CN106265277A - Shampoo for children and preparation method thereof - Google Patents

Shampoo for children and preparation method thereof Download PDF

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Publication number
CN106265277A
CN106265277A CN201610766224.2A CN201610766224A CN106265277A CN 106265277 A CN106265277 A CN 106265277A CN 201610766224 A CN201610766224 A CN 201610766224A CN 106265277 A CN106265277 A CN 106265277A
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extract
sodium
shampoo
children
parts
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CN106265277B (en
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张启明
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Bio Branch (shanghai) Biological Polytron Technologies Inc
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Bio Branch (shanghai) Biological Polytron Technologies Inc
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20Halogens; Compounds thereof
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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    • A61K8/34Alcohols
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    • A61K8/00Cosmetics or similar toiletry preparations
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    • A61K8/34Alcohols
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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    • A61K8/37Esters of carboxylic acids
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
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    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
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    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • AHUMAN NECESSITIES
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    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

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Abstract

The invention discloses a kind of shampoo for children and preparation method thereof, described shampoo for children is prepared from by following raw material: water, sodium laureth sulfate, ethylene glycol bisthioglycolate stearic acid, coconut oleoyl amine MEA, betaines surfactant, sodium chloride, dimethiconol, polydimethylsiloxane, carbomer, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract, sorbitol, essence, ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride, sodium hydroxide, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid.Shampoo for children of the present invention, contains multiple natural component, gives child triple love: Shu Rou, moisten, protection, while helping effectively clean scalp and hair-care, water profit scalp, soft bright hair, make that the hair of child is soft and moist distributes gloss.

Description

Shampoo for children and preparation method thereof
Technical field
The present invention relates to daily-use chemical industry technical field, be specifically related to a kind of shampoo for children and preparation method thereof.
Background technology
Along with the acceleration of human industryization process, in air, pollutant component becomes more and more, such as vehicle exhaust and Chemical composition contained in haze is extremely complex, thus hair, the scalp of human body is also brought more threat.
Shampoo is one of domestic bathing articles for use.The shampoo articles for use sold in the market are various in style, quality discrepancy The biggest.Generally only there is clean result, function singleness.Further, tradition shampoo, in order to improve cleaning force and ability of deoiling, adds The surfactant that a large amount of alkalescence are extremely strong, foaming agent, the composition such as soap base, and the skin of human body is weakly acidic, for a long time Use Diazolidinyl Urea.More seriously, the sebum film of skin also can be destroyed.Once losing sebum film, skin is easy to be subject to To external injury.
Shampoo for children needs specialty to develop, and child skin is tender and lovely, it is impossible to uses the cleaning chemical products of adult, otherwise can injure Skin, and the chemical substance contained in cleaning chemical products of being grown up can affect children's health.
Summary of the invention
For above-mentioned deficiency present in prior art, one of the technical problem to be solved is to provide a kind of youngster Virgin shampoo.
Solve the technical problem that the two of the present invention are to provide the preparation method of a kind of shampoo for children.
The present invention seeks to be achieved through the following technical solutions:
A kind of shampoo for children, is prepared from by following raw material: water, sodium laureth sulfate, ethylene glycol bisthioglycolate are stearic Acid, coconut oleoyl amine MEA, betaines surfactant, sodium chloride, dimethiconol, polydimethylsiloxane, card ripple Nurse, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract, sorbitol, essence, ammonia end Polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride, sodium hydroxide, methylchloroisothiazandnone, methyl-isothiazol Quinoline ketone, phenoxyethanol, EDTA tetra-sodium, citric acid.
A kind of shampoo for children, is prepared from by the raw material of following weight parts: sodium laureth sulfate 45-55 part, Ethylene glycol bisthioglycolate stearic acid 15-25 part, coconut oleoyl amine MEA 35-45 part, betaines surfactant 45-55 part, sodium chloride 1- 10 parts, dimethiconol 1-10 part, polydimethylsiloxane 1-10 part, carbomer 5-15 part, hydrolyzed-silk glue protein 15- 25 parts, tip edge Fucus Vesiculosus extract 1-10 part, yellow tang extract 1-10 part, thorn Asparagus toxiformis (Delile) Coll et Harv extract 1-10 part, sorbitol 5- 15 parts, ammonia end polydimethylsiloxane 1-10 part, guar hydroxypropyltrimonium ammonium chloride 5-15 part, sodium hydroxide 1-10 part, Methylchloroisothiazandnone 0.1-1 part, Methylisothiazolinone 0.1-1 part, phenoxyethanol 1-10 part, EDTA tetra-sodium 1-10 part, Citric acid 1-10 part, essence 0.1-1 part, water 700-900 part.
Preferably, described essence is vanillin, Fructus Citri Limoniae essence, Mint Essence, lavandula angustifolia essence, rose essence etc..
Preferably, described betaines surfactant is cocamido propyl betaine, 3-sulfopropyl cetyl The mixture of one or more in diformazan glycine betaine, oleamide CAB.
It is highly preferred that described betaines surfactant is by cocamido propyl betaine, 3-sulfopropyl hexadecane Base diformazan glycine betaine, oleamide CAB mix, described cocamido propyl betaine, 3-sulfopropyl cetyl Diformazan glycine betaine, the mass ratio of oleamide CAB are (1-3): (1-3): (1-3).
Present invention also offers the preparation method of above-mentioned shampoo for children, comprise the following steps:
Heat water to 65-85 DEG C, under stirring condition, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate tristearin Acid, coconut oleoyl amine MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, ammonia end Polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 45-55 DEG C, sequentially add Sorbitol, essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, hydroxide Sodium, sodium chloride, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract stirring mixing are all Even and get final product.
Concrete, in the present invention:
Fructus Citri Limoniae essence, uses the Fructus Citri Limoniae essence that Shanghai bright moon daily use chemicals company limited provides in the embodiment of the present invention.
Cocamido propyl betaine, No. CAS: 86438-79-1.
3-sulfopropyl etradecyldimethylamine glycine betaine, No. CAS: 2281-11-0.
Oleamide CAB, No. CAS: 25054-76-6.
Ethylene glycol bisthioglycolate stearic acid, No. CAS: 627-83-8.
Dimethiconol, No. CAS: 68938-54-5, the embodiment of the present invention use Dow Corning Corporation provide Model is PMX-1403 dimethiconol.
Polydimethylsiloxane, No. CAS: 9016-00-6.
Carbomer, No. CAS: 76050-42-5.The embodiment of the present invention use U.S. Lu Runbo (former promise reputation) company provide Acritamer 940.
Hydrolyzed-silk glue protein, uses the side of embodiment two in number of patent application 201310511239.0 in the embodiment of the present invention Prepared by method.
Ammonia end polydimethylsiloxane, No. CAS: 71750-80-6, the embodiment of the present invention uses the fragrant refined chemical industry in Guangzhou The ammonia end polydimethylsiloxane TCN-620 that company limited provides.
Guar hydroxypropyltrimonium ammonium chloride, No. CAS: 65497-29-2, the embodiment of the present invention uses sea, Yutai County Receive Environmental Protection Technology Co., Ltd provide guar hydroxypropyltrimonium ammonium chloride C-14S.
Phenoxyethanol, i.e. ethylene glycol phenyl ether, No. CAS: 122-99-6.
Sodium laureth sulfate, No. CAS: 9004-82-4.The embodiment of the present invention use Japanese Kao company provide The sodium laureth sulfate that model is EMAL 270S.
Coconut oleoyl amine MEA, i.e. Coconut Fatty Acid Monoethanolamide, No. CAS: 68140-00-1.The embodiment of the present invention uses four The FS600-CMEA Coconut Fatty Acid Monoethanolamide (without glycerol) that Chuan Hua language Fine Chemical Co., Ltd provides.
EDTA tetra-sodium, i.e. tetrasodium ethylenediamine tetraacetate, No. CAS: 64-02-8.
Sodium chloride, No. CAS: 7647-14-5.
Citric acid, No. CAS: 77-92-9.
Sodium hydroxide, No. CAS: 1310-73-2.
Methylchloroisothiazandnone, No. CAS: 26172-55-4.
Methylisothiazolinone, No. CAS: 2682-20-4.
Sorbitol, also known as D-Sorbitol, No. CAS: 50-70-4.
Tip edge Fucus Vesiculosus extract, English name: Fucus Serratus Extrac, derive from Boulez Brittany area Tip edge Fucus Vesiculosus, locals is referred to as " gold Sargassum ".This algae extract has reinforcing fiber archeocyte vigor, and protective wire plastochondria is thin Born of the same parents, promote dermal respiration, bring powerful moisture-keeping efficacy, Cucumber Extract water storage function for skin, also can promote tissue regeneration, increase Cell viability recovers skin life, promotes the metabolism of skin, is effective against free radical, antagonism cell senescence, discharges simultaneously Active-energy, improvement is dried, prevention microgroove, wrinkle produce, delay skin aging.Tip edge Fucus Vesiculosus extract can be prepared or purchase Can buy, preparation method can be conventional water extraction or alcohol extracting method, according to solid-liquid after such as being cleaned and crush by tip edge Fucus Vesiculosus Immersing mass fraction than (g/ml) 1:10-1:30 is in 95% ethanol, soaks 8-12h, is heated to reflux 4-6h, and cooling is filtered, will After filtrate concentrates, it is lyophilized into powder.Tip edge Fucus Vesiculosus extract used in the present invention is to buy from Nanjing Ze Lang medicine section Skill company limited, specification is 10:1, i.e. the 1g tip edge Fucus Vesiculosus extract that 10g tip edge Fucus Vesiculosus extracts.
Yellow tang extract, English name: Ascophyllum Nodosum Extract, have antitumor, antiviral, Antibacterial, elimination free radical, anti-oxidation efficacy.Yellow tang extract can be prepared or be commercially available, and preparation method can be conventional Water extraction or alcohol extracting method, after such as yellow tang being cleaned and crush according to solid-to-liquid ratio (g/ml) 1:10-1:30 immerse mass fraction It is in 95% ethanol, soaks 8-12h, be heated to reflux 4-6h that cooling is filtered, after filtrate being concentrated, is lyophilized into powder.The present invention Used in yellow tang extract be to buy from Xi'an incomparably bio tech ltd, specification is 10:1, i.e. 10g yellow tang The 1g yellow tang extract extracted.
Thorn Asparagus toxiformis (Delile) Coll et Harv Sargassum extract, English name: Asparagopsis Armata Extract, rich in activated silica, energy Effectively optimize skin cell metabolism, there is skin reconstruction, steatolysis, opposing edema, skin quality moisture-keeping efficacy.Thorn Asparagus toxiformis (Delile) Coll et Harv Sargassum extract can be prepared or be commercially available, and preparation method can be conventional water extraction or alcohol extracting method, such as will sting Haimen It is in 95% ethanol that winter Sargassum immerses mass fraction according to solid-to-liquid ratio (g/ml) 1:10-1:30 after cleaning and crush, and soaks 8-12h, It is heated to reflux 4-6h, cooling, filter, after filtrate being concentrated, be lyophilized into powder.Thorn Asparagus toxiformis (Delile) Coll et Harv Sargassum used in the present invention carries Taking thing is to buy beautiful (EXSYMOL) company in west of regarding for oneself, and specification is 10:1, i.e. the 1g that 10g thorn Asparagus toxiformis (Delile) Coll et Harv Sargassum extract extracts Thorn Asparagus toxiformis (Delile) Coll et Harv Sargassum extract.
Shampoo for children of the present invention, contains multiple natural component, gives child triple love: Shu Rou, moist, protection, side While helping effectively clean scalp and hair-care, water profit scalp, soft bright hair, make that the hair of child is soft and moist distributes gloss.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, is only the preferable enforcement to the present invention Example, not does the restriction of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above Technology contents be changed to the Equivalent embodiments that changes on an equal basis.Every without departing from the present invention program content, according to the present invention Technical spirit any simple modification that following example are done or equivalent variations, all fall within protection scope of the present invention.
Embodiment 1
Shampoo for children raw material (weight portion): sodium laureth sulfate 50 parts, ethylene glycol bisthioglycolate stearic acid 20 parts, cocos nucifera oil Amide MEA 40 parts, 51 parts of betaines surfactant, 5 parts of sodium chloride, dimethiconol 3 parts, poly dimethyl silicon 2 parts of oxygen alkane, carbomer 7 parts, hydrolyzed-silk glue protein 20 parts, tip edge Fucus Vesiculosus extract 4 parts, yellow tang extract 4 parts, thorn Haimen Winter extract 4 parts, sorbitol 10 parts, ammonia end polydimethylsiloxane 2 parts, guar hydroxypropyltrimonium ammonium chloride 10 parts, hydrogen Sodium oxide 2 parts, methylchloroisothiazandnone 0.15 part, Methylisothiazolinone 0.15 part, phenoxyethanol 3 parts, EDTA tetra-sodium 1.2 Part, citric acid 4 parts, Fructus Citri Limoniae essence 0.18 part, 800 parts of water.
Described betaines surfactant is by cocamido propyl betaine, 3-sulfopropyl etradecyldimethylamine Radix Betae Alkali, oleamide CAB are uniformly mixed for 1:1:1 in mass ratio and obtain.
The preparation method of above-mentioned shampoo for children, comprises the following steps:
Heat water to 75 DEG C, under 500 revs/min of stirring conditions, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate Stearic acid, coconut oleoyl amine MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, Ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 48 DEG C, sequentially add Sorbitol, Fructus Citri Limoniae essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, hydrogen-oxygen Change sodium, sodium chloride, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract stirring mixing Uniformly.Obtain the shampoo for children of embodiment 1.
Embodiment 2
Shampoo for children raw material (weight portion): sodium laureth sulfate 50 parts, ethylene glycol bisthioglycolate stearic acid 20 parts, cocos nucifera oil Amide MEA 40 parts, 51 parts of betaines surfactant, 5 parts of sodium chloride, dimethiconol 3 parts, poly dimethyl silicon 2 parts of oxygen alkane, carbomer 7 parts, hydrolyzed-silk glue protein 20 parts, tip edge Fucus Vesiculosus extract 6 parts, yellow tang extract 6 parts, sorbitol 10 parts, ammonia end polydimethylsiloxane 2 parts, guar hydroxypropyltrimonium ammonium chloride 10 parts, sodium hydroxide 2 parts, methyl chloride different Thiazolinone 0.15 part, Methylisothiazolinone 0.15 part, phenoxyethanol 3 parts, 1.2 parts of EDTA tetra-sodium, citric acid 4 parts, Fructus Citri Limoniae 0.18 part of essence, 800 parts of water.
Described betaines surfactant is by cocamido propyl betaine, 3-sulfopropyl etradecyldimethylamine Radix Betae Alkali, oleamide CAB are uniformly mixed for 1:1:1 in mass ratio and obtain.
The preparation method of above-mentioned shampoo for children, comprises the following steps:
Heat water to 75 DEG C, under 500 revs/min of stirring conditions, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate Stearic acid, coconut oleoyl amine MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, Ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 48 DEG C, sequentially add Sorbitol, Fructus Citri Limoniae essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, hydrogen-oxygen Change sodium, sodium chloride, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract are uniformly mixed.Obtain embodiment The shampoo for children of 2.
Embodiment 3
Shampoo for children raw material (weight portion): sodium laureth sulfate 50 parts, ethylene glycol bisthioglycolate stearic acid 20 parts, cocos nucifera oil Amide MEA 40 parts, 51 parts of betaines surfactant, 5 parts of sodium chloride, dimethiconol 3 parts, poly dimethyl silicon 2 parts of oxygen alkane, carbomer 7 parts, hydrolyzed-silk glue protein 20 parts, tip edge Fucus Vesiculosus extract 6 parts, thorn Asparagus toxiformis (Delile) Coll et Harv extract 6 parts, Pyrusussuriensis Alcohol 10 parts, ammonia end polydimethylsiloxane 2 parts, guar hydroxypropyltrimonium ammonium chloride 10 parts, sodium hydroxide 2 parts, methyl chloride Isothiazolone 0.15 part, Methylisothiazolinone 0.15 part, phenoxyethanol 3 parts, 1.2 parts of EDTA tetra-sodium, citric acid 4 parts, lemon 0.18 part of lemon essence, 800 parts of water.
Described betaines surfactant is by cocamido propyl betaine, 3-sulfopropyl etradecyldimethylamine Radix Betae Alkali, oleamide CAB are uniformly mixed for 1:1:1 in mass ratio and obtain.
The preparation method of above-mentioned shampoo for children, comprises the following steps:
Heat water to 75 DEG C, under 500 revs/min of stirring conditions, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate Stearic acid, coconut oleoyl amine MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, Ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 48 DEG C, sequentially add Sorbitol, Fructus Citri Limoniae essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, hydrogen-oxygen Change sodium, sodium chloride, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed.Implemented The shampoo for children of example 3.
Embodiment 4
Shampoo for children raw material (weight portion): sodium laureth sulfate 50 parts, ethylene glycol bisthioglycolate stearic acid 20 parts, cocos nucifera oil Amide MEA 40 parts, 51 parts of betaines surfactant, 5 parts of sodium chloride, dimethiconol 3 parts, poly dimethyl silicon 2 parts of oxygen alkane, carbomer 7 parts, hydrolyzed-silk glue protein 20 parts, yellow tang extract 6 parts, thorn Asparagus toxiformis (Delile) Coll et Harv extract 6 parts, sorbitol 10 Part, ammonia end polydimethylsiloxane 2 parts, guar hydroxypropyltrimonium ammonium chloride 10 parts, sodium hydroxide 2 parts, the different thiophene of methyl chloride Oxazoline ketone 0.15 part, Methylisothiazolinone 0.15 part, phenoxyethanol 3 parts, 1.2 parts of EDTA tetra-sodium, citric acid 4 parts, NINGMENGXIANG Essence 0.18 part, 800 parts of water.
Described betaines surfactant is by cocamido propyl betaine, 3-sulfopropyl etradecyldimethylamine Radix Betae Alkali, oleamide CAB are uniformly mixed for 1:1:1 in mass ratio and obtain.
The preparation method of above-mentioned shampoo for children, comprises the following steps:
Heat water to 75 DEG C, under 500 revs/min of stirring conditions, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate Stearic acid, coconut oleoyl amine MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, Ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 48 DEG C, sequentially add Sorbitol, Fructus Citri Limoniae essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, hydrogen-oxygen Change sodium, sodium chloride, hydrolyzed-silk glue protein, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed.Obtain embodiment 4 Shampoo for children.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described betaines surfactant is by 3-sulfopropyl 16 Alkyl-dimethyl glycine betaine, oleamide CAB are uniformly mixed for 1:1 in mass ratio and obtain.Obtain the youngster of embodiment 5 Virgin shampoo.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described betaines surfactant is by cocamidopropyl propyl amide Glycine betaine, oleamide CAB are uniformly mixed for 1:1 in mass ratio and obtain.Obtain the shampoo for children of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described betaines surfactant is by cocamidopropyl propyl amide Glycine betaine, 3-sulfopropyl etradecyldimethylamine glycine betaine are uniformly mixed for 1:1 in mass ratio and obtain.Obtain embodiment 7 Shampoo for children.
Test case 1
According to the method disclosed in " foundation of shampoo anti-dandruff effect detection evaluation methodology and applied research " to embodiment The shampoo that 1-7 prepares carries out inhibition zone diameter test, is evaluated anti-dandruff effect of shampoo product.Inhibition zone diameter is more Greatly, anti-dandruff effect is the best.Test data are shown in Table 1.
Wherein, " foundation of shampoo anti-dandruff effect detection evaluation methodology and applied research ", where, Wang Tan, Jia Zebao, flood Dawn roc, Peng Jin, research and development department of Si Bao daily use chemicals company limited, household chemicals science, o. 11th in 2009.
Table 1: anti-dandruff efficacy test tables of data
Inhibition zone diameter, mm
Embodiment 1 23.5
Embodiment 2 18.7
Embodiment 3 19.5
Embodiment 4 18.8
Embodiment 5 20.2
Embodiment 6 19.6
Embodiment 7 20.1
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv Extract compound) anti-dandruff effect be substantially better than embodiment 2-4 (tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv carry Take in thing arbitrarily that the two is compounding);Comparing embodiment 1 and embodiment 5-7, embodiment 1 (cocamido propyl betaine, 3-sulphur third Base etradecyldimethylamine glycine betaine, oleamide CAB are compounding) anti-dandruff effect is substantially better than embodiment 5-7 (coconut oleoyl amine In CAB, 3-sulfopropyl etradecyldimethylamine glycine betaine, oleamide CAB, arbitrarily the two is compounding).
Test case 2
Shampoo for children embodiment 1-7 prepared, carries out fill with dark brown vial respectively, opens wide bottle cap, is placed in Preservation 90 days under ambient temperature 40 DEG C, relative humidity 85% environment, then carries out staphylococcus aureus (ATCC 6538) bacterium colony Sum test, measures with reference to GBT 4789.2-2008 microbiological test of food hygiene total plate count.Concrete test result is shown in Table 2。
Table 2: total plate count test table
S. aureus colonies sum, cfu/g
Embodiment 1 253
Embodiment 2 783
Embodiment 3 767
Embodiment 4 763
Embodiment 5 572
Embodiment 6 584
Embodiment 7 559
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv Extract compound) antiseptic property be substantially better than embodiment 2-4 (tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv carry Take in thing arbitrarily that the two is compounding);Comparing embodiment 1 and embodiment 5-7, embodiment 1 (cocamido propyl betaine, 3-sulphur third Base etradecyldimethylamine glycine betaine, oleamide CAB are compounding) antiseptic property is substantially better than embodiment 5-7 (coconut oleoyl amine In CAB, 3-sulfopropyl etradecyldimethylamine glycine betaine, oleamide CAB, arbitrarily the two is compounding).

Claims (5)

1. a shampoo for children, it is characterised in that be prepared from by following raw material: water, sodium laureth sulfate, second two The acid of alcohol distearyl, coconut oleoyl amine MEA, betaines surfactant, sodium chloride, dimethiconol, poly dimethyl silicon Oxygen alkane, carbomer, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract, sorbitol, Essence, ammonia end polydimethylsiloxane, guar hydroxypropyltrimonium ammonium chloride, sodium hydroxide, methylchloroisothiazandnone, first Base isothiazolone, phenoxyethanol, EDTA tetra-sodium, citric acid.
2. a shampoo for children, it is characterised in that be prepared from by the raw material of following weight parts: sodium laureth sulfate 45-55 part, ethylene glycol bisthioglycolate stearic acid 15-25 part, coconut oleoyl amine MEA 35-45 part, betaines surfactant 45-55 part, Sodium chloride 1-10 part, dimethiconol 1-10 part, polydimethylsiloxane 1-10 part, carbomer 5-15 part, hydrolyzed-silk Glue protein 15-25 part, tip edge Fucus Vesiculosus extract 1-10 part, yellow tang extract 1-10 part, thorn Asparagus toxiformis (Delile) Coll et Harv extract 1-10 part, Sorbitol 5-15 part, ammonia end polydimethylsiloxane 1-10 part, guar hydroxypropyltrimonium ammonium chloride 5-15 part, sodium hydroxide 1-10 part, methylchloroisothiazandnone 0.1-1 part, Methylisothiazolinone 0.1-1 part, phenoxyethanol 1-10 part, EDTA tetra-sodium 1-10 part, citric acid 1-10 part, essence 0.1-1 part, water 700-900 part.
3. shampoo for children as claimed in claim 1 or 2, it is characterised in that: described betaines surfactant is coconut palm In oleamide CAB, 3-sulfopropyl etradecyldimethylamine glycine betaine, oleamide CAB, one or more is mixed Compound.
4. shampoo for children as claimed in claim 3, it is characterised in that: described betaines surfactant is by cocos nucifera oil acyl Amine CAB, 3-sulfopropyl etradecyldimethylamine glycine betaine, oleamide CAB mix, described coconut oleoyl amine CAB, 3-sulfopropyl etradecyldimethylamine glycine betaine, the mass ratio of oleamide CAB are (1-3): (1-3): (1-3)。
5. the preparation method of the shampoo for children as according to any one of claim 1-4, it is characterised in that include following step Rapid:
Heat water to 65-85 DEG C, under stirring condition, be sequentially added into sodium laureth sulfate, ethylene glycol bisthioglycolate stearic acid, coconut palm Oleamide MEA, betaines surfactant, dimethiconol, polydimethylsiloxane, carbomer, ammonia end poly-two Methylsiloxane, guar hydroxypropyltrimonium ammonium chloride are uniformly mixed, and are cooled to 45-55 DEG C, sequentially add Pyrusussuriensis Alcohol, essence, methylchloroisothiazandnone, Methylisothiazolinone, phenoxyethanol, EDTA tetra-sodium, citric acid, sodium hydroxide, chlorine Change sodium, hydrolyzed-silk glue protein, tip edge Fucus Vesiculosus extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed i.e. ?.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107669552A (en) * 2017-10-31 2018-02-09 思拓科(上海)生物科技股份有限公司 Organic baby's shampoo
CN107822975A (en) * 2017-11-29 2018-03-23 桂林华诺威生物科技有限公司 A kind of draft collagen shampoo
CN107913230A (en) * 2017-11-27 2018-04-17 曾万祥 A kind of ginger juice albumen conserves shampoo
CN108125804A (en) * 2018-01-29 2018-06-08 南阳师范学院 A kind of antibacterial light shampoo paste and preparation method thereof
CN115813819A (en) * 2022-12-03 2023-03-21 福建省梦娇兰日用化学品有限公司 Children shampoo free of silicone oil and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103720637A (en) * 2014-01-22 2014-04-16 云南龙润茶科技有限公司 Natural plant shampoo and hair conditioner and preparation methods thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103720637A (en) * 2014-01-22 2014-04-16 云南龙润茶科技有限公司 Natural plant shampoo and hair conditioner and preparation methods thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
如新: "《http://www.cosdna.com/chs/cosmetic_02ed243054.html》", 18 July 2016 *
王建新: "《化妆品植物原料大全》", 30 June 2012 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107669552A (en) * 2017-10-31 2018-02-09 思拓科(上海)生物科技股份有限公司 Organic baby's shampoo
CN107913230A (en) * 2017-11-27 2018-04-17 曾万祥 A kind of ginger juice albumen conserves shampoo
CN107822975A (en) * 2017-11-29 2018-03-23 桂林华诺威生物科技有限公司 A kind of draft collagen shampoo
CN108125804A (en) * 2018-01-29 2018-06-08 南阳师范学院 A kind of antibacterial light shampoo paste and preparation method thereof
CN115813819A (en) * 2022-12-03 2023-03-21 福建省梦娇兰日用化学品有限公司 Children shampoo free of silicone oil and preparation method thereof

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