CN104559279A - Novel wood-plastic composite material - Google Patents
Novel wood-plastic composite material Download PDFInfo
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- CN104559279A CN104559279A CN201510054005.7A CN201510054005A CN104559279A CN 104559279 A CN104559279 A CN 104559279A CN 201510054005 A CN201510054005 A CN 201510054005A CN 104559279 A CN104559279 A CN 104559279A
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- 229920001587 Wood-plastic composite Polymers 0.000 title claims abstract description 58
- 239000011155 wood-plastic composite Substances 0.000 title claims abstract description 58
- 239000000463 material Substances 0.000 title claims abstract description 32
- 239000002910 solid waste Substances 0.000 claims abstract description 45
- 239000002023 wood Substances 0.000 claims abstract description 45
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 13
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims description 35
- 230000004048 modification Effects 0.000 claims description 25
- 238000012986 modification Methods 0.000 claims description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 22
- 229920003023 plastic Polymers 0.000 claims description 14
- 239000004033 plastic Substances 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000004698 Polyethylene Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 235000021355 Stearic acid Nutrition 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 10
- 239000012188 paraffin wax Substances 0.000 claims description 10
- 239000008117 stearic acid Substances 0.000 claims description 10
- 239000001993 wax Substances 0.000 claims description 10
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000003245 coal Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000010881 fly ash Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000011246 composite particle Substances 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 18
- 238000002156 mixing Methods 0.000 abstract description 2
- 235000013312 flour Nutrition 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 7
- 230000001737 promoting effect Effects 0.000 description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 206010011224 Cough Diseases 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000001093 anti-cancer Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000013332 literature search Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 208000024794 sputum Diseases 0.000 description 1
- 210000003802 sputum Anatomy 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Landscapes
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a novel wood-plastic composite material, which is prepared from modified wood flour, solid waste and thermoplastic by crushing, blending, granulating and extrusion molding. Discarded mushrooms rods and the solid waste can be comprehensively utilized, and are modified to be used as raw materials to prepare the wood-plastic composite material with low cost and excellent mechanical property. The wood-plastic composite material has the characteristics of low cost and high strength, and has excellent usability; and meanwhile, the production method is easy to operate, the process condition and production equipment requirements are relatively low, the large-scale promotion production can be realized, and the market efficiency is excellent.
Description
Technical field
The present invention relates to a kind of matrix material, be specifically related to a kind of Novel wood-plastic composite material.
Background technology
Mushroom is of a great variety, rich in nutritive value, has and improves immunity of organisms, the function such as relieving cough and reducing sputum, anticancer, dark liking by all parts of the world people.Along with the expansion of mushroom cultivation scale, the discarded mushroom rod of generation also gets more and more.Literature search not yet has the report utilized about discarded mushroom rod, the mode process that mushroom breeding enterprise is stacked mainly with landfill, and simple landfill is stacked and caused the great wasting of resources.Discarded mushroom rod is formed primarily of wood chip and residual mushroom root, can be used as by analysis preparing wood plastic composite.
Wood plastic composite adopts plastic processing Compound Machining or the material processed further or product by cellulose materials and thermoplastics, there is excellent mechanical property, and anti-aging, good stability of the dimension, not ftracture, there is again the processing characteristics of similar wood.More and more extensive in the application of the industries such as building, automobile, indoor and outdoor floor, finishing material and logistics packaging.At present, wood is moulded the wood powder adopted in industry and is derived from fast-growing wood, sawdust and agricultural crop straw, is mainly calcium carbonate, talcum powder in order to the performance improving wood plastic composite with the addition of inorganic mineral powder.Not yet have and utilize discarded mushroom rod as wood powder source, utilize solid waste to replace calcium carbonate, talcous report.Therefore by utilizing, discarded mushroom is excellent, solid waste joins in thermoplastics in the present invention, has prepared the wood plastic composite that price is more cheap.
Summary of the invention
The technical issues that need to address of the present invention are just the defect overcoming prior art, provide a kind of Novel wood-plastic composite material.The present invention can to the comprehensive utilization of discarded mushroom rod, solid waste, by discarded mushroom rod, solid waste modified as raw material, preparation cost is cheap, the wood plastic composite of good mechanical performance, has the characteristic that cost is low, intensity is high, has splendid use properties; Meanwhile, this production method easy handling, processing condition and production unit require lower, can realize promoting production on a large scale, have splendid market efficiency.
For solving the problem, the present invention adopts technical scheme to be:
A kind of Novel wood-plastic composite material, described wood plastic composite is with modified wood powder, solid waste, thermoplastics for raw material, and through pulverizing, the process such as blended, granulation and extrusion moulding obtains;
The preparation method of described wood plastic composite comprises the steps:
(1) be milled to 60 ~ 100 orders by after modified wood powder drying, solid waste drying and crushing to 200 order, then with titanate coupling agent, silane resin acceptor kh-550, modification carried out to modified wood powder and solid waste respectively;
(2) thermoplastics or resin 30 ~ 50 parts is taken, modified wood powder after modification 40 ~ 60 parts, solid waste after modification 10 ~ 30 parts, maleic anhydride graft PE 0.5 ~ 1 part, ethylene waxes 0.5 ~ 1 part, 0.5 ~ 1 part, paraffin, stearic acid 0.5 ~ 1 part, Zinic stearas 0.5 ~ 1 part, joins in mixer, mixes 10 ~ 30 minutes;
(3) by mixed raw material twin screw extruder extruding pelletization, wood plastics composite particle is obtained;
(4) compression molding or injection molding is adopted to prepare wood-plastic composite material products the wood plastics composite particle prepared.
Present method utilizes discarded mushroom rod to prepare wood plastic composite with solid waste; it is low that its advantage is to have abundant raw material source cost; be easy to implement easy; open up the utilization ways of discarded mushroom rod with solid waste; serve the effect of protection of the environment; can carry out the production of mass-producing, be a kind of product innovation with promotional value.
Preferably, modified wood powder is discarded mushroom rod.The cost of discarded mushroom rod is low, and working method is simply efficient, can realize promoting the use of on a large scale, and the material produced has splendid intensity, can meet the requirement of strength of material, have splendid result of use.
Preferably, solid waste is the mixture of one or more in iron tailings, flyash, coal gangue.Like this, effectively can reduce the cost of raw material, effectively can reduce the production cost of product like this, make product have the splendid market competitiveness.
Preferably, thermoplastics or resin are the mixture of one or more in polyethylene, polypropylene, polystyrene, polyvinyl chloride, reprocessed plastic(s).
Preferably, 70 ~ 90 orders are milled to after modified wood powder drying.
Preferably, being operating as of step (2): take thermoplastics or resin 35 ~ 45 parts, modified wood powder after modification 45 ~ 55 parts, the solid waste after modification 15 ~ 25 parts, maleic anhydride graft PE 0.65 ~ 0.85 part, ethylene waxes 0.55 ~ 0.90 part, 0.55 ~ 0.85 part, paraffin, stearic acid 0.6 ~ 0.9 part, Zinic stearas 0.65 ~ 0.8 part, join in mixer, mix 15 ~ 25 minutes.
Preferably, being operating as of step (2): take PE 25 parts, discarded mushroom rod modified wood powder 50 parts after modification, 25 parts, solid waste iron tailings powder after modification, maleic anhydride graft PE 0.85 part, ethylene waxes 0.55 part, 0.85 part, paraffin, stearic acid 0.9 part, Zinic stearas 0.65 part, join in mixer, mix 20 minutes.
Advantage of the present invention and beneficial effect are:
Novel wood-plastic composite material of the present invention, can to the comprehensive utilization of discarded mushroom rod, solid waste, by discarded mushroom rod, solid waste modified as raw material, preparation cost is cheap, the wood plastic composite of good mechanical performance, there is the characteristic that cost is low, intensity is high, there is splendid use properties;
Novel wood-plastic composite material of the present invention, the production method easy handling of this Wood-plastic material, processing condition and production unit require lower, can realize promoting production on a large scale, have splendid market efficiency;
Novel wood-plastic composite material of the present invention, discarded mushroom rod is utilized to prepare wood plastic composite with solid waste, it is low that its advantage is to have abundant raw material source cost, be easy to implement easy, open up the utilization ways of discarded mushroom rod with solid waste, serving the effect of protection of the environment, can carry out the production of mass-producing, is a kind of product innovation with promotional value;
Novel wood-plastic composite material of the present invention, it is 30 MPa that products obtained therefrom stretches intensity, and bending strength reaches 50 MPa, and I-zod resistance to impact shock reaches 16 KJ/m
2.
Embodiment
The following example will further illustrate the present invention.
embodiment
1
The present invention adopts technical scheme to be a kind of Novel wood-plastic composite material, and described wood plastic composite is with modified wood powder, solid waste, thermoplastics for raw material, and through pulverizing, the process such as blended, granulation and extrusion moulding obtains;
The preparation method of described wood plastic composite comprises the steps:
(1) be milled to 60 ~ 100 orders by after modified wood powder drying, solid waste drying and crushing to 200 order, then with titanate coupling agent, silane resin acceptor kh-550, modification carried out to modified wood powder and solid waste respectively;
(2) PE 25 parts is taken, the modified wood powder after modification 50 parts, 25 parts, solid waste iron tailings powder after modification, maleic anhydride graft PE 1 part, ethylene waxes 1 part, 1 part, paraffin, stearic acid 0.5 part, Zinic stearas 0.5 part, joins in mixer, mixes 20 minutes;
(3) by mixed raw material twin screw extruder extruding pelletization, wood plastics composite particle is obtained;
(4) compression molding or injection molding is adopted to prepare wood-plastic composite material products the wood plastics composite particle prepared.
Modified wood powder is discarded mushroom rod.Solid waste is iron tailings.
embodiment
2
On the basis of embodiment 1, the present embodiment is a kind of Novel wood-plastic composite material, and described wood plastic composite is with modified wood powder, solid waste, thermoplastics for raw material, and through pulverizing, the process such as blended, granulation and extrusion moulding obtains;
The preparation method of described wood plastic composite comprises the steps: that (2) take regeneration PE 30 parts, modified wood powder after modification 50 parts, solid waste after modification 20 parts, maleic anhydride graft PE 1 part, ethylene waxes 1 part, 1 part, paraffin, stearic acid 0.5 part, Zinic stearas 0.5 part, joins in mixer, mixes 25 minutes;
Solid waste is the mass mixing such as iron tailings, coal gangue thing.Other parts are identical with embodiment 1.
embodiment
3
On the basis of embodiment 1, the present embodiment is a kind of Novel wood-plastic composite material,
Preparation method's step of described wood plastic composite:
(2) regeneration PE 35 parts is taken, the modified wood powder after modification 50 parts, the solid waste after modification 15 parts, maleic anhydride graft PE 0.65 part, ethylene waxes 0.75 part, 0.85 part, paraffin, stearic acid 0.65 part, Zinic stearas 0.75 part, joins in mixer, mixes 20 minutes;
Solid waste is flyash.Other parts are identical with embodiment 1.
embodiment
4
On the basis of embodiment 1, the present embodiment is a kind of Novel wood-plastic composite material, preparation method's step of described wood plastic composite:
(2) polystyrene 45 parts is taken, the modified wood powder after modification 55 parts, the solid waste after modification 18 parts, maleic anhydride graft PE 0.5 part, ethylene waxes 0.75 part, 0.95 part, paraffin, stearic acid 0.65 part, Zinic stearas 0.65 part, joins in mixer, mixes 15 minutes; Solid waste is coal gangue.Other parts are identical with embodiment 1.
embodiment
5
On the basis of embodiment 1, the present embodiment is the preparation method of a kind of Novel wood-plastic composite material, described wood plastic composite, and wherein solid waste is the mixture of the quality such as iron tailings, flyash, coal gangue.Other parts are identical with embodiment 1.
comparative example
1
On the basis of embodiment 1, the preparation method of wood plastic composite, modified wood powder adopts fast-growing wood, and solid waste adopts calcium carbonate to replace, and other parts are identical with embodiment 1.
comparative example
2
On the basis of embodiment 1, the preparation method of wood plastic composite, modified wood powder adopts sawdust, and solid waste adopts talcum powder to replace, and other parts are identical with embodiment 1.
Comparative example 1 and comparative example 2 are the raw material that existing Wood-plastic material adopts, the product that comparative example obtains, and the fast-growing wood that it adopts and the wood powder cost of sawdust are 600 ~ 800 yuan/ton, and adopt the cost of the wood powder of discarded mushroom rod preparation about 100 yuan/ton; Simultaneously, adopt the cost of iron tailings, flyash, coal gangue also well below calcium carbonate and talcous price, therefore, wood plastic composite prepared by the present invention has low-down raw materials cost, product is keeping preferably while performance, there is lower production cost, there is very large economic benefit and ecological significance.Therefore, wood plastic composite prepared by comparative example 1 and comparative example 2, its cost is high, and adopts fast-growing wood can cause a large amount of exploitations of forest, causes great destruction to environment.
To sum up, Novel wood-plastic composite material of the present invention, can to the comprehensive utilization of discarded mushroom rod, solid waste, by discarded mushroom rod, solid waste modified as raw material, preparation cost is cheap, the wood plastic composite of good mechanical performance, there is the characteristic that cost is low, intensity is high, there is splendid use properties; In addition, the wood plastic composite of discarded mushroom rod preparation is utilized to distribute light mushroom fragrance.
The production method easy handling of this Wood-plastic material, processing condition and production unit require lower, can realize promoting production on a large scale, have splendid market efficiency; Discarded mushroom rod is utilized to prepare wood plastic composite with solid waste, it is low that its advantage is to have abundant raw material source cost, be easy to implement easy, open up the utilization ways of discarded mushroom rod with solid waste, serve the effect of protection of the environment, can carry out the production of mass-producing, be a kind of product innovation with promotional value;
Novel wood-plastic composite material of the present invention, it is 30 MPa that products obtained therefrom stretches intensity, and bending strength reaches 50 MPa, and I-zod resistance to impact shock reaches 16 KJ/m
2.There is splendid mechanical property, the requirement of strength of Wood plastic boards can be met, there is splendid result of use.
In traditional wood plastic composite, the modification reinforcement Wood-plastic materials such as multiplex calcium carbonate, talcum powder.The tailing waste things such as iron tailings, flyash, coal gangue are same after pulverizing has modification reinforcing effect to wood plastic composite.Iron tailings, flyash, coal gangues etc. self, with color, utilize mine tailing to replace calcium carbonate, talcum powder etc. to serve dyeing to wood plastic composite while generation strengthening action, not only can save production cost, also widen Tailings utilization channel.
Last it is noted that obviously, above-described embodiment is only for example of the present invention is clearly described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.And thus the apparent change of amplifying out or variation be still among protection scope of the present invention.
Claims (7)
1. a Novel wood-plastic composite material, is characterized in that, described wood plastic composite is with modified wood powder, solid waste, thermoplastics for raw material, and through pulverizing, the process such as blended, granulation and extrusion moulding obtains;
The preparation method of described wood plastic composite comprises the steps:
(1) be milled to 60 ~ 100 orders by after modified wood powder drying, solid waste drying and crushing to 200 order, then with titanate coupling agent, silane resin acceptor kh-550, modification carried out to modified wood powder and solid waste respectively;
(2) thermoplastics or resin 30 ~ 50 parts is taken, modified wood powder after modification 40 ~ 60 parts, solid waste after modification 10 ~ 30 parts, maleic anhydride graft PE 0.5 ~ 1 part, ethylene waxes 0.5 ~ 1 part, 0.5 ~ 1 part, paraffin, stearic acid 0.5 ~ 1 part, Zinic stearas 0.5 ~ 1 part, joins in mixer, mixes 10 ~ 30 minutes;
(3) by mixed raw material twin screw extruder extruding pelletization, wood plastics composite particle is obtained;
(4) compression molding or injection molding is adopted to prepare wood-plastic composite material products the wood plastics composite particle prepared.
2. wood plastic composite as claimed in claim 1, is characterized in that, modified wood powder is discarded mushroom rod.
3. wood plastic composite as claimed in claim 1, it is characterized in that, solid waste is the mixture of one or more in iron tailings, flyash, coal gangue.
4. wood plastic composite as claimed in claim 1, it is characterized in that, thermoplastics or resin are the mixture of one or more in polyethylene, polypropylene, polystyrene, polyvinyl chloride, reprocessed plastic(s).
5., as the wood plastic composite as described in arbitrary in claim 1-4, it is characterized in that, after modified wood powder drying, be milled to 70 ~ 90 orders.
6. as the wood plastic composite as described in arbitrary in claim 1-4, it is characterized in that, being operating as of step (2): take thermoplastics or resin 35 ~ 45 parts, the modified wood powder after modification 45 ~ 55 parts, solid waste after modification 15 ~ 25 parts, maleic anhydride graft PE 0.65 ~ 0.85 part, ethylene waxes 0.55 ~ 0.90 part, 0.55 ~ 0.85 part, paraffin, stearic acid 0.6 ~ 0.9 part, Zinic stearas 0.65 ~ 0.8 part, joins in mixer, mixes 15 ~ 25 minutes.
7. wood plastic composite as claimed in claim 6, it is characterized in that, being operating as of step (2): take PE 25 parts, the discarded mushroom rod modified wood powder 50 parts after modification, 25 parts, solid waste iron tailings powder after modification, maleic anhydride graft PE 0.85 part, ethylene waxes 0.55 part, 0.85 part, paraffin, stearic acid 0.9 part, Zinic stearas 0.65 part, joins in mixer, mixes 20 minutes.
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Cited By (12)
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CN105440724A (en) * | 2015-11-29 | 2016-03-30 | 福建梭罗复合材料研究有限公司 | Molding compound containing iron ore tailings |
CN105482221A (en) * | 2015-12-21 | 2016-04-13 | 浙江天达环保股份有限公司 | High-weatherability doped silica-aluminum plastic composite material and preparation method thereof |
CN105504853A (en) * | 2016-02-03 | 2016-04-20 | 中国地质大学(北京) | Novel wood-plastic composite material |
CN106009752A (en) * | 2016-07-29 | 2016-10-12 | 安徽科邦树脂科技有限公司 | Edible fungus stick plant fiber synthetic resin and preparation technique thereof |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105440724A (en) * | 2015-11-29 | 2016-03-30 | 福建梭罗复合材料研究有限公司 | Molding compound containing iron ore tailings |
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CN105482221A (en) * | 2015-12-21 | 2016-04-13 | 浙江天达环保股份有限公司 | High-weatherability doped silica-aluminum plastic composite material and preparation method thereof |
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