CN106243857A - 一种超薄型电缆防火涂料 - Google Patents

一种超薄型电缆防火涂料 Download PDF

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CN106243857A
CN106243857A CN201610643174.9A CN201610643174A CN106243857A CN 106243857 A CN106243857 A CN 106243857A CN 201610643174 A CN201610643174 A CN 201610643174A CN 106243857 A CN106243857 A CN 106243857A
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cable
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骆垠旭
瞿庆广
王汉才
李登军
杜超群
高德明
赵宏春
徐苏皖
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Anhui Aics Technology Group Co Ltd
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Abstract

本发明公开了一种超薄型电缆防火涂料，涉及电缆涂料技术领域，由如下重量份数的原料制成：氟碳树脂30‑40份、萜烯树脂10‑15份、低密度聚乙烯8‑12份、活性白土6‑10份、聚醚橡胶6‑10份、马来酸酐改性松香甘油酯5‑8份、菜籽饼5‑8份、氯化石蜡4‑6份、绝缘助剂4‑6份、明胶3‑5份、亚乙基双硬脂酸酰胺2‑4份、聚丙烯酸钠2‑4份、纳米氧化锌1‑2份、水100‑150份。本发明涂料属于超薄型涂料，涂于电缆后能快速固化形成致密而坚硬的涂层，涂层附着力强，并具有优异阻燃性、耐油性、耐腐蚀性、耐磨性和耐高温性，防火效果好，能够有效保护电缆线芯，保证电缆的正常工作和延长电缆的使用寿命。

Description

一种超薄型电缆防火涂料
技术领域：
本发明涉及电缆涂料技术领域，具体涉及一种超薄型电缆防火涂料。
背景技术：
电缆防火涂料适用于电厂、工矿、电信和民用建筑电线电缆的阻燃处理，也可用于木结构、金属结构建筑物及地下工程的可燃烧性基材等物体的防火保护。目前，电缆防火涂料主要采用溶剂型，含有大量的挥发性有机溶剂，影响施工环境，威胁施工人员的人体健康。
发明内容：
本发明所要解决的技术问题在于提供一种具有优异阻燃性、耐油性、耐腐蚀性、耐磨性和耐高温性的超薄型电缆防火涂料。
本发明所要解决的技术问题采用以下的技术方案来实现：
一种超薄型电缆防火涂料，由如下重量份数的原料制成：
氟碳树脂30-40份、萜烯树脂10-15份、低密度聚乙烯8-12份、活性白土6-10份、聚醚橡胶6-10份、马来酸酐改性松香甘油酯5-8份、菜籽饼5-8份、氯化石蜡4-6份、绝缘助剂4-6份、明胶3-5份、亚乙基双硬脂酸酰胺2-4份、聚丙烯酸钠2-4份、纳米氧化锌1-2份、水100-150份；
其制备方法如下：
(1)将氟碳树脂、聚醚橡胶、明胶和纳米氧化锌加入水中，于微波频率2450MHz、功率700W下微波处理10min，再加入萜烯树脂和氯化石蜡，继续微波处理5min，即得物料I；
(2)将活性白土和绝缘助剂充分混合，加热至70-80℃保温混合5min，再加入低密度聚乙烯和马来酸酐改性松香甘油酯，继续加热至110-120℃保温混合10min，即得物料II；
(3)趁热向物料I中加入物料II、菜籽饼、亚乙基双硬脂酸酰胺和聚丙烯酸钠，充分混合后于室温下静置1h，再于0-5℃下静置1h，最后转入球磨机中，球磨至细度小于50μm。
所述绝缘助剂由如下重量份数的原料制成：煅烧高岭土15-20份、聚四氟乙烯10-15份、陶瓷微粉8-11份、巴西棕榈蜡6-9份、氯磺化聚乙烯6-9份、石棉粉4-7份、三聚氰胺3-5份、玻璃纤维粉2-3份、石油沥青2-3份、纳米胶粉1-2份、硅酸镁铝1-2份、蓖麻油10-15份、松香水25-30份，其制备方法为：将聚四氟乙烯、氯磺化聚乙烯和纳米胶粉加入松香水中，充分混合后静置30min，再于微波频率2450MHz、功率700W下微波处理10min，待自然冷却至80-85℃后加入巴西棕榈蜡、石油沥青和蓖麻油，保温混合10min，继续自然冷却至室温，最后加入煅烧高岭土、陶瓷微粉、石棉粉、三聚氰胺、玻璃纤维粉和硅酸镁铝，充分混合均匀后送入真空干燥机，所得固体经粉碎机制成粉末。
该绝缘助剂的加入不仅能够有效提高涂料的绝缘性，还能作为填料提高漆膜的机械性能。
本发明的有益效果是：本发明以氟碳树脂为主要原料，辅以萜烯树脂、低密度聚乙烯以及多种填料和功能助剂制得电缆防火涂料，该涂料属于超薄型涂料，涂于电缆后能快速固化形成致密而坚硬的涂层，涂层薄且附着力强，从而避免过度增加电缆重量，并具有优异阻燃性、耐油性、耐腐蚀性、耐磨性和耐高温性，防火效果好，能够有效保护电缆线芯，保证电缆的正常工作和延长电缆的使用寿命。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)将30份氟碳树脂、8份聚醚橡胶、3份明胶和1份纳米氧化锌加入100份水中，于微波频率2450MHz、功率700W下微波处理10min，再加入15份萜烯树脂和4份氯化石蜡，继续微波处理5min，即得物料I；
(2)将8份活性白土和4份绝缘助剂充分混合，加热至70-80℃保温混合5min，再加入10份低密度聚乙烯和5份马来酸酐改性松香甘油酯，继续加热至110-120℃保温混合10min，即得物料II；
(3)趁热向物料I中加入物料II、6份菜籽饼、3份亚乙基双硬脂酸酰胺和2份聚丙烯酸钠，充分混合后于室温下静置1h，再于0-5℃下静置1h，最后转入球磨机中，球磨至细度小于50μm。
绝缘助剂的制备：将15份聚四氟乙烯、8份氯磺化聚乙烯和1份纳米胶粉加入30份松香水中，充分混合后静置30min，再于微波频率2450MHz、功率700W下微波处理10min，待自然冷却至80-85℃后加入6份巴西棕榈蜡、3份石油沥青和10份蓖麻油，保温混合10min，继续自然冷却至室温，最后加入20份煅烧高岭土、8份陶瓷微粉、5份石棉粉、3份三聚氰胺、2份玻璃纤维粉和1份硅酸镁铝，充分混合均匀后送入真空干燥机，所得固体经粉碎机制成粉末。
实施例2
(1)将40份氟碳树脂、6份聚醚橡胶、3份明胶和2份纳米氧化锌加入150份水中，于微波频率2450MHz、功率700W下微波处理10min，再加入10份萜烯树脂和5份氯化石蜡，继续微波处理5min，即得物料I；
(2)将10份活性白土和5份绝缘助剂充分混合，加热至70-80℃保温混合5min，再加入8份低密度聚乙烯和5份马来酸酐改性松香甘油酯，继续加热至110-120℃保温混合10min，即得物料II；
(3)趁热向物料I中加入物料II、8份菜籽饼、2份亚乙基双硬脂酸酰胺和2份聚丙烯酸钠，充分混合后于室温下静置1h，再于0-5℃下静置1h，最后转入球磨机中，球磨至细度小于50μm。
绝缘助剂的制备：将10份聚四氟乙烯、6份氯磺化聚乙烯和1份纳米胶粉加入25份松香水中，充分混合后静置30min，再于微波频率2450MHz、功率700W下微波处理10min，待自然冷却至80-85℃后加入6份巴西棕榈蜡、2份石油沥青和12份蓖麻油，保温混合10min，继续自然冷却至室温，最后加入15份煅烧高岭土、10份陶瓷微粉、4份石棉粉、3份三聚氰胺、2份玻璃纤维粉和2份硅酸镁铝，充分混合均匀后送入真空干燥机，所得固体经粉碎机制成粉末。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (2)

1.一种超薄型电缆防火涂料，其特征在于，由如下重量份数的原料制成：
氟碳树脂30-40份、萜烯树脂10-15份、低密度聚乙烯8-12份、活性白土6-10份、聚醚橡胶6-10份、马来酸酐改性松香甘油酯5-8份、菜籽饼5-8份、氯化石蜡4-6份、绝缘助剂4-6份、明胶3-5份、亚乙基双硬脂酸酰胺2-4份、聚丙烯酸钠2-4份、纳米氧化锌1-2份、水100-150份；
其制备方法如下：
(1)将氟碳树脂、聚醚橡胶、明胶和纳米氧化锌加入水中，于微波频率2450MHz、功率700W下微波处理10min，再加入萜烯树脂和氯化石蜡，继续微波处理5min，即得物料I；
(2)将活性白土和绝缘助剂充分混合，加热至70-80℃保温混合5min，再加入低密度聚乙烯和马来酸酐改性松香甘油酯，继续加热至110-120℃保温混合10min，即得物料II；
(3)趁热向物料I中加入物料II、菜籽饼、亚乙基双硬脂酸酰胺和聚丙烯酸钠，充分混合后于室温下静置1h，再于0-5℃下静置1h，最后转入球磨机中，球磨至细度小于50μm。
2.根据权利要求1所述的超薄型电缆防火涂料，其特征在于，所述绝缘助剂由如下重量份数的原料制成：煅烧高岭土15-20份、聚四氟乙烯10-15份、陶瓷微粉8-11份、巴西棕榈蜡6-9份、氯磺化聚乙烯6-9份、石棉粉4-7份、三聚氰胺3-5份、玻璃纤维粉2-3份、石油沥青2-3份、纳米胶粉1-2份、硅酸镁铝1-2份、蓖麻油10-15份、松香水25-30份，其制备方法为：将聚四氟乙烯、氯磺化聚乙烯和纳米胶粉加入松香水中，充分混合后静置30min，再于微波频率2450MHz、功率700W下微波处理10min，待自然冷却至80-85℃后加入巴西棕榈蜡、石油沥青和蓖麻油，保温混合10min，继续自然冷却至室温，最后加入煅烧高岭土、陶瓷微粉、石棉粉、三聚氰胺、玻璃纤维粉和硅酸镁铝，充分混合均匀后送入真空干燥机，所得固体经粉碎机制成粉末。
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