CN106009752A - Edible fungus stick plant fiber synthetic resin and preparation technique thereof - Google Patents
Edible fungus stick plant fiber synthetic resin and preparation technique thereof Download PDFInfo
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- CN106009752A CN106009752A CN201610618763.1A CN201610618763A CN106009752A CN 106009752 A CN106009752 A CN 106009752A CN 201610618763 A CN201610618763 A CN 201610618763A CN 106009752 A CN106009752 A CN 106009752A
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- edible fungi
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the field of chemical materials, particularly an edible fungus stick plant fiber synthetic resin and a preparation technique thereof. The edible fungus stick plant fiber synthetic resin is prepared from edible fungus stick powder, carnauba wax, polyvinyl alcohol, butanediol, mung bean starch, sorbitol, colophony powder, shell powder and polylactic acid fibers. The preparation technique comprises the following steps: (1) preparing microparticle edible fungus stick powder; (2) preparing a primary mixture; (3) preparing edible fungus stick fiber powder; (4) preparing a mixed additive material; and (5) uniformly stirring the mixed additive material and polylactic acid fibers, carrying out blend extrusion, and carrying out injection molding to obtain the edible fungus stick plant fiber synthetic resin. In order to avoid the waste of crop scraps and other resources, the crop scraps are sufficiently utilized, and the environmental pollution is reduced. The edible fungus stick plant fiber synthetic resin has the advantages of low production cost and wide application range, can display the advantages of rural resources, and provides an effective method and way for rational utilization of scrap crops.
Description
Technical field
The present invention relates to chemical material field, particularly relate to a kind of edible fungi rod Plant fiber's synthetic resin and preparation technology thereof.
Background technology
China is as large agricultural country, and along with agricultural is scored consecutive bumper harvests, agricultural crop straw and other waste material yield the most significantly rise, wherein
Light straw yield is about 6.5 hundred million t/, and the process of wastes of crops straw etc. has become social problem, except small part is worked as
Make outside feedstuff, fertilizer etc. develops, major part is committed to the flames, not only wastes resource, and serious harm natural, ecological ring
Border, therefore, the comprehensive utilization of waste agronomic crop is significant.And the mankind are while creating modern civilization, also it is negatively affected
White pollution.Disposable tableware, Phthalates and agricultural mulching etc. are all difficult to be recycled, its process side
Method is to burn and to bury.Burning can produce substantial amounts of harmful gas, pollutes environment；Bury the polymer short time the most therein
In can not be decomposed by the microorganisms, also pollute environment.The residual plastic foil abandoned is present in soil, hinder crops root system growth and
To moisture, the absorption of nutrient, make the gas permeability of soil reduce, cause crop production reduction；After action eats the residual plastic foil abandoned, meeting
Cause intestinal obstruction and dead；Marine organisms are caused by synthetic netting and fishline that be lost in ocean or discard in ocean
Suitable harm, therefore advocates green consumption imperative with reinforcement environmental conservation.In the face of day by day exhausted petroleum resources, symbol
In the swim biodegradation material is just becoming a research and development focus as high-tech product and environment-friendly products.
Along with people are to resource, the raising of environmental consciousness, it has been recognized that resources conservation, environmental conservation are that the mankind can carry out can
The mandatory principle of sustainable development, is the inevitable requirement of the Scientific Outlook on Development.Existing tableware on the market, furniture, kitchen tools etc. are raw
Product of applying flexibly all use the products such as wood, bamboo, common plastics, and this type of product cost is high, be unfavorable for degraded, not environmentally, the most commonly
Plastics not only can not be degraded, and is widely acknowledged as " white pollution ", destroys the water penetration of soil, and wood, Bamboo products to be cut down gloomy
Woods, has contaminated wastewater in manufacture process, be not good environment-friendly materials.At present with the filling-modified plastics of Plant fiber by generation
The attention of various countries of boundary, this technology meets the theory of resources conservation, environmental conservation.Lignocellulosic fiber source is abundant, cheap, its
Density is less than all inorfils, and modulus and hot strength are close with inorfil, during Plant fiber's potting resin materials processing
Less energy consumption, the loss to process equipment is little, the beneficially saving of the energy in the course of processing, and energy natural degradation, it is possible to reduce
Plastics use the pressure brought to environment in a large number, simultaneously for improving the production of people, life provides a kind of brand-new material.
Summary of the invention
It is an object of the invention to solve the problems of the prior art, it is provided that a kind of technique is simple, steady quality, low cost, energy
Edible fungi rod Plant fiber's synthetic resin of natural degradation and preparation technology thereof.
The technical solution adopted in the present invention is such that
A kind of edible fungi rod Plant fiber's synthetic resin, including the raw material of following weight portion: edible fungi rod powder 30～60 parts, Brazil
Palm wax 5～10 parts, polyvinyl alcohol 15～40 parts, butanediol 3～8 parts, green starch 15～40 parts, Sorbitol 3～
8 parts, Colophonium powder 3～8 parts, conch meal 5～10 parts, acid fiber by polylactic 10～20 parts；
Its preparation technology comprises the following steps:
(1), edible fungi rod is carried out super-refinement attrition process, obtain fine particle edible fungi rod powder；
(2), Sorbitol, butanediol are put into high speed mixer, be simultaneously introduced Brazil wax and stir, obtain the most mixed
Material；
(3), the edible fungi rod powder of step (1) is put into high speed mixer to mix, simultaneously with the first mixed material of step (2)
Add green starch to stir, be then cooled to room temperature, pulverize after one-tenth bulk to be solidified, obtain edible fungi rod fiber powder；
(4), polyvinyl alcohol and Colophonium powder are put into reaction vessel stir, at temperature is 100 DEG C～160 DEG C, reacts 60
Minute～120 minutes, be subsequently adding conch meal and edible fungi rod fiber powder continue to stir, at temperature is 80 DEG C～120 DEG C
React 60 minutes～120 minutes, pulverize after cooling, obtain mixing and add materials；
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, double
Blending extrusion in screw extruder, then injection mo(u)lding, obtain edible fungi rod Plant fiber's synthetic resin, packing and storing after cooling.
Preferably, in step (1), described edible fungi rod grinds to form the molecule edible fungi rod powder of 50～200 mesh；
Preferably, in step (2), described high speed mixer high-speed stirred 2～after 5 minutes, then stirring at low speed 5～8 points
To stirring fully, the temperature of high-speed stirred controls at 70 DEG C～90 DEG C clock, and the temperature of stirring at low speed controls at 20 DEG C～50 DEG C.
Preferably, the mix and blend temperature in described step (3) is 15 DEG C～40 DEG C.
By using preceding solution, the invention has the beneficial effects as follows:
The present invention is the waste for avoiding the resources such as wastes of crops, it is sufficiently utilized, to reach the purpose turned waste into wealth,
And reducing the pollution to environment, the product of the present invention has a resistance to freezing, high temperature resistant, high density, high intensity, smooth, nontoxic,
Service life, the characteristic such as length, and had superpower resistance to water, moreover it is possible to is degraded into organic fertilizer in large nature voluntarily, returns
Natural, it is the material of a kind of extremely environmental protection.Production low cost of the present invention, can be used for packing, tableware, bottle for cosmetics and medicine
The fields such as product bottle, disposable medical article, pesticide and slow-release fertilizer carrier matrix, biological medical polymer material, also have other
Relating to the various plastics of environmental conservation, such as building greening net, film etc., application is widely.The present invention opens newly
Raw material sources, rural resource advantage can be played, add farmers' income, alleviate the contradiction of shortage of resources, for waste agronomic crop
Appropriate application provide effective method and approach.
Detailed description of the invention
Being specifically described the present invention with embodiment below, the scope of the present invention should not be limited by the examples.
Embodiment 1:
A kind of edible fungi rod Plant fiber's synthetic resin, including the raw material of following weight portion: 30 parts of edible fungi rod powder, babassu
5 parts of wax, polyvinyl alcohol 15 parts, butanediol 3 parts, green starch 15 parts, Sorbitol 3 parts, Colophonium powder 3 parts, shell
5 parts of powder, acid fiber by polylactic 10 parts；
Its preparation technology comprises the following steps:
(1), edible fungi rod is carried out super-refinement attrition process, obtain fine particle edible fungi rod powder；
(2), Sorbitol, butanediol are put into high speed mixer, be simultaneously introduced Brazil wax and stir, obtain the most mixed
Material；
(3), the edible fungi rod powder of step (1) is put into high speed mixer to mix, simultaneously with the first mixed material of step (2)
Add green starch to stir, be then cooled to room temperature, pulverize after one-tenth bulk to be solidified, obtain edible fungi rod fiber powder；
(4), polyvinyl alcohol and Colophonium powder are put into reaction vessel stir, at temperature is 100 DEG C～160 DEG C, reacts 120
Minute, it is subsequently adding conch meal and edible fungi rod fiber powder continues to stir, at temperature is 80 DEG C～120 DEG C, reacts 60 points
Clock, pulverizes after cooling, obtains mixing and add materials；
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, double
Blending extrusion in screw extruder, then injection mo(u)lding, obtain edible fungi rod Plant fiber's synthetic resin, packing and storing after cooling.
In step (1), described edible fungi rod grinds to form the molecule edible fungi rod powder of 50～200 mesh；
In step (2), described high speed mixer high-speed stirred is after 2 minutes, then stirring at low speed extremely stirring in 8 minutes is abundant,
The temperature of high-speed stirred controls at 70 DEG C～90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C～50 DEG C.
Mix and blend temperature in described step (3) is 15 DEG C～40 DEG C.
Embodiment 2:
A kind of edible fungi rod Plant fiber's synthetic resin, including the raw material of following weight portion: 60 parts of edible fungi rod powder, babassu
10 parts of wax, polyvinyl alcohol 40 parts, butanediol 8 parts, green starch 40 parts, Sorbitol 8 parts, Colophonium powder 8 parts, shell
10 parts of powder, acid fiber by polylactic 20 parts；
Its preparation technology comprises the following steps:
(1), edible fungi rod is carried out super-refinement attrition process, obtain fine particle edible fungi rod powder；
(2), Sorbitol, butanediol are put into high speed mixer, be simultaneously introduced Brazil wax and stir, obtain the most mixed
Material；
(3), the edible fungi rod powder of step (1) is put into high speed mixer to mix, simultaneously with the first mixed material of step (2)
Add green starch to stir, be then cooled to room temperature, pulverize after one-tenth bulk to be solidified, obtain edible fungi rod fiber powder；
(4), polyvinyl alcohol and Colophonium powder are put into reaction vessel stir, at temperature is 100 DEG C～160 DEG C, reacts 60
Minute, it is subsequently adding conch meal and edible fungi rod fiber powder continues to stir, at temperature is 80 DEG C～120 DEG C, reacts 120
Minute, pulverize after cooling, obtain mixing and add materials；
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, double
Blending extrusion in screw extruder, then injection mo(u)lding, obtain edible fungi rod Plant fiber's synthetic resin, packing and storing after cooling.
In step (1), described edible fungi rod grinds to form the molecule edible fungi rod powder of 50～200 mesh；
In step (2), described high speed mixer high-speed stirred is after 5 minutes, then stirring at low speed extremely stirring in 5 minutes is abundant,
The temperature of high-speed stirred controls at 70 DEG C～90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C～50 DEG C.
Mix and blend temperature in described step (3) is 15 DEG C～40 DEG C.
Above example is only in order to illustrate technical scheme, rather than limiting the scope of the invention, although with reference to relatively
The present invention has been made to explain by good embodiment, it will be understood by those within the art that, can be to the technology of the present invention
Scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Claims (4)
1. edible fungi rod Plant fiber's synthetic resin, it is characterised in that include the raw material of following weight portion: edible fungi rod powder
30～60 parts, Brazil wax 5～10 parts, polyvinyl alcohol 15～40 parts, butanediol 3～8 parts, green starch 15～40
Part, Sorbitol 3～8 parts, Colophonium powder 3～8 parts, conch meal 5～10 parts, acid fiber by polylactic 10～20 parts；
Its preparation technology comprises the following steps:
(1), edible fungi rod is carried out super-refinement attrition process, obtain fine particle edible fungi rod powder；
(2), Sorbitol, butanediol are put into high speed mixer, be simultaneously introduced Brazil wax and stir, obtain the most mixed
Material；
(3), the edible fungi rod powder of step (1) is put into high speed mixer to mix, simultaneously with the first mixed material of step (2)
Add green starch to stir, be then cooled to room temperature, pulverize after one-tenth bulk to be solidified, obtain edible fungi rod fiber powder；
(4), polyvinyl alcohol and Colophonium powder are put into reaction vessel stir, at temperature is 100 DEG C～160 DEG C, reacts 60
Minute～120 minutes, be subsequently adding conch meal and edible fungi rod fiber powder continue to stir, at temperature is 80 DEG C～120 DEG C
React 60 minutes～120 minutes, pulverize after cooling, obtain mixing and add materials；
(5) mixing that step (4) obtains is added materials and acid fiber by polylactic is put into after high speed mixer stirs, double
Blending extrusion in screw extruder, then injection mo(u)lding, obtain edible fungi rod Plant fiber's synthetic resin, packing and storing after cooling.
The preparation technology of a kind of edible fungi rod Plant fiber's synthetic resin the most according to claim 1, it is characterised in that:
In step (1), described edible fungi rod grinds to form the molecule edible fungi rod powder of 50～200 mesh.
The preparation technology of a kind of edible fungi rod Plant fiber's synthetic resin the most according to claim 1, it is characterised in that:
In step (2), described high speed mixer high-speed stirred 2～after 5 minutes, then stirring at low speed 5～8 minutes are to stirring fully,
The temperature of high-speed stirred controls at 70 DEG C～90 DEG C, and the temperature of stirring at low speed controls at 20 DEG C～50 DEG C.
The preparation technology of a kind of edible fungi rod Plant fiber's synthetic resin the most according to claim 1, it is characterised in that: institute
Stating the mix and blend temperature in step (3) is 15 DEG C～40 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610618763.1A CN106009752A (en) | 2016-07-29 | 2016-07-29 | Edible fungus stick plant fiber synthetic resin and preparation technique thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610618763.1A CN106009752A (en) | 2016-07-29 | 2016-07-29 | Edible fungus stick plant fiber synthetic resin and preparation technique thereof |
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| CN106009752A true CN106009752A (en) | 2016-10-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610618763.1A Pending CN106009752A (en) | 2016-07-29 | 2016-07-29 | Edible fungus stick plant fiber synthetic resin and preparation technique thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114196183A (en) * | 2022-02-08 | 2022-03-18 | 湖北飞歌科技股份有限公司 | Preparation method for preparing degradable plastic by modifying waste mushroom sticks |
| CN114573996A (en) * | 2022-03-01 | 2022-06-03 | 辽宁大学 | Aluminum bran plate and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6083586A (en) * | 1993-11-19 | 2000-07-04 | E. Khashoggi Industries, Llc | Sheets having a starch-based binding matrix |
| CN101914294A (en) * | 2010-08-26 | 2010-12-15 | 成都新柯力化工科技有限公司 | Paper-imitating biodegradable resin and preparation method |
| CN102634072A (en) * | 2012-04-20 | 2012-08-15 | 桂中宇 | Degradable thermoplastic rubber membrane using agricultural plant resources as main material and preparation method of degradable thermoplastic rubber membrane |
| CN104017340A (en) * | 2014-06-25 | 2014-09-03 | 广州甘蔗糖业研究所 | Bagasse/cassava starch polylactic acid biodegradable material, and preparation method and application thereof |
| CN104559279A (en) * | 2015-02-03 | 2015-04-29 | 张以河 | Novel wood-plastic composite material |
-
2016
- 2016-07-29 CN CN201610618763.1A patent/CN106009752A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6083586A (en) * | 1993-11-19 | 2000-07-04 | E. Khashoggi Industries, Llc | Sheets having a starch-based binding matrix |
| CN101914294A (en) * | 2010-08-26 | 2010-12-15 | 成都新柯力化工科技有限公司 | Paper-imitating biodegradable resin and preparation method |
| CN102634072A (en) * | 2012-04-20 | 2012-08-15 | 桂中宇 | Degradable thermoplastic rubber membrane using agricultural plant resources as main material and preparation method of degradable thermoplastic rubber membrane |
| CN104017340A (en) * | 2014-06-25 | 2014-09-03 | 广州甘蔗糖业研究所 | Bagasse/cassava starch polylactic acid biodegradable material, and preparation method and application thereof |
| CN104559279A (en) * | 2015-02-03 | 2015-04-29 | 张以河 | Novel wood-plastic composite material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114196183A (en) * | 2022-02-08 | 2022-03-18 | 湖北飞歌科技股份有限公司 | Preparation method for preparing degradable plastic by modifying waste mushroom sticks |
| CN114573996A (en) * | 2022-03-01 | 2022-06-03 | 辽宁大学 | Aluminum bran plate and preparation method thereof |
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