CN106256761A - 一种批量制备石墨烯和掺杂石墨烯的方法 - Google Patents
一种批量制备石墨烯和掺杂石墨烯的方法 Download PDFInfo
- Publication number
- CN106256761A CN106256761A CN201510334460.2A CN201510334460A CN106256761A CN 106256761 A CN106256761 A CN 106256761A CN 201510334460 A CN201510334460 A CN 201510334460A CN 106256761 A CN106256761 A CN 106256761A
- Authority
- CN
- China
- Prior art keywords
- reactor
- graphene
- still
- self
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 95
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 85
- 238000000034 method Methods 0.000 title claims abstract description 51
- 239000007800 oxidant agent Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 230000003647 oxidation Effects 0.000 claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 11
- 239000002028 Biomass Substances 0.000 claims abstract description 7
- 230000001590 oxidative effect Effects 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 239000001117 sulphuric acid Substances 0.000 claims description 9
- 235000011149 sulphuric acid Nutrition 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 238000004062 sedimentation Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000004907 flux Effects 0.000 claims description 2
- 235000011194 food seasoning agent Nutrition 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229950000845 politef Drugs 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 claims description 2
- 238000011065 in-situ storage Methods 0.000 abstract description 5
- 238000007363 ring formation reaction Methods 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 24
- 230000008859 change Effects 0.000 description 15
- 229910021538 borax Inorganic materials 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000004328 sodium tetraborate Substances 0.000 description 6
- 235000010339 sodium tetraborate Nutrition 0.000 description 6
- 241000219146 Gossypium Species 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010408 sweeping Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 230000005355 Hall effect Effects 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000005307 ferromagnetism Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- -1 graphite alkenes Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 238000007243 oxidative cyclization reaction Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510334460.2A CN106256761B (zh) | 2015-06-16 | 2015-06-16 | 一种批量制备石墨烯和掺杂石墨烯的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510334460.2A CN106256761B (zh) | 2015-06-16 | 2015-06-16 | 一种批量制备石墨烯和掺杂石墨烯的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106256761A true CN106256761A (zh) | 2016-12-28 |
CN106256761B CN106256761B (zh) | 2018-02-16 |
Family
ID=57713391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510334460.2A Active CN106256761B (zh) | 2015-06-16 | 2015-06-16 | 一种批量制备石墨烯和掺杂石墨烯的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106256761B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111148719A (zh) * | 2017-09-29 | 2020-05-12 | 国立研究开发法人科学技术振兴机构 | 含杂元素的石墨烯 |
CN115650699A (zh) * | 2022-12-08 | 2023-01-31 | 长沙中瓷新材料科技有限公司 | 一种模压石墨匣钵及其制备方法与应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2617981Y (zh) * | 2003-06-03 | 2004-05-26 | 郭中枹 | 一种活塞式压力罐 |
CN102317660A (zh) * | 2008-06-10 | 2012-01-11 | 国立大学法人九州工业大学 | 活塞缸型的高压力产生装置 |
CN103016724A (zh) * | 2011-09-21 | 2013-04-03 | 陈启星 | 一种基于储压剂的液压存储仓及其液压系统 |
CN105060289A (zh) * | 2015-09-21 | 2015-11-18 | 中南大学 | 一种基于生物质废料制备少层石墨烯的方法 |
CN105236391A (zh) * | 2015-08-28 | 2016-01-13 | 华南理工大学 | 木质素溶液制备石墨烯的方法 |
CN105439135A (zh) * | 2015-12-30 | 2016-03-30 | 成都新柯力化工科技有限公司 | 一种利用木质素制备石墨烯的方法 |
-
2015
- 2015-06-16 CN CN201510334460.2A patent/CN106256761B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2617981Y (zh) * | 2003-06-03 | 2004-05-26 | 郭中枹 | 一种活塞式压力罐 |
CN102317660A (zh) * | 2008-06-10 | 2012-01-11 | 国立大学法人九州工业大学 | 活塞缸型的高压力产生装置 |
CN103016724A (zh) * | 2011-09-21 | 2013-04-03 | 陈启星 | 一种基于储压剂的液压存储仓及其液压系统 |
CN105236391A (zh) * | 2015-08-28 | 2016-01-13 | 华南理工大学 | 木质素溶液制备石墨烯的方法 |
CN105060289A (zh) * | 2015-09-21 | 2015-11-18 | 中南大学 | 一种基于生物质废料制备少层石墨烯的方法 |
CN105439135A (zh) * | 2015-12-30 | 2016-03-30 | 成都新柯力化工科技有限公司 | 一种利用木质素制备石墨烯的方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111148719A (zh) * | 2017-09-29 | 2020-05-12 | 国立研究开发法人科学技术振兴机构 | 含杂元素的石墨烯 |
CN111148719B (zh) * | 2017-09-29 | 2023-05-09 | 国立研究开发法人科学技术振兴机构 | 含杂元素的石墨烯 |
CN115650699A (zh) * | 2022-12-08 | 2023-01-31 | 长沙中瓷新材料科技有限公司 | 一种模压石墨匣钵及其制备方法与应用 |
CN115650699B (zh) * | 2022-12-08 | 2023-06-02 | 长沙中瓷新材料科技有限公司 | 一种模压石墨匣钵及其制备方法与应用 |
Also Published As
Publication number | Publication date |
---|---|
CN106256761B (zh) | 2018-02-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Yang et al. | Salt-template-assisted construction of honeycomb-like structured g-C3N4 with tunable band structure for enhanced photocatalytic H2 production | |
Zhang et al. | Enhanced charges separation to improve hydrogen production efficiency by organic piezoelectric film polarization | |
Guo et al. | PEGylated self-growth MoS2 on a cotton cloth substrate for high-efficiency solar energy utilization | |
Song et al. | Synthesis of metastable h-MoO3 by simple chemical precipitation | |
CN104773720B (zh) | 一种掺杂单层二硫化钼片的石墨烯复合薄膜的制备方法 | |
Kang et al. | Surface amino group regulation and structural engineering of graphitic carbon nitride with enhanced photocatalytic activity by ultrafast ammonia plasma immersion modification | |
Bai et al. | Solvothermal synthesis of the special shape (deformable) hollow g-C3N4 nanospheres | |
CN104071782B (zh) | 一种石墨烯的制备方法 | |
CN105384192B (zh) | 一种一维纳米棒自组装成花型的三维Nb2O5的制备方法 | |
CN104944392B (zh) | 一种宏量制备石墨相氮化碳纳米片的方法 | |
CN104817075B (zh) | 一种高度分散的氧化石墨烯纳米带液的制备方法 | |
Chen et al. | Direct synthesis and characterization of spongy CuO with nanosheets from Cu3 (btc) 2 microporous metal-organic framework | |
CN104370285A (zh) | 利用生物矿化材料宏量制备高质量石墨烯的方法 | |
CN103626141A (zh) | 一种利用化学剥离制备六方氮化硼纳米片的方法 | |
CN104876217A (zh) | 一种石墨烯的制备方法 | |
CN102583324A (zh) | 一种非晶态碳纳米管的制备方法 | |
Wang et al. | Efficient microwave-assisted functionalization of the aurivillius-phase Bi2SrTa2O9 | |
Chakraborty et al. | Physical modifications and algorithmic predictions behind further advancing 2D water splitting photocatalyst: an overview | |
CN106256761A (zh) | 一种批量制备石墨烯和掺杂石墨烯的方法 | |
Yu et al. | Enhanced visible-light-driven hydrogen evolution of ultrathin narrow-band-gap g-C3N4 nanosheets | |
CN104944402A (zh) | 一种快速高效制备氟含量可调氟化石墨烯的方法 | |
CN104071783A (zh) | 一种柔性纸状还原氧化石墨烯膜片的制备方法 | |
CN102070178A (zh) | 基于水热技术调控制备氧化钇微纳米材料的方法 | |
CN100534908C (zh) | In2O3纳米线的制造方法 | |
CN105836737B (zh) | 一种采用超声剥离与射流剥离相结合制备石墨烯的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181024 Address after: Room 201-202, Block F1, 100m northeast of Xinghua Road and Xinghua Sanzhi Road, Xiqing Economic and Technological Development Zone, Tianjin Patentee after: Tianjin Tian Zhao Yu Hua Technology Co., Ltd. Address before: 100191 Beijing Haidian District Xueyuan Road 37 new main building of Beihang University D4444 Patentee before: Song Yujun |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210705 Address after: Room 803, building D-2, future health science and Technology Innovation Park, 2959 yuhangtang Road, Cangqian street, Yuhang District, Hangzhou City, Zhejiang Province, 311121 Patentee after: HANGZHOU RUIDI BIOTECHNOLOGY Co.,Ltd. Address before: Room 201-202, Block F1, 100m northeast of Xinghua Road and Xinghua Sanzhi Road, Xiqing Economic and Technological Development Zone, Tianjin Patentee before: Tianjin Tianzhao Yuhua Technology Co.,Ltd. |