CN106243754A - A kind of stalky tea Plant fiber's synthetic resin and preparation technology thereof - Google Patents

A kind of stalky tea Plant fiber's synthetic resin and preparation technology thereof Download PDF

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Publication number
CN106243754A
CN106243754A CN201610614754.5A CN201610614754A CN106243754A CN 106243754 A CN106243754 A CN 106243754A CN 201610614754 A CN201610614754 A CN 201610614754A CN 106243754 A CN106243754 A CN 106243754A
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China
Prior art keywords
stalky tea
powder
parts
fiber
synthetic resin
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Withdrawn
Application number
CN201610614754.5A
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Chinese (zh)
Inventor
袁振洲
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Anhui Cobon Resin Technology Co Ltd
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Anhui Cobon Resin Technology Co Ltd
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Priority to CN201610614754.5A priority Critical patent/CN106243754A/en
Publication of CN106243754A publication Critical patent/CN106243754A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The present invention relates to chemical material field, particularly relate to a kind of stalky tea Plant fiber's synthetic resin and preparation technology thereof, including following raw material: stalky tea powder, polyanion cellulose, arabia gum, adipic acid, wheaten starch, diethylene glycol, Colophonium powder, Pulvis Talci, acid fiber by polylactic;Its preparation technology comprises the following steps: (1), prepared fine particle stalky tea powder;(2), the most mixed material is prepared;(3), stalky tea fiber powder is prepared;(4), prepare mixing to add materials;(5) mixing is added materials and after acid fiber by polylactic stirs, blending extrusion, injection mo(u)lding, obtain stalky tea Plant fiber's synthetic resin.The present invention is the waste for avoiding the resources such as wastes of crops, it is sufficiently utilized, and reduces the pollution to environment;The production cost of invention is low, and application widely, can play rural resource advantage, and the Appropriate application for waste agronomic crop provides effective method and approach.

Description

A kind of stalky tea Plant fiber's synthetic resin and preparation technology thereof
Technical field
The present invention relates to chemical material field, particularly relate to a kind of stalky tea Plant fiber's synthetic resin and preparation work thereof Skill.
Background technology
China is as large agricultural country, and along with agricultural is scored consecutive bumper harvests, agricultural crop straw and other waste material yield the most significantly go up Rising, wherein light straw yield is about 6.5 hundred million t/, and the process of wastes of crops straw etc. has become social problem, except few Outside part is taken as feedstuff, fertilizer etc. to develop, major part is committed to the flames, not only wastes resource, and serious harm Natural ecological environment, therefore, the comprehensive utilization of waste agronomic crop is significant.And the mankind are while creating modern civilization, also It is negatively affected white pollution.Disposable tableware, Phthalates and agricultural mulching etc. are all difficult to recycling Utilizing, its processing method is to burn and to bury.Burning can produce substantial amounts of harmful gas, pollutes environment;Bury wherein The polymer short time in can not be decomposed by the microorganisms, also pollute environment.The residual plastic foil abandoned is present in soil, hinders farming The growth of thing root system and to moisture, the absorption of nutrient, makes the gas permeability of soil reduce, causes crop production reduction;Action eats residual abandoning Plastic foil after, intestinal obstruction can be caused and dead;The synthetic netting being lost in ocean or discard in ocean and fishline Marine organisms are caused suitable harm, has therefore advocated green consumption imperative with reinforcement environmental conservation.In the face of day by day Exhausted petroleum resources, popular biodegradation material is just becoming a research and development heat as high-tech product and environment-friendly products Point.
Along with people are to resource, the raising of environmental consciousness, it has been recognized that resources conservation, environmental conservation are that the mankind can enter The mandatory principle of row sustainable development, is the inevitable requirement of the Scientific Outlook on Development.Existing tableware on the market, furniture, kitchen tools All use the products such as wood, bamboo, common plastics etc. the articles for daily use, this type of product cost is high, be unfavorable for degraded, not environmentally, Qi Zhongpu Logical plastics not only can not be degraded, and is widely acknowledged as " white pollution ", destroys the water penetration of soil, and wood, Bamboo products to be cut down Forest, has contaminated wastewater in manufacture process, be not good environment-friendly materials.It is subject to the filling-modified plastics of Plant fiber at present The attention of countries in the world, this technology meets the theory of resources conservation, environmental conservation.Lignocellulosic fiber source is abundant, cheap, its Density is less than all inorfils, and modulus and hot strength are close with inorfil, Plant fiber's potting resin materials processing Time less energy consumption, the loss to process equipment is little, the beneficially saving of the energy in the course of processing, and can natural degradation, it is possible to subtract That lacks plastics uses the pressure brought to environment, in a large number simultaneously for improving the production of people, life a kind of brand-new material of offer.
Summary of the invention
It is an object of the invention to solve the problems of the prior art, it is provided that a kind of technique is simple, steady quality, cost Low, can stalky tea Plant fiber's synthetic resin of natural degradation and preparation technology thereof.
The technical solution adopted in the present invention is such that
A kind of stalky tea Plant fiber's synthetic resin, including the raw material of following weight portion: stalky tea powder 30~60 parts, polyanion Cellulose 5~10 parts, arabia gum 15~40 parts, adipic acid 3~8 parts, wheaten starch 15~40 parts, diethylene glycol 3~8 parts, Colophonium powder 3~8 parts, Pulvis Talci 5~10 parts, acid fiber by polylactic 10~20 parts;
Its preparation technology comprises the following steps:
(1), stalky tea is carried out super-refinement attrition process, obtain fine particle stalky tea powder;
(2), diethylene glycol, adipic acid are put into high speed mixer, be simultaneously introduced polyanion cellulose and stir, The most mixed material;
(3), by the stalky tea powder of step (1) put into high speed mixer to mix with the first mixed material of step (2), be simultaneously introduced Wheaten starch stirs, and is then cooled to room temperature, and pulverizes, obtain stalky tea fiber powder after one-tenth bulk to be solidified;
(4), arabia gum and Colophonium powder are put into reaction vessel to stir, at temperature is 100 DEG C~160 DEG C React 60 minutes~120 minutes, be subsequently adding Pulvis Talci and stalky tea fiber powder continues to stir, be 80 DEG C~120 in temperature React 60 minutes~120 minutes at DEG C, pulverize after cooling, obtain mixing and add materials;
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, Blending extrusion in double screw extruder, then injection mo(u)lding, obtain stalky tea Plant fiber's synthetic resin, packing and storing after cooling.
Preferably, in step (1), described stalky tea grinds to form the molecule stalky tea powder of 50~200 mesh;
Preferably, in step (2), described high speed mixer high-speed stirred 2~after 5 minutes, then stirring at low speed 5~8 Minute to stirring fully, the temperature of high-speed stirred controls at 70 DEG C~90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C~50 DEG C.
Preferably, the mix and blend temperature in described step (3) is 15 DEG C~40 DEG C.
By using preceding solution, the invention has the beneficial effects as follows:
The present invention is the waste for avoiding the resources such as wastes of crops, it is sufficiently utilized, with reach to turn waste into wealth Purpose, and reduce the pollution to environment, the product of the present invention has resistance to freezing, high temperature resistant, high density, high intensity, smooth, nothing The characteristics such as poison, length in service life, and there is superpower resistance to water, moreover it is possible in large nature, it is degraded into organic fertilizer voluntarily, Back to nature, is the material of a kind of extremely environmental protection.Production low cost of the present invention, can be used for packing, tableware, bottle for cosmetics and The fields such as drug bottle, disposable medical article, pesticide and slow-release fertilizer carrier matrix, biological medical polymer material, also have it It relates to the various plastics of environmental conservation, and such as building greening net, film etc., application is widely.The present invention opens New raw material sources, can play rural resource advantage, add farmers' income, alleviates the contradiction of shortage of resources, is discarded The Appropriate application of crops provides effective method and approach.
Detailed description of the invention
Being specifically described the present invention with embodiment below, the scope of the present invention should not be limited by the examples.
Embodiment 1:
A kind of stalky tea Plant fiber's synthetic resin, including the raw material of following weight portion: 30 parts of stalky tea powder, polyanion fiber Element 5 parts, arabia gum 15 parts, adipic acid 3 parts, wheaten starch 15 parts, diethylene glycol 3 parts, Colophonium powder 3 parts, Pulvis Talci 5 parts, poly- Acid fiber 10 parts;
Its preparation technology comprises the following steps:
(1), stalky tea is carried out super-refinement attrition process, obtain fine particle stalky tea powder;
(2), diethylene glycol, adipic acid are put into high speed mixer, be simultaneously introduced polyanion cellulose and stir, The most mixed material;
(3), by the stalky tea powder of step (1) put into high speed mixer to mix with the first mixed material of step (2), be simultaneously introduced Wheaten starch stirs, and is then cooled to room temperature, and pulverizes, obtain stalky tea fiber powder after one-tenth bulk to be solidified;
(4), arabia gum and Colophonium powder are put into reaction vessel to stir, at temperature is 100 DEG C~160 DEG C React 120 minutes, be subsequently adding Pulvis Talci and stalky tea fiber powder continues to stir, react at temperature is 80 DEG C~120 DEG C 60 minutes, pulverize after cooling, obtain mixing and add materials;
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, Blending extrusion in double screw extruder, then injection mo(u)lding, obtain stalky tea Plant fiber's synthetic resin, packing and storing after cooling.
In step (1), described stalky tea grinds to form the molecule stalky tea powder of 50~200 mesh;
In step (2), described high speed mixer high-speed stirred is after 2 minutes, then stirring at low speed is filled for 8 minutes to stirring Point, the temperature of high-speed stirred controls at 70 DEG C~90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C~50 DEG C.
Mix and blend temperature in described step (3) is 15 DEG C~40 DEG C.
Embodiment 2:
A kind of stalky tea Plant fiber's synthetic resin, including the raw material of following weight portion: 60 parts of stalky tea powder, polyanion fiber Element 10 parts, arabia gum 40 parts, adipic acid 8 parts, wheaten starch 40 parts, diethylene glycol 8 parts, Colophonium powder 8 parts, Pulvis Talci 10 parts, Acid fiber by polylactic 20 parts;
Its preparation technology comprises the following steps:
(1), stalky tea is carried out super-refinement attrition process, obtain fine particle stalky tea powder;
(2), diethylene glycol, adipic acid are put into high speed mixer, be simultaneously introduced polyanion cellulose and stir, The most mixed material;
(3), by the stalky tea powder of step (1) put into high speed mixer to mix with the first mixed material of step (2), be simultaneously introduced Wheaten starch stirs, and is then cooled to room temperature, and pulverizes, obtain stalky tea fiber powder after one-tenth bulk to be solidified;
(4), arabia gum and Colophonium powder are put into reaction vessel to stir, at temperature is 100 DEG C~160 DEG C React 60 minutes, be subsequently adding Pulvis Talci and stalky tea fiber powder continues to stir, react at temperature is 80 DEG C~120 DEG C 120 minutes, pulverize after cooling, obtain mixing and add materials;
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, Blending extrusion in double screw extruder, then injection mo(u)lding, obtain stalky tea Plant fiber's synthetic resin, packing and storing after cooling.
In step (1), described stalky tea grinds to form the molecule stalky tea powder of 50~200 mesh;
In step (2), described high speed mixer high-speed stirred is after 5 minutes, then stirring at low speed is filled for 5 minutes to stirring Point, the temperature of high-speed stirred controls at 70 DEG C~90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C~50 DEG C.
Mix and blend temperature in described step (3) is 15 DEG C~40 DEG C.
Above example is only in order to illustrate technical scheme, rather than limiting the scope of the invention, although Make to explain to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be to this Bright technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.

Claims (4)

1. stalky tea Plant fiber's synthetic resin, it is characterised in that include the raw material of following weight portion: stalky tea powder 30~60 Part, polyanion cellulose 5~10 parts, arabia gum 15~40 parts, adipic acid 3~8 parts, wheaten starch 15~40 parts, two Glycol 3~8 parts, Colophonium powder 3~8 parts, Pulvis Talci 5~10 parts, acid fiber by polylactic 10~20 parts;
Its preparation technology comprises the following steps:
(1), stalky tea is carried out super-refinement attrition process, obtain fine particle stalky tea powder;
(2), diethylene glycol, adipic acid are put into high speed mixer, be simultaneously introduced polyanion cellulose and stir, obtain the most mixed Material;
(3), by the stalky tea powder of step (1) put into high speed mixer to mix with the first mixed material of step (2), be simultaneously introduced Semen Tritici aestivi Starch stirs, and is then cooled to room temperature, and pulverizes, obtain stalky tea fiber powder after one-tenth bulk to be solidified;
(4), arabia gum and Colophonium powder are put into reaction vessel stir, react at temperature is 100 DEG C~160 DEG C 60 minutes~120 minutes, it is subsequently adding Pulvis Talci and stalky tea fiber powder continues to stir, at temperature is 80 DEG C~120 DEG C React 60 minutes~120 minutes, pulverize after cooling, obtain mixing and add materials;
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, at double spiral shells Blending extrusion in bar extruder, then injection mo(u)lding, obtain stalky tea Plant fiber's synthetic resin, packing and storing after cooling.
The preparation technology of a kind of stalky tea Plant fiber's synthetic resin the most according to claim 1, it is characterised in that: in step (1), in, described stalky tea grinds to form the molecule stalky tea powder of 50~200 mesh.
The preparation technology of a kind of stalky tea Plant fiber's synthetic resin the most according to claim 1, it is characterised in that: in step (2) in, described high speed mixer high-speed stirred 2~after 5 minutes, then stirring at low speed 5~8 minutes are to stirring fully, high-speed stirring The temperature mixed controls at 70 DEG C~90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C~50 DEG C.
The preparation technology of a kind of stalky tea Plant fiber's synthetic resin the most according to claim 1, it is characterised in that: described step Suddenly the mix and blend temperature in (3) is 15 DEG C~40 DEG C.
CN201610614754.5A 2016-07-29 2016-07-29 A kind of stalky tea Plant fiber's synthetic resin and preparation technology thereof Withdrawn CN106243754A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113402897A (en) * 2021-07-06 2021-09-17 茶纤之维(福建)环保科技有限公司 High-content tea fiber and plant starch modified composite material, preparation method and application
CN114043596A (en) * 2021-12-16 2022-02-15 牛豫华 Biomass packaging material prepared from tea processing derivatives and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101629022A (en) * 2009-08-14 2010-01-20 东北林业大学 Aramid fiber enhanced wood-plastic composite material and preparation method thereof
CN102775802A (en) * 2012-06-27 2012-11-14 磐安县丰源工艺品有限公司 Crop straw fiber-based composite material
CN105694503A (en) * 2016-02-19 2016-06-22 武秀英 Plant fiber biocomposite and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101629022A (en) * 2009-08-14 2010-01-20 东北林业大学 Aramid fiber enhanced wood-plastic composite material and preparation method thereof
CN102775802A (en) * 2012-06-27 2012-11-14 磐安县丰源工艺品有限公司 Crop straw fiber-based composite material
CN105694503A (en) * 2016-02-19 2016-06-22 武秀英 Plant fiber biocomposite and application thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113402897A (en) * 2021-07-06 2021-09-17 茶纤之维(福建)环保科技有限公司 High-content tea fiber and plant starch modified composite material, preparation method and application
CN114043596A (en) * 2021-12-16 2022-02-15 牛豫华 Biomass packaging material prepared from tea processing derivatives and preparation method thereof

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