background technique
Vinasse are the main wastes in liquor production industry, and production quantity is very big, and wherein remaining organic matter
It is dense, well beyond the discharge standard of national regulation, become a big pollution sources of pollution environment, even if increasing input progress
Processing before discharge also can not fundamentally solve the problems, such as environment protection treating, therefore to currently, the processing for vinasse is not only shadow
The big factor for ringing environment, also causes very big cost payout to liquor-making enterprises.
No. 99115046.5 patents " biological active organic fertilizer ", disclose a kind of production technology of organic fertilizer, feature exists
In being raw material using vinasse, puddling, peat, the leftover bits and pieces of food processing, differentiation coal, lignite etc., it is living to process a kind of biology
Property organic fertilizer.Its shortcoming is that the utilization in raw materials for production for vinasse is seldom, 35~40%, and other raw materials are only accounted for
Limited source, therefore the patented technology is caused to be difficult to promote.And the existing effect using vinasse production organic fertilizer is not so good as people
Meaning.
Azotobacteria is one of highly important functional group in soil ecosystem, is played not in soil nitrogen circulation
Alternative effect.As microbial manure Inoculant compared to chemical fertilizer have it is at low cost, use safe, lasting effect
Good, volume increase stablizes, non-renewable energy consumption less, to environment and food safety, high financial profit the features such as.Using nitrogen-fixing bacteria as
The research of Field inoculation agent is carried out extensively all over the world and achieves some gratifying achievements.Many result of study display inoculations
Nitrogen-fixing bacteria have facilitation to the growth of plant and with certain yield increasing effects.But it is single-minded due to bacterial strain and host plant
Property it is stronger, different niches are different from the type of plant nitrogen-fixing bacteria and characteristic, therefore, from specific habitat and plant rhizosphere separation obtain
High-efficiency nitrogen-fixing bacterial strain is had a very important significance with the special bio bacterial manure for developing suitable different niches and plant.
Colloid bacillus cereus (Bacillus mucilaginous) also known as bacillusmusilaginosiengineering, the country are normally referred to as
Silicate bacteria is a kind of multi-functional bacterium.Agriculturally, colloid bacillus cereus has potassium decomposing, Soluble phosphorus effect and easily forms root system
Sociales characteristic is one kind more important in current China's microbial manure product.Industrial aspect, colloid bacillus cereus is in nothing
It is also easy to produce significant exocellular polysaccharide pod membrane in nitrogen culture medium or biggish C/N culture medium, it is raw using the flocculation of this polysaccharide
Microbial flocculant with the obvious advantage is produced to have a extensive future.In metallurgical industry, colloid bacillus cereus can be applied to bacterium leaching and change
Into the characteristic of certain mineral materials, exploitation and the certain useful metals of recycling especially to low-grade mineral have good
Prospect.In terms of aquaculture, protein, the organic acid etc. that colloid bacillus cereus growth course generates can be used as feed supplement, mention
The value of high feed.Therefore the viable bacteria or Number of spores for improving colloid bacillus cereus are anticipated with quality with important practical application
Justice.
Bacillus megaterium is production spore bacillus, and is gram-positive bacteria and aerobic bacteria, is also saprophytic bacteria in common oil.
It industrially for producing glucose isomerase, while being also therefore organic phosphorus decomposer agriculturally can be used for manufacturing phosphorus
Bacterial fertilizer.Bacillus megaterium has effect organic phosphorus in degradation soil well, is to produce commonly using for biological organic fertilizer
It is administered on tobacco leaf only to tobacco fermentation flavouring effect is improved by strain, and the common strain of production water body inorganic agent
It is special.
How function bacterium to be introduced into the organic fertilizer using vinasse production, improve the utilization rate of vinasse, enhancing utilizes
The effect of the organic fertilizer of vinasse production is a problem to be solved.
Summary of the invention
The present invention overcomes the deficiencies in the prior art, provide a kind of preparation method of microbial organic fertilizer, solve existing
The problem of few to vinasse utilization in organic fertilizer production, and the organic fertilizer application effect produced is not so good as people's will.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of preparation method of microbial organic fertilizer, which is characterized in that steps are as follows:
(1) by weight it is 3:(5-6 by turf, vinasse, oil cake): (1-2) is mixed, and water is added to adjust moisture weight hundred
After dividing ratio to 60-65%, pH to 7-8 is adjusted, high temperature decomposing agent is added, carries out compost fermentation after mixing；
(2) first time compost fermentation is carried out；
(3) moisture weight percentage will be adjusted to 45-50% by the fertilizers with water of first time compost fermentation, adjust pH to
7-8, addition high temperature decomposing agent stir evenly；
(4) second of compost fermentation is carried out；
(5) function microbial inoculum is added in the fertilizer by second of compost fermentation to stir evenly；
(6) will treated, and fertilizer is sieved by step (5), both microbial organic fertilizer；
The function microbial inoculum is composite bacteria agent, and the composite bacteria agent includes azotobacter chroococcum, bacillus megaterium and glue
Freeze sample series bacillus, the bacterium solution of the azotobacter chroococcum, the bacterium solution of bacillus megaterium, gel-shaped series bacillus bacterium
Liquid volume ratio is (2-4): 1:1；The bacterium solution bacteria containing amount of the azotobacter chroococcum is hundred million/ml of 80-100, the bacillus megaterium
Bacterium solution bacteria containing amount be hundred million/ml of 4.5-5, the bacterium solution bacteria containing amount of the colloid bacillus cereus is hundred million/ml of 4.5-5；
The high temperature decomposing agent is liquid microbial inoculum, and the viable bacteria content of the liquid microbial inoculum is hundred million/ml of 1.8-2.5；It is described
The strain of liquid microbial inoculum includes bacillus subtilis, actinomyces and saccharomycete, the bacillus subtilis, actinomyces, saccharomycete
Strain quantity ratio be 3:4:3, the weight of the addition of the high temperature decomposing agent is after fertilizer matrix adjusts moisture content and pH value
Total weight 0.4-0.6%.
Further, the specific steps are when fertile heap internal temperature rises to 70 for the first time compost fermentation of the step (2)
After DEG C, daily turning is primary；After fertile heap internal temperature is down to 50 DEG C, the turning of progress in three days；The temperature inside fertile heap
When degree is down to 30 DEG C, fertilizer crushing is carried out.
Further, the specific steps are fertile heap internal temperature rises to 60 DEG C to second of compost fermentation of the step (4)
When, daily turning is primary；When fertile heap internal temperature is down to 40 DEG C, the turning of progress in three days；When temperature is down to 30 DEG C, addition
Function microbial inoculum carries out second of fertilizer crushing after mixing evenly.
Compared with prior art, the beneficial effects of the present invention are: vinasse contain compared with high organic and nutrient, wine is made full use of
Grain can economize on resources as fertilizer matrix, reduce waste, and the present invention substantially increases the utilization rate of vinasse, turns waste into wealth, and improve
The fertilizer efficiency of matrix；Solubility humic acid rich in the turf added in matrix, be it is a kind of it is nontoxic, nuisanceless, without dirt
Dye, the matrix of noresidue, fertilizer efficiency is long, promotes underground root system development, is conducive to plant growth；The present invention is also added into the brown fixed nitrogen of circle
The function bacteriums such as bacterium, bacillus megaterium and gel-shaped series bacillus, function strain of the invention can effectively be promoted organic
The matrix nutrition of fertilizer, can significantly decompose organic fertilizer enables crop to absorb, to promote the healthy growth of crops.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated.Embodiments of the present invention are including but not limited to following
Embodiment.
[embodiment 1]
A kind of preparation method of microbial organic fertilizer, steps are as follows:
(1) be by weight that 3:5:1 is mixed by turf, vinasse, oil cake, add water adjust moisture weight percentage to
After 60-65%, pH to 7 is adjusted, high temperature decomposing agent is added, carries out compost fermentation after mixing, the high temperature decomposing agent is
Liquid microbial inoculum, the viable bacteria content of the liquid microbial inoculum are 1.8 hundred million/ml；The strain of the liquid microbial inoculum include bacillus subtilis,
Actinomyces and saccharomycete, the bacillus subtilis, actinomyces, saccharomycete strain quantity ratio be 3:4:3, the high temperature is decomposed
The weight of the addition of agent is the 0.5% of the total weight that fertilizer matrix adjusts after moisture content and pH value；
(2) first time compost fermentation is carried out, after fertile heap internal temperature rises to 70 DEG C, daily turning is primary；When fertile heap
Internal temperature is down to after 50 DEG C, the turning of progress in three days；When fertile heap internal temperature is down to 30 DEG C, fertilizer crushing is carried out；
(3) by the fertilizers with water adjusting moisture weight percentage by first time compost fermentation to 45%, pH to 7 is adjusted,
Addition high temperature decomposing agent stirs evenly, and the high temperature decomposing agent is liquid microbial inoculum, and the viable bacteria content of the liquid microbial inoculum is 1.8
Hundred million/ml；The strain of the liquid microbial inoculum includes bacillus subtilis, actinomyces and saccharomycete, the bacillus subtilis, unwrapping wire
Bacterium, saccharomycete strain quantity ratio be 3:4:3, the weight of the addition of the high temperature decomposing agent is that fertilizer matrix adjusts moisture content
With 0.5% of the total weight after pH value；
(4) second of compost fermentation is carried out, when fertile heap internal temperature rises to 60 DEG C, daily turning is primary；Inside fertile heap
When temperature is down to 40 DEG C, the turning of progress in three days；When temperature is down to 30 DEG C, addition function microbial inoculum carries out second after mixing evenly
Secondary fertilizer crushes；
(5) function microbial inoculum is added in the fertilizer by second of compost fermentation to stir evenly；
(6) will treated, and fertilizer is sieved by step (5), both microbial organic fertilizer；
The function microbial inoculum is composite bacteria agent, and the composite bacteria agent includes azotobacter chroococcum, bacillus megaterium and glue
Freeze sample series bacillus, the bacterium solution of the azotobacter chroococcum, the bacterium solution of bacillus megaterium, gel-shaped series bacillus bacterium
Liquid volume ratio is 2:1:1；The bacterium solution bacteria containing amount of the azotobacter chroococcum is 8,000,000,000/ml, and the bacterium solution of the bacillus megaterium contains
Bacterium amount is 4.5 hundred million/ml, and the bacterium solution bacteria containing amount of the colloid bacillus cereus is 4.5 hundred million/ml.
[embodiment 2]
A kind of preparation method of microbial organic fertilizer, steps are as follows:
(1) be by weight that 3:6:2 is mixed by turf, vinasse, oil cake, add water adjust moisture weight percentage to
After 65%, pH to 8 is adjusted, high temperature decomposing agent is added, carries out compost fermentation after mixing, the high temperature decomposing agent is liquid
Microbial inoculum, the viable bacteria content of the liquid microbial inoculum are 2.5 hundred million/ml；The strain of the liquid microbial inoculum includes bacillus subtilis, unwrapping wire
Bacterium and saccharomycete, the bacillus subtilis, actinomyces, saccharomycete strain quantity ratio be 3:4:3, the high temperature decomposing agent
The weight of addition is the 0.4% of the total weight that fertilizer matrix adjusts after moisture content and pH value；
(2) first time compost fermentation is carried out, after fertile heap internal temperature rises to 70 DEG C, daily turning is primary；When fertile heap
Internal temperature is down to after 50 DEG C, the turning of progress in three days；When fertile heap internal temperature is down to 30 DEG C, fertilizer crushing is carried out；
(3) by the fertilizers with water adjusting moisture weight percentage by first time compost fermentation to 50%, pH to 8 is adjusted,
Addition high temperature decomposing agent stirs evenly, and the high temperature decomposing agent is liquid microbial inoculum, and the viable bacteria content of the liquid microbial inoculum is 2.5
Hundred million/ml；The strain of the liquid microbial inoculum includes bacillus subtilis, actinomyces and saccharomycete, the bacillus subtilis, unwrapping wire
Bacterium, saccharomycete strain quantity ratio be 3:4:3, the weight of the addition of the high temperature decomposing agent is that fertilizer matrix adjusts moisture content
With 0.4% of the total weight after pH value；
(4) second of compost fermentation is carried out, when fertile heap internal temperature rises to 60 DEG C, daily turning is primary；Inside fertile heap
When temperature is down to 40 DEG C, the turning of progress in three days；When temperature is down to 30 DEG C, addition function microbial inoculum carries out second after mixing evenly
Secondary fertilizer crushes；
(5) function microbial inoculum is added in the fertilizer by second of compost fermentation to stir evenly；
(6) will treated, and fertilizer is sieved by step (5), both microbial organic fertilizer；
The function microbial inoculum is composite bacteria agent, and the composite bacteria agent includes azotobacter chroococcum, bacillus megaterium and glue
Freeze sample series bacillus, the bacterium solution of the azotobacter chroococcum, the bacterium solution of bacillus megaterium, gel-shaped series bacillus bacterium
Liquid volume ratio is 4:1:1；The bacterium solution bacteria containing amount of the azotobacter chroococcum is 10,000,000,000/ml, and the bacterium solution of the bacillus megaterium contains
Bacterium amount is 500,000,000/ml, and the bacterium solution bacteria containing amount of the colloid bacillus cereus is 500,000,000/ml.
[embodiment 3]
A kind of preparation method of microbial organic fertilizer, steps are as follows:
(1) be by weight that 3:5:2 is mixed by turf, vinasse, oil cake, add water adjust moisture weight percentage to
After 62%, pH to 7.5 is adjusted, high temperature decomposing agent is added, carries out compost fermentation after mixing, the high temperature decomposing agent is liquid
State microbial inoculum, the viable bacteria content of the liquid microbial inoculum are 2.0 hundred million/ml；The strain of the liquid microbial inoculum includes bacillus subtilis, puts
Line bacterium and saccharomycete, the bacillus subtilis, actinomyces, saccharomycete strain quantity ratio be 3:4:3, the high temperature decomposing agent
The weight of addition be the 0.6% of the total weight that fertilizer matrix adjusts after moisture content and pH value；
(2) first time compost fermentation is carried out, after fertile heap internal temperature rises to 70 DEG C, daily turning is primary；When fertile heap
Internal temperature is down to after 50 DEG C, the turning of progress in three days；When fertile heap internal temperature is down to 30 DEG C, fertilizer crushing is carried out；
(3) moisture weight percentage will be adjusted to 47.5% by the fertilizers with water of first time compost fermentation, adjust pH to
7.5, addition high temperature decomposing agent stirs evenly, and the high temperature decomposing agent is liquid microbial inoculum, the viable bacteria content of the liquid microbial inoculum
For 2.0 hundred million/ml；The strain of the liquid microbial inoculum includes bacillus subtilis, actinomyces and saccharomycete, the bacillus subtilis
Bacterium, actinomyces, saccharomycete strain quantity ratio be 3:4:3, the weight of the addition of the high temperature decomposing agent is that fertilizer matrix adjusts
0.6% of total weight after moisture content and pH value；
(4) second of compost fermentation is carried out, when fertile heap internal temperature rises to 60 DEG C, daily turning is primary；Inside fertile heap
When temperature is down to 40 DEG C, the turning of progress in three days；When temperature is down to 30 DEG C, addition function microbial inoculum carries out second after mixing evenly
Secondary fertilizer crushes；
(5) function microbial inoculum is added in the fertilizer by second of compost fermentation to stir evenly；
(6) will treated, and fertilizer is sieved by step (5), both microbial organic fertilizer；
The function microbial inoculum is composite bacteria agent, and the composite bacteria agent includes azotobacter chroococcum, bacillus megaterium and glue
Freeze sample series bacillus, the bacterium solution of the azotobacter chroococcum, the bacterium solution of bacillus megaterium, gel-shaped series bacillus bacterium
Liquid volume ratio is 3:1:1；The bacterium solution bacteria containing amount of the azotobacter chroococcum is 9,000,000,000/ml, and the bacterium solution of the bacillus megaterium contains
Bacterium amount is 4.75 hundred million/ml, and the bacterium solution bacteria containing amount of the colloid bacillus cereus is 4.75 hundred million/ml.
[field trial]
Test site: Jiangyou City greatly healthy town spark village cabbage sample plot.
Test period: -2016 years on the 11st January 24 of September in 2015.
Experimental field basic condition: being experimental field located at subtropical humid monsoon climate zone, for trying soil category rice great soil group, periodical water-logging
Grey tide field penus, greyish brown damp sand mud field soil species, soil fertility is more uniform, and topography is flat, and 2 mu of test area.
For studying object: cabbage.
Experimental design: this test is 0.5 for four units, i.e. tetra- units of T1, T2, T3, T4, each cellar area is arranged
Mu.
T1 applies microbial organic fertilizer+conventional fertilizer application decrement 20% that embodiment 1 produces, and mu embodiment 1 produces micro-
Biological organic fertilizer 80kg, urea 18.78kg, calcium superphosphate (P2O3 >=12%) 66.67kg, potassium sulfate 11.52kg are as base fertilizer；
After plantation 30 days, mu imposes urea 12.52kg, potassium sulfate 7.68kg.
T2 applies matrix+conventional fertilizer application decrement 20%, mu matrix 80kg, urea 18.78kg, calcium superphosphate (P2O3 >=
12%) 66.67kg, potassium sulfate 11.52kg are as base fertilizer；After plantation 30 days, mu imposes urea 12.52kg, potassium sulfate 7.68kg.
T3 applies conventional fertilizer application, mu urea 23.48kg, calcium superphosphate (P2O3 >=12%) 83.3kg, potassium sulfate
14.4kg as base fertilizer；After plantation 30 days, mu imposes urea 15.56kg, potassium sulfate 9.6kg.
T4 does not apply any fertilizer.
Cabbage biological economy character analysis, as a result see the table below:
By upper table data it is found that the cabbage single plant weight and single plant of the microbial organic fertilizer that application embodiment 1 produces
Market vegetables has increased separately 0.207 kilogram, 0.165 kilogram than the cabbage of conventional fertilizer application again, increases production than conventional fertilizer application mu
495.5kg；The cabbage single plant weight for applying the microbial organic fertilizer that embodiment 1 produces and single plant market vegetables are again than applying base
The cabbage of matter has increased separately 0.140 kilogram, 0.101 kilogram, increases production 289.9kg than Matrix controls mu.
Therefore, illustrate that the fertility of microbial organic fertilizer produced by the invention is greatly improved compared to matrix.
It is as described above the embodiment of the present invention.The present invention is not limited to the above-described embodiments, anyone should learn that
The structure change made under the inspiration of the present invention, the technical schemes that are same or similar to the present invention each fall within this
Within the protection scope of invention.
Claims (3)
1. a kind of preparation method of microbial organic fertilizer, which is characterized in that steps are as follows:
(1) using turf, vinasse, oil cake as fertilizer matrix, the turf, vinasse, oil cake are 3:(5-6 by weight): (1-2)
It is mixed, after adding water to adjust moisture weight percentage to 60-65%, adjusts pH to 7-8, high temperature decomposing agent is added, mixing is equal
Compost fermentation is carried out after even；
(2) first time compost fermentation is carried out；
(3) by the fertilizers with water adjusting moisture weight percentage by first time compost fermentation to 45-50%, pH to 7-8 is adjusted,
Addition high temperature decomposing agent stirs evenly；
(4) second of compost fermentation is carried out；
(5) function microbial inoculum is added in the fertilizer by second of compost fermentation to stir evenly；
(6) will treated, and fertilizer is sieved by step (5), both microbial organic fertilizer；
The function microbial inoculum is composite bacteria agent, and the composite bacteria agent includes azotobacter chroococcum, bacillus megaterium and gel-shaped
Series bacillus, the bacterium solution of the azotobacter chroococcum, the bacterium solution of bacillus megaterium, gel-shaped series bacillus bacteria liquid
Product is than being (2-4): 1:1；The bacterium solution bacteria containing amount of the azotobacter chroococcum is hundred million/ml of 80-100, the bacterium of the bacillus megaterium
Liquid bacteria containing amount is hundred million/ml of 4.5-5, and the bacterium solution bacteria containing amount of the colloid bacillus cereus is hundred million/ml of 4.5-5；
The high temperature decomposing agent is liquid microbial inoculum, and the viable bacteria content of the liquid microbial inoculum is hundred million/ml of 1.8-2.5；The liquid
The strain of microbial inoculum includes bacillus subtilis, actinomyces and saccharomycete, the bacillus subtilis, actinomyces, saccharomycete bacterium
Kind quantity ratio is 3:4:3, and the weight of the addition of the high temperature decomposing agent is total after fertilizer matrix adjustment moisture content and pH value
The 0.4-0.6% of weight.
2. a kind of preparation method of microbial organic fertilizer according to claim 1, it is characterised in that: the step (2)
First time compost fermentation the specific steps are after fertile heap internal temperature rises to 70 DEG C, daily turning is primary；Inside fertile heap
Temperature is down to after 50 DEG C, the turning of progress in three days；When fertile heap internal temperature is down to 30 DEG C, fertilizer crushing is carried out.
3. a kind of preparation method of microbial organic fertilizer according to claim 1, it is characterised in that: the step (4)
Second of compost fermentation the specific steps are when fertile heap internal temperature rises to 60 DEG C, daily turning is primary；When fertile heap internal temperature
When being down to 40 DEG C, the turning of progress in three days；When temperature is down to 30 DEG C, addition function microbial inoculum carries out second of fertilizer after mixing evenly
Feed powder is broken.
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Application publication date: 20170104 Assignee: NANXI GUOKE ZHONGNONG BIO-TECHNOLOGY Co.,Ltd. Assignor: SICHUAN GUOKE ZHONGNONG BIOTECHNOLOGY Co.,Ltd. Contract record no.: X2020510000021 Denomination of invention: A preparation method of microbial organic fertilizer Granted publication date: 20190614 License type: Exclusive License Record date: 20200821 |